• Journal of the Mineralogical Society of Korea
• /
• v.24 no.4
• /
• pp.301-312
• /
• 2011

The study on the atomic structure of iron-bearing silicate glasses has significant geological implications for both diverse igneous processes on Earth surface and ultra-low velocity zones at the core-mantle boundary. Here, we report experimental results on the effect of iron content on the atomic structure in iron-bearing alkali silicate glasses ($Na_2O-Fe_2O_3-SiO_2$ glasses, up to 16.07 wt% $Fe_2O_3$) using $^{29}Si$ and $^{17}O$ solid-state NMR spectroscopy. $^{29}Si$ spin-lattice ($T_1$) relaxation time for the glasses decreases with increasing iron content due to an enhanced interaction between nuclear spin and unpaired electron in iron. $^{29}Si$ MAS NMR spectra for the glasses show a decrease in signal intensity and an increase in peak width with increasing iron content. However, the heterogeneous peak broa-dening in $^{29}Si$ MAS NMR spectra suggests the heterogeneous distribution of $Q^n$ species around iron in iron-bearing silicate glasses. While nonbridging oxygen ($Na-O-Si$) and bridging oxygen (Si-O-Si) peaks are partially resolved in $^{17}O$ MAS NMR spectrum for iron-free silicate glass, it is difficult to distinguish the oxygen clusters in iron-bearing silicate glass. The Lorentzian peak shape for $^{29}Si$ and $^{17}O$ MAS NMR spectra may reflect life-time broadening due to spin-electron interaction. These results demonstrate that solid-state NMR can be an effective probe of the detailed structure in iron-bearing silicate glasses.

• Economic and Environmental Geology
• /
• v.12 no.2
• /
• pp.95-104
• /
• 1979

The position of any point on the earth's surface can be. represented in the spherical coordinates by surface spherical harmonics. Since geomagnetic field is a function of position on the earth, it can be also expressed by spherical harmonic analysis as spherical harmonics of trigonometric series of $a_m({\theta})$ cos $m{\phi}$ and $b_m({\theta})$ sin $m{\phi}$. Coefficients of surface spherical harmonics, $a_m({\theta})$ and $b_m({\theta})$, can be drawn from the components of the geomagnetic field, declination and inclination, and vice versa. In this paper, components of geomagnetic field, declination and inclination in the Korean peninsula are obtained by spherical harmonic analysis using the Gauss coefficients calculated from the world-wide magnetic charts of 1960. These components correspond to the values of normal geomagnetic field having no disturbances of subsurface mass, structure, and so on. The vertical and total components offer the zero level for the interpretation of geomagnetic data obtained by magnetic measurement in the Korean peninsula. Using this zero level, magnetic anomaly map is obtained from the data of airborne magnetic. prospecting carried out during 1958 to 1960. The conclusions of this study are as follows; (1) The intensity of horizontal component of normal geomagnetic field in Korean peninsula ranges from $2{\times}10^4$ gammas to $2.45{\times}10^4$ gammas. It decreases about 500 with the increment of $1^{\circ}$ in latitude. Along the same. latitude, it increases 250 gammas with the increment of $1^{\circ}$ in longitude. (2) Intensity of vertical component ranges from $3.85{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases. about 1000 gammas with the increment of $1^{\circ}$ in latitude. Along the same latitude, it decreases. 150~240 gammas with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude than in lower latitude. (3) Total intensity ranges from $4.55{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases 600~700 gammas with the increament of $1^{\circ}$ in latitude. Along the same latitude, it decreases 10~90 gammas. with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude as the case of vertical component. (4) The declination ranges from $-3.8^{\circ}$ to $-11.5^{\circ}$. It increases $0.6^{\circ}$ with the increment of $1^{\circ}$ in latitude. Along the same latutude, it increases $0.6^{\circ}$ with the increment of l O in longitude. Unlike the cases of vertical and total component, the rate of change is considerably larger in lower latitude than in higher latitude. (5) The inclination ranges from $57.8^{\circ}$ to $66.8^{\circ}$. It increases about $1^{\circ}$ with 'the increment of $1^{\circ}$ in latitude Along the same latitude, it dereases $0.4^{\circ}$ with the increment of $1^{\circ}$ in longitude. (6) The Boundaries of 5 anomaly zones classified on the basis of the trend and shape of anomaly curves correspond to the geologic boundaries. (7) The trend of anomaly curves in each anomaly zone is closely related to the geologic structure developed in the corresponding zone. That is, it relates to the fault in the 3rd zone, the intrusion. of granite in the 1st and 5th zones, and mountains in the 2nd and 4th zones.

• Korean Chemical Engineering Research
• /
• v.53 no.1
• /
• pp.46-52
• /
• 2015

A leaching kinetics was conducted for the purpose of recovery of praseodymium in sulfuric acid ($H_2SO_4$) from REE slag concentrated by the smelting reduction process in an arc furnace as a reactant. The concentration of $H_2SO_4$ was fixed at an excess ratio under the condition of slurry density of 1.500 g slag/L, 0.3 mol $H_2SO_4$, and the effect of temperatures was investigated under the condition of 30 to $80^{\circ}C$. As a result, praseodymium oxide ($Pr_6O_{11}$) existing in the slag was completely converted into praseodymium sulfate ($Pr_2(SO_4)_3{\cdot}8H_2O$) after the leaching of 5 h. On the basis of the shrinking core model with a shape of sphere, the first leaching reaction was determined by chemical reaction mechanism. Generally, the solubility of pure REEs decreases with the increase of leaching temperatures in sulfuric acid, but REE slag was oppositely increased with increasing temperatures. It occurs because the ash layer included in the slag is affected as a resistance against the leaching. By using the Arrhenius expression, the apparent activation energy of the first chemical reaction was determined to be $9.195kJmol^{-1}$. In the second stage, the leaching rate is determined by the ash layer diffusion mechanism. The apparent activation energy of the second ash layer diffusion was determined to be $19.106kJmol^{-1}$. These relative low activation energy values were obtained by the existence of unreacted ash layer in the REE slag.

• Journal of Conservation Science
• /
• v.29 no.3
• /
• pp.223-229
• /
• 2013

It is not known in details for the A.D. period as the archaeomagnetic dating method to be fully facilitated in Korea but it has prepared for the revised shape of standard curve to trace the geomagnetic field variation, and there were cases to increase the survey on relics on the B.C. period to find out for the detailed archaeomagnetic field variation on the Bronze Age to the Early Iron Age. Furthermore, the survey cases on the relics on the Neolithic Age began to emerge a little by little archaeomagnetic field variation of the Neolithic Age through 34 pieces of the archaeomagnetic measurement data as making active advancement around mid-western region. Data is insufficient yet that it is difficult to find out the detailed trend of modification but it is estimated for approximate appearance. The archaeomagnetic field variation of the Neolithic Age made changes without breaking away from the scope of changes in the A.D. period as in the same way with the Bronze Age, and comparing to the variation of archaeomagnetic field for the Bronze Age, the magnetic inclination shifted within the scope of having almost no difference, but the declination is shown to skewed toward the east in its overall appearance. In addition, the comparison was made with the data of the Jomon Age in Japan and the archaeomagnetic measurement data of Korea has a little bit more depth for while the declination is skewed toward the east for 10 degree or more compared to those of Japan. However, in the part where the data is concentrated most intensely, the data for both countries has significant part to overlap to each other that the archaeomagnetic field variation of the Neolithic Age of Korea showed overall similar variation with certain partial changes when compared to those of Japan.

• Journal of the Korean Institute of Rural Architecture
• /
• v.21 no.2
• /
• pp.19-26
• /
• 2019

Pungsu theory is important one in the site selection and lay-out of traditional Korean village and house. In this aspect, Study with a view of Pungsu theory might be used as a proper method for understanding the traditional architecture in Korea. In this context, this study analyzes the Jeong, Dong-Ho's house which is designated no. 19 as an important folk cultural heritage, located in Jigok Ochu-gil 133-62, Godeok-myon, Yesan-gun, Chungnam province. The analysis of the site and space lay-out is carried out by Yong(Dragon), Hyoel(Auspicious Spot), Sa(Sands), Su(Water) aspects of the Pungsu(Fengshui) Hyungsei-ron. The house is depending upon soft dragon vein connecting with a earth type rear mountain. It looks southeast direction, Gonjwasonhyang(乾坐巽向). The hyeolseong(穴星) has classical venus shape, and there is no faults relatively. The Sasinsa condition is almost perfect that right blue dragon and left white tiger surround the hyeol with 3-4 layers and the facing mountain covers the front open area. The water flowing from inside of left and right mountain is joined in front of the house so it could stop flowing out of vital energy. Bibo forest(裨補樹) is placed properly to protect the easy disclose of water outlet. The house is well organized western house(西四宅) by analysis of Dongseosataek-ron(東西四宅論). Through the analysis, I found that the house has good Pungsu(Fengshui) environment fitted with Pungsu Hyungsei-ron. The house composed of small thatched roof is enclosed several times by low hills of back, left and right side. So it is believed that the site might be carefully evaluated by Yong, Hyoel, Sa, Su of Hyeongsei-ron for knowing whether the site condition could minimize the demage by strong winds and protect from the winter cold wind and secure water for drinking and farming and then selected. The method of Pungsu for evaluating the geographical condition of surrounding of a site is used as a traditional site analysis method for evaluating the suitability of long-term well and safe residence.

• The Journal of Engineering Geology
• /
• v.16 no.2 s.48
• /
• pp.201-214
• /
• 2006

To study the relationship between rainfall conditions and landslides according to a geological condition in land-slides areas such asJangheung Kyounggi, Sangju and Pohang Kyoungbuk, the data of rainfall and landslides are investigated and analyzed. Many landslides occurred at these areas because of the heavy rainfall in two or four days of the summer 1998. The data of rainfall are collected in observatories within a 50km radius from landslides occurrence areas, and the data of landslides are investigated directly in landslides areas. The data of rainfall are the accumulative rainfall and the rainfall intensity, and the data of landslides are the occurrence frequency considering the geological condition. These data are analyzed statistically to know the relationship the rainfall and landslides. The landslides are concentrated in the heavy rainfall area from the analysis of these data. It knows that the land-slides are triggered by the heavy rainfall. Meanwhile, the rainfall factors such as the accumulative rainfall, the rain-fall intensity and the dropping time are different in each landslides area, and the shape and frequency of landslides are different respectively. The landslides have occurred in the area of high accumulative rainfall, while the land-slides have not occurred around that area. Therefore, the rainfall is very important factor induced by the landslides, and the accumulative rainfall is really related to the frequency of landslides.

• Journal of Space Technology and Applications
• /
• v.2 no.1
• /
• pp.41-51
• /
• 2022

CubeSat is a satellite platform that is widely used not only for earth observation but also for space exploration. CubeSat is also used in magnetic field investigation missions to observe space physics phenomena with various shape configurations of magnetometer instrument unit. In case of magnetic field measurement, the magnetometer instrument should be far away from the satellite body to minimize the magnetic disturbances from satellites. But the accommodation setting of the magnetometer instrument is limited due to the volume constraint of small satellites like a CubeSat. In this paper, we investigated that the magnetic field interference generated by the cube satellite was analyzed how much it can affect the reliability of magnetic field measurement. For this analysis, we used a reaction wheel and Torque rods which have relatively high-power consumption as major noise sources. The magnetic dipole moment of these parts was derived by the data sheet of the manufacturer. We have been confirmed that the effect of the residual moment of the magnetic torque located in the middle of the 3U cube satellite can reach 36,000 nT from the outermost end of the body of the CubeSat in a space without an external magnetic field. In the case of accurate magnetic field measurements of less than 1 nT, we found that the magnetometer should be at least 0.6 m away from the CubeSat body. We expect that this analysis method will be an important role of a magnetic cleanliness analysis when designing a CubeSat to carry out a magnetic field measurement.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.6
• /
• pp.721-728
• /
• 2016

97% of water on earth exists in the form of seawater. Therefore, the use of marine resources is one of the most important research issues at present. The use of seawater is expanding in various fields (seawater desalination, cooling water for nuclear power plants, deep seawater utilization, etc.). Seawater intake systems utilizing sand filters in order to take in clean seawater are being actively employed. For the intake pipe used in this system, assuring equal intake flows through the respective holes is very important to improve the efficiency of the intake and filtering process. In this study, we analyzed the efficiency of the dual structure perforated pipe used in the seawater intake system using 3D numerical simulations and the inflow rate according to the gap of the up holes. In the case of decreasing gaps in the up holes toward the pipe end, the variation of the total inflow rate was small in comparison with the other cases. However, the standard deviation of the inflow rate through the up holes was the lowest in this case. Also, stable flow occurred, which can improve the efficiency of the intake process. In the future, a sensitivity analysis of the various conditions should be performed based on the results of this study, in order to determine the factors influencing the efficiency, which can then be utilized to derive optimal designs suitable for specific environments.

• Journal of Conservation Science
• /
• v.31 no.1
• /
• pp.75-86
• /
• 2015

A scale Armor is usually excavated in a scattered form weakened by corrosion after its burial. Therefore, they should be brought into the indoor in a safe environment for the on-site conservation treatment as it was excavated. They should be placed on a stable support with a reinforced base in the indoor treatment. In this process, the bottom surface which can not be observed after the conservation treatment is placed for a record by actual survey and photography. But this method had a limit on figuring out the whole aspects of the artifact. For compensating the defect, duplication of the artifact was considered as an alternative method for the previous two methods in the case of conservation of the scale Armor from Jinyoung 2-Area, Gimhae. Neck guard was excavated in a distorted form by the earth pressure, and was hard to recognize the original shape. However, whole real material of its original form was secured through the combination of each duplicated lamellae. Throughout the application of the duplication technique in the process of conservation of scale Armor and neck guard, it could secure the real material of the bottom surface and elevate the understanding of the artifact. Moreover, a constitution of the armor could be identified more effectively.

• Journal of the Korean earth science society
• /
• v.41 no.6
• /
• pp.557-574
• /
• 2020

The purpose of this study is to analyze the cause of high PM2.5 mass concentrations in Cheongju for the period of non-Asian dust days using the weather chart, the stream lines at 850 hPa, the backward trajectory, and the weather and air quality model. As a result of analyzing the time series of PM2.5 concentrations and weather charts for the episodic days in Cheongju, the weather patterns were shown in related to long-range transport of PM2.5 from China or surrounding areas. In fact, in the PM2.5 time series, 60-80 ㎍ m-3, which is more than 2-3 times higher than the concentration attributed to Cheongju activities, was observed as a background concentration related to long-range transport. The distribution of high PM2.5 concentration was typically dependent on the locations of the high and low pressures above the ground while the upper jet stream passed through the Korean Peninsula. Consequently, the high PM2.5 concentration in Cheongju is due to massive air pollutants in the form of smog originated from industrial, household and energy combustion sources of Beijing and other nearby regions of China. These air pollutants move along a fast zonal wind caused by the atmospheric pressure arrangement. high concentration of PM2.5 in Cheongju City is because the mass of air pollutants in the form of smog generated from industrial, household and energy combustion origins in Beijing or other nearby regions of China move along a fast wind speed zone according to the atmospheric pressure arrangement of long-distance transportation. Air pollutants including PM2.5 show an M-shaped pattern that passes through the topography of the Cheongju basin from north to south as a belt or band-shaped pollutant. The ground high pressure according to the above-ground high pressure expansion area and cut-off low or low pressure arrangement, or the bands in the form of river stems appear in a gradual incremental pattern that changes into a U-shape under the influence of the wind.