• Title/Summary/Keyword: segmented cell

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An Empirical Study about the Segmented Cell in Anode Side of PEMFC

  • Kim, Jae-Ho;Sohn, Young-Jun;Kim, Min-Jin;Park, Gu-Gon;Yim, Sung-Dae
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.357-360
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    • 2009
  • The present study focused on the segmented cell which has the similar performance to unaltered (not segmented) cell in real operating condition. Many literatures have been made the segmented cell to observe the behavior of local current density distribution in the single cell. However, it has been lack of scheme to segment the cell in that the detailed interpretation of segmenting in analytic point of view was insufficient. Hence, the basic idea of segmenting was introduced to determine the component to be segmented in anode side of unit cell. The electrical contact/bulk resistance was measured by using four wire/probe method through each part of cell components including MEA, GDL, Bipolar Plate and Current Collector. Electron transport mechanism was predicted by comparing resistance values which were obtained from the experiment. As a result, this offered a great benefit to segment the cell efficiently. With this method further experiments would be conducted in research areas which require current density distribution at the same operating condition as unaltered cell.

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Computational Justification of Current Distribution Measurement Technique Via Segmenting Bipolar Plate in Fuel Cells (분리판 분할을 통만 연료전지의 전류분포 측정법에 대한 수치적 검증)

  • Choi, Yong-Jun;Lee, Gi-Yong;Kang, Kyung-Mun;Kim, Whan-Gi;Ju, Hyun-Chul
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.1
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    • pp.1-11
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    • 2010
  • Current distribution measurement technique based on a segmented bipolar plate (BP) has been widely adopted to visualize the distribution of current density in a polymer electrolyte membrane. However, a concern is raised how closely the current density of a segmented BP can approach that of a corresponding non-segmented membrane. Therefore, in this paper, the accuracy of the measurement technique is numerically evaluated by applying a three-dimensional, two-phase fuel cell model to a $100\;cm^2$ area fuel cell geometry in which segmented BPs and non-segmented membrane are combined together. The simulation results reveal that the errors between the current densities of the segmented BPs and non-segmented membrane indeed exist, predicting the maximum relative error of 33% near the U-turn regions of the flow-field. The numerical study further illustrates that the erroneous result originates from the BPs segmented non-symmetrically based on the flow channels that allows some currents bypassing flow channels to flow into its neighboring segment. Finally, this paper suggests the optimal way for bipolar plate segmentation that can minimize the deviation of current measured in a segmented BP from that of a corresponding membrane region.

Evaluation of Properties and Fabrication of Tubular Supports Segmented-in-Series Solid Oxide Fuel Cell (SOFC) (세그먼트 SOFC 관형 세라믹 지지체의 제작 및 특성 평가)

  • Yun, Ui-Jin;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul;Han, Kyoo-Seung
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.3
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    • pp.214-219
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    • 2010
  • In this study, we fabricated tubular ceramic support for segmented-in-series solid oxide fuel cell (SOFC) by using CSZ(CaO-stabilized $ZrO_2$) as main material and activated carbon as pore former. Thermal expansion properties of ceramic support with different amounts of activated carbon were analyzed by using dilatometer to decide a suitable sintering temperature. The tubular ceramic supports with different amounts of activated carbon (5, 10, 15wt.%) were fabricated by the extrusion technique. After sintering at $1100^{\circ}C$ and $1400^{\circ}C$ for 5h., cross section and surface morphology of tubular ceramic support were analyzed by using SEM image. Also, the porosity, mechanical property, gas permeability of tubular ceramic supports was measured. Based on these results, we established the suitable fabrication technique of tubular ceramic support for segmented-in-series SOFC.

Fabrication and Cell Properties of Flattened Tube Segmented-in-Series Solid Oxide Fuel Cell-Stack Using Decalcomania Paper (전사지를 이용한 다전지식 평관형 고체산화물 연료전지 제작 및 셀 특성)

  • An, Yong-Tae;Ji, Mi-Jung;Park, Sun-Min;Shin, Sang-Ho;Hwang, Hae-Jin;Choi, Byung-Hyun
    • Korean Journal of Materials Research
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    • v.23 no.3
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    • pp.206-210
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    • 2013
  • In the segmented-in-series solid-oxide fuel cells (SIS-SOFCs), fabrication techniques which use decalcomania paper have many advantages, i.e., an increased active area of the electrode; better interfacial adhesion property between the anode, electrolyte and cathode; and improved layer thickness uniformity. In this work, a cell-stack was fabricated on porous ceramic flattened tube supports using decalcomania paper, which consists of an anode, electrolyte, and a cathode. The anode layer was $40{\mu}m$ thick, and was porous. The electrolyte layers exhibited a uniform thickness of about $20{\mu}m$ with a dense structure. Interfacial adhesion was improved due to the dense structure. The cathode layers was $30{\mu}m$ thick with porous structure, good adhesion to the electrolyte. The ohmic resistance levels at 800, 750 and $700^{\circ}C$ were measured, showing values of 1.49, 1.58 and $1.65{\Omega}{\cdot}cm^2$, respectively. The polarization resistances at 800, 750 and $700^{\circ}C$ were measured to be 1.63, 2.61 and $4.17cm^2$, respectively. These lower resistance values originated from the excellent interfacial adhesion between the anode, electrolyte and cathode. In a two-cell-stack SOFC, open-circuit voltages(OCVs) of 1.915, 1.942 and 1.957 V and maximum power densities(MPD) of 289.9, 276.1 and $220.4mW/cm^2$ were measured at 800, 750 and $700^{\circ}C$, respectively. The proposed fabrication technique using decalcomania paper was shown to be feasible for the easy fabrication of segmented-in-series flattened tube SOFCs.

Segmented Filamentous Bacteria Induce Divergent Populations of Antigen-Specific CD4 T Cells in the Small Intestine

  • Yi, Jaeu;Jung, Jisun;Han, Daehee;Surh, Charles D.;Lee, You Jeong
    • Molecules and Cells
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    • v.42 no.3
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    • pp.228-236
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    • 2019
  • CD4 T cells differentiate into $ROR{\gamma}t/IL$-17A-expressing cells in the small intestine following colonization by segmented filamentous bacteria (SFB). However, it remains unclear whether SFB-specific CD4 T cells can differentiate directly from naïve precursors, and whether their effector differentiation is solely directed towards the Th17 lineage. In this study, we used adoptive T cell transfer experiments and showed that naïve CD4 T cells can migrate to the small intestinal lamina propria (sLP) and differentiate into effector T cells that synthesize IL-17A in response to SFB colonization. Using single cell RT-PCR analysis, we showed that the progenies of SFB responding T cells are not uniform but composed of transcriptionally divergent populations including Th1, Th17 and follicular helper T cells. We further confirmed this finding using in vitro culture of SFB specific intestinal CD4 T cells in the presence of cognate antigens, which also generated heterogeneous population with similar features. Collectively, these findings indicate that a single species of intestinal bacteria can generate a divergent population of antigen-specific effector CD4 T cells, rather than it provides a cytokine milieu for the development of a particular effector T cell subset.

PEMFC Characterization Study by in-situ Analysis Method (In-Situ 분석법에 의한 연료전지 특성 연구)

  • Kim, Young-Min;Lee, Jong-Hyun;Im, Se-Joon;Ahn, Byung-Ki;Lim, Tae-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.3
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    • pp.208-215
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    • 2009
  • PEMFC stack power output is needed to be around 100 kW to meet the requirements of automotive application and scaling-up the active area of the stack cells will allow a higher power. In the case of scaling-up the active area of cells, it is difficult to obtain uniform in-plane internal conditions such as temperature, relative humidity and stoichiometry of the feed gas. These ununiformity with the location in the cell would affect both the performance and durability of the stack, so it is important to understand phenomena in the cell for improving them. In this study, the current density, electrochemical resistance and performance distribution measurement was performed to understand the ununiformity in a single cell using in-situ method; (1) Current Density Distribution (CDD) Device and (2) Segmented Cell Fixture. The influence of location of feed gas on the performance of a single cell was experimentally measured and discussed by using a segmented single cell which was composed of 8 compartments. The correlation between the location and performance in a single cell was discussed by these two tools and it was extended between the local characterization and the durability in a MEA by comparing the used cell with a fresh one. It was also studied in terms of electrochemistry by Electrochemical Impedance Spectroscopy.

Fabrification of Segmented Flat-Tubular SOFC cell (Segmented 평관형 SOFC 셀 제조)

  • Park, Sung-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Choi, Heon-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.137.1-137.1
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    • 2010
  • SOFC cell 하나의 전위차는 약1.1V이기 때문에 발전용으로 사용하기 위해서는 수많은 단전지를 직렬로 연결하는 구조가 필요하다. 이러한 stack의 디자인에서 발생하는 문제를 획기적으로 개선한 형태가 하나의 지지체에 셀을 직렬로 연결함으로 전극의 선폭 및 단위 셀 간의 간격이 기존 평판형, 원통형에 비해 대폭 축소되어 전극 및 연결재의 저항손실을 최소화할 수 있는 Segmented형 SOFC이다. Segmented SOFC에 적용하기 위한 세라믹 다공성 지지체는 연료와 공기에서의 화학적 안정성, 셀의 구성소재와 반응이 없으며 열팽창계수가 유사해야하는 특성을 가져야하는데 그 중에서도 지지체로써 적절한 기계적 강도와 높은 가스투과도가 요구되어진다. 본 연구에서는 고온에서 안정한 Spinel의 MgAl2O4를 주성분으로 하는 다공성 지지체를 압출 성형하여 평관형으로 제조하였으며 활성탄을 기공형성제로 사용하여 연료의 공급이 원활하도록 약 30%의 기공율을 가지는 다공성 세라믹 지지체를 제조하였다. 제조된 세라믹 지지체에 연료극(NiO/YSZ), 전해질(TZ8Y), 공기극(LSM)을 코팅하여 실제 SOFC에 적용이 가능함을 확인하였다.

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A 10-bit Current-steering DAC in 0.35-μm CMOS Process

  • Cui, Zhi-Yuan;Piao, Hua-Lan;Kim, Nam-Soo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.44-48
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    • 2009
  • A simulation study of a 10-bit two-stage DAC was done by using a conventional current switch cell. The DAC adopts the segmented architecture in order to reduce the circuit complexity and the die area. The 10-bit CMOS DAC was designed in 2 blocks, a unary cell matrix for 6 MSBs and a binary weighted array for 4 LSBs, for fabrication in a 0.35-${\mu}m$ CMOS process. To cancel the accumulation of errors in each current cell, a symmetrical switching sequence is applied in the unary cell matrix for 6 MSBs. To ensure high-speed operation, a decoding circuit with one stage latch and a cascode current source were developed. Simulations show that the maximum power consumption of the 10-bit DAC is 74 mW with a sampling frequency of 100 MHz.

Segmented Ulnar Transposition to Defect of Ipsilateral Radius in the Forearm (전완골 분절의 전위 이식술)

  • Chung, Duke-Whan;Han, Soo-Hong;Lee, Jae-Hoon;Kwon, Boo-Kyung
    • Archives of Reconstructive Microsurgery
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    • v.16 no.2
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    • pp.125-132
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    • 2007
  • Introduction: Ulna is nearly equal to radius in function and bony architecture and strength in forearm. But in lower extremity, fibula is 1/5 of tibia in anatomic and functional point so we can find fibula transposition is commonly used in defect of tibia. We cannot find other article about segmental forearm bone transposition in man. The purpose of this study was to report our clinical and functional result of undergoing segmented transposition of ipsilateral ulna with its own vascular supply in defect of radius in 6 cases. Material and method: From June 1994 to October 2007, 7 segmented bone transpositional grafts in forearm were performed in Kyung Hee Medical Center. The distribution of age was from 20 years old to 73 years old. There was male in 6 cases and female in 1 case. The causes of operation were giant cell tumor in 1 case and traumatic origin in 6 cases; it was nonunion in 2 cases and fracture with severe comminution in 4 cases. Ipsilaterally segmented ulna keeping its own vascular supply was transported to defect of radius in severe traumatic patients and one patient whose tumor in radius had been excised. Transported ulna was fixed to proximal and distal radius remnants by plate and screw. In one case with giant cell tumor, transported ulna was connected to radius across wrist joint as wrist joint fusion. Joint preserving procedures were performed in 6 cases with crushing injury of radius. Results: We could obtain solid bony union in all cases and good functional results. The disadvantage was relative shortening of forearm, but we could overcome this problem. Conclusion: We think that ipsilateral segmented ulna transposition keeping its own vascular supply to radius can be perfomed with one of procedures in cases with wide defect in radius.

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Gut-residing Microbes Alter the Host Susceptibility to Autoantibody-mediated Arthritis

  • Lee, Hyerim;Jin, Bo-Eun;Jang, Eunkyeong;Lee, A Reum;Han, Dong Soo;Kim, Ho-Youn;Youn, Jeehee
    • IMMUNE NETWORK
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    • v.14 no.1
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    • pp.38-44
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    • 2014
  • K/BxN serum can transfer arthritis to normal mice owing to the abundant autoantibodies it contains, which trigger innate inflammatory cascades in joints. Little is known about whether gut-residing microbes affect host susceptibility to autoantibody-mediated arthritis. To address this, we fed C57BL/6 mice with water containing a mixture of antibiotics (ampicillin, vancomycin, neomycin, and metronidazol) for 2 weeks and then injected them with K/BxN serum. Antibiotic treatment significantly reduced the amount of bacterial genomic DNA isolated from fecal samples, in particular a gene encoding 16S ribosomal RNA derived from segmented filamentous bacteria. Arthritic signs, as indicated by the arthritic index and ankle thickness, were significantly attenuated in antibiotic-treated mice compared with untreated controls. Peyer's patches and mesenteric lymph nodes from antibiotic-treated mice contained fewer IL-17-expressing cells than those from untreated mice. Antibiotic treatment reduced serum C3 deposition in vitro via the alternative complement pathway. IL-$17^{-/-}$ congenic C57BL/6 mice were less susceptible to K/BxN serum-transferred arthritis than their wild-type littermates, but were still responsive to treatment with antibiotics. These results suggest that gut-residing microbes, including segmented filamentous bacteria, induce IL-17 production in GALT and complement activation via the alternative complement pathway, which cause the host to be more susceptible to autoantibody-mediated arthritis.