• Title/Summary/Keyword: sillica

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Effect of Silica Coating on Particle Shape and Magnetic Properties of Iron Powder(I) (실리카 피착이 철립말의 입자형태 및 자기특성에 미치는 영향 (제1보))

  • 오재희;김종식;류병환
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.21-28
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    • 1985
  • The properties of magnetic recording materials largely depend on their shape magnetic anisotropy. The control of their shape and size distribution is very important for improving magnetic properties. The silica-coated goethite$(SiO_2$/$\alpha$-FeOOH=1.5wt%) having acicular shape was prepared. The sillica-coated goethite was heat-treated at 40$0^{\circ}C$~1,00$0^{\circ}C$ 1hr and then reduced at 50$0^{\circ}C$ 2hr. When the silica-coated goethite was heat-treated at 80$0^{\circ}C$ its acicular shape was maintained and its magnetic properties were improved(Hc: 1,325 Oe $\sigma$m:138.8 emu/g, Rs:0.56) However the acicular shape of the paricles was broken for non-coated hematite obtained by dehydration at 80$0^{\circ}C$ They were sintered and showed poor magnetic properties.

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The Influence of Polytypism and Impurities on the Phase Transformation of Kaolins : I. Kaolinite and Dickite (다구조형의 차이와 불순물이 카올린광물의 상전이에 미치는 영향: I.카올리나이트와 딕카이트)

  • 이수정
    • Economic and Environmental Geology
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    • v.32 no.4
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    • pp.399-409
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    • 1999
  • Mullitization of kaolinite and dickite was examined with special attention to the influence of polytypism and impurities on the phase transformation. The phase transformation sequence in dickite is identical with that in kaolinite except that cristobalite is crystallized at $50^{\circ}C$ higher temperature in dickite. Difference in phase transformation above $1000^{\circ}C$ in kaolin minerals is attributed to the different crystal structures of metadickite and metakaolinite on the effect of impurities. A part of quartz is transformaed into cristobalite. Spinel-type phase produced in disordered kaolins including illite occurs over a short range of temperatures. Primary mullite is transformed into orthorhombic mullite at higher temperature as well. These results sustain the idea that disintegration of methkaolin and the spinel-type phase supplies extra sillica and promotes the growth of mullite cristobalite.

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Field Application of the Corrosion Protection Method for Marine Concrete with Nano-Silica (Nano-Sillica를 이용한 해양콘크리트 방식공법 현장 적용)

  • Kim, Kyoung-Min;Ryu, Dong-Woo;Park, Sang-Joon;Kim, Jong-Baek;Jo, Sung-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.399-400
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    • 2009
  • This study arranged the result corrosion inhibition using Nano-silica for efficient prevention to diffusion of chloride ion. For the results, significant difference was not found on slump and air content, and there were superior effect to preventing diffusion of chloride ion on hardened concrete. It seemed to be Nano-silica prevented diffusion of chloride ion.

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Insulation Coating for non-oriented Silicon Steel Sheerts (무방향성 전기강판의 절연피막 코팅재)

  • 조남웅;장세기
    • Journal of the Korean institute of surface engineering
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    • v.30 no.6
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    • pp.382-390
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    • 1997
  • Good appearance of insulation coating is required for non-oriented silicon steel sheets, The property is influenced by both the chemical composition of coating solution and the species of resin. The composition of inorganic-organic coating was studied to obtain good surface quality for non-oriented silicon steel. The greenish degree of coating surface depended on $Cr^{3+}$ content in the coating layer, which was satisfied when chromate content was more than 54.60 wt. %, in the coating solution. The homogeneous pattern and roughness of the coating surface depended on spreading property of the resin. Surface appearance of the coating could be improved by using resin with good spreading property at the chemical composition of chromate 59.00 wt.%.. resin 34.23wt.%, and etyhylene glycol 6.67 wt.% without colloidal sillica.

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Production of Bluish Purple Pigment from Streptomyces californicus KS-89 (Streptomyces californicus KS-89 변이주에 의한 청자색소의 생산)

  • 이병호;이상훈
    • KSBB Journal
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    • v.9 no.2
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    • pp.147-156
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    • 1994
  • A study was carried out for production of a pigment : bluish purple, using a mutant Streptomyces californicus KS-89-7. The mutant was induced from Streptomyces californicus KS-89 with N-methyl-N-nitro-N-nitrosoquanidin(MNNG). It was immobilized on an inert substance made of colloidal sillica and 3.5% sodium alginate with 1 to 10 ratio. The diameter of inert bead was 2mm, and number of immobilized mutant spore was approximately $1.0{\times}10^7$/ml. It was packed in a column reactor and fermentation was conducted with a substrate made of soluble starch 1%, glycerol 1.0%, sodium glutamate 0.1%, sodium nitrate 0.05%, L-prolin 0.025% and with some trace elements. The aeration for production of the pigment was 2.5m1/min with semi-continuous fermentation. The pigment production reached at peak on 8 days of fermentation, and the mutant produced the pigment 1.8 times more than its parent strain with the maximum pigment production of $1.72g/\ell$. The pigment production continued for 24 hours of fermentation, and at the end of the fermentation the mutant produced the pigment $1.52g/\ell$.

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Neuraminidase Inhibitors from Reynoutria elliptica

  • Lee, Chu-Hyun;Kim, Sang-In;Lee, Kyung-Bok;Yoo, Yung-Choon;Ryu, Si-Young;Song, Kyung-Sik
    • Archives of Pharmacal Research
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    • v.26 no.5
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    • pp.367-374
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    • 2003
  • In the course of screening neuraminidase inhibitors from herbal medicines, Reynoutria elliptica exhibited high inhibitory activity. Four active compounds were isolated from the ethyl acetate soluble fraction by consecutive purification using sillica gel, Sephadex LH-20 chromatography, and recrystallization. The chemical structures of these compounds were identified as 1,3,8-trihydroxy-6-methylanthraquinone (emodin) 1,8-dihydroxy-3-methoxy-6-methylanthraquinone (emodin 3-methyl ether; physcion), 1,3,8-trihydroxy-6-hydoxymethylanthraquinone ($\omega$-hydroxyemodin), and 3,5,4 -trihydroxystilbene (trans-resvertrol) by spectral data including MS, $^1 H-, and ^{13}C-NMR. The IC_{50}$ values of emodin, emodin 3-methyl ether, $\omega$-hydroxyemodin, and trans-resvertrol were 2.81, 74.07, 10.49, and 8.77 $\mu$M, respectively. They did not inhibit other glycosidase such as glucosidase, mannosidase, and galactosidase, indicating that they were relatively specific inhibitors of neuraminidase.

Process Development of Self-Assembled Monolayers(SAMs) of Colloidal Particles (콜로이드 입자의 자기 배열성을 이용한 Monolayer 형성에 관한 연구)

  • Ko, Hwa-Young;Lee, Hae-Weon;Kim, Joo-Sun;Moon, Joo-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.981-987
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    • 2002
  • Monodispersed colloidal silica was prepared by Stober process. We have synthesized monodispersed colloidal silica of carious sizes (100 nm, 200 nm, 300 nm) by controlling volume ratios of TEOS(Tetraethylorthosilicate), $NH_4OH$, Ethanol and D. I. water. Shape and monodispersity of the synthesized colloidal particles were observed by Scanning Electron Microscopy(SEM) and laser light scattering particle analyzer. Self-assembled monolayer of monodispersed colloids was achieved by dipping Si substrate into a well-dispersed silica suspension. It was determined that uniformity and spatial extent of the self-assemble monolayer of monodispersed colloids are significantly influenced by the experimental parameters such as concentration, pH and surface tension of the colloidal suspension. We have observed a hexagonally well-ordered packing colloidal monolayer in a relatively large area (1.5 mm ${\times}$ 1.5 mm) as confirmed by SEM.

The Aroma Components of Duchung Tea and Persimmon Leaf Tea (두충차와 감잎차의 향기성분)

  • Choi, Sung-Hee
    • Korean Journal of Food Science and Technology
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    • v.22 no.4
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    • pp.405-410
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    • 1990
  • The aroma components of duchung tea and persimmon leaf tea were collected simultaneous distillation and extraction method. Those were analyzed and identified by GC-MS using a fused sillica capillary column. Seventy seven components, including 17 alcohols, 3 hydrocarbons, 15 ketones, 16 aldehydes, 8 esters,8 acids, 8 heterocyclic compounds and 2 phenols were confirmed in duchung tea. Seventy one components, including 17 alcohols, 10 hydrocabrons, 11 ketones, 13 aldehydes, 8 esters, 6 acids, 5 heterocyclic compounds and 1 phenol were confirmed in persimmon leaf tea. The most abundant components of duchung tea were aldehydes(23.31%) including 2-pentenal and heterocyclic compounds(16.71%) including $epoxy-{\beta}-ionone$. The most abundant components of persimmon leaf tea were alcohols(25.57%) including linalool and aldehydes(19.45%) including hexanal and hydrocarbons(10.40%) including ${\alpha}-copaene$.

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