• Bulletin of the Korean Chemical Society
• /
• 제31권11호
• /
• pp.3159-3162
• /
• 2010

To realize highly selective recognition of oxalate in water, a new chemosensing ensemble that behaves highly selective colorimetric recognition of oxalate in water at pH 7.4 has been developed. The ensemble was constructed by a pyrrole containing mononuclear copper complex and chromeazurol S. The ensemble shows a highly selective recognition of oxalate through an obvious color change from blue to yellow upon the addition of oxalate, whereas, other dicarboxylates such as malonate, succinate, fumarate, maleate, glutarate, adipate, phthalate, isophthalate and terephthalate do not induce any noticeable color changes. The oxalate recognition process is not significantly affected by other coexisting dicarboxylate.

• 한국통신학회논문지
• /
• 제30권3C호
• /
• pp.153-157
• /
• 2005

이동 통신 시스템에서 도플러 효과에 의해 주파수 선택적 페이딩 현상이 발생한다. DS-CDMA 시스템은 주파수 선택적 채널 하에서 다중 사용자 간섭의 영향에 의해서 성능이 급격하게 저하 된다. 이를 극복하기 위해서 다중 반송파 변조 방법을 채택하여 주파수 선택적 채널 효과를 극복할 수 있다. 그리고 다중 사용자 접속으로 인한 간섭 문제는 다중 사용자 검출 기법을 적용하여 해결 할 수 있다. 본 논문에서는 블라인드 다중 사용자 검출 기법과 병렬 간섭 제거기를 결합한 형태의 블라인드 MOE-PIC 다중 사용자 검출 기법을 제안하였다. 모의실험 결과 제안한 방식이 기존의 방식보다 더 좋은 성능을 나타내는 것을 알 수 있었다.

• Bulletin of the Korean Chemical Society
• /
• 제35권3호
• /
• pp.765-769
• /
• 2014

An analytical methodology was developed for qualitative and quantitative impurity profiling of the coloring agent Sudan III by high-performance liquid chromatography (HPLC)-diode array detection (DAD). The impurities in commercial Sudan III were characterized by comparison of their retention times and UV spectra with those of authentic standards. Four impurities regulated by International Committees in Sudan III were quantified by HPLC-selective UV detection. The impurities in Sudan dye were successfully separated on a reversed phase C18-column within 25 min and sensitively detected by UV spectrometry at two selective wavelengths. Method validation was conducted to determine linearity, precision, accuracy, and limit of quantification (LOQ). The linear dynamic range extended from 0.002 to 4.0%, with a correlation coefficient (R2) greater than 0.995. The LOQs of the impurities ranged from 8.04 to $54.29{\mu}g/mg$. Based on the established method, the levels of regulated impurities in five commercial Sudan III dyes were determined.

• 한국정보통신학회논문지
• /
• 제13권5호
• /
• pp.974-979
• /
• 2009

본 논문에서는 주파수 선택적 Rayleigh 페이딩 채널에서 MIMO 검출 기법의 성능이 이론적으로 분석된다. 제시되는 MIMO 검출 구조는 시공간 결합기와 ZF 검출기로 구성되며 이 구조는 $N_T$ 송신안테나, $N_R$ 수신안테나, 그리고 L 다중경로 성분을 활용하는 시스템으로 $LN_R-N_T+1$의 다양성을 얻을 수 있음을 보인다. 또한 주파수 선택적 Rayleigh 페이딩 채널에서의 BER 공식이 제공되고 시뮬레이션 결과와 비교 분석한다.

• 한국통신학회논문지
• /
• 제28권2C호
• /
• pp.172-180
• /
• 2003

본 논문에서는 선택적 부호화를 위한 매크로 블록 단위의 변화영역 검출 알고리즘을 제안한다. 기존의 변화 영역 검출 방식에서는 잡음의 영향으로 배경 매크로 블록임에도 불구하고 변화 영역으로 인식되는 문제점이 존재한다. 본 논문에서는 이러한 문제점을 개선하기 위해 잡음의 영향에 강인한 새로운 검정 통계량을 제안한다. 실험결과(그림1∼3)에서처럼 제안된 검정통계량을 이용한 변화영역 검출 알고리즘이 정확한 매크로 블록 단위의 분할결과를 나타냄을 알 수 있다. 또 표 1에 주어진 것처럼 제안된 방식이 기존 방식보다 프레임당 변화 영역에 속하는 평균 매크로 블록의 수가 55∼60% 줄어들기 때문에 부호화할 관심영역의 개수가 최소화되어 선택적 부호화와 같은 영상 부호화에 적용할 경우에 적은 비트량으로 우수한 재생화질을 얻을 수 있다.

• Bulletin of the Korean Chemical Society
• /
• 제32권1호
• /
• pp.122-126
• /
• 2011

A new phosphorescent cyclometalated heteroleptic iridium (III) complex with an ancillary ligand of 4-azacrownpicolinate was prepared and its metal ion selective phosphorescent chemosensing behavior was investigated. The new iridium (III) complex exhibits notable phosphorescence quenching for Hg2+ in aqueous 50% acetonitrile solution with respect to the selective phosphorescent detection of various metal ions including $Li^+,Na^+,K^+,Cs^+,Mg^{2+},Ca^{2+},Ba^{2+},Fe^{2+},Ni^{2+},Cu^{2+},Zn^{2+},Ag^+,Pb^{2+},Cd^{2+},Cr^{2+},Cr^{3+}$ and $Hg^{2+}$. The phosphorescence quenching for $Hg^{2+}$ increased linearly with increasing concentration of $Hg^{2+}$ in the range of $10{\mu}M-700{\mu}M$ even in the presence of other metal ions, except for $Cu^{2+}$. Consequently, the new iridium (III) complex has the potential to be utilized for the determination of parts per million levels of $Hg^{2+}$ in aqueous acetonitrile media.

• 한국표면공학회지
• /
• 제55권3호
• /
• pp.156-163
• /
• 2022

An ammonium ion with a size and charge similar to that of potassium can bind to valinomycin, which is used as an ion carrier for potassium, and cause a meaningful interference effect on the detection of potassium ions. Currently, there are few ion sensors that correct the interference effect of ammonium ions, and there are few studies that specifically suggest the mechanism of the interference effect. By fabricating a SPCE-based potassium ion-selective electrode, the electromotive force was measured in the concentration range of potassium in the nutrient solution, and the linear range was measured to be 10^-5 to 10^-2 M, and the detection limit was 10^-5.19 M. And the interference phenomenon of the potassium sensor was investigated in the concentration range of ammonium ions present in the nutrient solution. Therefore, a data-based analysis strategy using deep learning was presented as a method to minimize the interference effect.

• 대한원격탐사학회:학술대회논문집
• /
• 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
• /
• pp.289-291
• /
• 2003

Selective logging is currently a widely adopted management practice throughout the tropics. Monitoring of spatial extent and intensity of such logging is, therefore, becoming an important issue for sustainable management of forest. This study explores the possibility of using vegetation indices and Landsat 7 ETM+ image for this purpose. Two dataset acquired on 2002 and 2000 of Labanan concession area East Kalimantan, Indonesia were used. Three different vegetation indices (MSAVI, SAVI and NDVI) slicing and differentiating methods were tested. The results showed that the MSAVI is superior with overall accuracy of 77% and kappa 0.64.

• 대한임베디드공학회논문지
• /
• 제12권4호
• /
• pp.231-238
• /
• 2017

Detecting small infrared targets from the low-SCR images at a long distance is very hard. The previous Local Contrast Method (LCM) algorithm based on the human visual system shows a superior performance of detecting small targets by a background suppression technique through local contrast measure. However, its slow processing speed due to the heavy multi-scale processing overhead is not suitable to a variety of real-time applications. This paper presents a lightweight real-time small target detection algorithm, called by the Improved Selective Local Contrast Method (ISLCM), to reduce the scale-invariant computational overhead. The proposed ISLCM applies the improved local contrast measure to the predicted selective region so that it may have a comparable detection performance as the previous LCM while guaranteeing low scale-invariant computational load by exploiting both adaptive scale estimation and small target feature feasibility. Experimental results show that the proposed algorithm can reduce its computational overhead considerably while maintaining its detection performance compared with the previous LCM.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
• /
• pp.85-85
• /
• 2013

Label-free, sensitive and selective detection methods with high spatial resolution are critically required for future applications in chemical sensor, biological sensor, and nanospectroscopic imaging. Here I describe the development of Plasmon Resonance Energy Transfer (PRET)-based molecular imaging in living cells as the first demonstration of intracellular imaging with PRET-based nanospectroscopy. In-vivo PRET imaging relied on the overlap between plasmon resonance frequency of gold nanoplasmonic probe (GNP) and absorption peak frequencies of conjugated molecules, which leads to create 'quantized quenching dips' in Rayleigh scattering spectrum of GNP. The position of these dips exactly matched with the absorption peaks of target molecules. As another innovative application of PRET, I present a highly selective and sensitive detection of metal ions by creating conjugated metal-ligand complexes on a single GNP. In addition to conferring high spatial resolution due to the small size of the metal ion probes (50 nm in diameter), this method is 100 to 1,000 folds more sensitive than organic reporter-based methods. Moreover, this technique achieves high selectivity due to the selective formation of Cu2+complexes and selective resonant quenching of GNP by the conjugated complexes. Since many metal ion ligand complexes generate new absorption peak due to the d-d transition in the metal ligand complex when a specific metal ion is inserted into the complex, we can match with the scattering frequency of nanoplasmonic metal ligand systems and the new absorption peak.