• Bulletin of the Korean Chemical Society
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• 제16권10호
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• pp.972-976
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• 1995

A trace amount of 4-biphenylcarboxylate having a pre-twisted biphenyl moiety was attached to a poly(methyl methacrylate) side chain and the fluorescence properties of the chromophore were investigated in various solvents such as ethyl acetate and butyl chloride. At room temperature, the polymer exhibited a distinct red shift of the short wavelength emission (325 nm) and an enhanced emission intensity around 430 nm upon excitation at the absorption red edge. The temperature dependence of the intensity ratio (R) of the 325 nm emission to the 430 nm emission was observed when exciting at the red edge over the temperature range between -20 and 60 ℃. However, the temperature dependence was not observed when exciting at the shorter wavelength. The Arrhenius plot of the R value shows the activation energy of 6.0 kJ/mol which is in good agreement with the energy required for the twist of the biphenyl moiety. Together with the results of red edge excitation effects it was concluded that the pre-twisted geometry of the biphenyl moiety is preserved by the restriction of the polymer chain to facilitate the formation of the twisted intramolecular charge transfer (TICT) state upon excitation.

• 한국분말재료학회지
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• 제28권1호
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• pp.51-58
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• 2021

The conversion of carbon preforms to dense SiC by liquid infiltration is a prospectively low-cost and reliable method of forming SiC-Si composites with complex shapes and high densities. Si powder was coated on top of a 2.0wt.% Y2O3-added carbon preform, and reaction bonded silicon carbide (RBSC) was prepared by infiltrating molten Si at 1,450℃ for 1-8 h. Reactive sintering of the Y2O3-free carbon preform caused Si to be pushed to one side, thereby forming cracking defects. However, when prepared from the Y2O3-added carbon preform, a SiC-Si composite in which Si is homogeneously distributed in the SiC matrix without cracking can be produced. Using the Si + C → SiC reaction at 1,450℃, 3C and 6H SiC phases, crystalline Si, and Y2O3 were generated based on XRD analysis, without the appearance of graphite. The RBSC prepared from the Y2O3-added carbon preform was densified by increasing the density and decreasing the porosity as the holding time increased at 1,450℃. Dense RBSC, which was reaction sintered at 1,450℃ for 4 h from the 2.0wt.% Y2O3-added carbon preform, had an apparent porosity of 0.11% and a relative density of 96.8%.

• 한국재료학회지
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• 제31권5호
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• pp.301-311
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• 2021

The conversion of all carbon preforms to dense SiC by liquid infiltration can become a low-cost and reliable method to form SiC-Si composites of complex shape and high density. Reactive sintered silicon carbide (RBSC) is prepared by covering Si powder on top of 0.5-5.0 wt% Y₂O₃-added carbon preforms at 1,450 and 1,500℃ for 2 hours; samples are analyzed to determine densification. Reactive sintering from the Y₂O₃-free carbon preform causes Si to be pushed to one side and cracking defects occur. However, when prepared from the Y₂O₃-added carbon preform, an SiC-Si composite in which Si is homogeneously distributed in the SiC matrix without cracking can be produced. Using the Si + C = SiC reaction, 3C and 6H of SiC, crystalline Si, and Y₂O₃ phases are detected by XRD analysis without the appearance of graphite. As the content of Y₂O₃ in the carbon preform increases, the prepared RBSC accelerates the SiC conversion reaction, increasing the density and decreasing the pores, resulting in densification. The dense RBSC obtained by reaction sintering at 1,500 ℃ for 2 hours from a carbon preform with 2.0 wt% Y₂O₃ added has 0.20 % apparent porosity and 96.9 % relative density.

• 대한치과교정학회지
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• 제27권5호
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• pp.825-837
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• 1997

실험적 치아이동 후 보정기간 동안 고정방법이 치주인대 섬유의 재배열에 미치는 영향을 알아보기 위하여, 체중 20kg 내외의 성견에서 상악 제 3절치와 견치 사이에 견인 스프링을 이용하여 120 gm의 교정력을 3주간 가한 후 좌측에는 유연성 고정장치로 0.0215 인치 multistrand wire를, 우측에는 견고성 고정장치로 폴리 에틸렌 리본을 레진 접착제로 각각 장착한 다음 4주, 8주, 또는 12주 후 희생시켜 치주조직의 변화를 방사선 사진, 광학 현미경 관찰을 통하여 분석한 바 다음과 같은 결과를 얻었다. 1. 치아이동 후 압박측에서는 치주인대 공간의 압축과 함께 치주인대섬유가 굵어진 소견을 보였으며 인장측의 치주인대섬유는 신장되어 보였다. 2. 보정 4주 후 유연성 고정군에서는 치주인대섬유의 재배열이 관찰되었으나 견고성 고정군에서는 관찰되지 않았다. 3. 보정 8주 후부터는 두 군 모두에서 치주인대섬유의 재배열 소견이 관찰되었으며, 두 군간 치주인대섬유의 재배열 차이는 보이지 않았다. 4. 보정기간 동안 치주인대섬유의 재배열은 압박측 보다 인장측에서 빠른 소견을 보였다. 이상의 결과는 치아이동 후 견고하게 고정한 보정방법에서도 치주인대섬유의 재배열이 일어남을 보여주었고, 치아 보정시 폴리에틸렌 리본으로 고정한 보정장치도 유용하게 사용될 수 있음을 시사하였다.

• 한국전자파학회논문지
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• 제17권2호
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• pp.184-192
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• 2006

개구 합성 레이더(SAR)는 지형의 고 해상도의 영상을 획득하는데 주로 사용된다. 본 논문은 X-band 주파수 대역의 차량 탑재형 개구 합성 레이더(automobile-based SAR) 시스템에 적용하기 위한 $16{\times}16$ 배열 안테나의 설계 및 제작에 관한 것이다. 본 논문에서 구현된 안테나는 레이돔, 방사체, 슬롯, 급전 구조 그리고 허니콤과 같은 여러 층의 구조로 되어 있으며 각 층들은 구조적인 그리고 전기적인 측면의 설계 요구 조건들을 만족하기 위하여 결합되어 있다. Strip-Slot-Foam-Inverted-Patch(SSFIP) 구조와 허니콤을 사용하여 넓은 동작 주파수 대역폭과 기구적인 안정성을 만족하였다. 측정 결과와 시뮬레이션 결과를 비교 분석하였으며 본 논문에서 설계한 안테나는 1.7 GHz의 동작 주파수 대역폭과 20 dB 미만의 side-lobe level, 각각 $5^{\circ}$의 빔 폭과 25 dBi의 이득을 가졌으며 측정된 결과는 광대역 SAR 시스템에 적용 가능할 것으로 판단된다.

• 대한치과교정학회지
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• 제50권4호
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• pp.268-277
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• 2020

This case report demonstrates two different uprighting mechanics separately applied to mesially tipped mandibular first and second molars. The biomechanical considerations for application of these mechanisms are also discussed. For repositioning of the first molar, which was severely tipped and deeply impacted, a novel cantilever mechanics was used. The molar tube was bonded in the buccolingual direction to facilitate insertion of a cantilever from the buccal side. By twisting the distal end of the cantilever, sufficient uprighting moment was generated. The mesial end of the cantilever was hooked over the miniscrew placed between the canine and first premolar, which could prevent exertion of an intrusive force to the anterior portion of the dentition as a side effect. For repositioning of the second molar, an uprighting mechanics using a compression force with two step bends incorporated into a nickel-titanium archwire was employed. This generated an uprighting moment as well as a distal force acting on the tipped second molar to regain the lost space for the first molar and bring it into its normal position. This epoch-making uprighting mechanics could also minimize the extrusion of the molar, thereby preventing occlusal interference by increasing interocclusal clearance between the inferiorly placed two step bends and the antagonist tooth. Consequently, the two step bends could help prevent occlusal interference. After 2 years and 11 months of active treatment, a desirable Class I occlusion was successfully achieved without permanent tooth extraction.

• Smart Structures and Systems
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• 제9권6호
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• pp.505-534
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• 2012

The present work deals with second order statistics of post buckling response of piezoelectric laminated composite cylindrical shell panel subjected to hygro-thermo-electro-mechanical loading with random system properties. System parameters such as the material properties, thermal expansion coefficients and lamina plate thickness are assumed to be independent of the temperature and electric field and modeled as random variables. The piezoelectric material is used in the forms of layers surface bonded on the layers of laminated composite shell panel. The mathematical formulation is based on higher order shear deformation shell theory (HSDT) with von-Karman nonlinear kinematics. A efficient $C^0$ nonlinear finite element method based on direct iterative procedure in conjunction with a first order perturbation approach (FOPT) is developed for the implementation of the proposed problems in random environment and is employed to evaluate the second order statistics (mean and variance) of the post buckling load of piezoelectric laminated cylindrical shell panel. Typical numerical results are presented to examine the effect of various environmental conditions, amplitude ratios, electrical voltages, panel side to thickness ratios, aspect ratios, boundary conditions, curvature to side ratios, lamination schemes and types of loadings with random system properties. It is observed that the piezoelectric effect has a significant influence on the stochastic post buckling response of composite shell panel under various loading conditions and some new results are presented to demonstrate the applications of present work. The results obtained using the present solution approach is validated with those results available in the literature and also with independent Monte Carlo Simulation (MCS).

• 마이크로전자및패키징학회지
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• 제26권3호
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• pp.81-88
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• 2019

본 연구에서는 그래핀 산화(graphene oxide, GO) 분말 첨가가 ball grid array(BGA) 패키지와 printed circuit board(PCB)간 Sn-3.0Ag-0.5Cu(SAC305) 무연솔더 접합부의 electromigration(EM) 수명에 미치는 영향에 대하여 보고 하였다. 솔더 접합 직후, Ni/Au표면처리된 패키지 접합계면에서는 $(Cu,Ni)_6Sn_5$가 생성되었으며 organic solderability preservative(OSP) 표면처리 된 PCB 접합계면에서는 $Cu_6Sn_5$ 금속간화합물(intermetallic compound, IMC)이 생성되었다. $130^{\circ}C$, $1.0{\times}10^3A/cm^2$ 전류밀도 하에서 EM 수명평가 결과, GO를 첨가하지 않은 솔더 접합부의 평균 파괴 시간은 189.9 hrs으로 도출되었고, GO를 첨가한 솔더 접합부의 평균 파괴 시간은 367.1 hrs으로 도출되었다. EM에 의한 손상은 패키지 접합계면에 비하여 pad 직경이 작은 PCB 접합계면에서 전자 유입에 의한 Cu의 소모로 인하여 발생하였다. 한편, 첨가된 GO는 하부계면의 $Cu_6Sn_5$ IMC와 솔더 사이에 분포하는 것을 확인하였다. 따라서, SAC305 무연솔더에 첨가된 GO가 전류 집중 영역에서 Cu의 빠른 확산을 억제하여 우수한 EM 신뢰성을 갖는 것으로 생각된다.

• Journal of Photoscience
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• 제7권4호
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• pp.143-148
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• 2000

Studies have been conducted to explore single electron transfer(SET) promoted photocyclization of ($\omega$-phthalimidoalkoxy)acetic acids(alkoxy=ethoxy, n-propoxy and n-butyloxy). Photocyclizations occur in methanol or acetone in high yields to produce cyclized products in which phthalimide carbonyl carbon is bonded to the carbon of side chain in place of the carboxylic group. These photocyclizations are thought to proceed through pathways involving intramolecular SET from oxygen in the $\alpha$-carboxymethoxy groups to the singlet excited state phthalimide moieties followed by decarboxylation of the intermediate $\alpha$-carboxymethoxy cation fadicals and cyclizations by radical coupling. The photocyclizations occur ca. three times faster in both methanol or acetone with one equivalent of sodium hydroxide added to the reactions and occur slower in acetone than in methanol. The efficient and regiselective cyclization reactions observed for photolyses in methanol represent synthetically useful processes for construction of heterocyclic compounds.

• 한국전자파학회:학술대회논문집
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• 한국전자파학회 2005년도 종합학술발표회 논문집 Vol.15 No.1
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• pp.317-322
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• 2005

Synthetic Aperture Radars(SAR) are used mainly for high-resolution imaging of the terrain. This paper describes the 16$\times$16 array antenna designed for an X-band, automobile-based SAR(AutoSAR) system. This antenna has the structure of several layers such as radome, radiators, slots, feed network, and honeycomb cores. Each layer is adhesively bonded to meet different combination of structural and electrical design requirements. Using the Strip-Slot-Foam-Inverted-Patch(SSFIP) structure and dogbone slots, a wide bandwidth and a structural hardness were achieved. Measurement results were compared with simulation results. It was observed that the SAR antenna had a bandwidth of 1.7 GHz, side-lobe levels of less than -20 dB, half-power beamwidth of 5$^{\circ}$, and gains of 25.0 dBi. The observed results show that the designed array antenna is suitable for the broadband AutoSAR system.