• 제목/요약/키워드: secondary materials

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API X80 라인파이프강의 미세조직과 기계적 특성에 미치는 냉각조건의 영향 (Effect of Cooling Conditions on Microstructures and Mechanical Properties in API X80 Linepipe Steels)

  • 한승엽;신상용;이성학;배진호;김기수
    • 대한금속재료학회지
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    • 제47권9호
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    • pp.523-532
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    • 2009
  • In this study, four API X80 linepipe steel specimens were fabricated with varying cooling rates and finish cooling temperatures, and their microstructures and crystallographic orientations were analyzed to investigate the effects of cooling conditions on their tensile and Charpy impact properties. All the specimens consisted of acicular ferrite, granular bainite, and secondary phases such as martensite and martensiteaustenite constituent. The volume fraction of secondary phases increased with increasing cooling rate, and the higher finish cooling temperature resulted in the reduction in volume fraction and grain size of secondary phases. According to the crystallographic orientation analysis data, the effective grain size and unit crack path decreased as fine acicular ferrites having a large amount of high-angle grain boundaries were homogeneously formed, thereby leading to the improvement of Charpy impact properties. The specimen fabricated with the higher cooling rate and lower finish cooling temperature had the highest upper shelf energy and the lowest energy transition temperature because it contained a large amount of fine secondary phases homogeneously distributed inside fine acicular ferrites, while its tensile properties well maintained.

Alloy 625의 특성과 조직에 미치는 원심주조품 두께의 영향 (Effect of Centrifugal Casting Thickness on the Mechanical Properties and the Microstructure of Alloy 625)

  • 이유정;김병훈;주윤곤;조창용;이재현
    • 한국주조공학회지
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    • 제42권3호
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    • pp.153-160
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    • 2022
  • 초내열합금 625 튜브의 제조에 필요한 원심주조품의 두께에 따라 응고조직과 기계적 특성에 미치는 영향을 고찰하였다. 10, 17, 50 mm 두께로 원심주조한 625합금에서 두께의 증가에 따라 주상정 부분의 길이와 2차 수지상 간격이 약간 증가하였으나 상온 인장특성은 큰 차이를 보이지 않았다. 주상정 부분의 응고는 일방향응고의 형태로 응고가 진행되기 때문에 일방향응고 조건을 변화시켜 2차 수지상의 간격을 비교하여 각 두께의 주조품에서 응고속도를 계산하였다. 두꺼운 주조품일수록 내부 다결정 조직의 비율이 증가하였다. 다결정 부분의 인장특성은 주상정 부분의 평균값과 유사한 값을 보였으며 이는 2차 수지상의 간격보다 결정립 형태의 영향인 것으로 사료된다.

화학양론 변화를 통한 리튬 이온 치환 니오브산 칼륨 세라믹의 이차상 제어 연구 (Secondary Phase Control of Lithium Ion-Substituted Potassium Niobate Ceramics via Stoichiometry Modification)

  • 여태수;이주현;조욱
    • 한국전기전자재료학회논문지
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    • 제37권5호
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    • pp.533-540
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    • 2024
  • In line with the development of electronic devices and technologies, the demand for improving ferroelectric materials' performance is increasing. Since K0.5Na0.5NbO3 (KNN), an eco-friendly ferroelectric material that does not use lead and has a high Curie temperature, it is attracting attention to its usability as a high-temperature dielectric, and various studies are being conducted to increase performance. In a KNN having a perovskite structure, there was a simulation result that the KNN has higher spontaneous polarization when the A-site in which sodium ions exist is replaced with lithium ions. If the simulation results can be proven experimentally, the application range of KNN-based ferroelectric materials will increase. To this end, we tried to manufacture a K1-xLixNbO3 (KLN) with high electrical characteristics by fabricating niobium-deficient and potassium-excessive compositions, which attempt was made to solve the stoichiometry problem by volatilization and suppress secondary phases. If KLN's secondary phase suppression and relative permittivity improvement are successful, it will contribute to meeting the demand for developing electronic devices.

An Experimental Study on the Combustion Characteristics of a Low NOx Burner Using Reburning Technology

  • Ahn, Koon-Young;Kim, Han-Seok;Son, Min-Gyu;Kim, Ho-Keun;Kim, Yong-Mo
    • Journal of Mechanical Science and Technology
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    • 제16권7호
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    • pp.950-958
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    • 2002
  • The combustion characteristics of a low NOx burner using reburning technology have been experimentally studied. The return burner usually has three distinct reaction zones which include the primary combustion zone, the reburn zone and the burnout zone by provided secondary air. NOx is mainly produced in a primary combustion zone and a certain portion of NOx can be converted to nitrogen in the rebury zone. In the burnout zone, the unburned mixtures are completely oxidated by supplying secondary air. Liquefied Petroleum Gas (LPG) was used as main and reburn fuels. The experimental parameters investigated involve the main/reburn fuel ratio, the primary/secondary air ratio, and the injection location of rebury fuel and secondary air. When the amount of return fuel reaches to the 20-30% of the total fuel used, the overall NO reduction of 50% is achieved. The secondary air is injected by two different ways including vertical and parallel injection. The injector of secondary air is located at the downstream region of furnace for a vertical-injection mode, which is also placed at the inlet primary-air injection region for a parallel-injection mode. In case of the vertical injection of the secondary air flow, the NOx formation of stoichiometric condition at a primary combustion zone is nearly independent of the rebury conditions (locations, fuel/air ratios) while the NOx emission of the fuel-lean condition is considerably influenced by the reburn conditions. In case of the parallel injection of the secondary air, the NOx emission is sensitive to the air ratio rather than the fuel ratio and the reburning process often coupled with the multiple air-staging and fuel-staging combustion processes.

멤브레인 형 2차 방벽 이방성 복합재료의 섬유방향에 따른 기계적 성능 평가 (Evaluation of Mechanical Performance of Membrane Type Secondary Barrier Anisotropic Composites depending on Fiber Direction)

  • 정연제;김정대;황병관;김희태;오훈규;김용태;박성보;이제명
    • 대한조선학회논문집
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    • 제57권3호
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    • pp.168-174
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    • 2020
  • Recently, the size of Liquified Natural Gas (LNG) carriers has been increasing, in turn increasing the load generated during operation. To handle this load, the thickness of LNG Cargo Containment Systems (CCSs) should be increased. Despite increasing the thickness of LNG CCSs, a secondary barrier is still used in conventional thickness. Therefore, the mechanical performance of the existing secondary barrier should be verified. In this study, tensile test of the secondary barrier was performed to evaluate mechanical properties under several low- and cryogenic-temperature conditions considering LNG environment, and in each fiber direction considering that the secondary barrier is composed of anisotropic composite materials depending on the glass fibers. Additionally, the coefficient of thermal expansion was measured by considering the degradation of the mechanical properties of the secondary barrier caused by the generated thermal stress during periodical unloading. As a result, the mechanical performance of secondary barrier in the Machine Direction (MD) was generally found to be superior than that in the Transverse Direction (TD) owing to the warp interlock structure of the glass fibers.

산처리에 의해 개질된 리튬이온 이차전지용 흑연 전극의 특성 (Performance of Graphite Electrode Modified with Acid Treatment for Lithium Ion Secondary Battery)

  • 김명수;문승환;김문걸;김택래;함현식;박홍수
    • 한국응용과학기술학회지
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    • 제22권2호
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    • pp.142-150
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    • 2005
  • The natural graphite particles A and heat-treated graphite particles B at $1800\;^{\circ}C$ after pitch-coating were used as the anode base materials for lithium ion secondary battery. In order to improve the performance of anode materials, the base anode materials were treated with various acids. With the acid treatments of 62% $HNO_3$ and 95% $H_2SO_4$ aqueous solution, the specific surface area and electrical conductivity of base anode materials were increased, and the initial charge-discharge capacity and cycle performance were improved due to the elimination of structural defects.

원자력발전소 증기발생기 2차측 Free-Span 잔류물질 영향평가 전산 프로그램 개발 (Development of Program Evaluating the Effects on the Secondary Side of Nuclear Power Plant of Steam Generator due to Foreign Objects)

  • 유현주
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2006년 추계학술발표대회 개요집
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    • pp.26-28
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    • 2006
  • When materials such as metal are into the secondary side of steam generator, they, so called foreign objects, may have influences on the integrity of the steam generator tubes. They cause the tube wear due to the relative motion between the tubes and foreign objects and the tube impact due to flow. The best way to avoid the effects is to remove all the foreign objects. However, it is not easy to remove the foreign materials thoroughly due to their condition such as the location. Considering the wear and impact by the foreign materials, KEPRI(Korea Electric Power Research Institute) developed the methodology to evaluate the foreign materials analytically. This methodology was described with a computer program in order to obtain the fast results. The program informs whether the tubes have the structural integrity when the foreign material strikes the tubes. Moreover, this gives us the remaining life of the steam generator tubes. In this paper, the program, which evaluates the effects of the foreign objects in the secondary side of steam generator, is introduced.

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The Electrochemical Characteristics of Surface-modified Carbonaceous Materials by tin Oxides and Copper for Lithium Secondary Batteries

  • Lee, Joong-Kee;Ryu, D.H.;Shul, Y.G.;Cho, B.W.;Park, D.
    • Carbon letters
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    • 제1권3_4호
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    • pp.170-177
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    • 2001
  • Lithium intercalated carbon (LIC) are basically employed as an anode for currently commercialized lithium secondary batteries. However, there are still strong interests in modifying carbon surface of active materials of the anode because the amount of irreversible capacity, charge-discharge capacity and high rate capability are largely determined by the surface conditions of the carbon. In this study, the carbonaceous materials were coated with tin oxide and copper by fluidized-bed chemical vapor deposition (CVD) method and their coating effects on electrochemical characteristics were investigated. The electrode which coated with tin oxides gave the higher capacity than that of raw material. Their capacity decreased with the progress of cycling possibly due to severe volume changes. However, the cyclability was improved by coating with copper on the surface of the tin oxides coated carbonaceous materials, which plays an important role as an inactive matrix buffering volume changes. An impedance on passivation film was decreased as tin oxides contents and it resulted in the higher capacity.

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모듈형 제품수송을 통한 재사용 포장재 사용이 물류비용에 미치는 영향에 관한 연구 (A Study on the Effects of Reusable Packaging Materials through Module-Type Product Transportation on Logistics Costs)

  • 김병찬;양대용
    • 디지털산업정보학회논문지
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    • 제10권3호
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    • pp.261-272
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    • 2014
  • Home appliances go through a couple of packaging stages from the plant to consumers. The primary packaging, inner packaging for each part, happens for protection after products leave the plant. The secondary packaging happens in the unit of product, ensuring cushioning packaging to protect products from movement. The final tertiary packaging is for transportation and delivery. Each stage of product packaging, however, costs a lot of money because of disposable packaging materials used in each stage including vinyl, tapes, Styrofoam, and corrugated cardboards. Discarded packaging materials also cause environmental problems. In an effort to come up with a measure to solve those problems, this study proposed a plan to minimize logistics costs with semi-permanent packaging materials to replace disposable ones including Styrofoam, vinyl, and corrugated cardboards in the stages of inner packaging, cushioning packaging, product unit-based packaging, and transportation. The study also developed a model to cut down logistics costs by reducing various packaging stages including the primary, secondary, and tertiary stage only to the secondary one through module-type products instead of the transportation- and delivery-type ones, as well as demonstrated the excellence of the study through numerical analysis.