• Title/Summary/Keyword: silver solution

Search Result 416, Processing Time 0.024 seconds

Antimicrobial Effects of Laundering and Colloidal Silver Treatment on a Cotton Fabric (은 용액 처리와 세탁 조건에 따른 면직물의 항균효과)

  • Chung, Hae-Won;Kim, Mi-Kyung
    • Fashion & Textile Research Journal
    • /
    • v.7 no.3
    • /
    • pp.333-338
    • /
    • 2005
  • We examined the antimicrobial effects of the cotton fabrics which were laundered at different conditions and treated with a colloidal silver solution using Staphylococcus aureus. Colloidal silver solution was made from commercial colloidal silver generator by electrolysis. The fabric which was innoculated and washed with water before drying had no more Staphylococcus aureus, but which was innoculated and dried before washing with detergent solution had lower reduction rate. The fabric washed with oxygen bleach did not have an antimicrobial effect, but rinsed with 0.07% fabric softener showed antimicrobial properties. The fabric rinsed with 0.7ppm colloidal silver solution had better antimicrobial effects. As the treating concentration of silver solution increased, the antimicrobial property of the fabric was increased. The fabric treated with 5% silver solution sustained reflectance and whiteness of untreated fabric. The colloidal silver treated fabric lost antimicrobial property after washing because nano-sized silver particles were located on uneven fiber surface without chemical bonding forces.

Basic Studies on the Treatment and Recovery of Silver Contained in Waste Photographic Fixing Solution Using D2EHPA as an Extractant (D2EHPA를 추출제로 한 사진폐액 함유 은의 처리 및 회수에 대한 기초연구)

  • Chung, Won-Ju;Kim, Dong-Su;Lee, Hwa-Young
    • Journal of Korean Society on Water Environment
    • /
    • v.22 no.2
    • /
    • pp.288-293
    • /
    • 2006
  • Basic investigations have been carried out for the solvent extraction of silver contained in the waste photographic fixing solution using D2EHPA as an extractant. Extraction experiments were conducted using artificial waste solution which was made by dissolving $AgNO_3$ in distilled water along with actual waste fixing solution. For artificial waste solution, the extraction of silver was found to occur very rapidly at the initial stage of extraction. In addition, more silver was extracted as the volumetric ratio between aqueous phase and organic phase was decreased. The volumetric ratio of organic extractant to diluent was also taken as an influential variable and the extracted amount of silver was observed to decrease with temperature. The characteristics of silver extraction for actual fixing solution was generally similar to that for artificial waste solution. Regarding the kinetic analysis, the extraction of silver contained in the actual solution was observed to follow a first order reaction.

A Study on the Feasibility of a Cyanide-Free Silver Plating Bath (비시안 은도금욕의 가능성에 관한 연구)

  • 이상화
    • Journal of the Korean institute of surface engineering
    • /
    • v.29 no.2
    • /
    • pp.140-145
    • /
    • 1996
  • Silver deposits formed on copper substrates by replacement reactions show poor adhesion, and a silver film plated on such a deposit does not adhere. Silver ion makes a highly stable complex with cyanide ion, so that in a silver cyanide solution, the activity of silver ion is very small. This is one of the reasons for the universal use of cyanide baths in the industrial silver plating. However, the consideration of the difference between the values of the stability constants for bath the silver-iodide complex and the copper-iodide complex suggest that the rate of replacement deposition of silver on the copper substrate in si]ver-potassium iodide solution, could be comparatively low. To confirm this, the rate of replacement deposition of silver in both a silver-potassium iodide solution ($AgNO_3$0.10 mol/L, KI 2.00 mol/L ) and a strike silver plating bath (AgCN 0.028 mol/L, KCN 1.15 mol/L ) was estimated from the current density corresponding to the point of intersection of the anodic and the cathodic polarization curves. These estimated values were almost the same, and it is suggested that the silver-potassium iodide solution is not only a cyanide free silver plating bath capable of employing a copper substrate but a silver plating bath which requires no strike plating.

  • PDF

Characteristics of Silver Nanow ire Solution and Film Depending on Hydroxypropyl Methylcellulose Adhesion Promoter Addition (Hydroxypropyl methylcellulose 접착력 증진제 첨가에 따른 은 나노와이어 용액 및 필름의 특성 변화)

  • Seungju Kang;Kim
    • Journal of Adhesion and Interface
    • /
    • v.24 no.2
    • /
    • pp.54-59
    • /
    • 2023
  • Silver nanowire-based transparent electrodes are very attractive as a next-generation flexible and transparent electrode that can replace ITO-based flexible electrodes because they have excellent conductivity, transmittance and mechanical flexibility. However, weak understanding of the silver nanowire solution for the fabrication of silver nanowire-based transparent electrodes often cause abnormal operation of the electrical device or peeling problem of the electrode films when applied to electronic devices. Here, we studied a Hydroxypropyl Methylcellulose (HPMC) adhesion promoter, which is one of the additives for silver nanowire solution, to improve the understanding of silver nanowire solution. In detail, it is characterized how the HPMC changes the properties of silver nanowire solution and silver nanowire film, which is fabricated with silver nanowire solution including the HPMC adhesion promoter. As the characteristics of solution, polar surface tension and dispersive surface tension were measured. As the film characteristics, surface energy, surface morphology, silver nanowire density, and sheet resistance were analyzed.

Studies on the Homogeneous Precipitiation of Silver Halide (Silver Halide의 均一沈澱法에 關한 硏究)

  • Park, Doo-Won;Oh, Sang O.
    • Journal of the Korean Chemical Society
    • /
    • v.6 no.2
    • /
    • pp.122-124
    • /
    • 1962
  • The silver halide precipitate tends to separate in curdy form of flocculated colloid when it is precipitated by direct mixing of reactant solutions. This type of precipitate has a great tendency to adsorb or occlude foreign ions in the solution.When silver halide in precipitated from homogeneous solution using the slow hydrolysis of Alkyl halide or Ally halide, the precipitate becomes dense, filterable and uniform in particle size which is very advantageous in gravimetric analysis.We found that silver halide precipitates obtained from homogeneous solution with hydrogen halide formed by the hydrolysis of alkyl halide do not give the color change with fluorescein as adsorption indicater, while silver halide precipitates obtained by direct mixing method give sharply pink color which appear to be uniformly distributed through the solution in silver ion excess.

  • PDF

Fabrication of All-Solution Processed Transparent Silver Nanowire Electrode Using a Direct Printing Process

  • Baek, Jang-Mi;Lee, Rin;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.641-641
    • /
    • 2013
  • We report the transparentsilver nanowire electrode fabricated by a direct printing process, liquid-bridge-mediated nanotransfer molding. We fabricated silver nanowire arrays by liquidbridge- mediated nanotransfer molding using the silver nanoparticle ink and PEDOT:PSS polymer. Weinvestigated the formation of silver nanowire arrays by SEM and transmittance of the transparent silver nanowire electrode. We also measured the conductivity to confirm the potential of our approach.

  • PDF

Effect of Silver Ion Solution on the Inhibition of Microcystis Growth (은이온 수용액의 Microcystis 생장 억제 효과)

  • Choi, Gang-Guk;Lee, Sang-Hun;Bae, Kie-Seo;Shin, Jae-Ki;Oh, Hee-Mock
    • Korean Journal of Environmental Biology
    • /
    • v.26 no.3
    • /
    • pp.183-191
    • /
    • 2008
  • The effect of silver ion solution on the growth of Microcystis aeruginosa UTEX 2388 (cyanobacterium) and Chlorella sp. KCTC AG20136 (green alga) was investigated using separated and mixed culture in filtered natural water and BG11 medium. In separated culture, M. aeruginosa UTEX 2388 and Chlorella sp. KCTC AG20136 were found to be sensitive to 0.01 and 0.1 mg L$^{-1}$ of silver ion, respectively. Also, the silver ion concentrations for the growth inhibition of M. aeruginosa UTEX 2388 and Chlorella sp. KCTC AG20136 in the mixed culture were same in separated culture. Cyanobacteria were more sensitive to the silver ion solution than green algae. In bloom sample, the minimal inhibition concentration of silver ion solution for the low Chl-${\alpha}$ sample (110$\sim$190 ${\mu}g$ L$^{-1}$) and high Chl-${\alpha}$ sample (1,500$\sim$1,900 ${\mu}g$ L$^{-1}$) was about 0.1 and 3.0 mg L$^{-1}$, respectively. The silver ion concentration for the inhibition of algal bloom sample was affected by the algal biomass. In order to use silver ion solution for the control of algal bloom, the silver ion concentration must be determined in consideration of a minimal effect on the environment.

Fundamental Studies for the Removal and Recovery of Silver from Waste Photo-Developing Solution by Solvent Extraction (사진폐액으로부터 용매추출에 의한 은의 제거 및 회수에 대한 기초연구)

  • Lee, Sun-Hwa;Kim, Dong-Su;Lee, Hwa-Young
    • Journal of Korean Society on Water Environment
    • /
    • v.22 no.1
    • /
    • pp.122-127
    • /
    • 2006
  • Fundamental studies were carried out for an effective removal and recovery of silver from waste photo-developing solution by solvent extraction. The organic solvents examined for silver-extraction were ALIQUAT 336, D2EHPA, KELEX 100, and TBP. ALIQUAT 336, which is an anionic exchanger, was found to be efficient for the extraction of silver and the reason for this was considered to be due to the chloride ion contained in its structure. The extent of silver extraction was examined to increase with the concentration of ALIQUAT 336 until it reached 0.6 M and no more extraction was observed above this concentration. The extraction of silver by ALIQUAT 336 was found to reach its pseudo-equilibrium within a few minutes after the reaction started and additional slight increase in silver extraction was observed until 30 minutes of reaction time. The observed differences in silver extraction for artificial and actual waste solutions were considered to be based upon the different ionic form of silver-containing species in these solutions.

High Density Silver Nanowire Arrays using Self-ordered Anodic Aluminum Oxide(AAO) Membrane

  • Kim, Yong-Hyun;Han, Young-Hwan;Lee, Hyung-Jik;Lee, Hyung-Bock
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.4
    • /
    • pp.191-195
    • /
    • 2008
  • Highly ordered silver nanowire with a diameter of 10 nm was arrayed by electroless deposition in a porous anodic aluminum oxide(AAO) membrane. The AAO membrane was fabricated electrochemically in an oxalic acid solution via a two-step anodization process, while growth of the silver nanowire was initiated by using electroless deposition at the long-range-ordered nanochannels of the AAO membrane followed by thermal reduction of a silver nitrate aqueous solution by increasing the temperature up to $350^{\circ}C$ for an hour. An additional electro-chemical procedure was applied after the two-step anodization to control the pore size and channel density of AAO, which enabled us to fabricate highly-ordered silver nanowire on a large scale. Electroless deposition of silver nitrate aqueous solution into the AAO membrane and thermal reduction of silver nanowires was performed by increasing the temperature up to $350^{\circ}C$ for 1 h. The morphologies of silver nanowires arrayed in the AAO membrane were investigated using SEM. The chemical composition and crystalline structure were confirmed by XRD and EDX. The electroless-deposited silver nanowires in AAO revealed a well-crystallized self-ordered array with a width of 10 nm.

Studies on the Treatment of Photographic Wastewater by Electrowinning and Electrorefining of Silver (은의 전해채취 및 전해정련을 통한 사진폐액의 처리에 관한 연구)

  • Chung, Won-Ju;Kim, Dong-Su;Lee, Hwa-Young
    • Journal of Korean Society on Water Environment
    • /
    • v.22 no.4
    • /
    • pp.658-665
    • /
    • 2006
  • The removal characteristics of silver ion from waste photographic solution have been investigated by recovering silver electrochemically. Cyclic voltammetry for synthetic and actual wastewater which containing silver ion was investigated to understand its electrochemical behavior. For both synthetic and actual wastewater, the recovery of silver according to the electrowinning time was observed to be increased as the applied potential was raised. In addition, the applicable potential for the electrowinning of silver was found to be lower for synthetic wastewater compared with actual wastewater. As the temperature was increased, more silver was recovered for both wastewater, which indicated the electrowinning reaction was endothermic. The electrowinned silver was refined electrochemically to increase its purity and the variation of the purity of silver was examined according to the electrorefining potential.