• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.465-469
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• 2011

In this study, poly(ethyleneoxide) and poly(ethylene imine) polymer blends containing fumed silica fillers were studied in order to enhance the ion conductivity and interfacial properties. Lithium perchlorate ($LiClO_4$) as a salt, and silica($SiO_2$) as the inorganic filler were introduced into the polymer composite electrolyte composites and the composites were examined to evaluate their ionic conductivity for a possibility test of electrolyte application. As the diameter of semicircle in an impedance test became smaller, ionic conductivity of composite electrolytes had been enhanced by addition of 20 wt% silica filler. However, the conductivity was not greatly changed over 20 wt% content because the silica was sufficiently saturated in the polymer electrolytes. Diffraction peaks of PEO became weaker with the addition of inorganic fillers using XRD analysis. It showed that a crystallinity was proportionally reduced by increasing filler contents. The morphology of composite electrolyte films has been investigated by SEM. The heterogeneous morphology which silica was evenly dispersed by the strong adhesion of PEI was shown at higher contents of silica.

• Journal of Adhesion and Interface
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• v.23 no.3
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• pp.94-99
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• 2022

Ternary phased graphene/silica/EVOH nanocomposite coating materials were prepared via sol-gel process and solution blending process. From both SEM observations and XRD analysis, the exfoliated structure and dispersion state of graphene nanosheets and silica particles in the nanocomposites as well as the intercalated and exfoliated structure of the prepared graphene oxide were confirmed. The incorporation of GrO and silica at appropriate content resulted in remarkable improvement in oxygen barrier property of the ternary phased nanocompoiste-coated BOPP films, compared with that of binary(silica/EVOH) phased nanocomposite coating films, however, at excess amount of GrO and silica, very slight variation was observed due to incomplete exfoliation, dispersion of graphene tactoids, and formation of micro cracks in the silica clusters. In addition, the transparency of nanocomposite-coated film was investigated by measuring the light transmittance as a function of GrO contents, suggesting the possibility for the application of food packaging films.

• Advances in concrete construction
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• v.3 no.4
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• pp.317-331
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• 2015

This paper presents the effect of different micro-silica (MS) contents of 5, 10 and 15 wt.% as partial replacement of cement on mechanical and durability properties of high volume fly ash - recycled aggregate concretes (HVFA-RAC) containing 50% class F fly ash (FA) and 35% recycled coarse aggregate (RCA) as partial replacement of cement and natural coarse aggregate (NCA), respectively. The measured mechanical and durability properties are compressive strength, indirect tensile strength, elastic modulus, drying shrinkage, water sorptivity and chloride permeability. The effects of different curing ages of 7, 28, 56 and 91 days on above properties are also considered in this study. The results show that the addition of MS up to 10% improved the early age (7 days) strength properties of HVFA-RAC, however, at later ages (e.g. 28-91 days) the above mechanical properties are improved for all MS contents. The 5% MS exhibited the best performance among all MS contents for all mechanical properties of HVFA-RAC. In the case of measured durability properties, mix results are obtained, where 10% and 5% MS exhibited the lowest sorptivity and drying shrinkage, respectively at all ages. However, in the case of chloride ion permeability a decreasing trend is observed with increase in MS contents and curing ages. Strong correlations of indirect tensile strength and modulus of elasticity with square root of compressive strength are also observed in HVFA-RAC. Nevertheless, it is established in this study that MS contributes to the sustainability of HVFA-RAC significantly by improving the mechanical and durability properties of concrete containing 50%less cement and 35% less natural coarse aggregates.

• Elastomers and Composites
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• v.42 no.2
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• pp.102-106
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• 2007

Water swelling behaviors of SBR vulcanizates with different reinforcing systems of carbon black, silica without a coupling agent, and silica containing a coupling agent were studied. Distilled water and 3.5% NaCl solution were used as swelling media. The water swelling ratios in the distilled water were higher than those in the salt solution. The water swelling ratios of the carbon black-filled samples were lower than those of the silica-filled ones. For the silica-filled SBR vulcanizates, the specimens without the silane coupling agent had higher water swelling ratios than those containing it. Water swelling behaviors of SBR composites with different 1,2-unit contents were also compared. The water swelling ratios tended to decrease by increasing the 1,2-unit content.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.428-433
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• 2010

Waterborne polyurethane(WPU) was synthesized from isophorone diisocyanate(IPDI), poly(tetramethylene glycol)(PTMG), dimethylol propionic acid(DMPA), triethylamine(TEA), ethylenediamine(EDA) and 3-aminopropyl triethoxysilane(APS) as a coupling agent. Subsequently, WPU/silica nanocomposites with different silica contents(0 to 8 wt%) were prepared by performing sol-gel reactions with tetraethylorthosilicate in the WPU matrix. The average particle size of the nanocomposite solutions increased with increasing TEOS content. Also, the prepared nanocomposites showed better thermal stability than pure WPU.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2006.05a
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• pp.115-118
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• 2006

Nowadays the using of concrete is generalized, and construction material is demanded to be lightweight according to increasing the height and capacity of buildings. Therefore, it needs to develop the products having the great quality and various performance. Extruding concrete panel made of cement, silica source, and fiber, and it is a good lightweight concrete material in durability and thermostable. The silica of important ingredient is natural material with hish SiO2 contents and difficult in supply because of conservation of environment. On the other hand, the stone powder sludge discharged about 20-30% at making process of crushed fine aggregate and it is wasted. The stone powder sludge is valuable instead of silica ole because the stone powder sludge includes water of about 20-60%, SiO2 of about 64% and it has fine particles. This experiment is on the properties of extruding concrete panel using the stone powder sludge use instead of silica. From this experiment, we find that it is possible to replace the silica as stone power sludge up to 50%,

• Elastomers and Composites
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• v.37 no.2
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• pp.115-123
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• 2002

This study was carried out to investigate the influences or the vinyl content of polydimethylsiloxane(PDMS) and type of silica on the electrical and mechanical properties of silicone rubber far high voltage insulation. When the content of vinyl group was increased, cross-linking density and hardness were increased, and tensile strength, volume resistivity and tracking resistance were improved. The mechanical and electrical properties of silicone rubber reinforced with fumed silica were higher than those of silicone rubber reinforced with precipitated silica. It was found that the electrical and mechanical properties of silicone rubber were influenced greatly by the water contents of silica.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.223-226
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• 1999

The purpose of this study is no examine the combination effect on strength preperties of water-permeable concretes mixed with redispersible polymer, silica fume and polypropylene fibers for overlay in pavement. The water-permeable concrete with a water-cement ration of 25%, polymer-cement ratios of 0 to 10%, silica fume contents of 0 to 10% and polypropylene fiver contents of 0 to 1.5% are prepared, and tested for flexural strength, compressive strength and water permeability. It is concluded concretes are obtained at a polypropylene fiber content of 1.0% and a silica fume content of 10% with a void filling ratio of 50%. And the water-permeable concretes with a flexural strength of 14.1~28.0kgf/$\textrm{cm}^2$, a compressive strength of 71.2~128.0kgf/$\textrm{cm}^2$, and a coefficient of permeability of 1.22~2.52cm/s at a void filling ratio of 30% can be prepared. Also water-permeable concretes having flexural strength of 24.9~57.9kgf/$\textrm{cm}^2$, a compressive strength of 83.8~268.5kgf/$\textrm{cm}^2$, and a coefficient of permeability of 0.24~1.04cm/s at a void filling ratio of 50% can be prepared in the consideration of the mix proportioning factors.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.307-312
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• 1999

The purpose of this study is to ascertain the strength properties of water-permeable concrete with redispersible polymer powder, silica fume and polypropylene fibers. The water-permeable concrete using rediapersibel polymer powder with a water-cement ratio of 25%, polymer-cement ratios of 0 to 10%, silica fume contents of 0 to 10% and fiber contents of 0 to 1.5% are prepared, and tested for flexural strength, compressive strength and water permeability. From the test results, improvements in the strength properties of the water-permeable concrete due to the addition of the redispersible polymer powder, silica fume and fibers are discussed. It is concluded from the test results that the superior flexural and compressive strengths of water-permeable concretes are obtained at a propylene fiber content of 1.0% with a void filling ratio of 50%. And, the water-permeable concrete having a flexural strength of 15.6~28.4kgf/$\textrm{cm}^2$, a compressive strength of 63.5~120.6kgf/$\textrm{cm}^2$, and a coefficient of permeability of 1.14~1.70cm/s at a void filling ratio of 30% can be prepared. Also water-permeable concrete having a flexural strength of 35.6~57.9kgf/$\textrm{cm}^2$, a compressive strength of 164.0~290.0kgf/$\textrm{cm}^2$, and a coefficient of permeability of 0.19~1.04cm/s at a void filling ratio of 50% can be prepared in the consideration of the mix proprotioning factors.

• Asian-Australasian Journal of Animal Sciences
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• v.14 no.7
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• pp.935-940
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• 2001

To determine the effect of different growth stages and cultivars on the chemical composition of sorghum plant and its morphological fractions, samples of whole plant, leaf and stem of J.S-263, J.S-88 and Hegari cultivars, harvested at various growth stages were drawn for analysis. All the samples were analysed for their dry matter contents and various cell wall components such as NDF, ADF. hemicellulose, cellulose, lignin, cutin and silica. Significant increase in DM contents of whole sorghum plant, leaf and stem was observed with advancing stage of growth. The highest DM content was recorded in leaf fraction of the plant. All the cell wall constituents increased significantly in whole sorghum plant, leaf and stem as the plant matured. The maximum NDF, ADF, cellulose and lignin contents were observed in stem fraction, followed by whole plant. However, the hemicellulose, cutin and silica contents were higher in leaf fraction of the plant. The cultivars were found to have some effect on the chemical composition of whole plant, leaf and stem fractions. The results indicated that plant maturity had a much greater effect on the chemical composition of sorghum plant, whereas it was little affected by cultivars.