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Adsorption Kinetic and Isotherm Characteristics of Mn Ions with Zeolitic Materials Synthesized from Industrial Solid Waste (산업폐기물로부터 합성된 제올라이트 물질의 망간 이온 흡착속도 및 등온흡착 특성)

  • Choi, Jeong-Hak;Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.29 no.8
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    • pp.827-835
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    • 2020
  • Zeolite material having XRD peaks of Na-A zeolite in the 2θ range of 7.18 to 34.18 can be synthesized from the waste catalyst using a fusion/hydrothermal method. The adsorption rate of Mn ions by a commercial Na-A zeolite and the synthesized zeolitic material increased as the adsorption temperature increased in the range of 10 ~ 40℃. The adsorption of Mn ion were very rapid in the first 30 min and then reached to the equilibrium state after approximately 60 min. The adsorption kinetics of Mn ions by the commercial Na-A zeolite and the zeolitic material were found to be well fitted to the pseudo-2nd order kinetic model. Equilibrium data by the commercial Na-A zeolite and the zeolitic material fit the Langmuir, Koble-Corrigan, and Redlich-Peterson isotherm models well rather than Freundlich isotherm model. The removal capacity of the Mn ions by the commercial Na-A zeolite and the zeolitic material obtained from the Langmuir model was 135.2 mg/g and 128.9 mg/g at 30℃, respectively. The adsorption capacity of Mn ions by the synthesized zeolitic material was almost similar to that of commercial Na-A zeolite. The synthesized zeolitic material could be applied as an economically feasible commercial adsorbent.

Electro-controllable omni-directional laser emissions from a helical polymeric network composite film

  • Jang, Won-Gun;Park, Byoung-Choo;Kim, Min-A;Kim, Sun-Woong;Kim, Yun-Ki;Choi, Eun-Ha;Seo, Yoon-Ho;Cho, Guang-Sup;Kang, Seung-Oun;Takezoe, Hideo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.883-886
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    • 2008
  • In optical information technology, an electro-controllable Photonic Band Gap (PBG) in a photonic crystal (PC) material is potentially useful for the manipulation of light. Despite a great deal of research on PBGs, the reliable use of electro-active PBG material systems is restricted to only a few cases because of the complex and limiting nature of the structures involved. Here, we propose a PBG system that uses a liquid crystal (LC) polymer composite. The composite is made of nematic LCs (NLCs) embedded in polymeric helical networks of photo-polymerized cholesteric LCs (CLCs). The composite film shows a large field-induced reversible color shift over 150 nm of the reflection band, due to the reorientational undulation of the helical axis, similar to the Helfrich effect.

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A Study on the Preference of the Disabled and the Non-disabled for the Pedestrian Pavement (보행장애인과 비장애인의 보행도로 포장재료에 대한 선호도 비교)

  • Bae, So-Yeon;Bang, Jae-Sung;Yang, Byoung-E
    • KIEAE Journal
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    • v.8 no.2
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    • pp.65-70
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    • 2008
  • Recently, there has been growing interest in barrier-free design which makes safe and convenient space for every pedestrian, not only the non-disabled but also the disabled. The purpose of this study is to suggest the data on the pavement materials of barrier-free pedestrian environment in view of universal design. In order to this, the research is focused on evaluating the visual preference and preference factors for pavement scenery, which can be changed by pavement materials. And this research is also comparing the visual preference and preference factors of the disabled with that of the non-disabled. A multi-regression analysis method is adopted to analyse the correlation between the visual preference for pavement scenery and preference factors in this study. The result of this analysis is as follows. Firstly, there are some differences of visual preference for the pavement material between the disabled and the non-disabled. Secondly, independent variables influencing on preference are similar between two groups. Thirdly, there are some differences in the priority of preference between the disabled and the non-disabled. This study will contribute to the field of barrier-free design and sustainable development projects in order to maximize the human being's satisfaction.

Investigation of Shielding Effects of High Conductivity of High Permeability Materials on 60Hz ELF Magnetic Fields (60Hz ELF 자계에 대한 고 도전율 및 고 투자율 재료의 차폐효과 분석)

  • Song Ki-Hyun;Myung Sung-Ho;Min Suk-Won
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.166-171
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    • 2005
  • Shielding methods on ELF(Extremely Low Frequency) magnetic fields may include the use of induced currents, modification of magnetic field flux patterns using high permeability and/or high conductivity materials, and others. The magnetic shielding properties of enclosures can be utilized to reduce the magnetic field of current carrying conductors. In this paper, to get a more practical understanding of shielding phenomena, we have investigated the magnetic field reduction by means of 3 dimensional numerical analysis and experiments. We found copper could reduce flux density more then permalloy in both cases of box shield and cylindrical shield. Iron under l0$\mu$T of 1 phase could reduce flux density about $20\%$ more than silicon steel, but both of them under 50$\mu$T has a similar reduction rate of $10\%$. The 3 phase horizontal model gave the highest reduction rate and the 1mm thickness iron under 10$\mu$T of 3 phase lines did lowest.

Preparation of Carbon Nanofibers by Catalytic CVD and Their Purification

  • Lim, Jae-Seok;Lee, Seong-Young;Park, Sei-Min;Kim, Myung-Soo
    • Carbon letters
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    • v.6 no.1
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    • pp.31-40
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    • 2005
  • The carbon nanofibers (CNFs) were synthesized through the catalytic decomposition of hydrocarbons in a quartz tube reactor. The CNFs prepared from $C_3H_8$ at $550^{\circ}C$ was selected as the purification sample due to the higher content of impurity than that prepared from other conditions. In this study, we carried out the purification of CNFs by oxidation in air or carbon dioxide after acid treatment, and investigated the influence of purification parameters such as kind of acid, concentration, oxidation time, and oxidation temperature on the structure of CNFs. The metal catalysts could be easily eliminated from the prepared CNFs by liquid phase purification with various acids and it was verified by ICP analysis, in which, for example, Ni content decreased from 2.51% to 0.18% with 8% nitric acid. However, the particulate carbon and heterogeneous fibers were not removed from the prepared CNFs by thermal oxidation in air and carbon dioxide. This result can be explained by that the direction of graphene sheet in CNFs is vertical to the fiber axis and the CNFs are oxidized at about the similar rate with the impurity carbon.

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The correlation of the eletrochemical properties for $Li[Li_yMn_{2-y}]O_4$ cathode materials ($Li[Li_yMn_{2-y}]O_4$ 정극 활물질에 대한 전기화학적 특성의 상호관계)

  • Jeong, In-Seong;Kim, Min-Sung;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.269-272
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    • 2000
  • Spinel $LiMn_2O_4$ samples are prepared by heating a $LiOH{\cdot}H_2O/MnO_2$ mixture in air at $800^{\circ}C$ for 36h, and their structure and electrochemical performance are studied by using X-ray diffraction, Cyclic Voltammetry, AC Impedance, and Charge-discharge measurements. It was found that the electrochemical properties of the $LiMn_2O_4$ samples are very sensitive to substituted volume of lithium. Initial impedances of all cathode was similar. Initial resistance was $60{\sim}70{\Omega}$. Reaction peak of Cyclic voltammetry was weak by increase of substituted volume of lithium. $Li[Li_{0.08}Mn_{1.92}]O_4$ and $Li[Li_{0.1}Mn_{1.9}]O_4$ cathode materials showed the charge and discharge capacity of about 125mAh/g at first cycle, and about 95mAh/g after 70th cycle. It showed excellent property in sample revealed good structure and other electrochemical property.

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A Study of the Ferroelectric Properties of PbZr0.4Ti0.6O3 (PZT) Grains Using Kelvin Force Microscopy Analysis

  • Heo, Jin-Hee
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.6
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    • pp.275-278
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    • 2010
  • We have examined the Ferroelectric properties of $PbZr_{0.4}Ti_{0.6}O_3$ (PZT) grains by monitoring the surface potential through the utilization of Kelvin force microscopy. Hysteretic and time dependent behaviors of small and large grains were compared with each other. The smaller grain yields had smaller values of surface potential. However, the normalized voltage versus surface potential behavior indicates that the smaller grains became saturated earlier with respect to the writing voltages than did the larger grains. On the other hand, the surface potential hysteresis loop obtained from the smaller grains showed a similar shape to what might be obtained from a Zr rich PZT film. In contrast the hysteresis loop of the larger grain looks like that obtained from a Ti-rich film. In addition, the time dependent behaviors of the smaller grains also revealed a better response than the response of larger grains. The overall ferroelectric properties of the smaller grains seem better than corresponding properties for larger grains. The Ti/Zr ratio of the PZT film which was examined in this study was 60/40.

Effects of Ag on the Characteristics of Sn43Bi57Agx(wt%) Lead-free Solder for Photovoltaic Ribbon (태양광 리본용 Sn43Bi57Agx(wt%) 무연 솔더의 특성에 미치는 Ag의 영향)

  • Jeong, Joo-Hyeon;Cho, Tae-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.119-125
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    • 2017
  • We have studied the effects of Ag on the characteristics of $Sn_{43}Bi_{57}Ag_x$(wt%) lead-free solders for photovoltaic ribbon. Ag atoms in the solder formed an alloy phase of Ag3Sn after reacting with some part of Sn atoms, while they did not react with Bi atoms, but decreased the mean size of Bi solid phase and the thickness of solder. When Ag atoms of 3.0 wt% was added to eutectic $Sn_{43}Bi_{57}$(wt%) solder, it showed the optimally useful results that the peel strength of photovoltaic ribbon greatly increased and the sheet resistance of the solder decreased. In the meanwhile, the eutectic $Sn_{43}Bi_{57}$(wt%) solder showed a low melting temperature of $138.9^{\circ}C$, and showed a very similar result regardless of the added amount of Ag atoms.

Small Molecules that Potentiate Neuroectodermal Differentiation of Mouse Embryonic Stem Cells

  • Lee, Jonghwan;Rhee, Ki-Jong;Jung, Dongju
    • Biomedical Science Letters
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    • v.19 no.1
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    • pp.32-40
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    • 2013
  • Pluripotent stem cells (PSCs) have enormous potential in the biomedical sciences because they can grow continuously and differentiate into any kind of cell in the body. However, for future application in regenerative medicine, it is still a challenge to control the differentiation of PSCs without using genetic materials. To control the differentiation of PSCs, small molecules might be the best substitute for genetic materials considering the following advantages: small size, which enables penetration of plasma membrane; easy-to-modify structure; and low chance of genetic recombination in treated cells. Herein, we introduce small molecules that induce the neuroectodermal differentiation of mouse embryonic stem cells (ESCs). The small molecules were identified via ESC-based consecutive screenings of small-molecule libraries composed of 324 natural compounds or 93 selected drugs. The natural compounds discovered in the first screening were used to select 93 structurally similar drugs out of 1,200 approved drugs. In the second screening, among the 93 compounds, we found 4 drugs that induced the neuroectodermal differentiation of ESCs. These drugs were progesteroneor corticoid-derivatives. Our results suggest that small molecules targeting the progesterone receptor or glucocorticoid receptor could be used as chemical tools to induce the differentiation of PSCs into a specific germ lineage.

Fabrication of Carbon/Basalt Hybrid Composites and Evaluation of Mechanical Properties (탄소/현무암 섬유강화 하이브리드 복합재료의 성형과 기계적 특성 평가)

  • Lee, Jin-Woo;Kim, Yun-Hae;Jung, Min-Kyo;Yoon, Sung-Won;Park, Jun-Mu
    • Composites Research
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    • v.27 no.1
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    • pp.14-18
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    • 2014
  • Carbon Fiber Reinforced Plastic (CFRP) has strong and superb material properties, especially in mechanical and heat-resisting aspects, but the drawback is its high price. In this study, we made a hybrid composite using carbon fiber and basalt fiber, which is expected to attribute to its strong material properties and its financial benefits. We found out that the higher the content of basalt fiber included, the lower the intensity, and carbon's intensity contents of 80% showed the similar intensity level as that of CFRP. Besides it was possible to get a better mechanical properties using the composite that included the mixed fiber, instead of using a composition of separate fibers filed.