• Title/Summary/Keyword: secondary materials

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Investigation on Interfacial Microstructures of Stainless Steel/Inconel Bonded by Directed Energy Deposition of alloy Powders (레이저 직접 용착공정으로 형성된 스테인레스/인코넬 합금 계면의 미세조직 분석)

  • Eom, Yeong Seong;Kim, Kyung Tae;Jung, Soo-Ho;Yu, Jihun;Yang, Dong Yeol;Choe, Jungho;Sim, Chul Yong;An, Seung Jun
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.219-225
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    • 2020
  • The directed energy deposition (DED) process of metal 3D printing technologies has been treated as an effective method for welding, repairing, and even 3-dimensional building of machinery parts. In this study, stainless steel 316L (STS316L) and Inconel 625 (IN625) alloy powders are additively manufactured using the DED process, and the microstructure of the fabricated STS316L/IN625 sample is investigated. In particular, there are no secondary phases in the interface between STS316L and the IN625 alloy. The EDS and Vickers hardness results clearly show compositionally and mechanically transient layers a few tens of micrometers in thickness. Interestingly, several cracks are only observed in the STS 316L rather than in the IN625 alloy near the interface. In addition, small-sized voids 200-400 nm in diameter that look like trapped pores are present in both materials. The cracks present near the interface are formed by tensile stress in STS316L caused by the difference in the CTE (coefficient of thermal expansion) between the two materials during the DED process. These results can provide fundamental information for the fabrication of machinery parts that require joining of two materials, such as valves.

Fabrication of Ceramic Filters via Binder Jetting Type 3D Printing Technology (바인더 젯팅 적층제조기술을 활용한 다공성 세라믹필터 제작)

  • Mose Kwon;Jong-Han Choi;Kwang-Taek Hwang;Jung-Hoon Choi;Kyu-Sung Han;Ung-Soo Kim;Jin-Ho Kim
    • Korean Journal of Materials Research
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    • v.33 no.7
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    • pp.285-294
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    • 2023
  • Porous ceramics are used in various industrial applications based on their physical properties, including isolation, storage, and thermal barrier properties. However, traditional manufacturing environments require additional steps to control artificial pores and limit deformities, because they rely on limited molding methods. To overcome this drawback, many studies have recently focused on fabricating porous structures using additive manufacturing techniques. In particular, the binder jet technology enables high porosity and various types of designs, and avoids the limitations of existing manufacturing processes. In this study, we investigated process optimization for manufacturing porous ceramic filters using the binder jet technology. In binder jet technology, the flowability of the powder used as the base material is an important factor, as well as compatibility with the binder in the process and for the final print. Flow agents and secondary binders were used to optimize the flowability and compatibility of the powders. In addition, the effects of the amount of added glass frit, and changes in sintering temperature on the microstructure, porosity and mechanical properties of the final printed product were investigated.

Material Life Cycle Assessment of Graphene 2wt% Added to Li1.6Ni0.35Mn0.65O2 Half-Cell (그래핀 2wt%를 첨가한 Li1.6Ni0.35Mn0.65O2 Half-Cell의 물질 전 과정 평가)

  • CHO, KYOUNG-WON;LEE, YOUNG-HWAN;HAN, JEONG-HEUM;YU, JAE-SEON;HONG, TAE-WHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.1
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    • pp.132-137
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    • 2020
  • Lithium secondary batteries have become an important power source for portable electronic devices such as cellular phones, laptop computers. Presently, commercialized lithium-ion batteries use a LiCoO2 cathode. However, due to the high cost and environmental problems resulting from cobalt, an intensive search for new electrode materials is being actively conducted. Recently, solid solution LiMn1-xNixO2 have become attractive because of high capacity and enhanced safety at high voltages over 4.5 V. The Li1.6Ni0.35Mn0.65O2 compounds were conventionally prepared by a sol-gel method, which can produce the layered Li-Ni-Mn-O compounds with a high homogeneity. And by adding a graphene 2wt% the first charge-discharge voltage profiles was increased over Li1.6Ni0.35Mn0.65O2 compound. Also, the variation s of the discharge capacities with cycling showed a higher capacity retention rater. In this study, material lifecycle evaluation was performed to analyze the environmental impact characteristics of Li1.6Ni0.35Mn0.65O2 & graphene 2wt% half-cell manufacturing process. The software of material life cycle assessment was Gabi. Through this, environmental impact assessment was performed for each process. The environmental loads induced by Li1.6Ni0.35Mn0.65O2 & graphene 2wt% synthesis process were quantified and analyzed, and the results showed that the amount of power had the greatest impact on the environment.

Analysis of Pre-service Secondary Chemistry Teachers' Uses of Teacher's Guide in Planning Lessons (중등 예비화학교사의 수업 계획에서 교사용 지도서의 활용 방식 분석)

  • Yang, Chanho;Song, Nayoon;Kim, Minhwan;Noh, Taehee
    • Journal of The Korean Association For Science Education
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    • v.36 no.4
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    • pp.681-691
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    • 2016
  • In this study, we investigated pre-service secondary chemistry teachers' use of teacher's guide in planning lessons. Eleven pre-service teachers at a college of education in Seoul participated in this study. Textbooks and teacher's guide books including various teaching materials were provided. Pre-service teachers used teacher's guide while they planned two lessons, which were a lecture and an instruction using science teaching model. A semi-structured interview was conducted. All of the teaching-learning materials and interviews were analyzed. The analyses of the results revealed that most pre-service teachers followed each lesson presented in teacher's guide, but they did not consider the structure of the whole unit and science curriculum. There were some cases that the exemplary lesson planning in teacher's guide helped them to select science teaching model. They modified the questions of textbook activity in planning their lecture. On the other hand, they modified the activity to fit each stage of the model in planning their instruction using science teaching models. Most pre-service teachers constructed their own worksheets by applying the materials of the teacher's guide. They recognized the components of assessment by considering exemplary lesson planning from the teacher's guide, and created questions by modifying the content of textbooks and teacher's guide books including various teaching materials. However, the questions which they made were limited in context of knowledge. They evaluated that introductory questions were not of interest to students, and modified or added new materials. Educational implications of these findings are discussed.

Magnetic Properties of Melt-spun Fe-Nd-C Alloys (급속응고에 의해 제조된 Fe-Nd-C 합금의 자기적 특성)

  • Jang, T.S.;Lim, K.Y.;Cho, D.H.
    • Korean Journal of Materials Research
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    • v.7 no.12
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    • pp.1063-1069
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    • 1997
  • For me1t-spun Fe-Nd-C alloys, variation of phase development and magnetic properties with the variety of alloy compositions and production conditions were investigated. To find out whether hard magnetic $Fe_{14}Nd_2C$ is crystallized direct1y from the melt by rapid quenching, the phase development of the as-spun ribbons spun at various speed was a1so studied. For the ribbons spun at 10m/s, ${\alpha}-Fe$ was the primary crystallization phase followed by the secondary $Fe_{17}Nd_2C$. At 20m/s ${\alpha}-Fe$ was suppressed so that the primary $Fe_{17}Nd_2C$ coexisted with the secondary ${\alpha}-Fe$ and the amorphous phase. Above 30m/s the ribbons were a1most amorphous, and the amorphization was complete at 40m/s. $Fe_{14}Nd_2C$ therefore was not found in as-spun state but obtained after heat treating the ribbons. The effective temperature range ($700{\sim}900^{\circ}C$) in which $Fe_{14}Nd_2C$ can be obtained was wider than that of a cast alloy. An alloy made with the wheel speed of 20 or 30m/s yielded higher coercivities after heat treatment. In iron-rich Fe-Nd-C, the composition range in which a high coercivity (more than 10kOe) is expected is narrow, i.e., 77~78 Fe and 7~8 C(at.%).

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Misconception on the Yellow Sea Warm Current in Secondary-School Textbooks and Development of Teaching Materials for Ocean Current Data Visualization (중등학교 교과서 황해난류 오개념 분석 및 해류 데이터 시각화 수업자료 개발)

  • Su-Ran Kim;Kyung-Ae Park;Do-Seong Byun;Kwang-Young Jeong;Byoung-Ju Choi
    • Journal of the Korean earth science society
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    • v.44 no.1
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    • pp.13-35
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    • 2023
  • Ocean currents play the most important role in causing and controlling global climate change. The water depth of the Yellow Sea is very shallow compared to the East Sea, and the circulation and currents of seawater are quite complicated owing to the influence of various wind fields, ocean currents, and river discharge with low-salinity seawater. The Yellow Sea Warm Current (YSWC) is one of the most representative currents of the Yellow Sea in winter and is closely related to the weather of the southwest coast of the Korean Peninsula, so it needs to be treated as important in secondary-school textbooks. Based on the 2015 revised national educational curriculum, secondary-school science and earth science textbooks were analyzed for content related to the YSWC. In addition, a questionnaire survey of secondary-school science teachers was conducted to investigate their perceptions of the temporal variability of ocean currents. Most teachers appeared to have the incorrect knowledge that the YSWC moves north all year round to the west coast of the Korean Peninsula and is strong in the summer like a general warm current. The YSWC does not have strong seasonal variability in current strength, unlike the North Korean Cold Current (NKCC), but does not exist all year round and appears only in winter. These errors in teachers' subject knowledge had a background similar to why they had a misconception that the NKCC was strong in winter. Therefore, errors in textbook contents on the YSWC were analyzed and presented. In addition, to develop students' and teachers' data literacy, class materials on the YSWC that can be used in inquiry activities were developed. A graphical user interface (GUI) program that can visualize the sea surface temperature of the Yellow Sea was introduced, and a program displaying the spatial distribution of water temperature and salinity was developed using World Ocean Atlas (WOA) 2018 oceanic in-situ measurements of water temperature and salinity data and ocean numerical model reanalysis field data. This data visualization materials using oceanic data is expected to improve teachers' misunderstandings and serve as an opportunity to cultivate both students and teachers' ocean and data literacy.

Analysis of Auxiliary Device in a Gas-solid Cyclone by Experimental and Computational Approaches

  • Lee, Ju-Yeol;Park, Duck-Shin;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E1
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    • pp.21-28
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    • 2003
  • An auxiliary device, called Post Cyclone (PoC). had been introduced and primarily examined in earlier works which proved the reduction of the emission of fine dust from the gas-solid cyclones without incurring significant increase of cost and pressure drop. It has been known that the PoC has some advantages over other secondary dust treatment devices such as (a) simple design, (b) low cost of manufacture, (c) minimum additional pressure drop, (d) high recoverbility of the product dust, and (e) simplicity of operation. Despite the potential advantage, however, lack of practical data confined its plausible application in wide areas. Thus, in this work, a few serial experiments were conducted in terms of a few operation conditions, and the particle trajectories throughout the cyclone set-up were visually analyzed by using a commercial computer simulation program (FLUENT).

Boron Analysis in High Carbon Graphitized Steel using Neutron Autoradiography (Neutron Radiography를 이용한 고탄소흑연강에서 붕소 분석)

  • U, Gi-Do;Yang, Chang-Ho;Park, Hui-Chan;Lee, Chang-Hui;Sim, Cheol-Mu;Jang, Jin-Seong;Kim, Hyeon-Gyeong
    • Korean Journal of Materials Research
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    • v.11 no.12
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    • pp.1074-1079
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    • 2001
  • To study the distribution of boron and the boron effect for nucleation of graphite in high carbon steel, neutron induced autoradiography method is used. High carbon steel is easy to make the graphitization by addition of boron. It is easy to analysis of boron distribution using neutron radiography with neutron fluence of $1.9$\times${\times}10^{13}/cm^2$in the boron added high carbon steel. By the neutron induced autoradiography technique, it was found that the distribution of boron depended on boron content, graphitiging temperature and time. And by the analysis of secondary ion mass spectroscopy (SIMS) and electron probe micro analysis (EPMA), boron or boride were acted at nucleation site of graphite in high carbon steel.

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Behavior of Woven-glass/Epoxy Composites after Impact Loading (접촉하중형태에 따른 복합재의 거동변화)

  • 이재준;김병식;황성식;김태우;김찬묵
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.53-56
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    • 2002
  • External low-velocity impact loadings onto the composites cause reduction of stiffness and/or strength. The reductions indicate that internal(external) damages were developed within the composites. These damages could be matrix cracking, fiber/matrix debonding, or delamination between layers. In previous studies, damage evaluation have been done by applying secondary mechanical loading such as buckle-driven compressive, or fatigue, or flexural loadings. An evaluation method by applying indentation loadings on the composites was proposed. The load-displacement curves obtained from the indentation testing provided the extent of damages within the composites due to impact loadings.

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Curing Kinetics of Amine Terminated Polyetherimide/Epoxy Resin Blends and Its Application on the High Toughness Composites (Amine terminated polyetherimide/Epoxy 블렌드의 경화공정과 고강인성 복합재료에의 응용)

  • 김민영;김성호;이광기;김원호;안병현
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.49-52
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    • 2001
  • The investigation of cure kinetics, morphology, and fracture toughness studies on epoxy resin/amine terminated PEI/Anhydride system were performed by differential scanning calorimetry and scanning electron microscopy. Modified autocatalystic kinetics model was applied by isothermal scan test. The fracture toughness for the neat epoxy resin was 2.15 MPa m0.5 and the fracture toughness was improved 45% as neat epoxy resin system. The generation of secondary phase of AT-PEI was observed and its size was grown up by increasing contents of PEI.

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