• Composites Research
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• 제30권1호
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• pp.41-45
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• 2017

Magnetite nanoparticles were synthesized by adding an ammonium hydroxide to a mixed solution of iron (II) and (III) chlorides. A silicon surfactant of ${\alpha},{\omega}$-(3-aminopropyl)polydimethylsiloxane was adsorbed on the particles as dispersant and a polydimethylsiloxane polymer was used to prepare ferrofluids of silicone oil base. Fluorinated surfactants of anionic ammoniated perfluoroalkyl sulfonamide and nonionic fluoroaliphatic polymeric esters were applied to the particles and a perfluoropolyether was used to prepare ferrofluids of fluorine oil base. The experimental conditions were used for preparing the ferrofluids with concentrations of 200, 300 and 400 mg/mL, and density, magnetization and viscosity of the products were characterized. The density values increased in proportion to the concentration, indicating 1.11-1.27 g/mL for silicone-oil-based fluids and 1.95-2.10 g/mL for fluorine-oil-based fluids in the range of 200-400 mg/mL. The saturation magnetization of the silicone-oil-based and fluorine-oil-based fluids indicated 14.7, 24.4, and 30.7 mT and 15.8, 23.3, and 33.7 mT for 200, 300, and 400 mg/mL, respectively, depending on the content of magnetic particles in the fluid. The viscosity of the silicone-oil-based ferrofluids was highly stable compared to that of the fluorine-oil-based with increasing temperatures. The ferrofluids are usually applied to seals and speakers with the silicone base and to seals with the fluorine base.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 추계학술발표대회 논문집
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• pp.141-144
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• 2005

Sensing and interfacial evaluation of Ni nanowire strands/polymer composites were investigated using Electro-micromechanical technique. Electro-micromechanical techniques can be used as sensing method for micro damage, loading, temperature of interfacial properties. Using Ni nanowire strands/silicone composites with different content, load sensing response of electrical contact resistivity was investigated under tensile and compression condition. The mechanical properties of Ni nanowire strands with different type/epoxy composites were measured using uniformed cyclic loading and tensile test. Ni nanowire strands/epoxy composites showed humidity and temperature sensing within limited ranges, 20 vol% reinforcement. Some new information on temperature and humidity sensing plus loading sensing of Ni nanowire strands/polymer composites could be obtained from the electrical resistance measurement as a new concept of the nondestructive interfacial evaluation.

• 소성∙가공
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• 제15권6호
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• pp.436-440
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• 2006

A rapid tooling (RT) method fur the resin transfer molding (RTM) have been investigated. We fabricated a curved I-beam to verify the method. After creating a three-dimensional CAD model of the beam we fabricated a prototype of the model using a rapid prototyping (RP) machine. A soft mold was made using the prototype by the conventional silicone mold technique. The procedure and method of mold fabrication is described. The mold was cut into several parts to allow easier placement of the fiber preform. We conducted the resin transfer molding process and manufactured a composite beam with the mold. The preform was built by stacking up eight layers of delicately cut carbon fabrics. The fabrics were properly stitched to maintain the shape while placement. The manufactured composites beam was inspected and found well-impregnated. The fiber volume ratio of the fabricated beam was 16.85%.

• Elastomers and Composites
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• 제45권2호
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• pp.106-111
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• 2010

천연고무와 실리콘고무에 자기장응답형 분말을(Magnetic Responsible Powder; MRP) 배합하여 자기장응답형 엘라스토머(Magneto-rheological Elastomer; MRE)를 제조하였다. MRP의 최적 사용량은 30 vol.% 였으며 천연고무 기반 MRE의 기계적 물성은 실리콘고무 기반 MRE 보다 우수했지만, magneto-rheological (MR) 효과는 실리콘고무 기반 MRE가 더욱 우수하였다. MR 효과는 Self-modified Electromagnet Applied Fast Fourier Transform Analyser (SEFFTA)를 사용하여 측정되었는데 천연고무 기반 MRE의 경우는 10%, 실리콘고무 기반 MRE의 경우는 최대 35.7%까지 나타내었다. 네오디뮴 자석을 이용하여 MRE를 경화시키기 전 MRP를 선 배향 시킬 경우 더욱 우수한 MR 효과를 얻을 수 있었으며, MRP의 배향은 주사전자현미경을 이용하여 분석하였다.

• Elastomers and Composites
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• 제41권3호
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• pp.157-163
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• 2006

침전실리카와 친수성 및 소수성 흄실리카를 사용하여 첨가량에 따른 실리콘 고무인상재의 젖음성과 기계적 물성 향상 연구를 수행하였다. 고무인상재의 경화시간에는 흄실리카 종류보다는 입자크기가 영향을 미쳤으며, 입자크기가 가장 작은 A300을 사용할 경우 약 9분 정도의 경화시간 지연을 초래하였다. 소수성 흄실리카인 R972를 대체 사용할 경우 고무인상재의 젖음성 특성이 가장 우수하였다. 침전실리카와 A300 흄실리카를 85:15로 혼합하여 사용할 경우 인열강도가 약 1.5N/mm 정도 증가하지만 경화시간의 과도한 지연과 더불어 점도가 상승하기 때문에, 흐름성 및 기계적물성 측면에서 침전실리카와 흄실리가(A300)를 90:10으로 혼합하여 사용하는 것이 최적이었다.

• Transactions on Electrical and Electronic Materials
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• 제18권4호
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• pp.203-206
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• 2017

The effect of the content of microsilica and nanosilica continuously modified with hydroxy silane and epoxy-modified silicone in cycloaliphatic epoxy/microsilica/nanosilica composites (EMNCs) on the mechanical and water repellent properties was evaluated. Surface-modified micro- and nanosilica was well-mixed with a cycloaliphatic epoxy resin in the presence of polyester-modified polydimethylsiloxane (PEM-PDMS) as a dispersing agent using an ultrasonicator. Tensile and flexural tests were carried out using a universal testing machine (UTM). The water repellent property was evaluated by contact angle measurements of water on the composite surface. Tensile strength of the composite could be enhanced by 32.2% up to 91.4 MPa, and the flexural strength was raised to 122.0 MPa, which is 38.8% higher than that of neat epoxy. The contact angle of water on the composite was as high as $104.1^{\circ}$.

• Elastomers and Composites
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• 제53권4호
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• pp.195-201
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• 2018

Three kinds of rubber compounds were prepared, and their underwater acoustical properties were investigated for anechoic coating. Dynamic mechanical properties of the rubber compounds were measured using a dynamic mechanical analyzer and extended to 100 kHz using time-temperature superposition. The sound speed, reflection coefficient, and attenuation constant were calculated. Silicone rubber showed the lowest reflection coefficient, and nitrile rubber showed the highest attenuation constant. The acoustic properties of nitrile rubber compounds with various compositions were investigated. The sound speed, reflection coefficient, and transmission coefficient of the nitrile rubber in the frequency range of 200-1000 kHz were measured in a water-filled tank.

• Composites Research
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• 제27권6호
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• pp.242-247
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• 2014

전기활성고분자의 종류 중 하나인 유전성 탄성체의 거동에 대응할 수 있는 유연전극 제조에 대한 연구를 수행하였다. 전도성 고분자(PEDOT:PSS)에 가소제 역할을 하는 자이리톨(Xylitol)을 첨가하여 기계적 특성을 평가하였다. 자이리톨을 첨가한 전극의 유연성을 확인하기 위해 실리콘 시편에 전극을 도포하여 인장시험을 수행하였다. 자이리톨을 70 wt% 첨가한 조건에서 연신률이 크게 증가함을 확인하였고 실리콘 거동에 큰 영향을 미치지 않는 것을 확인하였다. 또한, 전극과 실리콘의 접착성을 향상시키기 위해 표면조도가 다른 실리콘 필름을 제작하였으며 사포 #120으로 처리한 시편에서 실리콘 필름과 전극의 접착성이 향상됨을 확인하였다.

• 폴리머
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• 제26권5호
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• pp.644-652
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• 2002

전자파 차폐용 개스킷으로 적용할 수 있는 금속계 입자와 상온경화형 실리콘 수지의 페이스트계에 대한 정량적인 해석을 수행하였다. 금속입자 충전 복합재료의 전기 전도성 및 유변학적 거동은 입자의 형상, 크기, 분산상태에 많은 영향을 받는다. 고충전계에서 입자들은 매우 복잡한 응집상태를 형성하며 전단속도와 같은 외부요인에 의해 응집구조가 변하고 이에 따라 전기 전도도가 달라지게 된다. 본 연구에서는 금속입자의 평균직경 및 분산성에 따른 영향을 점도측정 및 전기 전도도 측정 방법을 통해 해석하였으며 이를 통해 금속입자의 선정기준을 제시하였다. 금속입자의 종류에 따라 점도분포, 전단응력의 영향, 전기 전도성의 변화 등이 차이를 보였다. 상대적으로 직경이 큰 입자에서 전단응력에 의한 영향이 두드러지게 나타났으며 동일 함량에서 분산성의 제어를 통해 점도 및 전기 전도도의 개선이 가능함을 보였다.

• 전기학회논문지
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• 제68권1호
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• pp.61-68
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• 2019

Only the power is converted from AC to DC, in accordance with IEC 60587 based test method, in order to develop the LSR(Liquid Silicone Rubber) insulator material for HVDC, the experiment of Inclined Plate Tracking and Erosion Resistance was conducted. A contaminant (2.5 mS/cm: ammonium chloride) was applied at a rate of 0.3 ml/min and a voltage of ${\pm}3.5kV$, and was evaluated on the basis of 60 mA/2s. The samples were prepared by dispersing LSR/Nano silica_25wt% Composites in LSR. The erosion phenomena of surface discharge and tracking due to DC polarity and negative polarity were measured by image, leakage current maximum and thermal camera. The thermal imaging camera measured the surface temperature generated by the joule heat of the leakage current due to the drying discharge and the conductive current. After the measurement, the tracking and erosion mechanisms were evaluated for erosion weight, erosion depth and erosion length. Positive and negative polarity of LSR/Nano Silica_25wt% composite Tracking and erosion results show that positive polarity is more severe than negative polarity.