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Characteristics of Carbon Dioxide Destruction with a Plasma Torch and Effect of Additives (플라즈마 토치를 이용한 이산화탄소 분해특성과 첨가제의 영향)

  • Kim, Seong Cheon;Jeon, Jeong Hyeon;Chun, Young Nam
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.3
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    • pp.287-296
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    • 2013
  • To decompose carbon dioxide, which is a representative greenhouse gas, a plasma torch was designed and manufactured. To examine the characteristics of carbon dioxide decomposition via plasma discharge, a case wherein pure carbon dioxide was supplied and a case wherein methane and/or $TiCl_4$ were injected as additives were investigated and compared. The carbon dioxide and methane conversion rate, energy decomposition efficiency, produced gas concentration, carbon monoxide and hydrogen selectivity, carbon-black and $TiO_2$ were also investigated. The maximum carbon dioxide conversion rate was 28.9% when pure carbon dioxide was supplied; 44.6% when $TiCl_4$ was injected as am additive; and 100% percent when methane was injected as an additive. Therefore, this could be explained that the methane injection showed the highest carbon dioxide decomposition. Furthermore, the carbon-black and $TiO_2$ were compared with each commercial materials through XRD and SEM. It was found that the carbon-black that was produced in this study is similar for commercial materials. It was found that the $TiO_2$ that was produced in this study is suitable for photocatalyst and pigment because it has mixed anataze and rutile.

Synthesis of YAG:Ce3+ Phosphor Powders by Polymer Solution Route and Alumina Seed Application (폴리머용액법 및 알루미나 seed를 도입한 YAG:Ce3+ 형광체 분말 합성)

  • Kim, Yong-Hyeon;Lee, Sang-Jin
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.37-42
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    • 2013
  • $YAG:Ce^{3+}$ phosphor powders were synthesized using a $Al_2O_3$ seed (average particle size: 5 ${\mu}m$) by the polymer solution route. PVA solution was added to the sol precursors consisting of the seed powder and metal nitrate salts for homogeneous mixing in atomic scale. All dried precursor gels were calcined at $500^{\circ}C$ and then heated at $1400^{\circ}C{\sim}1500^{\circ}C$ in $N_2/H_2$ atmosphere. The final powders were characterized by using XRD, SEM, PSA, PL and PKG test. All synthesized powders were crystallized to YAG phase without intermediate phases of YAM or YAP. The phosphor properties and morphologies of the synthesized powders were strongly dependent on the PVA content. Finally, the synthesized $YAG:Ce^{3+}$ phosphor powder heated at $1500^{\circ}C$, which is prepared from 12:1 PVA content and has an average particle size of 15 ${\mu}m$, showed similar phosphor properties to a commercial phosphor powder.

Characterization of a Crystallized ZnO/CuSn/ZnO Multilayer Film Deposited with Low Temperature Magnetron Sputtering

  • Kim, Dae-Il
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.5
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    • pp.169-172
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    • 2009
  • The ZnO/CuSn/ZnO (ZCSZ) multilayer films were deposited on polycarbonate substrates using reactive RF and DC magnetron sputtering. The thickness of each layer was 50 nm/5 nm/45 nm, respectively. The ZCSZ films showed a sheet resistance of $44{\Omega}$/Sq, which was an order of magnitude lower than that indium tin oxide (ITO) films. Although the ZCSZ films had a CuSn interlayer that absorbed visible light, both films had similar optical transmittances of 74% in the visible wavelength region. The figure of merit of the ZCSZ films was $1.0{\times}10^{-3}{\Omega}^{-1}$ and was greater than the value of the ITO films, $1.6{\times}10^{-4}{\Omega}^{-1}$. From the X-ray diffraction (XRD) analysis, the ITO films did not show any diffraction peaks, whereas the ZCSZ films showed diffraction peaks for the ZnO (100) and (002) phases. The hardness of the ITO and ZCSZ films were 5.8 and 7.1 GPa, respectively, which were determined using nano-indentation. From these results, the ZCSZ films exhibited greater optoelectrical performance and hardness compared to the conventional ITO films.

Study of complete transparent nano-emulsions which contain oils

  • Kwak, Jong-Im;Kim, Ju-Duck;J, i-Hong-Geun
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.258-267
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    • 2003
  • Recently inside nano liposome particles or nano-emulsions which contain tough-melting physiology activity materials or the coefficient of low organism utilization promote the coefficient of organism utilization, so this part has been studied a lot because they can absorb selectly cosmetics, specially physiology activity materials, into the skin. Also, in particle size, cells interstitial lipid interval are 30~50nm, so nano-emulsions that the size is similar to 30~50 nm are made to study for absorbing quickly into the skin. And transparent skin which contains oils in common skin lotion dosage form has become the center of public interest. The used nano-emulsions in this study were unsaturated lecithin/co-surfactant! ethanol/ oil / water. And polysorbate 20/ polysorbate 80/ Dicetyl phosphate/hydrogenated .caster oil/ isoceteth-20/SLS were used in co-surfactant. The used oils were cyclomethicone and caprylic/capric triglyceride. The manufacturing process was that microfluidizer was fixed in 1000bar and transit times were changed from 1 to 10 times. From transparency and particle size, the transparency sequence was SLS> polysorbate 20= polysorbate 80> isoceteth-20> dicetyl phosphate >hydrogenated caster oil and the particle size was small. Specially cyclomethicone nano-emulsions, when we made unsaturated lecithin /SLS /ethanol/water/cyclomethicone, cyclomethicone 5% was good for transparency. And 20% of this was used for making transparent skin toner in common skin dosage form.

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Properties of $MgB_2$ Intragrain Nanobridges ($MgB_2$ 결정립 나노브릿지 특성에 관한 연구)

  • Hong, Sung-Hak;Lee, Soon-Gul;Seong, Won-Kyung;Kang, Won-Nam;Kim, Dong-Ho;Kim, Young-Kuk;Chung, Kook-Chae
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.74-78
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    • 2009
  • Inter-grain nanobridges of the $MgB_2$ superconductor have been fabricated by focused-ion-beam(FIB) and their electrical transport properties were studied. The $MgB_2$ film was prepatterned into microbridges by a standard argon ion milling technique and then FIB-patterned into 100 nm$\times$100 nm bridges. Current-voltage characteristics showed a strong flux-flow type behavior at all temperatures with a trait of Josephson coupling near $T_c$. At low temperatures, the curves showed a two-step resistance-doubled transition with occasional hysteresis. The resistance-doubling transition is believed to be due to a two-channel flux-flow effect. The temperature-dependent critical current data showed $I_c(T){\propto}(1-T/T_c)^2$ near $T_c$, same as a normal barrier junction, and $I_c(T){\propto}(1-T/T_c)^{1.2}$ at low temperatures, similar to that of a film.

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Characteristics of Physical and Adsorption of Korean Traditional Charcoal (우리나라 전통 숯의 물리.화학적 특성)

  • Kim, Joon-Tae;Kim, Sun-Hwa;Kim, Hae-Jin
    • Journal of environmental and Sanitary engineering
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    • v.21 no.4 s.62
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    • pp.77-86
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    • 2006
  • The water purification was very important in Korea which has not sufficient water resource and while adsorption method among the various methods to eliminate the water pollutants has been widely used by activated carbon. This study was conducted the basic experiment for hall distribution, pH, conductivity, electronic microscope, cation exchange and inorganic materials the adsorption capacity of Korean traditional charcoal which has similar characteristics to activated carbon of organic pollutants. As a result of observing Korean traditional charcoal with electronic microscope, it was found that it has porous structure, oak charcoal has circular structure, pine charcoal has square structure and bamboo charcoal has hexagonal structure, which has high void fraction per unit area because of its thin cell wall structure. As a result of experimenting hall distribution, hall distribution of bamboo high temperature charcoal is high as 0.269cc/g and has the greatest inorganic contents and cation exchange capacity(CEC) which are the important factor of chemical adsorption.

Properties of Ag Thin Films Deposited in Oxygen Atmosphere Using in- line Magnetron Sputter System (In-line 마그네트론 스퍼터 장치를 사용하여 산소 분위기에서 제작한 Ag 박막의 특성)

  • Ku, Dae-Young;Kim, Won-Mok;Cho, Sang-Moo;Hwang, Man-Soo;Lee, In-Kyu;Cheong, Byung-Ki;Lee, Taek-Sung;Lee, Kyeong-Seok;Cho, Sung-Hun
    • Korean Journal of Materials Research
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    • v.12 no.8
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    • pp.661-668
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    • 2002
  • A study was made to examine the electrical, compositional, structural and morphological properties of Ag thin films deposited by DC magnetron sputtering in $O_2$ atmosphere with deposition temperature from room temperature to 15$0^{\circ}C$ using in-line sputter system. The Ag films deposited at temperature above $100^{\circ}C$ in oxygen atmosphere gave a similar specific resistivity to and even lower oxygen content than those deposited using pure Ar sputter gas The Ag films deposited with pure Ar gas was mainly composed of crystallites with [111] preferred orientation, while, for those deposited in oxygen atmosphere, more than 50% of the volume was composed of crystallites with [100] orientation. The difference in the micro structure did not cause any difference in the specific resistivity of Ag films. The results showed that the transparent conducting oxide films and the Ag films could be processed sequentially in the same deposition chamber with careful control of deposition temperature, which might result in a cost reduction for constructing the large scale in-line deposition system.

The Effect of Oligomer Blending on the Flow Properties of Polycarbonate

  • Cho, Sung-Hwan;Kim, Sun-Mi;Cho, Mi-Suk;Lee, Young-Kwan;Kim, Dong-Min;Kim, Whan-Gi
    • Macromolecular Research
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    • v.17 no.12
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    • pp.1021-1024
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    • 2009
  • We successfully prepared high-flow polycarbonate (PC) by blending commercial PC with a low molecular weight PC oligomer. The oligomer was synthesized by the addition of a large quantity of mono functional phenol groups, and the chain end group was reacted with p-tertiary butyl phenol (PTBP) to block the reactivity. The viscosity average molecular weight ($M_v$) for the oligomer was about 4,000-5,000 g/mol, compared to ~19,000 g/mol for the PC blend obtained by blending 10 wt% of the prepared oligomer with the commercial grade PC ($M_v$ of 21,000 g/mol). The blended PC had a melt flow index of 45, which is 2.5 times higher, and a processing temperature that was $20^{\circ}C$ lower, than that of commercial grade PC having a similar $M_v$.

Effect of Heat Flux on the Melting Efficiency and Penetration Shape in TIG Welding (TIG 용접에서 열유속이 용융효율과 용입형상에 미치는 영향)

  • Oh, Dong-Soo;Cho, Sang-Myung
    • Journal of Welding and Joining
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    • v.27 no.2
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    • pp.44-50
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    • 2009
  • The characteristics of arc pressure, current density and heat flux distribution are important factors in understanding physical arc phenomena, which will have a marked effect on the penetration, size and shape of a weld in TIG welding. The purpose of this study is to find out the effect of the heat flux on the melting efficiency and penetration shape in TIG welding using the results of the previous investigators. The conclusions obtained permit to draw a proper method which derived the heat flux distributions by arc pressure distribution measurements, but previous researchers calculated heat flux and current distribution with the heat intensity measurements by the calorimetry. Heat flux of Ar gas arc was concentrated at the central part and distributed low from the arc axis to the radial direction, that of He mixing arc was lower than that of Ar gas, and it was wide distributed to radial direction. That showed a similar characteristic with the Nestor's by calorimetry calculated values. Throughout heat flux drawn in this study was discussed melting efficiency and penetration shape on Ar gas and He mixing gas arc.

A Study about the Conservation theory of Architectural Monuments -with a Focus on similar work done in Japan- (목조(木造) 건조물문화재(建造物文化財)의 보존이론(保存理論)에 관한 연구 -일본(日本) 건조물문화재(建造物文化財)의 수리사례(修理事例)를 중심(中心)으로-)

  • Kim, Wang-Jik;Lee, Sang-Hae
    • Journal of architectural history
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    • v.11 no.3 s.31
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    • pp.35-51
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    • 2002
  • This study is about the preservation of wooden buildings as cultural properties. I got the idea for preservation and repair of cultural properties of wooden buildings by watching the process of repairing them in Japan. The Japanese have been endeavored to restoring old wooden buildings to their original forms for more than a hundred years. The idea to change decayed materials into new materials or the new approach to the process of restoration used to be in conflict with the concept of 'Authenticity'--the criteria for evaluation of the value of cultural properties, based on the Western of thinking, established by UNESCO. Since 'Nara Conference on Authenticity', held in 1994 in Nara, however, the concept of 'Authenticity' has changed, and the peculiarity of certain cultural properties of the wooden buildings and their diversity of culture have now begun to be recognized by UNESCO. This is a crucial change for the study of preservation, repair and restoration of cultural properties of wooden buildings. The purpose of this study is, therefore, to look closely at the process of change of the concept 'Authenticity' and find a better method for preservation of cultural properties of wooden buildings.

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