• Title/Summary/Keyword: silver halide

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SERS of Dithiocarbamate Pesticides Adsorbed on Silver Surface; Thiram

  • Kang, Jae-Soo;Hwang, Seon-Yeong;Lee, Chul-Jae;Lee, Mu-Sang
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1604-1610
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    • 2002
  • In the present work, we studied thiram on silver surface by SERS. Investigations of disulfides with SERS revealed that the molecules undergo a surface reaction on silver, namely easy cleavage of the S-S bond. We believe that the two S atoms of resonance formed from the thiram may be chemisorbed strongly on Ag sol. This resonance form adheres perpendicularly to the Ag surface via the two S atoms, since the ${\delta}(CH3)$ and n (CN) mode perpendicular to the surface showed strong enhancement. The important roles of halide anion adsorption have been discussed and the pH effects of thiram on Ag sol in acidic, neutral, and alkaline conditions were examined.

The Effects of Hydroxymethane Sulfonic Acid Sodium Salt and 5,5-Dimethylhydantoin on the Photographic Characteristics of Silver Halide Emulsion (할로겐화은(化銀) 유제(乳劑)의 사진특성(寫眞特性)에 미치는 Hydroxymethane Sulfonic Acid Sodium Salt와 5,5-Dimethylhydantoin의 첨가효과(添加效果))

  • Kang, Tai-Sung
    • Journal of radiological science and technology
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    • v.6 no.1
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    • pp.43-67
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    • 1983
  • In order to increase the sensitivity of the photographic emulsion, one of the chemical sensitizers hydroxymethane sulfonic acid sodium salt(HMS) was applied through the chemical ripening process and following four types of emulsion were prepared. Their grain sizes were determined through the electron microscope. The ranges of average grain sizes were $0.05-0.40{\mu}m$ for silver chlorobromide emulsion of low sensitivity $0.10-0.45{\mu}m$ for the silver chlorobromide emulsion of medium sensitivity, $0.60-1.05{\mu}m$ for the silver iodobromide emulsion of high sensitivity, and $0.90-1.55{\mu}m$ for the ammonical silver iodobromide emulsion of high sensitivity. Through the reduction sensitization with HMS, they showed significant sensitivity enhancement by the increment of HMS concentration above pH 5.5 and pBr 3.0. Required sensitivity was obtained above pH 6.2 and pBr 3.3 when sulfur and gold sensitization were applied. Fog formed along the reduction sensitization was successfully prevented by the addition of 5.5-dimethylhydantion.

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Development of the silver-white decoy for squid automatic jigging machine and fishing performance (오징어채낚기용 은백색 유인체 개발과 어획성능)

  • An, Young-Il;Jang, Ung-Jeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.49 no.3
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    • pp.208-217
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    • 2013
  • Decoys for automatic jigging machines, the body part of a squid hook, have been developed in small and existing sizes in consideration of squid food, color blindness, and retinomotor responses and in utilization of pearl pigment, PP of high transparency, and combined mixture. In comparison of the developed silver-white decoy and existing decoys, the optical characteristics were examined, and the fishing performance of small size silver-white squid hooks was assessed in application of 4 fishing boats with the squid automatic jigging machine and metal halide fishing lamp in July, 2012. The luminances of the three squid hook colors-green, dark green and silver-white-increased as the intensity of illumination increased. Among these, the increase of silver-white was particularly distinguished. As to the average contrast of squid hooks, that of silver-white was 10.33, which was the highest, and then green 1.86 and dark green -0.10 in the order. As to the fishing performance of the silver-white hook, that of the 202 Geumyeong-ho and 101Yongjin-ho which caught squids were similar to that of the existing green hook and was relatively low in the case of the Dongbu-ho. However, that of the Haengbok-ho which caught relatively small squids whose average length was 19.9cm and installed silver-white hook in all automatic jigging machines was significantly excellent. In order to enhance the fishing performance of small size silver-white hooks, therefore, it would be effective to install in every automatic jigging machines of fishing boat and to start fishing before July by which small squids are caught.

The Additive Effect of Polyoxyethylene Compounds on the Photographic Characters of Photographic Emulsion

  • Youn, Min-Young;Ahn, Hong-Chan;Kang, Tai-Sung
    • Journal of Photoscience
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    • v.7 no.2
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    • pp.45-46
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    • 2000
  • The polyoxyethylene compounds were added into the photographic emulsion during the physical ripening of photo sensitive silver halide crystal in this emulsion. The polyoxyethylene compounds improved the photographic properties of the film to a great extent increasing the photo sensitivity and decreasing the fog density.

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Development of holographic Optical Elements (홀로그래픽 광학소자 개발)

  • 정만호;송재봉;이인원
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.07a
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    • pp.87-93
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    • 1990
  • Estimation and collection of the suitable recording materials are important for the fabrication of the holographic optical elements. In this study, silver halide emulsion, photoresist and dichromated gelatin are selected as a recording materials to investigate the properties and processing methods. Some parameters which affect the diffraction efficiencies of the holographic optical elements (HOE) are presented. As an example of the HOE, the results of design and the fabrication method of the off axis 12P hologram lens are also presented.

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Material Analysis of Black and White Photograph - Photograph from Borobudur - (흑백 사진의 재질 분석 - 보로부두르 사진을 중심으로 -)

  • Yun, Eun Young;Habibi, Modhamad;Jin, Hong Ju
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.385-391
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    • 2019
  • In order to examine the material characteristics of a black and white photograph of the Borobudur temple, in Indonesia, several analyses were conducted. A sample was taken from a black and white photograph; microscopy, Fourier transform-infrared spectroscopy, scanning electron microscopy/energy dispersive spectroscopy, X-ray diffraction, and X-ray fluorescence analyses showed that the black and white photograph was composed of four layers including a paper substrate, baryta, binder and surface layers. It was confirmed that the substrate was paper made of cellulose fiber from Cannabis sativa, the baryta layer was made of barium sulfate(BaSO4) in powder form, the binder was an emulsion containing silver halide, and the surface protective layer was made of gelatin. Since photographs have different characteristics and require different preservation environments depending on the material of construction, it is necessary to study various black and white photographic material characteristics corresponding to each time period.

Measurements of temperature distribution using an infrared optical fiber during radiofrequency ablation (적외선 투과 광섬유를 이용한 고주파 열치료 과정에서의 온도분포 측정)

  • Yoo, Wook-Jae;Seo, Jeong-Ki;Cho, Dong-Hyun;Jang, Kyoung-Won;Shin, Sang-Hun;Lee, Bong-Soo;Tack, Gye-Rae;Park, Byung-Gi;Moon, Joo-Hyun
    • Journal of Sensor Science and Technology
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    • v.17 no.6
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    • pp.397-405
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    • 2008
  • In this study, we have measured temperature distribution using infrared optical fibers during radiofrequency ablation (RFA). Infrared radiations generated from the water around inserted electrode are transferred by silver halide optical fibers and are measured by a thermopile sensor. Also, the output voltages of a thermopile sensor are compared with those of the thermocouple recorder. It is expected that a noncontact temperature sensor using an infrared optical fiber can be developed for the temperature monitoring during RFA treatments based on the results of this study.

Measurement of Crystallite Size of Method and Evaluation of Crystal Defects (X선 회절법에 의한 할로겐화 은 유제입자의 크리스탈라이트 크기 측정과 결정결함 평가에 관한 연구)

  • Bae, Chang-Hwan;Lee, Ju-Hee;Han, Chang-Suk
    • Korean Journal of Materials Research
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    • v.19 no.6
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    • pp.330-336
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    • 2009
  • The size of crystallites in mono-dispersed cubic silver bromide grains was measured by applying a powder X-ray diffraction method and Scherrer's equation to grains that were suspended in swollen gelatin layers. In order to evaluate the existence of defects, the measured crystallite size was compared to those measured by using a scanning electron microscope. In the case of the grains prepared by the controlled double jet method, the size of crystallites was equal to the edge length of the grains that had edge lengths smaller than 400 nm. This result proved the usefulness of the above-stated method for measuring the size of crystallites and also evaluating the presence of any crystal defect in each grain. In the case of the grains, which were precipitated in the presence of a sensitizing dye and potassium iodide, the size of crystallites was smaller than the edge's length, indicating the discontinuities in the grains introduced during the precipitation process.