• 한국표면공학회지
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• 제49권4호
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• pp.323-330
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• 2016

The flexible transparent conducting films (TCFs) are required to realize flexible optoelectronic devices. 1D nanomaterials such as carbon nanotubes (CNTs), metal nanowires are good candidates to replace indium tin oxide that is currently used to fabricate transparent electrode. Particularly, silver nanowires are used to produce flexible TCFs. In this review, we introduce TCF technologies based on silver nanowires/CNTs hybrid structures. CNTs can compromise drawbacks of silver nanowires for applications in high performance TCFs for optoelectronic devices.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.58.1-58.1
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• 2012

Direct write technologies provide flexible and economic means to manufacture low-cost large-area electronics. In this regard inkjet printing has frequently been used for the fabrication of electronic devices. Full advantage of this method, which is capable of reliable direct patterning with line and space dimensions in the 10 to 100 um regime, is only made with all-solution based processing. Among these printable electronic materials, silver and copper nanoparticles have been used as interconnecting materials. Specially, solutions of organic-encapsulated silver and copper nanoparticles may be printed and subsequently annealed to form low-resistance conductor patterns. In this talk, we describe novel processes for forming silver nanoplates and copper ion complex which have unique properties, and discuss the optimization of the printing/annealing processes to demonstrate plastic-compatible low-resistance conductors. By optimizing both the interconnecting materials and the surface treatments of substrate, it is possible to produce particles that anneal at low-temperatures (< $200^{\circ}C$) to form continuous films having low resistivity and appropriate work function for formation of rectifying contacts.

• Bulletin of the Korean Chemical Society
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• 제35권4호
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• pp.1001-1004
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• 2014

We have synthesized disc-like large silver nanomaterials that have nanostructured bumps on the surface using smaller nanoplate seeds. The size and shape of the bumpy nanostructures are rationally controlled by changing the concentrations of nanoplate seeds, silver ion, reductant, and citrate ion. Importantly, the synthetic mechanism of these bumpy nanostructures is remarkably similar to that of the conventional seed-mediated growth based on tiny seeds. We have further investigated the catalytic properties of the bumpy nanostructures for the reduction of 4-nitrophenol, which is associated with a concomitant color change from yellow to colorless.

• Elastomers and Composites
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• 제54권3호
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• pp.252-256
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• 2019

Fullerene oxide[$C_{60}(O)_n$, ($n{\geq}1$)] was synthesized by dissolving fullerene[$C_{60}$] and 3-chloroperoxybenzoic acid in toluene under refluxing condition for 5 h. Hybrid fullerene oxide-silver nanoparticle composites were synthesized by dissolving fullerene oxide and silver nitrate[$AgNO_3$] in diethylene glycol under ultrasonic irradiation for 3 h. The synthesized hybrid nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet-visible[UV-vis] spectroscopy. The catalytic activity for the reduction of various nitroanilines[NAs] was identified by UV-vis spectrophotometer. The efficiency of the catalytic reduction by the synthesized hybrid nanocomposites has an order of 4-NA > 2-NA > 3-NA.

• 한국폐기물자원순환학회지
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• 제35권7호
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• pp.670-682
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• 2018

Engineered nanomaterials (ENMs) can be released to humans and the environment through the generation of waste containing engineered nanomaterials (WCNMs) and the use and disposal of nano-products. Nanoparticles can also be introduced intentionally or unintentionally into waste streams. This study examined WCNMs in domestic industries, and target nanomaterials, such as silicon dioxide, titanium oxide, zinc oxide, nano silver, and carbon nanotubes (CNTs), were selected. We tested 48 samples, such as dust, sludge, ash, and by-products from manufacturing facilities and waste treatment facilities. We analyzed leaching and content concentrations for heavy metals and hazardous constituents of the waste. Chemical compositions were also measured by XRD and XRF, and the unique properties of nano-waste were identified by using a particle size distribution analyzer and TEM. The dust and sludge generated from manufacturing facilities and the use of nanomaterials showed higher concentrations of metals such as lead, arsenic, chromium, barium, and zinc. Oiled cloths from facilities using nano silver revealed high concentrations of copper, and the leaching concentrations of copper and lead in fly ash were higher than those in bottom ash. In XRF measurements at the facilities, we detected compounds such as silicon dioxide, sulfur trioxide, calcium oxide, titanium dioxide, and zinc oxide. We found several chemicals such as calcium oxide and silicon dioxide in the bottom ash of waste incinerators.

• 멤브레인
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• 제20권2호
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• pp.169-172
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• 2010

Poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA) 가지형 공중합체를 합성한 후, 이를 이용하여 $80^{\circ}C$에서 열적으로 환원하여 은 나노입자를 제조하였다. 반응 시간을 바꿈에 따라 다양한 구조의 은 나노입자를 제조하는데 성공하였다. 1시간 정도의 짧은 반응 시간에서는 가지형 공중합체의 미세 상분리 구조를 크게 변화시키지 않고 5 nm 크기의 작은 은 나노입자가 생성되었다. 5시간 정도의 중간 반응 시간에서는 30 내지 50 nm 정도의 크기를 갖는 은 나노입자가 생성되었다. 18시간 정도의 긴 반응 시간에서는, 은입자가 뭉친 허리케인 모양의 은 집합체가 관찰되었다.

• Advances in nano research
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• 제9권1호
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• pp.25-32
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• 2020

In this work, we report the use of caffeine as an alternative source of nitrogen to successfully dope graphene (quaternary 400.6 eV and pyridinic at 398 eV according XPS), as well as the growth of silver nanowires (in-situ) in the surface of nitrogen doped graphene (NG) sheets. We used the improved graphene oxide method (IGO), chemical reduction of graphene oxide (GOx), and impregnation with caffeine as source of nitrogen for doping and subsequently, silver nanowires (NW) grow in the surface by the reduction of silver salts in the presence of NG, achieving a numerous of growth of NW in the graphene sheets. As supporting experimental evidence, the samples were analyzed using conventional characterization techniques: SEM-EDX, XRD, FT-IR, micro RAMAN, TEM, and XPS.

• 한국습지학회지
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• 제20권3호
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• pp.272-280
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• 2018

기존의 독성평가는 생물의 생존가능성에 영향을 줄 수 있는 이상행동반응에 대한 평가를 거의 하지 않았다. 따라서 본 연구에서는 행동학적 이해를 바탕으로 양서류 유생들의 생존가능성과 직결되는 포식자회피반응 행동을 이용하여 fullerene nanowhisker(FNW)와 nanowhisker-silver nanoparticle composites(FNW-Ag복합체)의 독성을 평가해 보았다. 우리는 나노물질에 노출되지 않는 그룹과 5가지 농도에 따른 나노물질에 노출되는 그룹(FNW $10{\mu}g/ml$, $100{\mu}g/ml$, $500{\mu}g/ml$과 FNW-Ag복합체 $10{\mu}g/ml$, $50{\mu}g/ml$)으로 나누어 실험하였다. 그 결과, FNW-Ag복합체 $50{\mu}g/ml$농도에 노출된 유생들을 제외하고는 평소 활동량에는 차이가 없었지만, FNW $10{\mu}g/ml$농도에 노출된 유생들을 제외하고는 모두 포식자인식 반응에 따른 활동변화에서는 통계적으로 유의한 차이가 나타났다. 즉, 나노물질노출 유무는 평소 움직임에는 영향을 주지 않지만, 행동학적 이해를 바탕으로 한 분석결과 포식자회피반응에 영향을 준다는 것을 알 수 있었다. 따라서 생물을 대상으로 하는 독성평가연구에 행동학적 분석이 이루어져야 할 것으로 판단된다.

• Advances in nano research
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• 제2권3호
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• pp.135-145
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• 2014

Nanomaterials synthesized by natural bioresources such as microorganisms, animals and plants in nature can also be synthesized in laboratories even on large scale. This is considered as an attractive prospect for eco-friendly or so-called green synthesis. Development of eco-friendly synthesis of biocompatible nanoparticles and their potential biomedical applications introduces the concept of nanobiotechnology. The lower cost and lesser side effects as compare to chemical methods of synthesis are the main advantages of biosynthesis. This review article demonstrates the role of various biological resources e.g. bacteria, fungi, actinomycetes, plant leaves, fruits and honey as well as animal tissues for the synthesis of nanoparticles mainly gold and silver with an overview of their potential applications.

• 센서학회지
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• 제26권6호
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• pp.391-396
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• 2017

Human body motion detection is important in several industry sectors, such as entertainment, healthcare, rehabilitation, and so on. In this paper, we first discuss commercial human motion detection technologies (optical markers, MEMS acceleration sensors, infrared imaging, etc.) and then explain recent advances in the development of flexible and stretchable strain sensors for human motion detection. In particular, flexible and stretchable strain sensors that are fabricated using carbon nanotubes, silver nanowires, graphene, and other materials are reviewed.