• 제목/요약/키워드: self assembled monolayer

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금 나노입자가 배열된 STO기판에서 성장된 Y-Ba-Cu-O박막의 Flux pinning 특성 (Flux pinning properties of Y-Ba-Cu-O thin films grown on STO substrates with assembled Au nanoparticles)

  • 오세권;장건익;이초연;현옥배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.375-375
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    • 2009
  • For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. We report measurements of critical current in $YBa_2Cu_3O_{7-\delta}$ films deposited by PLD on $SrTiO_3$ substrates decorated with Au nanoparticles. Au nanoparticles were synthesized on STO substrates with self assembled monolayer. Microstructural analysis of the obtained YBCO films was performed by using cross-section transmission electron microscopy(TEM). Phase and textural analysis was done using X-ray diffraction. The surface morphology and surface roughness(Ra) of the layers was measured by atomic force microscopy(AFM).

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분자구조에 따른 Viologen 단분자막의 전기화학적 특성 연구 (Study on the Electrochemical Behavior of the Viologen Monolayers by Different Chemical Structure)

  • 옥진영;신훈규;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.918-921
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    • 2003
  • The electrochemical behavior of vilogen self-assembled monolayer has been investigated with QCM, which has been known as ng order mass detector. The self-assembly process of viologen was monitored using resonant frequency(${\Delta}F$) and resonant resistance(R). The QCM measurements indicated a mass adsorption for viologen assembling on the gold surface with a frequency change about 300, 135 Hz and calculated its surface coverage($\Gamma$) to be $5.02{\times}10^{-9}$ and $1.64{\times}10^{-9}mol/cm^2$. Also a reversible redox process was observed and analyzed with an ionic interaction at the Viologen/solution interface using ${\Delta}F$.

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다양한 유기분자막의 마찰특성 비교 (Comparison of the Tribological behaviors of Various Organic Molecular Films)

  • 김두인;안효석;김충현
    • Tribology and Lubricants
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    • 제17권5호
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    • pp.386-390
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    • 2001
  • Monolayers such as self-assembled monolayer (SAM) have received considerable attention to reduce stiction and friction in micro-devices and microelectromechanical systems (MEMS). Various organic molecular films were investigated to obtain better understanding of their tribological behaviors and adhesion property. The organic molecular films studied in this work are: epoxysilane SAMs, octadecyltricholosilane (OST), multi-layers composed of epoxysilane SAMs, poly[styrene-b-(ethylene-co-butylene)-b-styrene](SEBS) and compound of epoxy resin and poly (paraphenylene)(EP/PPP). The pull-off forces of these films were also obtained from force-distance curves measured in static mode of operation of atomic force microscope(AFM). Tribological tests were conducted with a ball-on-flat reciprocating friction tester. The OST showed the lowest pull-off force, indicating its low adhesion property. It was revealed that, the OST, EP/PPP and the multi-layer of epoxysilane SAMs, SEBS and EP/PPP exhibited good tribological properties at the lower load (0.3 N) whereas the OST showed best performance at the higher load (1.8 N).

나노스피어 리소그라피를 이용한 OLED 광추출 효율의 향상 (Improvement of Extraction Efficiency of OLED by Nanosphere Lithography)

  • 한광민;여종빈;이현용
    • 한국전기전자재료학회논문지
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    • 제24권12호
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    • pp.1002-1009
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    • 2011
  • The light extraction efficiency of top-emitting organic light-emitting diode (OLED) was improved by insertion of corrugation patterns between indium tin oxide and organic layers. The corrugation patterns was fabricated by nanosphere lithography, which could form a self-assembled particle monolayer over a large area. The electrical and optical properties for the OLED devices fabricated by vacuum evaporation, were investigated. We have demonstrated the enhancement of the power efficiency of corrugated OLED. As a result, the power efficiency of the corrugated OLED was found to be more than 42%.

Polymer brush: a promising grafting approach to scaffolds for tissue engineering

  • Kim, Woonjung;Jung, Jongjin
    • BMB Reports
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    • 제49권12호
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    • pp.655-661
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    • 2016
  • Polymer brush is a soft material unit tethered covalently on the surface of scaffolds. It can induce functional and structural modification of a substrate's properties. Such surface coating approach has attracted special attentions in the fields of stem cell biology, tissue engineering, and regenerative medicine due to facile fabrication, usability of various polymers, extracellular matrix (ECM)-like structural features, and in vivo stability. Here, we summarized polymer brush-based grafting approaches comparing self-assembled monolayer (SAM)-based coating method, in addition to physico-chemical characterization techniques for surfaces such as wettability, stiffness/elasticity, roughness, and chemical composition that can affect cell adhesion, differentiation, and proliferation. We also reviewed recent advancements in cell biological applications of polymer brushes by focusing on stem cell differentiation and 3D supports/implants for tissue formation. Understanding cell behaviors on polymer brushes in the scale of nanometer length can contribute to systematic understandings of cellular responses at the interface of polymers and scaffolds and their simultaneous effects on cell behaviors for promising platform designs.

Dynamic Effects of Bouncing Water Droplets on Superhydrophobic Tungsten Oxide nanowire surfaces

  • 곽근재;이미경;용기중
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.25.1-25.1
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    • 2009
  • The effects of surface energyon the wetting transition for impinging water droplets were experimentally investigated on the chemically modified WOx nanowire surfaces. We could modify the surface energy of the nanostructures through chemisorption of alkyltrichlorosilanes with various carbon chain lengths and by the UV-enhanced decomposition of self assembled monolayer (SAM) molecules chemically adsorbedon the array. Three surface wetting states could be identified through the balance between antiwetting and wetting pressures. This approach establishes simple strategy for the design criteria for water-repellent surface to impinging droplets.

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Detection of viability Change of Escherichia coli O157:H7 using Surface Plasmon Resonance

  • 박광원;이우창;이원홍;최정우
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XII)
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    • pp.635-638
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    • 2003
  • For the acute assessment on biological toxicity of wastewater, surface plasmon resonance(SPR) based cell viability detection was performed using gold surface-confined cell as a result of adhesion-modifying chemicals. Escherichia coli O157:H7 (E. coli O157:H7) was investigated after exposure to EDTA. Cells were immobilized on gold coated slide glass for SPR analysis by the method of cross-linking carboxyl group on the bacterial surface with amine group of poly-L-lysine that had been coupled to the gold surface modified by a self-assembled monolayer of 11-mercaptounde canoic acid (11-(MUA)). Reflective intensity of each flow step was changed with respect to confect of ethylenediaminetetraacetic acid (EDTA) disodium salt and phosphate-buffered saline (PBS) solution. The proposed detection technique can be used for biological toxicity test.

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Extended Gate를 이용한 MOSFET형 단백질 센서 제작 및 특성 (Fabrication and chracteristics of MOSFET type protein sensor using extended gate)

  • 이상권;손영수;최시영
    • 센서학회지
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    • 제16권2호
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    • pp.104-109
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    • 2007
  • In this paper, we have fabricated on extended-gate field effect transistor (EGFET)-type protein sensor for the application to a CRP detection. We used the self-assembled monolayer (SAM) to adhere or entrap biomolecules, namely CRP antibodies. The experimental result shows that the proposed SAM is well immobilized on the gold gate surface. So the drain current was varied by antigen-antibody interactions on the gate surface because of the CRP charge. Experimental results related to the formation of SAM, antibody, antigen were obtained by measuring the electrical characteristics of the EGFET device.

Fabrication of Micro/Nano-patterns using MC-SPL(Mechano-Chemical Scanning Probe Lithography) Process

  • Sung, In-Ha;Kim, Dae-Eun
    • International Journal of Precision Engineering and Manufacturing
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    • 제4권5호
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    • pp.22-26
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    • 2003
  • In this work, a new non-photolithographic micro-fabrication technique is presented. The motivation of this work is to overcome the demerits of the most commonly used photolithographic techniques. The micro-fabrication technique presented in this work is a two-step process which consists of mechanical scribing followed by chemical etching. This method has many advantages over other micro-fabrication techniques since it is simple, cost-effective, rapid, and flexible. Also, the technique can be used to obtain a metal structure which has sub-micrometer width patterns. In this paper, the concept of this method and its application to microsystem technology are described.

미세탐침기반 기계-화학적 리소그래피공정에 의한 마이크로/나노패턴 제작 (Fabrication ofMicro/Nano-patterns using MC-SPL (Mechano-Chemical Scanning Probe Lithography) Process)

  • 성인하;김대은
    • 한국정밀공학회지
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    • 제19권11호
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    • pp.228-233
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    • 2002
  • In this work, a new non-photolithographic micro-fabrication technique is presented. The motivation of this work is to overcome the demerits of the most commonly used photolithographic techniques. The micro-fabrication technique presented in this work is a two-step process which consists of mechanical scribing followed by chemical etching. This method has many advantages over other micro-fabrication techniques since it is simple, cost-effective, rapid, and flexible. Also, the technique can be used to obtain a metal structure which has sub-micrometer width patterns. In this paper, the concept of this method and its application to microsystem technology are described.