Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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SERS of Dithiocarbamate Pesticides Adsorbed on Silver Surface; Thiram

  • Published : 2002.11.20
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Abstract

In the present work, we studied thiram on silver surface by SERS. Investigations of disulfides with SERS revealed that the molecules undergo a surface reaction on silver, namely easy cleavage of the S-S bond. We believe that the two S atoms of resonance formed from the thiram may be chemisorbed strongly on Ag sol. This resonance form adheres perpendicularly to the Ag surface via the two S atoms, since the ${\delta}(CH3)$ and n (CN) mode perpendicular to the surface showed strong enhancement. The important roles of halide anion adsorption have been discussed and the pH effects of thiram on Ag sol in acidic, neutral, and alkaline conditions were examined.

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References

  1. Surface Enhanced Raman Scattering; Chang, R. K., Furtak, T. E. Eds.; Plenum: New York, 1982.
  2. Creighton, J. A. Raman Spectroscopy of Adsorbates at Metal Surface in Vibrational Spectroscopy of Adsorbates; springer series in chemical physics; Wills, R. F., Ed.; Springer: Berlin, Heidelberg, New York, 1980; vol. 15, p 145. https://doi.org/10.1007/978-3-642-88644-7_9
  3. Joo, S. W.; Han, S. W.; Kim, K. J. Colloid Interface Sci. 2001, 240, 391. https://doi.org/10.1006/jcis.2001.7692
  4. Jung, Y. M.; Lim, J. W.; Kim, E. R.; Lee, H.; Lee, M. S. Bull. Korean Chem. Soc. 2001, 22, 318.
  5. Zeman, E. J.; Schatz, G. C. J. Phys. Chem. 1987, 91, 634. https://doi.org/10.1021/j100287a028
  6. Matejka, P.; Vlckova, B.; Volhlichol, J.; Pancoska, P.; Banmrnk, V. J. Phys. Chem. 1992, 96, 1361. https://doi.org/10.1021/j100182a063
  7. Moskovits, M. Rev. Mod. Phys. 1985, 57, 783. https://doi.org/10.1103/RevModPhys.57.783
  8. Moskovits, M.; Suh, J. S. J. Phys. Chem. 1984, 88, 5526. https://doi.org/10.1021/j150667a013
  9. Suh, J. S. J. Korean Chem. Soc. 1992, 36, 327.
  10. Yim, Y. H.; Kim, K.; Kim, M. S. J. Phys. Chem. 1990, 94, 2552. https://doi.org/10.1021/j100369a061
  11. Cardona, M.; Guntherodt, G. Light Scattering in Solids; Springer: Berlin, 1984; Vol. IV.
  12. Matthews, G. A.; Hislop, E. C. Application Technology for Crop Protection; 1993.
  13. Daruich, J.; Zirulnik, F.; Gimenez, M. S. Environ. Res. 2001, 85, 226. https://doi.org/10.1006/enrs.2000.4229
  14. Anderson, M. R.; Erans, D. H. J. Am. Chem. Soc. 1988, 110, 6612. https://doi.org/10.1021/ja00228a003
  15. Albrecht, M. G.; Creighton, J. A. J. Am. Chem. Soc. 1977, 99, 5215. https://doi.org/10.1021/ja00457a071
  16. Lee, S. B.; Kim, K.; Kim, M. S. J. Phys. Chem. 1992, 96, 9940. https://doi.org/10.1021/j100203a066
  17. Watanabe, T.; Maeda, H. J. Phys. Chem. 1989, 93, 3258. https://doi.org/10.1021/j100345a075
  18. Macomber, S. H.; Furtak, T. E. Chem. Phys. Lett. 1982, 90(1), 59. https://doi.org/10.1016/0009-2614(82)83325-3
  19. Joo, T. H.; Yim, Y. H.; Kim, K.; Kim, M. S. J. Phys. Chem. 1989, 93, 1422. https://doi.org/10.1021/j100341a048
  20. Kwon, C. K.; Kim, K.; Kim, M. S.; Lee, S. B. Bull. Korean Chem. Soc. 1989, 10(3), 254.
  21. Nichols, H.; Hexter, R. M. J. Chem. Phys. 1981, 74, 2059. https://doi.org/10.1063/1.441252
  22. Weaver, M. J.; Hupp, J. T. J. Electroanal. Chem. 1984, 160, 321. https://doi.org/10.1016/S0022-0728(84)80135-7
  23. Wetzel, H.; Gerischer, H.; Pettinger, B. Chem. Phys. Lett. 1981, 78, 392. https://doi.org/10.1016/0009-2614(81)80040-1
  24. Loo, B. H. Chem. Phys. Lett. 1982, 89(4), 346. https://doi.org/10.1016/0009-2614(82)83513-6
  25. Pettinger, B.; Phillpott, M. R.; Gordon, J. G. J. Phys. Chem. 1981, 85, 2746. https://doi.org/10.1021/j150619a012
  26. Takahashi, M.; Furukwa, H.; Fujita, M.; Ito, M. J. Phys. Chem. 1987, 91, 5940. https://doi.org/10.1021/j100307a025
  27. Garrel, R. L.; Shaw, K. D.; Krimm, S. J. Chem. Phys. 1981, 75(8), 4155. https://doi.org/10.1063/1.442504
  28. Muniz-Miranda, M.; Sbrana, G. J. Raman Spectrosc. 1996, 27, 105. https://doi.org/10.1002/(SICI)1097-4555(199602)27:2<105::AID-JRS933>3.0.CO;2-L
  29. Sanches-Cortes, S.; Garcia-Ramos, J. V. J. Raman Spectrosc. 1992, 23, 61. https://doi.org/10.1002/jrs.1250230108
  30. Larkin, D.; Guyer, K. L.; Hupp, J. T.; Weaver, M. J. J. Electroanal. Chem. 1982, 138, 401. https://doi.org/10.1016/0022-0728(82)85091-2
  31. Kim, M.; Koichi, I. J. Phys. Chem. 1987, 91, 126. https://doi.org/10.1021/j100285a029
  32. Salaita, G. N.; Lu, F.; Languren-Davidson, L.; Hubbard, A. T. J. Electroanal. Chem. 1987, 229, 1. https://doi.org/10.1016/0022-0728(87)85127-6

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  30. Dithiocarbamates: Functional and Versatile Linkers for the Formation of Self-Assembled Monolayers vol.22, pp.2, 2002, https://doi.org/10.1021/la052952u
  31. Solvent extraction followed by ultraviolet detection for investigation of tetramethylthiuram disulfide at soil-water interface vol.5, pp.4, 2002, https://doi.org/10.1007/bf03326052
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  34. Surface-enhanced Raman spectroscopy of Omethoate adsorbed on silver surface vol.78, pp.1, 2002, https://doi.org/10.1016/j.saa.2010.09.018
  35. High performance Au/Ag core/shell bipyramids for determination of thiram based on surface‐enhanced Raman scattering vol.43, pp.10, 2002, https://doi.org/10.1002/jrs.4087
  36. Periodic silver nanodishes as sensitive and reproducible surface-enhanced Raman scattering substrates vol.4, pp.7, 2002, https://doi.org/10.1039/c3ra45935g
  37. Flexible and Adhesive Surface Enhance Raman Scattering Active Tape for Rapid Detection of Pesticide Residues in Fruits and Vegetables vol.88, pp.4, 2002, https://doi.org/10.1021/acs.analchem.5b03735
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  48. A functional Au array SERS chip for the fast inspection of pesticides in conjunction with surface extraction and coordination transferring vol.144, pp.18, 2002, https://doi.org/10.1039/c9an01123d
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