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Characteristics of SOFC Anode of Ni/YSZ Core-shell Manufactured Using sSpherical Ni and Nano YSZ Powders (구형 Ni과 나노 YSZ Powder를 이용하여 제조한 Ni/YSZ Core-shell의 SOFC 연료극 특성)

  • Choi, Byung-Hyun;Koo, Ja-Bin;Seol, Kwang-Hee;Ji, Mi-Jung
    • Journal of Hydrogen and New Energy
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    • v.28 no.1
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    • pp.40-46
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    • 2017
  • We reviewed the electrical properties of SOFC anode manufactured using spherical Ni and nano YSZ powder. When core-shell is fabricated by using submicron Ni as core and nano-sized YSZ as shell for SOFC anode, the electrical conductivity of the $0.2{\mu}m$ Ni-YSZ core-shell was 3 times higher than that of $1.0{\mu}m$ NiO or $1.0{\mu}m$ Ni-YSZ. Hydrogen selectivity was similar at $800^{\circ}C$, but hydrogen selectivity and methane conversion rate under $750^{\circ}C$ was 10~25% higher, Power density was more than 2 times, ASR was about 1/3, when exposed to $H_2$ atmosphere at $750^{\circ}C$ for a long time, Ni particles did not have any growth or cut off conduction path.

Effects of Electrode Material on Electrochemical Conversion of Carbon Dioxide Using Molten Carbonate Electrolyte (용융탄산염 전해질에서 이산화탄소의 전기화학적 전환에 전극 재질이 미치는 영향)

  • Ju, Hong Su;Eom, Seong Yong;Kang, Ki Joong;Choi, Gyung Min;Kim, Duck Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.11
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    • pp.727-734
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    • 2017
  • The electrochemical conversion of $CO_2$ is one of the methods for reducing $CO_2$. Four materials (Ag, Ni, Pt, and Ir) were selected as the electrodes. The electrochemical conversion was performed under a cell voltage of 4.0 V at $600^{\circ}C$. The amounts of $CO_2$ reduction and carbon production were at the highest for Ag, followed by, Pt, Ni, and then Ir. The produced carbon samples were analyzed by thermogravimetric analysis and XRD. The thermogravimetric analysis results indicated that all the carbon produced at each electrode exhibited similar thermal reactivity. The XRD results showed that the crystallization of carbon was different depending on the electrode utilized. Although electrochemical conversion was the highest for the Ag electrode, a loss of material accompanied it. Therefore, for this study, the optimal electrode is Pt, taking into account reactivity and material losses.

Variation of Cone Crack Shape in Ceramic Materials According to Spherical Impact Velocity (입자충격속도에 따른 세라믹재료의 콘크랙 형상 변화)

  • O, Sang-Yeop;Sin, Hyeong-Seop;Seo, Chang-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.2
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    • pp.380-386
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    • 2002
  • Damage behaviors induced in silicon carbide by an impact of particle having different material and size were investigated. Especially, the influence of the impact velocity of particle on the cone crack shape developed was mainly discussed. The damage induced by spherical impact was different depending on the material and size of particles. Ring cracks on the surface of specimen were multiplied by increasing the impact velocity of particle. The steel particle impact produced larger ring cracks than that of SiC particle. In the case of high velocity impact of SiC particle, radial cracks were produced due to the inelastic deformation at the impact site. In the case of the larger particle impact, the damage morphology developed was similar to the case of smaller particle one, but a percussion cone was farmed from the back surface of specimen when the impact velocity exceeded a critical value. The zenithal angle of cone cracks developed into SiC material decreased monotonically with increasing of the particle impact velocity. The size and material of particle influenced more or less on the extent of cone crack shape. An empirical equation, $\theta$= $\theta$$\sub$st/, v$\sub$p/(90-$\theta$$\sub$st/)/500 R$\^$0.3/($\rho$$_1$/$\rho$$_2$)$\^$$\frac{1}{2}$/, was obtained as a function of impact velocity of the particle, based on the quasi-static zenithal angle of cone crack. It is expected that the empirical equation will be helpful to the computational simulation of residual strength in ceramic components damaged by the particle impact.

A Study on the Application Characteristic of Objet Concept to Materials in Housing Space - Focused on the Housing Space of $99m^2{\sim}162m^2$ in Daegu - (주거공간 마감재에 대한 오브제개념의 적용특성 연구 - 대구지역 $99m^2$(30평형)~$162m^2$(40평형)의 아파트 주거공간을 중심으로 -)

  • Seo, Ji-Eun
    • Korean Institute of Interior Design Journal
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    • v.19 no.4
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    • pp.58-65
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    • 2010
  • The purpose of this study is to be applied with the basic data for the design method in the housing space which is differential. So, we analyzed the expression method and the application characteristic to materials of units in housing complex. To that, we researched on the condition of finishing material about the kind of material, color, texture and pattern for components in living room space. The results of this study are as follows : First, at the present time, the Object concept is expressed by 'mixing' and 'juxtaposition' of material, texture and pattern of finishing materials in housing space. But, we could find that the Object concept was used restrictively in housing space. So, we have to find different expression methods to be the effective and differential design by being applied Object concept for the housing space. Second, the 'mixing' which is the method to express the Object concept is showed in only 'art wall'. so, we can estimate that the method is the limited method to plan the varied housing. It is needed various expression methods to design components for the housing space. Third, it showed that the 'mixing' was a passive expression method using a little differential for design of housing space. We could estimate that similar methods were applied to the housing design. By results of this study, we can think that the develop study is needed to find design methods for expression of the Object in housing space.

Charge-discharge capacity and AC impedance of $LiMn_{2-y}M_{y}O_{4}$(M=Mg, Zn) cathode ($LiMn_{2-y}M_{y}O_{4}$(M=Mg, Zn) 정극의 충방전 용량 및 AC 임피던스 특성)

  • 정인성;위성동;이승우;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.455-458
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    • 2001
  • Spinel $LiMn_{2-y}$$M_{y}$ $O_4$powder was prepared solid-state method by calcining the mixture of LiOH - $H_2O$, Mn $O_2$, ZnO and MgO at 80$0^{\circ}C$ for 36h. To investigate the effect of substitution with Mg, Zn cation, charge-discharge experiments and initial impedance spectroscopy performed. The structure of $LiMn_{2-y}$$M_{y}$ $O_4$crystallites was analyzed from powder X-ray diffraction data as a cubic spinel, space group Fd3m. all cathode material showed spinel phase based on cubic phase in X-ray diffraction. Ununiform which calculated by (111) face and (222) face was constant in spite of the change of y value, except PUf\ulcorner LiM $n_2$ $O_4$. The discharge capacities of the cathode for the cation subbstitUtes $LiMn_{2-y}$$M_{y}$ $O_4$/Li cell at the 1st cycle and at the 40th cycle were about 120~124 and 108~112mAh/g except LiM $n_{1.9}$Z $n_{0.1}$ $O_4$/Li cell, respectively. This cell capacity is retained by 93% after 40th cycle. AC impedance of $LiMn_{2-y}$$M_{y}$ $O_4$/Li cells revealed the similar resistance of about 65~110$\Omega$ before cycling. before cycling.g.g.

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A Study on the Applicability of 3D Ceramic Printing Technology for Restoration of the Missing Part of Damaged Ceramics (훼손 도자기 결실부 복원을 위한 3D 세라믹 프린팅 기술의 기초 적용성 연구)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of the Korea Convergence Society
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    • v.11 no.11
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    • pp.165-173
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    • 2020
  • ABS and PLA are applied for restoring missing part of damaged ceramics, but are not similar to the material of ceramics, so this study conducted a research on the properties and applicability of ceramic resin. This study conducted actual restoration of ABS and ceramic resin as well as cast restoration method with experiment of properties. Results show that manufacturing of restored part showed higher precision than existing materials, which enables printing of tiny shapes showing excellent surface texture and gloss than L30 and ABS resin. As a result of measuring properties, the material showed excellent durability than existing materials with no contraction and deformation and compressive strength, but value of specific gravity and hardness can lower processability after manufacturing. Long-term monitoring, evaluation of reliability of ceramic resin applied in this study, additional researches on the restorability of the original shape when printing too thin or long restored part are needed.

Applications of the Copper Slags as Ground Improvement Material (지반개량재로써 동제련슬래그의 활용에 관한 연구)

  • Chun, Byung-Sik;Jung, Hun-Chul;Cho, Han-Young
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.1
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    • pp.27-36
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    • 2002
  • This study is about the applicability of copper slag as the ground improvement material. By the geo-technical characteristics of the copper slag and by the effect of consolidation and under drainage condition, it is proved that the copper slag can be used for ground improvement material as substitution for sand. As a result of laboratory tests, it was shown that the permeability of the copper slag was similar to that of sands under the vertical drainage condition. In addition, the copper slag showed higher critical hydraulic gradient than that of sand under up-ward vertical flow state. The copper slag has potential safety against piping and it has internal stability of particles. The conclusion is that the copper slag is suitable for drainage and filter material.

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Probabilistic Strength Assessment of Ice Specimen considering Spatial Variation of Material Properties (물성치의 공간분포를 고려한 빙 시험편의 확률론적 강도평가)

  • Kim, Hojoon;Kim, Yooil
    • Journal of the Society of Naval Architects of Korea
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    • v.57 no.2
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    • pp.80-87
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    • 2020
  • As the Arctic sea ice decreases due to various reasons such as global warming, the demand for ships and offshore structures operating in the Arctic region is steadily increasing. In the case of sea ice, the anisotropy is caused by the uncertainty inside the material. For most of the research, nevertheless, estimating the ice load has been treated deterministically. With regard to this, in this paper, a four-point bending strength analysis of an ice specimen was attempted using a stochastic finite element method. First, spatial distribution of the material properties used in the yield criterion was assumed to be a multivariate Gaussian random field. After that, a direct method, which is a sort of stochastic finite element method, and a sensitivity method using the sensitivity of response for random variables were proposed for calculating the probabilistic distribution of ice specimen strength. A parametric study was conducted with different mean vectors and correlation lengths for each material property used in the above procedure. The calculation time was about ten seconds for the direct method and about three minutes for the sensitivity methods. As the cohesion and correlation length increased, the mean value of the critical load and the standard deviation increased. On the contrary, they decreased as the friction angle increased. Also, in all cases, the direct and sensitivity methods yielded very similar results.

Effect of Bed Soil with Polypropylene Spunbonded Fabrics on Rice Seedling Production

  • Lee, Sang-Chul;Lee, Ji-Ean;Shon, Tae-Kwon;Jeong, Ki-Po;Daniel Acquah;Kim, Sang-Kuk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.2
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    • pp.89-95
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    • 2003
  • The study of this experiment is focused on labor saving of healthy rice seedling production using PSF (polypropylene spunbonded fabrics) as thermal protection material. Several factors such as different compositions of nursery soil and PSF materials were tested to produce healthy rice seedlings. The inner thermal protection material in PE film (polyethylene film) showed $0.9-1.7^{\circ}C$ higher than that of PSF 40-100 $\textrm{gm}^{-2}$. The light transmittance-ratio also showed similar trends. It is considered that the appropriate PSF material density was 40 gm$\textrm{gm}^{-2}$ in accordance with economic values and healthy rice seedlings. Plant height and dry weight according to various nursery soil showed the rang-es of 8.5-14.2cm and 5.5-10.0mg, respectively. In composition of nursery soil, artificial soil combined with paddy soil was effective in producing healthy seedling for rice seedling production. The total sugar content also showed the difference between PSF 40, 60 $\textrm{gm}^{-2}$ PE film (0.43-0.52mg FW $\textrm{g}^{-1}$) and PSF 80, 100 $\textrm{gm}^{-2}$ (0.28-0.35mg FW $\textrm{g}^{-1}$) and it showed the same tendency among varieties as well as various nursery soil. These results demonstrate that PSF 40 $\textrm{gm}^{-2}$ economically affordable, and can be recommended as thermal protection material for producing good healthy rice seedling.

Safety Assessment of Embankment by Analysis of Electrical Properties (전기비저항 물성 분석을 통한 제체의 안정성 검토)

  • Oh, Seok-Hoon;Suh, Baik-Soo
    • The Journal of Engineering Geology
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    • v.18 no.3
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    • pp.245-255
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    • 2008
  • The variation of the electrical property of embankment material was analyzed from laboratory experiments and the result of field survey, in order to enhance the interpretation of electrical resistivity survey frequently used for safety assessment of embankment. At first, the kaolinite, showing similar physical property with core material of embankment, was used to examine the variation of the resistivity value according to degree of consolidation. The test showed that a drop of shear strength induces increase of resistivity value regardless of degree of water content. This result means that porous zones of weak core material in embankment may be appeared as highly resistive part in the electrical resistivity survey. This observation implies that it may fail to detect weak core material by electrical method, if we only try to and zones showing low resistivity value. And, we performed Standard Penetration Test (SPT) to analyze the correlation between electrical property and ground stiffness. Finally, a mechanism to describe the variation of electrical resistivity due to grouting effect was proposed and real field data were analyzed.