• Title/Summary/Keyword: sbr

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Drying Shrinkage and Strength Properties of Polymer-Modified Mortars Using Redispersible Polymer Powder (재유화형 분말수지 출입 폴리머 시멘트 모르타르의 건조수축 및 강도특성)

  • Yeon, Kyu-Seok;Joo, Myung-Ki;Lee, Hyun-Jong;Jin, Xing-Qi;Lee, Chi-Won
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.1
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    • pp.51-60
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    • 2006
  • This study was conducted to investigate experimentally the drying shrinkage and the strength properties of redispersible SBR and PAE powder-modified mortars. Polymer-cement ratio, content of shrinkage-reducing agent and antifoamer content were manipulated as the experimental variables. The peculiarity of this study is to obtain a high early-age strength by using the portland cement and alumina cement with the ratio of 8 : 2. Until 7 days of age, the drying shrinkage remarkably increased up to $1\~2\times10^{-4}$, while it tended to decrease as the ratio of polymer to cement ratio and the content of shrinkage-reducing agent increased. Polymer-cement ratio was effective in improving the flexural, tensile and adhesive strengths: As the ratio increased, the strengths correspondingly increased. The flexural strength was in the range of $7\~11$ MPa, the tensile strength was $3.5\~5$ MPa and the adhesive strength was $1.2\~3.9$ MPa. On the other hand, the compressive strength tended to decrease as the polymer-cement ratio increased, and it was in the range of $23\~39$ MPa. All strengths, flexural, tensile, adhesive and compressive strengths, decreased as the content of powder shrinkage-reducing agent increased. It turned out that the polymer-cement ratio influenced more on the behavior of drying shrinkage and the properties of strength than the powder shrinkage-reducing agent did.

An Experimental Study on the Mechanical Properties of Fiber Reinforced Fly Ash.Lime.Gypsum Composites (섬유보강 플라이애쉬.석고.복합체의 역학적특성에 관한 실험적 연구)

  • 박승범
    • Magazine of the Korea Concrete Institute
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    • v.5 no.4
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    • pp.145-155
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    • 1993
  • The results of an experimental study on the manufacture and the mechanical properties of fiber reinforced fly ash$\cdot$lime$\cdot$gypsum composites are presented in this paper. 'The composites using fly ash, lime, and gypsum were prepared with various fibers (PAN-derived and Pitch-derived carbon fiber, alkali-resistance glass fiber) and a small amount of polymer emulsion-styrene butadiene rubber latex (SBR). As the test results show, the manufacturing process technology of fly ash$\cdot$lime$\cdot$gypsum composites was developed and its optimum mix proportions were successfully proposed. And the flexural strength and toughness of fiber reinforced fly ash$\cdot$lime $\cdot$gypsum composites were increased remarkably by fiber contents, but the compressive strength of the composites were influenced by the kinds fiber more than by the fiber contents. Also, the addition of a polymer emulsion to the composites decreased the bulk specific gravity, but the compressive and flexural strength, and the toughness of the composites were not influenced by it, but were considerably improved by increasing fiber contents.

Permeation of Organic Chemicals through Gasketed Cast Iron Pipe (주물 파이프 Gasket을 통한 유기화학물질의 이동)

  • Yong-Chan Seo;Nack-Joo Kim
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.45-50
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    • 1999
  • Four cast iron pipe sections containing 3 styrene butadiene rubber (SBR) gaskets (1 joint and 2 end caps) were filled with water and maintained at approximately 40 psi internal pressure. The pipe sections were placed inside 16 gallon drums filled with initially clean sand. Three of the tanks were subsequently contaminated with gasoline, gasoline spiked with pyrene and naphthalene, and toluene. The forth tank served as a control. The water inside each pipe was monitored over time for organic chemical contamination. Permeation of organic chemicals into the water inside the pipe systems was found to occur in all 3 contaminated pipe systems after approximately 100 days as measured organic chemicals concentrations were significantly above those in the uncontaminated cell. Flushing experiments in which the water inside the contaminated pipes was replaced with initially clean water showed that organic chemical concentrations inside the pipe rapidly (12 days) reached their preflushing levels.

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Elastomer Nanocomposites(I) (엘라스토머 나노복합체(I))

  • Bang, Dae-Suk;Kye, Hyoung-San;Cho, Ur-Ryong;Min, Byung-Gak;Shin, Kyung-Chul
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.22-33
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    • 2009
  • Recently, elastomer-nanocomposites reinforced with low volume fraction of nanofillers have attracted great interest due to their fascinating properties. The incorporation of nanofillers, such as, layered silicate clays, carbon nanotubes, nanofibers, calcium carbonate, metal oxides or silica nanoparticles into elastomers improves significantly their mechanical, thermal, dynamic mechanical, barrier properties, flame retardancy, etc. The properties of nanocomposites depend greatly on the chemistry of polymer matrices, nature of nanofillers, and the method in which they are prepared. The uniform dispersion of nanofillers in elastomer matrices is a general prerequisite for achieving desired mechanical and physical characteristics. In this paper, current developments in the field of elastomer nanocomposites reinforced with layered silicates, silica, carbon nanotubes, nanofibers and various other nanoparticles have been addressed.

Determination of Strain Energy Function of Rubber Materials Considering Stress Softening Behavior (응력연화거동을 고려한 고무 재료의 변형률 에너지 함수 결정)

  • Kim, W.S.;Hong, S.I.
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.168-176
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    • 2007
  • When the rubber vulcanizates reinforced with carbon black or silica are subjected to cyclic loading from its virgin state, the stress required on reloading is less than that on the initial loading. This stress softening phenomenon is referred to as the Mullins effect. The strain energy function of rubber vulcanizates was investigated using theory of pseudo-elasticity incorporated damage parameter that Ogden and Roxburgh have proposed to describe the damage-induced stress softening effect in rubber-like solids. The quasi-static cyclic loading test was performed using the NR-SBR vulcanizates reinforced with carbon black, and then the effect of a damage parameter to stress-strain curve in reloading and subsequent reloading paths was studied. The strain energy function of the rubber vulcanizates with a different filler content was also evaluated.

Local Control and Remote Optimization for CSTR Wastewater Treatment Systems (CSTR 하.폐수처리장의 국지 제어 및 원격 최적화 시스템)

  • Bae, Hyeon;Seo, Hyun-Yong;Kim, Sung-Shin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05a
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    • pp.21-25
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    • 2002
  • Activated sludge processes are widely used in biological wastewater treatment processes. The main motivation of this research is to develop an intelligent control strategy for activated sludge process (ASP). ASP is a complex and nonlinear dynamic system because of the characteristic of wastewater, the change in influent rate, weather conditions, and so on. The mathematical model of ASP also includes uncertainties which are ignored or not considered by process engineer or controller designer. The ASP model based on Matlab/Simulink is designed in this paper. The performance of the model is tested by IWA (International Water Association) and COST (European Cooperation in the filed of Scientific and Technical Research) data that include steady-state results during 14 days. In this paper, fuzzy logic control approach is applied to control the DO (dissolved oxygen) concentration. The fuzzy logic controller that includes two inputs and one output can adjust air flowrate. Also, this paper introduces the remote monitoring and control system that is applied for the CSTR (Continuously Stirred Tank Reactor) wastewater treatment system. The CSTR plant has a local control and the remote monitoring system which is contained communication parts which consist of LAN (Local Area Network) network and CDMA (Code Division Multiple Access) wireless module. Remote control and monitoring systems are constructed in the laboratory.

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Properties of Polymer-Modified Mortar with Styrene-Butyl Acrylate and Styrene Butadiene Rubber (S/BA와 SBR을 혼입한 폴리머 시멘트 모르타르의 특성)

  • Mun, Kyung-Ju;Song, Hae-Ryong;Hyung, Won-Gil
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.555-560
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    • 2008
  • Polymer-modified mortars have been largely used as paving materials, flooring, waterproofing material, adhesives, anticorrosive linings, deck coverings, and other various materials. The various types and properties of the mixed polymer largely affect the characteristics of polymer-modified mortar that has been mixed with polymer latexes. Consequently, its application purposes are varied according to these properties. This paper investigates the typical properties of polymer-modified mortars that contain styrene and butyl acrylate latexes and styrene butadiene rubber. They are then tested to obtain air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the superior flexural strength of polymer-modified mortars is obtained at a S/BA-2 and a polymer-cement ratio of 20%. And, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the types of polymer. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete.

Research on Flame Retardant Formaldehyde-Free Plywood Glued by Aqueous Polymer Isocyanate Adhesive

  • WEN, Ming-Yu;ZHU, Jia-Zhi;ZHU, Meng;SUN, Yao-Xing;PARK, Hee-Jun;SHI, Junyou
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.5
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    • pp.755-764
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    • 2020
  • Due to pronounced mechanical performance and being environmental friendly, aqueous polymer isocyanate adhesive (API) has been widely applied in the production of formaldehyde-free wood products. In this study, flame retardant formaldehyde-free plywood was prepared by incorporation of flame retardants into the API adhesive. Partially phosphorylated poly (vinyl alcohol) (PPVA) which was prepared by reacting poly (vinyl alcohol) with phosphoric acid was used to replace PVA in API formula. In addition, Mg-Al layered double hydroxides (LDH) was chosen as additive flame retardant, replacing traditional filler CaCO3 in API adhesive formula. And then, the flame retardant API adhesive with main agent (PPVA replacing PVA70wt.%, SBR emulsion 30wt.%), curing agent 10wt.% (accounts for of the main agent), and 20wt.% LDHs (accounts of the main agent) was used to prepare flame retardant plywood. The effect of application of PPVA and Mg-Al LDH on bonding strength of plywood was investigated. The flammability characteristics of the plywood were determined by cone calorimeter test (CCT). The results revealed that compared with the plywood prepared with API adhesive, the use of PPVA and LDH enhanced the flame retardancy of plywood without negatively affecting bonding strength. The CCT tests indicated that the heat release and smoke production flame retardant API plywood were lower than those of the ordinary API glued plywood. Promising developments for flame retardant API adhesive were expected in future applications of flame retardant formaldehyde-free plywood.

Greenhouse gases emission from aerobic methanotrophic denitrification (AeOM-D) in sequencing batch reactor

  • Lee, Kwanhyoung;Choi, Oh Kyung;Lee, Jae Woo
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.171-184
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    • 2017
  • This study presents the effect of hydraulic retention time (HRT) on the characteristics of emission of three major greenhouse gases (GHGs) including $CH_4$, $CO_2$ and $N_2O$ during operation of a sequencing batch reactor for aerobic oxidation of methane with denitrification (AeOM-D SBR). Dissolved $N_2O$ concentration increased, leveled-off and slightly decreased as the HRT increased from 0.25 to 1d. Concentration of the dissolved $N_2O$ was higher at the shorter HRT, which was highly associated with the lowered C/N ratio. A longer HRT resulted in a higher C/N ratio with a sufficient carbon source produced by methanotrophs via methane oxidation, which provided a favorable condition for reducing $N_2O$ formation. With a less formation of the dissolved $N_2O$, $N_2O$ emission rate was lower at a longer HRT condition due to the lower C/N ratio. Opposite to the $N_2O$ emission, emission rates of $CH_4$ and $CO_2$ were higher at a longer HRT. Longer HRT resulted in the greater total GHGs emission as $CO_2$ equivalent which was doubled when the HRT increased from 0.5d to 1.0 d. Contribution of $CH_4$ onto the total GHGs emission was most dominant accounting for 98 - 99% compared to that of $N_2O$ (< 2%).

Qualitative Analysis and Plasma Characteristics of Soil from a Desert Area using LIBS Technique

  • Farooq, W. Aslam;Tawfik, Walid;Al-Mutairi, Fahad N.;Alahmed, Zeyad A.
    • Journal of the Optical Society of Korea
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    • v.17 no.6
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    • pp.548-558
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    • 2013
  • In this work, laser induced breakdown spectroscopy (LIBS) is used to investigate soil samples collected from different desert areas of Riyadh city in Saudi Arabia. Both qualitative analysis and plasma parameters are studied via the observed LIBS spectra. These experiments have been done using a Spectrolaser-7000 system with 50 mJ fundamental wavelength of Nd:YAG laser and detection delay time of 1 microsecond. Many spectral lines are highly resolved for many elements like Al, Fe, Mg, Si, Mn, Na, Ca and K. The electron temperatures Te and electron densities Ne, for the constituent of generated LIBS plasma, are determined for all the collected samples. It is found that both Te and Ne vary from one desert area to other. This variation is due to the change of the elemental concentration in different desert areas that affects the sample's matrices. Time dependent measurements have also been performed on the soil samples. While the signal-to-base ratio (SBR) reached its optimal value at 1 microsecond, the plasma parameters Ne and Te reach values of $4{\times}10^{17}cm^{-3}$ and 9235 K, respectively, at 2.5 microsecond. The later indicate that the plasma cooling processes are slow in comparison to the previously observed results for metallic samples. The observed results show also that in the future it is possible to enhance the exploitation of LIBS in the remote on-line environmental monitoring application, by following up only the values of Ne and Te for one element of the soil desert sample using an optical fiber probe.