• Title/Summary/Keyword: secondary materials

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Three-dimensional Numerical Modeling of Fluid Flow and Heat Transfer in Continuously Cast Billets (연속주조 빌렛의 3차원 열 및 유동해석)

  • Lee, Sung-Yoon;Lee, Sang-Mok;Park, Joong-Kil;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.20 no.5
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    • pp.290-299
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    • 2000
  • A three-dimensional model was developed in order to simulate heat and fluid flow of a continuous casting billet. The model was coded with the general-purpose CFD program FIDAP, using the finite element method. The present model consists of 2 individual calculation schemes, named model 1 and model 2. Mold region only was calculated to check the pouring stream through submerged nozzle with model 1. Entire region, which consists of mold, secondary cooling, radiation cooling was calculated to predict crater end position, temperature profile and solid shell profile(model 2). Standard $k-{\bullet}\hat{A}$ turbulence model has been applied to simulate the turbulent flow induced by submerged nozzle. Enthalpy method was adopted for the latent heat of solidification. Fluid flow in mushy zone was treated using variable viscosity approach. The more casting speed and superheat increased, the more metallurgical length increased. The shell thickness at the mold exit is proved to be mainly controlled by superheat by the present simulation. It may be concluded that the present model can be successfully applied far the prediction of heat and fluid flow behavior in the continuous casting process.

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A perspective on the 'Differentiated Curriculum'based on the results of implementing current 'differentiated classes' in mathematics (현행 수준별 수업 분석에 기초한 수준별 교육과정의 성공을 위한 처방)

  • 황혜정
    • Journal of Educational Research in Mathematics
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    • v.8 no.1
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    • pp.183-197
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    • 1998
  • Many schools of the secondary level have been recently carrying out 'differentiated class'based on ability grouping between classed(DC). They are usually consisted of three levels; high level available to enriched course, middle level, and low level available to supplemental course. Phrhaps, almost all of the schools might nave executed DC before 2000 year. To do this, a lots of teachers have to develop differentiated teaching and learning materials for themselves. But, these mateirals are usually consisted of differentiated mathematics not on 'content'but on 'items'. So, for the successful 7th differentiated curriculum, the issues such as teaching and learning methods, materials, and evaluation system should be considered in depth focused on DC. .Decide issues related to DC(for example, mathematical contents, methods, activities, class speed,extra)based not on teachers or experts but on students. .Differentiate teaching and learning mateirals according to DC and develop the materials(including guidelines, supplementary books, multimedia, extra) based not on mathematical items but on mathematical contents. .Introduce new mathematical concepts or laws using not only not only definition and explanation but also concrete examples or problems. .Suggest differentiated diverse projects related to mathematical subjects suitable to enhance students` thinking ability to each class. .Have students to develop projects successfully by collecting, representing, analyzing, and interpreting data through communications in a cooperative learning environment.

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Effect of W Addition on the Hardenability of Low-Carbon Boron Steels (저탄소 보론강의 경화능에 미치는 W 첨가의 영향)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.24 no.9
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    • pp.488-494
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    • 2014
  • The effect of tungsten (W) addition on the hardenability of low-carbon boron steels was investigated using dilatometry, microstructural observations and secondary ion mass spectroscopy. The hardenability was discussed with respect to transformation behaviour aspects depending on the segregation and precipitation of boron at austenite grain boundaries. A critical cooling rate producing a hardness corresponding to 90 % martensite structure was measured from a hardness distribution plot, and was used as a criterion to estimate hardenability at faster cooling rates. In the low-carbon boron steel, the addition of 0.50 wt.% W was comparable to that of 0.20 wt.% molybdenum in terms of critical cooling rate, indicating hardenability at faster cooling rates. However, the addition of 0.50 wt.% W was not more effective than the addition of .0.20 wt.% molybdenum at slower cooling rates. The addition of 0.20 wt.% molybdenum completely suppressed the formation of eutectoid ferrite even at the slow cooling rate of $0.2^{\circ}C/s$, while the addition of 0.50 wt.% W did not, even at the cooling rate of $1.0^{\circ}C/s$. Therefore, it was found that the effect of alloying elements on the hardenability of low-carbon boron steels can be differently evaluated according to cooling rate.

Catalytic Oxidation of Phenol Analogues in Aqueous Medium Over Fe/SBA-15

  • Mayani, Suranjana V.;Mayani, Vishal J.;Kim, Sang-Wook
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.3009-3016
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    • 2012
  • This study evaluated the use of iron-impregnated SBA-15 (Fe/SBA-15) as a catalyst for the oxidative degradation of persistent phenol analogues, such as 2-chlorophenol (2-CP), 4-chlorophenol (4-CP), 2-nitrophenol (2-NP), 4-nitrophenol (4-NP) and 2,4,6-trichlorophenol (2,4,6-TCP) in water. The oxidation reactions were carried out with reaction time, concentration of the phenols, amount of the catalysts, reaction temperature, pH of the reaction mixture as the process variables with or without using hydrogen peroxide as the oxidizing agent. The conversion achieved with Fe/SBA-15 at 353 K for 2-CP, 4-CP, 2-NP, 4-NP, 2,4,6-TCP was 80.2, 71.2, 53.1, 62.8, 77.3% in 5h with a reactant to $H_2O_2$ mole ratio of 1:1, and 85.7, 65.8, 61.9, 63.7, 78.1% in the absence of $H_2O_2$, respectively. The reactions followed pseudo first order kinetics. The leachability study indicated that the catalyst released very little iron into water and therefore, the possibility of secondary pollution is negligible.

Recovery of Indium for the Recycling of End-of-life Flat Panel Display Devices (폐 디스플레이 재활용을 위한 인듐 회수기술)

  • Uhm, Sunghyun;Cho, Sungsu;Lee, Sooyoung
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.389-393
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    • 2015
  • Recovery of indium from secondary sources have been attracting over years not only because of increasing demand together with development of flat panel display industry but also industrial criticality of indium. Applied technology to recover indium for recycling of end-of-life FPD devices can be broadly divided into three major steps, disassembly or dismantling, enrichment or upgrading, and refining or purification. In addition, advanced technology such as zone-refining can be employed for ultra-high purity products. In this mini-review, we present currently applied technologies for recovery of indium and the outlook for total recycling of FDP devices.

Development of Silicon Coated by Carbon with PVDF Precursor and Its Anode Characteristics for Lithium Batteries (PVDF 전구체를 이용한 탄소 도포 실리콘 재료의 개발 및 리튬이차전지 음극특성)

  • Doh, Chil-Hoon;Jeong, Ki-Young;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Yun, Mun-Soo;Choi, Im-Goo;Park, Cheol-Wan;Lee, Kyeong-Jik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.7
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    • pp.636-643
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    • 2006
  • Si-C materials were synthesized by the heating the mixture of silicon and polyvinylidene fluoride (PVDF). The electrochemical properties of the Si-C materials as the high capacitive anode materials of lithium secondary batteries were evaluated by the galvanostatic charge-discharge test through 2032 type $Si-C{\mid}Li$ coin cells. Charge-discharge tests were performed at C/10 hour rate(C = 372 mAh/g). Initial discharge and charge capacities of $Si-C{\mid}Li$ cell using a Si-C material derived from PVDF(20wt.%) were found to be 1,830 and 526 mAh/g respectively. The initial discharge-charge characteristics of the developed Si-C electrode were analyzed by the electrochemical galvanostatic test adopting the capacity limited charge cut-off condition(GISOC). The range of reversible specific capacity IIE(intercalation efficiency at initial discharge-charge) and IICs(surface irreversible specific capacity) were 216 mAh/g, 68 % and 31 mAh/g, respectively.

Purification of pivalic acid : its evaluation as a temperature standard reference material (온도표준 기준 물질로의 개발을 위한 pivalic acid의 고순도 정제)

  • M. Karthikeyan;M. B. Koss;M. E. Glicksman;Kee-Kahb Koo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.151-162
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    • 1997
  • The suitability of pivalic acid was confirmed as a secondary temperature standard material. Triple-point cells of pivalic acid were obtained by using combined process of vacuum distillation with zone refining. A detailed description of the purification process was given. The melting curves were used as criteria for determination of purities of pivalic acid. Triple points of these cells with purity of 99.9997% were measured to be $35.956\pm 0.003^{\circ}C$ by using the melting plateau curves. Thus the triple point cells of pivalic acid appear to be able to use for the calibration of thermistor thermometers with moderate precision.

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A Study on the Improvement of Adhesive Strength of Between Metal and Polyethylene Materials (금속재와 폴리에틸렌 재료간의 접착강도 향상에 대한 연구)

  • Lee, Ji-Hoon;Kim, Hyun-Ju;Jung, Dong-Ho;Rhee, Kyong-Yop
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.12
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    • pp.143-148
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    • 2007
  • Polyethylene is a typical hydrophobic material and it is difficult to bond the polyethylene material with metal material. Thus, it is important to modify the surface of polyethylene material to improve the bonding strength between the polyethylene and the metal materials. In this study, the surface modification of polyethylene material was investigated to improve the interfacial strength between the polyethylene and the steel materials. Polyethylene material was surface-modified in a plasma cleaner using an oxygen gas. Two cases of composites (surface-modified pelyethylene/steel composite and regular (as-received) pelyethylene/steel composite) were fabricated using a secondary bonding method. Shear and bending tests have been performed using the two cases of composites. The results showed that the contact angle did not change much as the modification time increased. However, the contact angle decreased from ${\sim}76^{\circ}\; to\;{\sim}41^{\circ}$ with the modification. The results also showed that the shear strength and the bending strength were improved about 3030 % and 7 %, respectively when the polyethylene was plasma-modified using an oxygen gas.

Growth of ZnSnO3 Thin Films on c-Al2O3 (0001) Substrate by Pulsed Laser Deposition

  • Manh, Trung Tran;Lim, Jae-Ryong;Yoon, Soon-Gil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.5
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    • pp.297-302
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    • 2014
  • $La_{0.5}Sr_{0.5}CoO_3$ (LSCO) electrode thin films with a resistivity of ~ 1,600 ${\mu}{\Omega}cm$ were grown on c-$Al_2O_3$ (0001) substrate. $ZnSnO_3$ (ZTO) thin films with different thicknesses were directly grown on LSCO/c-$Al_2O_3$ (0001) substrates at a substrate temperature that ranged from 550 to $750^{\circ}C$ using Pulsed Laser Deposition (PLD). The secondary phase $Zn_2SnO_4$ occurred during the growth of ZTO films and it became more significant with further increasing substrate temperature. Polarization-electric-field (P-E) hysteresis characteristics, with a remnant polarization and coercive field of 0.05 ${\mu}C/cm^2$ and 48 kV/cm, respectively, were obtained in the ZTO film grown at $700^{\circ}C$ in 200 mTorr.

Stress Corrosion Cracking Behavior of Alloy 690 in Crevice Environment (Pb + S + Cl) in a Steam Generator Tube (증기발생기 전열관 틈새복합환경(Pb+S+Cl)에서 Alloy 690의 응력부식균열거동)

  • Shin, Jung-Ho;Lim, Sang-Yeop;Kim, Dong-Jin
    • Corrosion Science and Technology
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    • v.17 no.3
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    • pp.116-122
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    • 2018
  • The secondary coolant of a nuclear power plant has small amounts of various impurities (S, Pb, and Cl, etc.) introduced during the initial construction, maintenance, and normal operation. While the concentration of impurities in the feed water is very low, the flow of the cooling water is restricted, so impurities can accumulate on the Top of Tubesheet (TTS). This environment is chemically very complicated and has a very wide range of pH from acidic to alkaline. In this study, the characteristics of the oxide and the mechanism of stress corrosion cracking (SCC) are investigated for Alloy 690 TT in alkaline solution containing Pb, Cl, and S. Reverse U-bend (RUB) specimens were used to evaluate the SCC resistance. The test solution comprises 3m NaCl + 500ppm Pb + 0.31m $Na_2SO_4$ + 0.45m NaOH. Experimental results show that Alloy 690 TT of the crevice environment containing Pb, S, and Cl has significant cracks, indicating that Alloy 690 is vulnerable to stress corrosion cracking under this environment.