• Proceedings of the Korea Water Resources Association Conference
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• 2005.09b
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• pp.1184-1184
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• 2005

• Elastomers and Composites
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• v.54 no.2
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• pp.156-160
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• 2019

The changes in the dispersion of carbon black in liquid polyisoprene under shear flow with time have been investigated by time-resolved ultra small-angle X-ray scattering (USAXS) method. The analyses of USAXS profile immediately after the start of shear flow clarified that the aggregates of carbon black with a mean radius of gyration of 14 nm and surface fractal dimension of 2.5 form the fractal network structure with mass-fractal dimension of 2.9. After the application of the shear flow, the scattering intensity increases with time at the observed whole entire q region, and then the a shoulder appears at $q=0.005nm^{-1}$, indicating that the agglomerate is broken and becomes smaller by shear flow. The analysis by the Unified Guinier/Power-law approach yielded several characteristic parameters, such as the sizes of aggregate and agglomerate, mass-fractal dimension of agglomerate, and surface fractal dimension of the primary particle. While the mean radius of gyration of the agglomerate decreases with time, the mean radius of gyration of the aggregate, mass fractal dimension, and surface fractal dimension don't change with time, indicating that the aggregates peel off the surface of the agglomerate.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.540-548
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• 2016

The non-Newtonian flow curves of sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals were obtained in various concentrations and temperatures by using a cone-plate rheometer. By applying non-Newtonian flow equation to the flow curves for AOT-water lamellar liquid crystal samples, the rheological parameters were obtained. Particular attention is given to the hysteresis loop detected when the liquid crystal samples are shear under increasing-decreasing shear stress modes which result in thixotropic and dilatant behavior. Sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals behave as weak gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, the dispersion still preserves much of its structure and consequently its shear stress remains higher than the values measured in the increasing shear rate mode.

• Wind and Structures
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• v.8 no.6
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• pp.427-442
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• 2005

Numerical and wind tunnel simulations of pollutant dispersion around rectangular obstacles with five aspect ratios have been conducted in order to identify the effects of flow patterns induced by buildings on plume dispersion in the near wake of buildings. An emission from a low source located upwind of obstacles was used in this simulation. The local flow patterns and concentrations around a cubical obstacle were initially investigated using three RANS turbulence models, (the standard $k-{\varepsilon}$, Shear Stress Transport (SST), Reynolds-Stress RSM turbulence model) and also using Large-eddy simulation (LES). The computed concentrations were compared with those measured in the wind tunnel. Among the three turbulence models, the SST model offered the best performance and thus was used in further investigations. The results show, for normal aspect ratios of width to height, that concentrations in the near wake are appreciably affected because of plume capture by the horseshoe vortex and convection by the vertical vortex pairs. These effects are less important for high aspect ratios. Vertical vortex pairs present a strong ability to exchange mass vertically and acts efficiently to reduce ground-level concentrations in the near wake.

• Asian Journal of Atmospheric Environment
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• v.11 no.3
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• pp.153-164
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• 2017

Odor dispersion around a cubic building from rooftop odor emissions was investigated using computational fluid dynamics (CFD). The Shear Stress Transport (here after SST) $k-{\omega}$ model in FLUENT CFD code was used to simulate the flow and odor dispersion around a cubic building. The CFD simulations were performed for three different configurations of cubic buildings comprised of one building, two buildings or three buildings. Five test emission rates were assumed as 1000 OU/s, 2000 OU/s, 3000 OU/s, 4000 OU/s and 5000 OU/s, respectively. Experimental data from wind tunnels obtained by previous studies are used to validate the numerical result of an isolated cubic building. The simulated flow and concentration results of neutral stability condition were compared with the wind tunnel experiments. The profile of streamline velocity and concentration simulation results show a reasonable level of agreement with wind tunnel data. In case of a two-building configuration, the result of emission rate 1000 OU/s illustrates the same plume behavior as a one-building configuration. However, the plume tends to the cover rooftop surface and windward facet of a downstream building as the emission rate increases. In case of a three-building configuration, low emission rates (<4000 OU/s) form a similar plume zone to that of a two-building configuration. However, the addition of a third building, with an emission rate of 5000 OU/s, creates a much greater odorous plume zone on the surface of second building in comparison with a two-building configuration.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.9
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• pp.835-843
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• 2008

We have fabricated the source-drain electrodes for OTFTs by screen printing method and manufactured Ag pastes as conductive paste. To obtain excellent conductivity and screen-printability of Ag pastes, the dispersion characteristics of Ag pastes prepared from two types of acryl resins with different molecular structures and Ag powder treated with caprylic acid, triethanol amine and dodecane thiol as surfactant respectively were investigated. The Ag pastes containing Ag powder treated with dodecane thiol having thiol as anchor group or AA4123 with carboxyl group(COOH) of hydrophilic group as binder resin exhibited excellent dispersity. But, Ag pastes(CA-41, TA-41, DT-41) prepared from AA4123 fabricated the insulating layer since the strong interaction between surface of Ag powder and carboxyl group(COOH) of AA4123 interfered with the formation of conduction path among Ag powders. The viscosity behavior of Ag pastes exhibited shear-thinning flow in the high shear rate range and the pastes with bad dispersion characteristic demonstrated higher shear-thinning index than those with good dispersity due to the weak flocculated network structure. The output curve of OTFT device with a channel length of 107 ${\mu}m$ using screen-printed S-D electrodes from DT-30 showed good saturation behavior and no significant contact resistance. And this device exhibited a saturation mobility of $4.0{\times}10^{-3}$ $cm^2/Vs$, on/off current ratio of about $10^5$ and a threshold voltage of about 0.7 V.

• Korean Journal of Food Science and Technology
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• v.21 no.6
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• pp.742-748
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• 1989

Rheological properties of gelatinized millet starch dispersions were evaluated. Gelatinized nonwaxy and waxy millet starch dispersion were typical pseudoplastic fluids. At constant shear rate, gelatinized waxy millet starch dispersion showed higher shear stress than nonwaxy millet starch dispersion. Flow behaviours of gelatinized nonwaxy and waxy millet starch dispersion were well fitted to Herschel-Bulkley equation and flow behaviour index (n) and consistency index (K) were strongly concentration dependent. There was a linear relationship between concentration of gelatinized starch dispersion and square root of yield stress. The concentrations of gelatinized nonwaxy and waxy millet starch dispersion where yield stresses become zero were estimated as 2.19 and 1.69%, respectively. Pseudoplastic constant (m) approaches to a constant value in each type of millet starch when the concentration of gelatinized starch dispersion was increased. As the measuring temperatures increase, n value was increased, whereas, K value was decreased. The activation energies of gelatinized nonwaxy and waxy millet starch dispersion were 2.89 and 3.18kcal/mol, respectively.

• Korea-Australia Rheology Journal
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• v.15 no.1
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• pp.19-25
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• 2003

Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2004.11a
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• pp.323-329
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• 2004

The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

• KSTLE International Journal
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• v.5 no.2
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• pp.49-51
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• 2004

The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.