• Title/Summary/Keyword: second order effects

Search Result 1,889, Processing Time 0.031 seconds

Dark Fermentative Hydrogen Production using the Wastewater Generated from Food Waste Recycling Facilities (혐기 발효 공정을 통한 음식물류 폐기물 탈리액으로부터 수소 생산)

  • Kim, Dong-Hoon;Lee, Mo-Kwon;Lim, So-Young;Kim, Mi-Sun
    • Journal of Hydrogen and New Energy
    • /
    • v.22 no.3
    • /
    • pp.326-332
    • /
    • 2011
  • The authors examined the effects of operating parameters on the $H_2$ production by dark fermentation of the wastewater generated from food waste recycling facilities, in short "food waste wastewater (FWW)". Central composite design based response surface methodology was applied to analyze the effect of initial pH (5.5-8.5) and substrate concentration (2-20 g Carbo. COD/L) on $H_2$ production. The experiment was conducted under mesophilic ($35^{\circ}C$) condition and a heat-treated ($90^{\circ}C$ for 20min)anaerobic digester sludge was used as a seeding source. Although there was a little difference in carbohydrate removal, $H_2$ yield was largely affected by the experimental conditions, from 0.38 to 1.77 mol $H_2$/mol $hexose_{added}$. By applying regression analysis, $H_2$ yield was well fitted based on the coded value to a second order polynomial equation (p = 0.0243): Y = $1.78-0.17X_1+0.30X_2+0.37X_1X_2-0.29X_1{^2}-0.35X_2{^2}$, where $X_1$, $X_2$, and Y are pH, substrate concentration (g Carbo. COD/L), and hydrogen yield (mol $H_2$/mol $hexose_{added}$), respectively. The 2-D response surface clearly showed a high inter-dependency between initial pH and substrate concentration, and the role of these two factors was to control the pH during fermentation. According to the statistical optimization, the optimum condition of initial pH and substrate concentration were 7.0 and 13.4 g Carbo. COD/L, respectively, under which predicted $H_2$ yield was 1.84 mol $H_2$/mol $hexose_{added}$. Microbial analysis using 16S rRNA PCR-DGGE showed that $Clostridium$ sp. such as $Clostridium$ $perfringens$, $Clostridium$ $sticklandii$, and $Clostridium$ $bifermentans$ were main $H_2$-producers.

A Study on Integrated Assessment of Baekdu Mountain Volcanic Aisaster risk Based on GIS (GIS기법을 이용한 백두산 화산재해 종합평가 연구)

  • Xiao-Jiao, Ni;Choi, Yun Soo;Ying, Nan
    • Spatial Information Research
    • /
    • v.22 no.4
    • /
    • pp.77-87
    • /
    • 2014
  • Recently there are many disasters caused by volcanic activities such as the eruptions in Tungurahua, Ecuador(2014) and $Eyjafjallaj\ddot{o}kull$, Iceland(2010). Therefore, it is required to prepare countermeasures for the disasters. This study analyzes the Baekdu Mountain area, where is the risky area because it is active volcano, based on the observed data and scientific methods in order to assess a risk, produce a hazard map and analyze a degree of risk caused by the volcano. Firstly, it is reviewed for the research about the Baekdu mountain volcanic eruption in 1215(${\pm}15$ years) done by Liu Ruoxin. And the factors causing volcanic disaster, environmental effects, and vulnerability of Baekdu Mountain are assessed by the dataset, which includes the earthquake monitoring data, the volcanic deformation monitoring data, the volcanic fluid geochemical monitoring data, and the socio-economic statistics data. A hazard, especially caused by a volcano, distribution map for the Baekdu Mountain Area is produced by using the assessment results, and the map is used to establish the disaster risk index system which has the four phases. The first and second phases are very high risky area when the Baekdu Mountain erupts, and the third and fourth phases are less dangerous area. The map shows that the center of mountain has the first phase and the farther area from the center has the lower phase. Also, the western of Baekdu Mountain is more vulnerable to get the risk than the eastern when the factors causing volcanic disasters are equally applied. It seems to be caused by the lower stability of the environment and the higher vulnerability.

The Coating Effects of Al2O3 on a Li[Li0.2Mn0.54Co0.13Ni0.13]O2 Surface Modified with (NH4)2SO4

  • Oh, Ji-Woo;Oh, Rye-Gyeong;Hong, Jung-Eui;Yang, Won-Geun;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.5
    • /
    • pp.1516-1522
    • /
    • 2014
  • A series of 20 wt % $(NH_4)_2SO_4$ and 3 wt % $Al_2O_3$ surface treatments were applied to $Li[Li_{0.2}Mn_{0.54}Co_{0.13}Ni_{0.13}]O_2$ substrates. The $Li[Li_{0.2}Mn_{0.54}Co_{0.13}Ni_{0.13}]O_2$ substrates were synthesized using a co-precipitation method. Sample (a) was left pristine and variations of the 20 wt % $(NH_4)_2SO_4$ and 3 wt % $Al_2O_3$ were applied to samples (b), (c) and (d). XRD was used to verify the space group of the samples as R$\bar{3}$m. Additional morphology and particle size data were obtained using SEM imagery. The $Al_2O_3$ coating layers of sample (b) and (d) were confirmed by TEM images and EDS mapping of the SEM images. 2032-type coin cells were fabricated in a glove box in order to investigate their electrochemical properties. The cells were charged and discharged at room temperature ($25^{\circ}C$) between 2.0V and 4.8V during the first cycle. The cells were then charged and discharged between 2.0V and 4.6V in subsequent cycles. Sample (d) exhibited lower irreversible capacity loss (ICL) in the first charge-discharge cycle as compared to sample (c). Sample (d) also had a higher discharge capacity of ~250 mAh/g during the first and second charge-discharge cycles when compared with sample (c). The rate capability of the $Al_2O_3$-coated sample (b) and (d) was lower when compared with sample (a) and (c). Sample (d), coated with $Al_2O_3$ after the surface treatment with $(NH_4)_2SO_4$, showed an improvement in cycle performance as well as an enhancement of discharge capacity. The thermal stability of sample (d) was higher than that of the sample (c) as the result of DSC.

A Method for Application of Ammonium-based Pretreatment Solution in Preparation of Copper Flakes Coated by Electroless Ag Plating (구리 플레이크의 무전해 은도금에서 암모늄계 구리 전처리 용액의 적용법)

  • Kim, Ji Hwan;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.22 no.4
    • /
    • pp.57-63
    • /
    • 2015
  • In order to prepare a low-cost conductive filler material possessing improved anti-oxidation property, Ag-coated Cu flakes were fabricated and the effects of an applying method of ammonium-based pretreatment solution on the Cu flakes were analyzed. The pretreatment solution was used to remove the surface oxide layer on Cu flake. During a single-stage pretreatment process, hole-shaped defects were formed on the flake surface during the pretreatment after 2 min, and the number and size increased in proportion to the pretreatment time. In the case that Ag plating solution was injected in the pretreatment solution after the pretreatment for 2 min, the defects were also formed during Ag plating. In contrast, the defects tremendous decreased in the case that the pretreatment solution was removed after the first pretreatment for 2 min and the Ag plating proceeded after the second pretratment using a low concentration pretreatment solution. As the final result, the 15 wt% Ag-coated Cu flake sample which was fabricated using the single-stage pretreatment oxidized at $166^{\circ}C$, but the sample fabricated by the double-stage pretreatment oxidized at $224^{\circ}C$, indicating definitely improved anti-oxidation property.

The effects of balanced English approach program on five-year-old children's English reading and writing Ability (균형적 영어접근 프로그램이 만5세 유아의 읽기와 쓰기능력에 미치는 영향)

  • Cha, Kyong Na;Bae, Jae Jung;Chung, Chung Hee
    • Korean Journal of Childcare and Education
    • /
    • v.6 no.2
    • /
    • pp.57-81
    • /
    • 2010
  • The purpose of this study is to examine the balanced English approach program on five-year-old children's English reading and writing ability. For this study, two classes consisting of five-year-old children in HATBEAT kindergarten in D city were selected. One class was designated as the experimental group and the other as the control group. The balanced English approach program was performed on the experimental group but not on the control group. The balanced English approach program was carried out for 8 weeks. The experimental procedures were in the order of pre-test, the experimental treatment, and post-test. The result of the experiment was evaluated by comparing the pre-test and post-test results. Analysis of data was performed by ANCOVA. The result of the study are as follows. First, in the English reading ability, the experimental group was more enhanced than the control group. Also, for sub-factors of English reading such as alphabet and English word reading ability, the experimental group was more enhanced than the control group. However, in the English book reading ability as a sub- factor of the English reading, there was not much difference in the result between the experimental group and the control group. Second, in the English writing ability, the experimental group were more enhanced than the control group.

The Influence of Work-Life Balance(WLB) Support Systerm on Employee Engagement - Focused on Moderating Effect of Perceived Organizational Support - (일과 삶의 균형(WLB) 지원제도가 종업원 인게이지먼트에 미치는 영향 - 조직지원인식 조절효과를 중심으로 -)

  • Park, Soon;Chang, Young-Chul
    • Management & Information Systems Review
    • /
    • v.34 no.5
    • /
    • pp.49-69
    • /
    • 2015
  • The objective of this study is to understand the influence of Work-Life Balance (WLB) support system on employee engagement (organizational commitment and job commitment) and to examine the moderating effect of perceived organizational support (instrumental and emotional) on the relationship between WLB and employee engagement. To test the research model and hypotheses, this study analyzed 537 responses from employees of sample companies that were carrying out the WLB support system during the period of December 1 through 31, 2014, and the results of the analysis are as follows: First, the correlation between employee engagement (organizational commitment) and the WLB support system showed that the influence of WLB support system on employee engagement(organizational commitment) was greater in the order of growth, job, and family support system. Second, the correlation between WLB support system and employee engagement(job involvement) showed that growth and job support system had significant relationship. Third, in the relationship between WLB support system and employe engagement(organizational commitment), there was no moderating effect of perceived organizational support. Fourth, in the relationship between the WLB support system and employee engagement(the job involvement), both institutional and emotional supports factors of the perceived organizational support had moderating effects in the relationship between growth support system and employee engagement(job involvement). This study has academic significance in that it is an empirical study examining the relationship between the WLB support system and employee engagement, which has not actively investigaged in Korea.

  • PDF

Effects of Physical Activity University Students on Time Perspective in Leisure Constraints and Leisure Flow (신체활동 대학생들의 시간관이 여가제약, 여가몰입에 미치는 영향)

  • Seo, Soo-Jin
    • Journal of Digital Convergence
    • /
    • v.15 no.11
    • /
    • pp.567-579
    • /
    • 2017
  • The purpose of this study was conducted to clarify physical activity university students on time perspective in leisure constraints and leisure flow. To achieve this purpose, subjects of this study were sampled 295 Physical Activity University Students participant using purposeful sampling method for 2 months from May to June of 2017. Using questionnaires stratified cluster random sampling in university students in D city and C city. The analysis method was used t-test, one-way ANOVA, multiple regression analysis, correlation analysis methods in order to solve problems of the study. According to the study Result, First, studies show that female have high levels of leisure constraints than males. Males have higher levels of leisure flow than females. The first grader show high level of individual constraints and past negation were also high. In the series of majors, natural affiliates and humanities are high in the past negation, present destiny, the service major currently high in pleasure and of leisure, autotelic experience of leisure flow. In the rhythmic type of Activity type, the past negation, present destiny and leisure constraints are highly likely to be higher. In the competitive have shown that is high. Second, leisure constraints on students' participation in physical activities have been found to have negative influence on their students. Third, leisure flow have shown that they have a positive effect on past affirmation and present pleasure.

An Empirical Study on Information Service Satisfaction of Shipping Market Reports (해운시황리포트 정보서비스 만족도에 관한 연구)

  • Lee, Seok-Yong
    • Journal of Korea Port Economic Association
    • /
    • v.31 no.4
    • /
    • pp.1-15
    • /
    • 2015
  • During global recessions, such as the 2008 financial crisis, Korean shipping companies have been undergoing a liquidity crisis that is comparably worse than other shipping companies worldwide. One of the reasons behind this repetitive vicious cycle can be the lack of ability to foresee the future by analyzing and understanding the volatile shipping market. Traditionally, in order to assimilate the shipping market, larger Korean shipping companies have been purchasing market reports published by Europe-based research companies and shipping brokers, leading to a digital divide by company size. To resolve this issue, the Maritime Exchange Information Center (MEIC) has been publishing shipping market reports that include essential shipping information such as freight rates by different routes; commodity trends for iron ore, grain, and coal; ship-building trends for new-building, second-hand, and demolition markets; as well as bunker price and port congestion. This research was conducted to analyze the effectiveness of four variables-information usefulness, market reflection, information composition, and latest information-on information satisfaction. If the information satisfaction was found to be adequate, the analysis of actual proof was used to determine if the customers would be willing to purchase MEIC's report when it is chargeable. All the four variables were found to have positive effects on information satisfaction. In particular, latest information was found to directly affect the intention to purchase. Furthermore, high information satisfaction was related to the intention to purchase.

Experimental Study on Flow Characteristics in Meandering Channel (사행수로에서 흐름 특성에 관한 실험적 연구)

  • Seo, Il-Won;Sung, Ki-Hoon;Baek, Kyong-Oh;Jeong, Seong-Jin
    • Journal of Korea Water Resources Association
    • /
    • v.37 no.7
    • /
    • pp.527-540
    • /
    • 2004
  • In order to investigate characteristics of the primary flow and the secondary currents in the meandering channel, laboratory experiments were conducted in the meandering channel made up of alterative bends haying 120。 arc angle. Experiments were performed in two types of cross-sections, a rectangular cross-section and a curved cross-section which was made to adopt a beta probability function. Three-dimensional velocity fields were measured using a micro-ADV. As the result of experiments, in case of the rectangular cross-section, the primary flow occurred taking the shortest course, which is similar to the result of previous researches. In case of the curved cross-section, the primary flow was expected to occur along the thalweg. but it occurred almost along the shortest way. This is considered due to effects of bottom roughness and sinuosity Not only a main cell but also a secondary cell of secondary currents were clearly shown by mean of the stream function. The secondary current intensity has the maximum value near the apex of the second bend for cases of both rectangular and curved cross-sections. However, the value of the secondary current intensity for the curved section is slightly larger than that for the rectangular cross-section. Also, in case of the rectangular cross-section, the higher the ratio of width to depth is, the larger the secondary current intensity is.

The Effects of Transformational Leadership on Employees Job Satisfaction & Organizational Identification in Korean Hotel Industry (호텔기업 종사원의 변혁적 리더십이 직무만족과 조직 동일시에 미치는 영향에 관한 연구)

  • Lee, Jun-Hyuk;Kim, Dong-Ki;Park, Ki-Ho
    • Journal of Global Scholars of Marketing Science
    • /
    • v.15 no.2
    • /
    • pp.27-48
    • /
    • 2005
  • This study analyzed the structural elements of transformational leadership on hotel employees job satisfaction and organizational identification, and inquired into how moderating variables such as demographical characteristics and the features of hotels affect transformational leadership. The ultimate purpose of this study was to provide managerial implications to hotel business operators and hotel employees. The main results of this study are as follows; According to the result of factor analysis on transformational leadership and hotel employees job satisfaction, 18 variables were derived as two factors 'obliging leadership' & 'vision leadership' factor in the area of transformational leadership, and 31 variables were derived as four factors 'welfare and work environment', 'ability display and job stability', 'colleague relationship and job performance' and 'company policy' factor. Second, stepwise regression analysis on whether the type of transformational leadership at hotels has a significant effect on employees job satisfaction & organizational identification, 'vision leadership' and job satisfaction and the both 'vision leadership' & 'obliging leadership' among the types of transformational leadership appeared to have a significant effect on hotel employees organizational identification. Third, One-Way ANOVA and t-test in order to examine significant difference in the type of transformational leadership according to demographical characteristics and general characteristics, statistically significant difference was found according to income level, the current position, work experience, the type of hotel operation and the experience of job change.

  • PDF