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Ru employed as Counter Electrode for TCO-less Dye Sensitized Solar Cells (투명전도층이 없는 염료감응형 태양전지의 Ru 상대전극 연구)

  • Noh, Yunyoung;Yoo, Kicheon;Yu, Byungkwan;Han, Jeungjo;Ko, Minjae;Song, Ohsung
    • Korean Journal of Metals and Materials
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    • v.50 no.2
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    • pp.159-163
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    • 2012
  • A TCO-less ruthenium (Ru) catalytic layer on glass substrate instead of conventional Ru/TCO/ glass substrate was assessed as counter electrode (CE) material in dye sensitized solar cells (DSSCs) by examining the effect of the Ru thickness on the DSSC performance. Ru films with different thicknesses (34, 46, 69, and 90 nm) were deposited by atomic layer deposition (ALD) on glass substrates to replace both existing catalyst and electrode layer. In order to make our comparison, we also prepared an Ru catalytic layer by a similar method on FTO/glass substrate. Finally, we prepared the $0.45cm^2$ DSSC device the properties of the DSSCs were examined by cyclic voltammetry (CV), impedance spectroscopy (EIS), and current-voltage (I-V) method. CV measurements revealed an increase in catalytic activity with increasing film thickness. The charge transfer resistance at the interface between the electrolyte and Rudecreased with increasing Ru thickness. I-V results showed that the energy conversion efficiency increased up to 1.96%. Our results imply that TCO-less Ru/glass might perform as both catalyst and electrode layer when it is used in counter electrodes in DSSCs.

An analysis of the income impact of Self-Sufficiency training Program - by using Propensity Score Matching - (자활직업훈련 사업의 임금 효과 분석 - Propensity Score Matching 방법으로 -)

  • Yeon, Ahn-seo
    • Korean Journal of Social Welfare Studies
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    • no.37
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    • pp.171-197
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    • 2008
  • This study focuses on the following question; self-supporting training program increases participants' income compare to non-participants who have similar characteristics. This question is based on counterfactual assumption. In other words, this study concentrates on what the outcomes would have been if the participants were to be absent. This study adopts a quasi-experimental design. To overcome previous study's methodological weaknesses, especially selection bias, I applied matching procedure based on a propensity-score matching. Matching process was performed by using 'MatchIt' software. The major findings are as follows From Least Squares Regression analysis, I found the poor's income are significantly different according to age, pre-intervention earning, material status, and participation of training. Since the poor have homogeneous education level, education variable was not statistically significant. From the Simulation Quantities of Interest analysis, I also found that treatment group's expected incomes are lower than control's expected incomes. In other words, participation of training has a negative effect on the participants' earnings.

Statistical bias indicators for the long-term displacement of steel-concrete composite beams

  • Moreno, Julian A.;Tamayo, Jorge L.P.;Morsch, Inacio B.;Miranda, Marcela P.;Reginato, Lucas H.
    • Computers and Concrete
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    • v.24 no.4
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    • pp.379-397
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    • 2019
  • Steel-concrete composite beams are widely employed in constructions and their performance at the serviceability stage is of concern among practitioners and design regulations. In this context, an accurate evaluation of long-term deflections via various rheological concrete models is needed. In this work, the performance and predict capability of some concrete creep and shrinkage models ACI, CEB, B3, FIB and GL2000 are ascertained, and compared by using statistical bias indicators. Ten steel-concrete composite beams with existing experimental and numerical results are then modeled for this purpose. The proposed modeling technique uses the finite element method, where the concrete slab and steel beam are modeled with shell finite elements. Concrete is considered as an aging viscoelastic material and cracking is treated with the common smeared approach. The results show that when the experimental ultimate shrinkage strain is used for calibration, all studied rheological models predict nearly similar deflections, which agree with the experimental data. In contrast, significance differences are encountered for some models, when none calibration is made prior to. A value between twenty and thirty times the cracking strain is recommended for the ultimate tensile strain in the tension stiffening model. Also, increasing the relative humidity and decreasing the ambient temperature can lead to a substantial reduction of slab cracking for beams under negative flexure. Finally, there is not a unique rheological model that clearly excels in all scenarios.

Effects of Type of Synthetic Fiber on Material Properties of Cementless Composite (합성섬유 종류가 무시멘트 복합재료의 재료 거동에 미치는 영향)

  • Choi, Jeong-Il;Park, Se-Eon;Cha, Sang Lyul;Lee, Bang Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.255-261
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    • 2019
  • The purpose of this study is to investigate effects of types of synthetic fibers on mechanical properties of alkali-activated slag composite. Materials and mixture proportion for matrix are determined, and the compressive strength, tensile performance, and cracking patterns of three composites reinforced by polypropylene, polyvinyl-alcohol, and polyethylene fibers. From the test results, it was observed that polyvinyl-alcohol fiber-reinforced composite and polyethylene fiber-reinforced composite had similar tensile performance. On the other hand, polypropylene fiber-reinforced composite showed low tensile performance. And it was exhibited that other factors except tensile strength and aspect ratio of fiber influence significantly tensile behavior of composite.

Merging the cryptic genera Radicilingua and Calonitophyllum (Delesseriaceae, Rhodophyta): molecular phylogeny and taxonomic revision

  • Wolf, Marion A.;Sciuto, Katia;Maggs, Christine A.;Petrocelli, Antonella;Cecere, Ester;Buosi, Alessandro;Sfriso, Adriano
    • ALGAE
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    • v.36 no.3
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    • pp.165-174
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    • 2021
  • Radicilingua Papenfuss and Calonitophyllum Aregood are two small genera of the family Delesseriaceae that consist of only three and one taxonomically accepted species, respectively. The type species of these genera, Radicilingua thysanorhizans from England and Calonitophyllum medium from the Americas, are morphologically very similar, with the only recognized differences being vein size and procarp development. To date, only other two species were recognized inside the genus Radicilingua: R. adriatica and R. reptans. In this study, we analysed specimens of Radicilingua collected in the Adriatic and Ionian Sea (Mediterranean), including a syntype locality of R. adriatica (Trieste, northern Adriatic Sea), alongside material from near the type locality of R. thysanorhizans (Torpoint, Cornwall, UK). The sequences of the rbcL-5P gene fragment here produced represent the first molecular data available for the genus Radicilingua. Phylogenetic reconstruction showed that the specimens from the Adriatic and Ionian Seas were genetically distinct from the Atlantic R. thysanorhizans, even if morphologically overlapping with this species. A detailed morphological description of the Mediterranean specimens, together with an accurate literature search, suggested that they were distinct also from R. adriatica and R. reptans. For these reasons, a new species was here described to encompass the Mediterranean specimens investigated in this study: R. mediterranea Wolf, Sciuto & Sfriso. Moreover, in the rbcL-5P tree, sequences of the genera Radicilingua and Calonitophyllum grouped in a well-supported clade, distinct from the other genera of the subfamily Nitophylloideae, leading us to propose that Calonitophyllum medium should be transferred to Radicilingua.

Evaluation of the Radon Contribution Rate in Apartments through Evaluation of the Radon Exhalation Rate from Building Materials (건축자재 라돈 방출률 평가를 통한 공동주택 내 라돈 기여율 평가)

  • Hong, Hyungjin;Choi, Jiwon;Yoon, Sungwon;Kim, Heechun;Lee, Cheolmin
    • Journal of Environmental Health Sciences
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    • v.47 no.5
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    • pp.425-431
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    • 2021
  • Background: This study evaluated the radon contribution rate through an evaluation of the exhalation rate of radon from building materials. Objectives: This study compared and evaluated the computation of the radon contribution rate based on each different exhalation rate in a building. Methods: The six demonstration houses that are the subject of this study are wall structures or Rahmen structures, and include demonstration houses similar to general residential environments and non-finishing houses with some walls exposed. Results: The highest exhalation rate was found at 62.98 Bq/m2 per day from the non-finishing floor, and the second highest exhalation rate was from stone materials at 58.76 Bq/m2 per day. Based on this result, investigating the contribution rate of building materials derived from building materials among indoor radon concentrations, house three was the highest at 81.7%, and house one was confirmed to be 33.96%. Conclusions: It can be judged that the effect of exposed concrete and stone is high, and that it is possible to reduce radon emitted from indoor building structures by controlling the indoor materials.

Color evaluation by thickness of interim restorative resin produced by digital light processing 3D printer (디지털 광학기술인 3D 프린터로 제작된 임시수복용 레진의 두께별 색 평가)

  • Kang, Wol;Kim, Won-Gi
    • Journal of Technologic Dentistry
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    • v.43 no.3
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    • pp.77-83
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    • 2021
  • Purpose: The purpose of this in vitro study was to measure and compare the thickness-dependent color dimensions of digital light processing (DLP) three-dimensional (3D) printer and conventional interim restorative resin. Methods: Specimens (N=60) were fabricated using either subtractive manufacturing (S group) or DLP 3D printing (D group) material. All milled and 3D-printed specimens were allocated into three different groups (n=10) according to different thicknesses as follows: 1.0, 1.5, and 2.0 mm. Color measurements in the CIELab coordinates were made using a spectrophotometer under room light conditions (1,003 lux). The color differences (𝚫E*) between the specimen and control target data were calculated. Data were analyzed using the oneway analysis of variance (ANOVA). Post hoc comparisons were conducted using Tukey's honestly significant difference method (α=0.05 for all tests). Results: The 𝚫L*, 𝚫a*, 𝚫b*, and 𝚫E* values of interim restorative resin produced by DLP 3D printing were obtained in terms of the specimen's thickness increased compared with the increases by subtractive manufacturing. When the thickness was similar, the color difference between subtractive manufacturing and DLP 3D printing was ≥5.5, which is a value required by the dentist for remanufacturing. Conclusion: Color was influenced by the thickness of the interim restorative resin produced by DLP 3D printing.

Static and Fatigue Flexural Tests of Ductile High-performance Fiber Reinforced Cementitious Composites (고인성 섬유보강 콘크리트의 정적 및 피로 휨시험)

  • Shin, Kyung-Joon;Lee, Do-Keun;Lee, Kyoung-Chan;Kim, Sung-Il
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.602-608
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    • 2021
  • Recently, research and development has been conducted to impart high performance and functionality to concrete materials by mixing various reinforcing materials into the matrix. Ductile fiber reinforced concrete using a large amount of fibers shows a distributed multiple cracking behavior, and various studies are being conducted on this material. However, research is focused on static behavioral analysis but studies on cyclic behaviors are not sufficient. In this study, beams were made of ductile fiber reinforced concrete with various fiber contents, and static and fatigue flexural tests were performed. As a result, the effect of fiber content on the flexural behavior was analyzed. Also, the applied load level and fatigue life relationship of ductile fiber reinforced concrete was proposed. Concrete with high ductile property could be achieved with a fiber content of 2%. When 0.5% fiber was more added, the maximum flexural strength was similar, but the flexural toughness is nearly doubled. On the other hand, there was no significant difference in the fatigue life of these two mixtures.

The Effects of Reducing Skin Wrinkles and Improving Skin Elasticity from Korean Radish Extract

  • Kim, Hyun-Kyoung
    • International journal of advanced smart convergence
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    • v.8 no.1
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    • pp.113-125
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    • 2019
  • The radish skin and radish greens are an edible part of the radish. But they are removed before eating the radish and used as a byproduct or an animal feed material because of their tough and rough texture. This study was conducted to investigate the effect of supercritical heat-treated radish-extract on UV-induced HRM-2 wrinkled mouse animal model on anti-aging wrinkles. Supercritical heat-treated radish-extract was applied on the back of seven-weeks old HRM-2 mice. The effect of HRE on skin thickness, elasticity and wrinkle formation of the mice was observed by using UVB lamp to induce melanogenesis and wrinkle formation. As the result, increased depth of wrinkles was observed in the negative control group in comparison to the normal group. In contrast, decreased depth of wrinkles was observed in the radish-extract-free group compared to the negative control group. In the study of the effect of radish-extract on wrinkle-formation related gene expression and protein what protein expression, MMP-2 and MMP-9 gene expression significantly increased in the negative control group compared to the normal group. The gene expression reduced in dependence to the mass of radish-extract treated. Similar to quantitative results of mRNA expression, the expression of MMP-2 protein increased as a result of UVB-irradiation. The MMP-2 expression was inhibited in dependence to the mass of radish-extract treated. In conclusion, the supercritical heat-treated radish-extract has an effect on improving skin wrinkles not only when it is applied to the skin but also when orally ingested. Thus, it can be effectively used as a composition to health functional products. Therefore we can also conclude that radish a food that does not show any side-effects even upon long-term intake can reduce wrinkle formation as well as improve skin elasticity when taken regularly for a long period.

Evaluation of Creep Reduction Factor for Geosynthetic Strip Reinforcement with Folding Grooves (접힘홈이 형성된 띠형 섬유보강재의 크리프 감소계수 평가)

  • Lee, Kwang-Wu;Cho, Sam-Deok
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.4
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    • pp.213-224
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    • 2018
  • In this study, a series of accelerated creep tests (SIM) was carried out on geosynthetic strip reinforcements with folding grooves having different tensile strengths (15 kN, 25 kN, 35 kN, 50 kN, 70 kN, and 90 kN) to analyze creep characteristics and to assess creep reduction factors. In particular, long-term creep tests were conducted on geosynthetic strip reinforcements with 25 kN tensile strength, which is widely used, to compare and analyze the accelerated creep test results. As a result, the creep reduction factor increased with an increasing design life of reinforcement. In addition, geosynthetic strip reinforcement using the same material and manufacturing method showed similar creep reduction factors at the same design life for different tensile strengths. When both long-term and accelerated creep test data were used, the creep reduction factors from the accelerated test were estimated to be 5.9%~7.1% less than those from the long-term creep test for the design life ranging from 50 to 100 years.