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The Oxidation Behavior of Sintered STS 316L at High-Temperature in the Air (STS 316L 소결체의 대기중 고온산화 거동)

  • Kim, Hye Seong;Lee, Jong Pil;Park, Dong Kyu;Ahn, In Shup
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.432-438
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    • 2013
  • In this study, analysis on the oxidation behavior was conducted by a series of high-temperature oxidation tests at both $800^{\circ}C$, $900^{\circ}C$ and 1000 in the air with sintered STS 316L. The weight gain of each oxidized specimen was measured, the oxidized surface morphologies and composition of oxidation layer were analyzed with Scanning Electron Microscope-Energy Dispersive x-ray Spectroscopy (SEM-EDS), finally, the phase change and composition of the oxidized specimen were shown by X-Ray Diffraction (XRD). As a result, the weight gain increased sharply at $1000^{\circ}C$ when oxidation test was conducted for 210 hours. Also, a plentiful of pores were observed in the surface oxidation layers at $900^{\circ}C$ for 210 hours. In addition, the following conclusions on oxidation behavior of sintered STS 316L can be obtained: $Cr_2O_3$ can be formed on pores by influxing oxygen through open-pores, $(Fe_{0.6}Cr_{0.4})_2O_3$ can be generated on the inner oxidation layer, and $Fe_2O_3$ was on the outer oxidation layer. Also, $NiFe_2O_4$ could be precipitated if the oxidation time was kept longer.

The Effect of SiO2 addition on Oxidation and Electrical Resistance Stability at High-temperature of P/M Fecralloy Compact (P/M Fecralloy 성형체의 고온산화 및 전기저항 안정성에 미치는 SiO2 첨가 효과)

  • Park, Jin-Woo;Ok, Jin-Uk;Jung, Woo-young;Park, Dong-kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.24 no.4
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    • pp.292-297
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    • 2017
  • A metallic oxide layer of a heat-resistant element contributes to the high-temperature oxidation resistance by delaying the oxidation and has a positive effect on the increase in electrical resistivity. In this study, green compacts of Fecralloy powder mixed with amorphous and crystalline silica are oxidized at $950^{\circ}C$ for up to 210 h in order to evaluate the effect of metal oxide on the oxidation and electrical resistivity. The weight change ratio increases as per a parabolic law, and the increase is larger than that observed for Fecralloy owing to the formation of Fe-Si, Fe-Cr composite oxide, and $Al_2O_3$ upon the addition of Si oxide. Si oxides promote the formation of $Al_2O_3$ and Cr oxide at the grain boundary, and obstruct neck formation and the growth of Fecralloy particles to ensure stable electrical resistivity.

Comparison of Forage Production and Nutritional Value of Italian ryegrass, Rye and Whole Crop Barley as Winter Forage Crops in Southern Region of Korea

  • So, Min Jeong;Kim, Hyeon Shup;Kim, Ji Hye;Lee, Sang-Hoon;Lee, Ki-Won;Jung, Jeong Sung;Sung, Kyung-Il;Peng, Jing lun;Park, Hyung Soo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.35 no.3
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    • pp.245-250
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    • 2015
  • This study was conducted from October 2014 to May 2015 to explore forage production and feed values of Italian ryegrass, Rye and whole crop barley as winter forage crops in the Southern region of Korea. The experimental location was over 10 points for each species and each sampling point area was $1m^2$ (Width: 1 m ${\times}$ Length: 1 m). Air mean temperature and rainfall in the Southern region of Korea during the experimental period was $6.95{\pm}5.75^{\circ}C$ and $70.45{\pm}54.68mm$, respectively. Fresh forage yield of Italian ryegrass, the most cultivated forage in the Southern region of Korea, was $44.4{\pm}7.0ton/ha$. The percentage of dry matter for whole crop barley was $28.9{\pm}7.0%$. Crude protein (CP) was higher in Italian ryegrass ($10.7{\pm}5.3%$) while total digestible nutrient (TDN) had the highest value in whole crop barley. Crude protein was not significantly different by location. However, the neutral detergent fiber (NDF), acid detergent fiber (ADF) and total digestible nutrient value of forage from Jeonbuk province were higher than in forage from Gyeongnam province.

Conjoined twins in Holstein calf : a case of thoracopagus siamese calf (젖소 흉부결합체 송아지 1례)

  • Hur, Tai-young;Kang, Seog-jin;Choe, Chang-yong;Jung, Young-Hun;Cho, Yong-il;Son, Dong-su;Ryu, Il-Sun;Kim, Hyeon-shup;Suh, Guk-hyun
    • Korean Journal of Veterinary Research
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    • v.46 no.1
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    • pp.63-66
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    • 2006
  • This case was found in Holstein cow suffering from dystocia. The twin calves in uterus were dead and removed by fetotomy. Gross anatomical analysis of thoracopagus siamese calf was carried out. Two normal heads were present on two necks, however, the twins were fused in the thoracic region. There were four forelimbs and an abnormal orientation of ribs. Two separate vertebral columns along the length of the animal ended with two tails. A single pericardium lay on the midline when opening the thorax. However, there were two almost completely hearts within the pericardial sac. Two heart were joined by a common cavernous venous sinuous. There were two sets of lungs. Each twins had a separate esophagus that entered a separated stomach. A large liver was fused and connected into two duodenums. The pelvis, large intestines and urinary tracts were separated. The twins are female and have a full complement of limb.

A Study on the Development of Compactability and Electrical Resistivity for P/M Fecralloy (P/M Fecralloy의 성형성 및 전기저항특성 향상에 관한 연구)

  • Park, Jin-Woo;Ko, Byung-Hyun;Jung, Woo-Young;Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.426-431
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    • 2016
  • The Fe-Cr-Al alloy system shows an excellent heat resistance because of the formation of an $Al_2O_3$ film on the metal surface in an oxidizing atmosphere at high temperatures up to $1400^{\circ}C$. The Fecralloy needs an additive that can act as a binder because of its bad compactability. In this study, the green compacts of STS434L and Al powder added to Fecralloy are oxidized at $950^{\circ}C$ for up to 210 h. Fecralloy and Al is mixed by two types of ball milling. One is vented to air and the other was performed in a sealed jar. In the case of Al addition, there are no significant changes in the electrical resistance. Before the oxidation test, Al oxides are present in the Fecralloy surface, as determined from the energy dispersive spectroscopy results. The addition of Al improves the compactability because of an increased density, and the addition of STS434L increases the electrical resistivity by forming a composite oxide.

The Effects of Si or Sn on the Sintered Properties of Fe-(Mo,Mn)-P Lean alloy (Fe-(Mo,Mn)-P계 Lean alloy의 소결특성에 미치는 Si와 Sn의 영향)

  • Jung, Woo-Young;Ok, Jin-Uk;Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.302-308
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    • 2018
  • A lean alloy is defined as a low alloy steel that minimizes the content of the alloying elements, while maintaining the characteristics of the sintered alloy. The purpose of this study is to determine the change in microstructure and mechanical properties due to the addition of silicon or tin in Fe-Mo-P, Fe-Mn-P, and Fe-Mo-Mn-P alloys. Silicon- or tin-added F-Mo-P, Fe-Mn-P, and Fe-Mo-Mn-P master alloys were compacted at 700 MPa and subsequently sintered under a $H_2-N_2$ atmosphere at $1120^{\circ}C$. The sintered density of three alloy systems decreases under the same compacting pressure due to dimensional expansion with increasing Si content. As the diffusion rate in the Fe-P-Mo system is higher than that in the Fe-P-Mn system, the decrease in the sintered density is the largest in the Fe-P-Mn system. The sintered density of Sn added alloys does not change with the increasing Sn content due to the effect of non-dimensional changes. However, the effect of Si addition on the transverse rupture strengthening enhancement is stronger than that of Sn addition in these lean alloys.

The Densification Properties of Distaloy AE-TiC Cermet by Spark Plasma Sintering (방전 플라즈마 소결에 의한 Distaloy AE-TiC 써멧의 치밀화 특성)

  • Cho, Ho-Jung;Ahn, In-Shup;Lee, Young-Hee;Park, Dong-Kyu
    • Journal of Powder Materials
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    • v.14 no.4
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    • pp.230-237
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    • 2007
  • The fabrication of Fe alloy-40 wt.%TiC composite materials using spark plasma sintering process after ball-milling was studied. Raw powders to fabricate Fe alloy-TiC composite were Fe alloy, $TiH_{2}$ and activated carbon. Fe alloy powder was Distaloy AE (4%Ni-1%Cu-0.5%Mo-0.01%C-bal.%Fe) made by Hoeganes company with better toughness and lower melting point. These powders were ball-milled in horizontal attrition ball mill at a ball-to-powder weight ratio of 30 : 1. After that, these mixture powders were sintered by using spark plasma sintering apparatus for 5 min at $1200-1275^{\circ}C$ in vacuum atmosphere under $10^{-3}$ torr. DistaloyAE-40 wt.%TiC composite was directly synthesized by dehydrogenation and carburization reaction during sintering process. The phase transformation of as-milled powders and sintered materials was confirmed using X-ray diffraction (XRD) and transmission electron microscope (TEM). The density and harness materials was measured in order to confirm the densification behavior. In case of DistaloyAE-40 wt.%TiC composite retained for 5 min at $1275^{\circ}C$, it has the relative density of about 96% through the influence of rapid densification and fine TiC particle reinforced Fe-based composites materials.

Efficacy of a Cue-Mate Intravaginal Insert and Injection of Prostaglandin $F_{a{\alpha}}$ for Synchronizing Estrus in Hanwoo Cattle

  • Cho, Sang-Rae;Kumar, Kuldeep;Yeon, Seong-Heum;Lee, Sung-Hwan;Kim, Ui-Hyung;Chung, Ki-Yong;Kim, Hyeon-Shup;Lee, Myeung Sik;Park, Chang-Seok;Yang, Byoung-Chul
    • Journal of Embryo Transfer
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    • v.29 no.4
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    • pp.321-325
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    • 2014
  • The present study was performed on farm animals to test the effectiveness of progesterone-releasing intravaginal device (Cue-Mate$^{(R)}$ 1.56 g) and injection of prostaglandin $F_{2{\alpha}}$ ($PGF_{2{\alpha}}$) for synchronization estrus in Hanwoo cattle. The cattle were at random stage of the estrus cycle. The cows were artificially inseminated at day 7 after Cue-Mate withdrawal, using commercial semen from Korean native bulls. There was a season effect on the estrus synchronization rate. It was higher in spring (94.3%) followed by winter (93.3%), autumn (90.4%) and summer (67.2%). In summary, The results of this study revealed that season has influences on estrus behavior of cattle with no significant effect on pregnancy rate. In summary, we suggest summer reproductive management to alleviate the effects of heat stress. It should be based on intensive cooling combined with hormonal treatment. Given that different subgroups of cows benefit differently from the treatments, selective hormonal administration should be considered.

The Effects of Vitamin A Administration to Heifer and Pregnant Cow on the Changes of Hormonal and Body Weight

  • Cho, Sang-Rae;Kim, Ui-Hyung;Kumar, Kuldeep;Lee, Seung-Hwan;Lee, Myeung-Sik;Kim, Hyeon-Shup;Lee, Hyun-Jae;Yang, Byoung-Chul
    • Journal of Embryo Transfer
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    • v.29 no.4
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    • pp.327-331
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    • 2014
  • The objective of this study was to investigate the interrelationship of weight and hormonal changes through the administration of vitamin A to first time pregnant heifers. A total of 28 Korean heifers was used for this study. The heifers were divided into two groups - with vitamin A (n=14) and without vitamin A (control) (n=14) in the feed. Body weight increased in vitamin A treated heifers starting 9 months until 15 months. After pregnancy, vitamin A treated heifers were found to maintain higher body weights than the control group. Pre-pregnancy and post pregnancy progesterone levels were not different between the two groups. Serum estradiol levels of heifers at different growth stages showed relatively higher E2 levels than the control. Also, the control during pregnancy may show higher serum E2 levels than the vitamin A treated heifers. The growth phase serum estradiol levels in heifers may be relatively higher than the control. During pregnancy it showed a similar trend. Serum levels of vitamin A treated heifers did not differ from pregnant heifers at 5 months of age. However, after 5 months from conception until 8 months of treatment it showed a high level. Serum cholesterol in pregnant cows was higher in the control group than the treatment from beginning until the end of pregnancy. This is considered to be related to fetus development during pregnancy, as well as the mother's health.

Studies on the Relationship between Number of Repeat and Duration of Estrous Behavior in Hanwoo and Holstein Cattle (한우와 젖소의 발정 행동 반복수와 지속 시간에 관한 연구)

  • Son, Jun-Kyu;Park, Seong-Jai;Baek, Kwang-Soo;Choi, You-Lim;Lee, Myeung-Sik;Kim, Sang-Bum;Kim, Hyeon-Shup;Shin, Seung-Oh;Park, Choon-Keun;Park, Soo-Bong
    • Journal of Embryo Transfer
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    • v.23 no.3
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    • pp.141-145
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    • 2008
  • The objective of this study was to investigate the relationship between behavioral signs and duration of estrous in Hanwoo and Holstein cattle for the prediction of optical insemination. Fifty two of 58 and 71 of 89 in Hanwoo and Holstein cows or heifers showed estrous exhibition within 72 h after 2 days following $PGF_{2}\alpha$ administration, respectively. The number of mounting and standing heat were 54.2 and 57.6, 59.4 and 53.5, 42.0 and 30.8 and 16.2 and 10.7 times in Hanwoo cows, Hanwoo heifers, Holstein cows and Holstein heifers, respectively. Duration of mounting were no significantly difference for Hanwoo cows ($21.2\pm11.3$), Hanwoo heifers ($19.9\pm11.4$), Holstein cows ($8.7\pm4.4$) and Holstein heifers ($16.9\pm8.0$). Duration of standing heat were significantly (p<0.05) shorter for Holstein cows ($5.4\pm3.4$) than for Hanwoo cows ($17.1\pm9.6$), Hanwoo heifers ($16.5\pm6.3$) and Holstein heifers ($15.0\pm7.2$). Time until mounting after injection of $PGF_{2}\alpha$ were significantly (p<0.05) longer for Holstein cows ($56.3\pm11.45$) than for Hanwoo cows ($42.71\pm10.44$), Hanwoo heifers ($36.6\pm8.21$) and Holstein heifers ($40.70\pm6.15$). Time until standing heat after injection of $PGF_{2}\alpha$ were significantly (p<0.05) longer for Holstein cows ($61.6\pm8.92$) than for Hanwoo cows ($46.2\pm11.49$), Hanwoo heifers ($42.7\pm6.06$) and Holstein heifers ($44.1\pm6.72$). In the results of this study, duration of standing heat was the shortest in Holstein cows ($5.4\pm3.4$). The estimation of estrous with Holstein cows has more difficulty because to significantly shorter duration of standing heat than for Hanwoo cows, Hanwoo heifers and Holstein heifers. The standing heat can be a good predictor for time of ovulation but it is concluded that mounting behavior could be the best predictor for time of ovulation.