• Resources Recycling
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• v.3 no.1
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• pp.9-16
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• 1994

Fine cobalt metal powders was produced from domestic Stellite scrap by decomposing it with molten sodium hydroxide. Complete decomposition of the scrap could be obtained with the weigth ratio of sodium hydroxide to Stellite being about 2 at the temperature ranges of $750~800^{\circ}C$ for an hour. The cobalt-bearing compound was identified as $Co_2O_3{\dot}H_2O$ by X-ray analysis and D.T.-T.G.a.. The compound was then digested in HCI to form cobalt chloride, and after iron removal by adjusting the pH of the solution, cobaltous or cobaltic hydroxide was precipitated at the pH of about 13 or 4, respectively. The precipitates were reduced by hydrogen in the temperatures of $400~500^{\circ}C$ to fine cobalt powders of high purity with the size of 1.0 to $1.5\mu\textrm{m}$. The recovery of cobalt from Stellite scrap was about 75~86% by weight.

• Journal of the Korea Organic Resources Recycling Association
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• v.8 no.4
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• pp.93-99
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• 2000

Treatment of shaving scrap, a chrome containing solid scrap generated by leather manufacturing process, has been so far depended on mainly incineration, soil landfill and ocean dumping, which give bad impact on environment and cause pollution. Shaving scrap generates from the mechanical work for controlling the final thickness of leather and its main components are collagen protein and pan of chromium compound. For the purpose of reusing this leather waste as resources, researches in connection with collagen fiber recovery, gelable protein recovery and liquid fertilizer is being speedily progressed. In the experiment, shaving scrap went through wet pulverizing treatment by physical and chemical methods. Then, making the leather sheet evenly, it is mixed with natural latex and every kind of binding materials in the container, and the mixtures were passed through experimental hydraulic press machine and applied to Fourdrinier machine respectively. Lastly, a test for fading out physical strength and properties of multiple-purpose of leather-like material was performed on a continuous leather sheet prepared by the experiment. In result, the physical strength and properties of leather-like material showed noticeable differences according to mixing ratio of binding materials, beating methods and the Ends of binding materials selected, and generally tear strength was the weakest property among others. Also, by the pilot scale experiment in sequence, it was possible to manufacture recycled goods made of soft and hard types of leather-like material with various performances.

• Journal of Powder Materials
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• v.28 no.6
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• pp.497-501
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• 2021

Cobalt (Co) is mainly used to prepare cathode materials for lithium-ion batteries (LIBs) and binder metals for WC-Co hard metals. Developing an effective method for recovering Co from WC-Co waste sludge is of immense significance. In this study, Co is extracted from waste cemented carbide soft scrap via mechanochemical milling. The leaching ratio of Co reaches approximately 93%, and the leached solution, from which impurities except nickel are removed by pH titration, exhibits a purity of approximately 97%. The titrated aqueous Co salts are precipitated using oxalic acid and hydroxide precipitation, and the effects of the precipitating agent (oxalic acid and hydroxide) on the cobalt microstructure are investigated. It is confirmed that the type of Co compound and the crystal growth direction change according to the precipitation method, both of which affect the microstructure of the cobalt powders. This novel mechanochemical process is of significant importance for the recovery of Co from waste WC-Co hard metal. The recycled Co can be applied as a cemented carbide binder or a cathode material for lithium secondary batteries.

• Resources Recycling
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• v.30 no.2
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• pp.46-52
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• 2021

Off-grade Ti generated from smelting and mechanical processing has a high oxygen content. In this work, off-grade Ti was deoxidized using Mg and a chloride mixture as the reductant and flux, respectively. The experiments were conducted in the α-Ti temperature range (1,023~1,123 K) and the effects of the reaction time, reaction temperature, quantitiy of Mg and chloride ratio on deoxidation were investigated. Notably, when YCl3 is used as the flux to react with MgO, it is possible to reduce the activity of MgO. Therefore Ti can be deoxidized using Mg. In this study, the O content was decreased from 0.5 wt% to 0.1004 wt% at 1073 K, for 6 hours, with Mg=3.6 g and $X_{YCl_3}=0.22$.

• Design & Manufacturing
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• v.2 no.3
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• pp.51-57
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• 2008

It is important factor to design the strip layout drawing according to product properties in press die design. Press dies are important processes in production such as a car component, house electronics, computer parts etc. In this paper, the strip layout of parts was designed for transfer dies. Results of this study can be modify the punch, trim position and notching shapes of strip layout. Utilization ratio was 70.3% by conducting piercing and notching for scrap design and materials were arranged with wide width of blank layout.

• Journal of Ocean Engineering and Technology
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• v.27 no.5
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• pp.28-35
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• 2013

In this paper, a research on the composition of the nesting algorithm fitness function is carried out by performing various numerical experiments to inspect how it affects the scrap efficiency, allocation characteristics, and time consumption, targeting the nesting results of ship parts. This paper specifically concentrates on a method to minimize the scrap ratio and efficiently use the well-defined remnants of a raw plate after the nesting process for the remnant nesting. Therefore, experiments for various ship parts are carried out with the weighting factor method, one of the multi-objective optimum design methods. Using various weighting factor sets, the nesting results are evaluated in accordance with the above purposes and compared with each set for each ship part groups. Consequently, it is suggested that the nesting algorithm fitness function should be constructed differently depending on the characteristics of the parts and the needs of the users.

• Earthquakes and Structures
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• v.24 no.6
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• pp.415-428
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• 2023

Low-cost techniques with seismic isolation performance and excellent resilience need to be explored in the case of rural low-rise buildings because of the limited buying power of rural residents. As an inexpensive and eco-friendly isolation bearing, scrap tire pads (STPs) have the issue of poor resilience. Thus, a seismic isolation system under a column (SISC) integrated with STP needs to be designed for the seismic protection of low-rise rural buildings. The SISC, which is based on a simple exterior design, maintains excellent seismic performance, while the mechanical behavior of the internal STP provides elastic resilience. The horizontal behaviors of the SISC are studied through load tests, and its mechanical properties and the intrinsic mechanism of the reset ability are discussed. Results indicate that the average residual displacement ratio was 24.59%, and the reset capability was enhanced. Comparative experimental and finite element analysis results also show that the load-displacement relationship of the SISC was essentially consistent. The dynamic characteristics of isolated and fixed-base buildings were compared by numerical assessment of the response control effects, and the SISC was found to have great seismic isolation performance. SISC can be used as a low-cost base isolation device for rural buildings in developing countries.

• Resources Recycling
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• v.33 no.1
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• pp.22-30
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• 2024

To synthesize the Ti₃AlC₂ MAX phase, a crucial precursor for generating the two-dimensional material MXene, the use of Ti scrap as an initial material is an economically feasible approach. This study aims to optimize the synthesis conditions for the phase fraction of the Ti₃AlC₂ MAX phase utilizing Ti scrap as the Ti source. The deoxidation of Ti powders, prepared through the hydrogenation-dehydrogenation process from Ti scrap, was effectively accomplished using the deoxidation in solid-state (DOSS) process. The optimal synthesis conditions were established by blending DOSS-Ti, Al, and graphite powders with particle sizes ranging from 25 ~ 32 ㎛ in a molar ratio of 3:1.1:2. The resulting phase fractions were as follows: Ti₃AlC₂ at 97.25 wt.%, TiC at 0.93 wt.%, and Al₃Ti at 1.82 wt.%. Furthermore, the oxygen content of the Ti₃AlC₂ MAX powder, spanning from 25 ~ 45 ㎛, was measured at 4,210 ppm.

• Resources Recycling
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• v.33 no.4
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• pp.36-46
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• 2024

We investigated a hydrometallurgical process of nickel recovery from Inconel 713C scrap. The process proceeded with a series of i) comminution of pyrometallurgical treated scrap, ii) sulfuric acid leaching, iii) solvent extraction of unreacted acid, molybdenum, aluminum, and precipitation of chromium, iv) crystallization of nickel sulfate by vacuum evaporation, and v) nickel electrowinning. The nickel-aluminum intermetallic compound, Ni₂Al₃, was formed by the pyrometallurgical pretreatment readily grounded under 75 ㎛. Sulfuric acid leaching was done for 2 hours in 2 mol/L, 20 g/L solid/liquid ratio, and 80 ℃. It revealed that over 98 % of nickel and aluminum was dissolved, whereas 28 % of molybdenum was. A nickel sulfate solution with 2.34 g/L for the crystallization of nickel sulfate hydrate was prepared via solvent extraction and precipitation. Over 99 % of molybdenum and aluminum and 93 % of chromium was removed. Nickel metal with 99.9 % purity was obtained by electrowinning with the nickel sulfate monohydrate in the cell equipped with anion exchange membranes for catholyte pH control. The membrane did not work well, resulting in a low current efficiency of 73.3 %.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.05a
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• pp.283-287
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• 2003

In recent years, design of an optimal blank shape is very important for sheet metal forming process in the automobile industry because the raw material cost rate is significant part in the automobile industry. With the design of an optimal blank shape, the engineer can protect a blank from an excessive holding force to improve the quality and reduce the ratio of material scrap. Therefore design of an optimal blank shape is inevitable in sheet metal forming process. However, if it causes a complicated shape of blank, it may be difficult to do the blank layout optimally. In this study, we developed software of optimal blank layout connected with the software of optimal blank shape design which was created in the past by the present authors. And by using these softwares, we would like to present the method in order to get optimal utilization ratio easily and precisely within short time for the sequence of works from design to blank layout.