• The Korean Journal of Pesticide Science
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• v.18 no.2
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• pp.69-78
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• 2014

In the present study, we developed an official individual analytical method for cymoxanil using HPLC/UVD, respectively in different representative crops. Individual analytical methods for these pesticides are not included in the Korea food code. The samples were extracted with acetonitrile, concentrated and partitioned with dichloromethane and saturated sodium chloride solution. For cymoxanil, extracts were concentrated and clean-up through silica gel column chromatography with dicloromethane/acetone (60/40 v/v) and subjected to instrumental analysis. The limit of detection (LOD) for cymoxanil were 0.1 ng and 1 ng respectively and limit of quantitation (LOQ) were 0.02 mg/kg. Recoveries for cymoxail ranged from 79.6~107.6% respectively, at fortification level of 0.02 mg/kg (LOQ), 0.2 mg/kg (10 LOQ) and 1.0 mg/kg (50 LOQ) and the coefficient of variation (CV) was less than 10%, regardless of sample types. These results were further confirmed with LC/MS. The proposed simultaneous analysis method is reproducible and sensitive enough to determine the residues of cymoxanil in the agricultural commodities. According to the validation data and performance characteristics and high sample throughput, the proposed method is suitable for routine application.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.2
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• pp.90-96
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• 2018

Tracer experiments were carried out on two laboratory modes, "without media mode" and "with media mode", to examine the hydraulic characteristics of the anaerobic fluidized bed bioreactor (AFBR). For both configurations, a formula was derived for the hydraulics and data interpretation to obtain the actual characteristics of the reactor. The dispersion model is based on the assumption that carriers are non-reacting and the dispersion coefficient is constant. The model represents the one-dimensional unsteady-state concentration distribution of the non-reacting tracer in the reactors. The experimental results showed that the media increased the mixing conditions in the reactor considerably. For the reactor without media, in the range tested, the dispersion coefficient was at least an order of magnitude smaller than that of the reactor with media. Advective transport dominates and the flow pattern approaches the plug flow reactor (PFR) regime. The dispersion coefficient increased significantly as us, the superficial liquid velocity, was increased proportionally to 0.82cm/s. On the other hand, for the reactor with media, the flow pattern was in between a PFR and a completely mixed flow reactor (CMFR) regime, and the dispersion coefficient was saturated at us=0.41cm/s, remaining relatively constant, even at us=0.82cm/s. The dispersion coefficient depends strongly on the liquid Reynolds number (Re) or the particle Reynolds number (Rep) over the range tested.

• Journal of the Korean Wood Science and Technology
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• v.41 no.3
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• pp.173-180
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• 2013

This study was carried to provide basic data for the research of the effect of PEG impregnation on preventing wood from cracking during heat treatment. Three popular softwood species were selected for investigating the PEG penetration rate and retention depending on PEG molecular weight, PEG retention after heat treatment and their EMCs. The average retentions of PEG400 were reversely proportional to the basic densities of three species and those of the other PEGs showed similar behaviour as well. It is obvious that PEG retention decreased as PEG molecular weight increased with a species. PEG impregnation increased or decreased the moisture contents of the specimens within 2%, and increased their basic densities by 16.8% as a maximum. The Weight Percentage Losses of PEG400 during heat treatment were the largest among three PEG levels, which implied that lower molecular weight PEG leached more than the highers. There was less difference in EMC between PEG impregnated and control specimens at low RH, but their difference increased at high RH.

• Journal of Korea Water Resources Association
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• v.50 no.6
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• pp.387-395
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• 2017

Sea level rise, accompanied by climate change, is expected to exacerbate seawater intrusion in the coastal groundwater system. As the salinity of saturated groundwater increases, salinity can increase even in the unsaturated soil above the groundwater surface, which may cause crop damage in the agricultural land. The other adverse impact of sea level rise is reduced unsaturated soil thicknesses. In this study, a composite model to assess impacts of sea level rise in coastal agricultural land is proposed. The composite model is based on the combined applications of a three dimensional model for simulating saltwater intrusion into the groundwater and a vertical one dimensional model for simulating unsaturated zone flow and transport. The water level and salinity distribution of groundwater are calculated using the three dimensional seawater intrusion model. At some uppermost nodes, where salinity are higher than the reference value, of the 3D mesh one dimensional unsaturated zone modeling is conducted along the soil layer between the ground water surface and the ground surface. A particular location is judged salinized when the concentration at the root-zone depth exceeds the tolerable salinity for ordinary crops. The developed model is applied to a hypothetical agricultural reclamation land. IPCC RCP 4.5 and 8.5 scenarios were used as sea level rise data. Results are presented for 2050 and 2100. As a result of the study, it is predicted that by 2100 in the climate change scenario RCP 8.5, there will be 7.8% increase in groundwater saltwater-intruded area, 6.0% increase of salinized soil area, and 1.6% in increase in water-logging area.

• Korean Journal of Medicinal Crop Science
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• v.13 no.4
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• pp.190-193
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• 2005

Hemp is cultivated to produce fiber and seeds for extracting vegetable oil. This study was carried out to obtain reliable data on fatty acid profile including ${\gamma}-linolenic$ acid (GLA) in seeds of hemp accessions with regard to suitability for both human nutrition and pharmaceutical purposes. The ratio of unsaturated fatty acid including ${\alpha}-linolenic$ acid were high but saturated fatty acid including palmitic acid were low in the seeds of hemp accessions, perilla and evening primrose. The ratio of GLA in fatty acid profile of evening primrose and hemp seeds were 12.5% and 2.1 %, respectively but not detected in perilla seeds. In the fatty acid profile of hemp seeds accessions, the range and coefficient of variation of GLA were $0.8%{\sim}3.8%$ and 42.9%, respectively which are highest among the fatty acid. Among the major characteristics and fatty acid ratios, flowering date and ${\alpha}-linolenic$ acid showed highly positive correlation but not showed any significant correlation between THC (Tetrahydrocannabinol) and any fatty acids. Among the fatty acid ratios, negative correlation were showed between palmitic acid and ${\gamma}-linolenic$ acid, and showed highly negative correlation between oleic acid and ${\alpha}-linolenic$ acid, linoleic acid and a-linolenic acid. The accessions of high GLA ratio were originated from Europe including Central Russia, and were short in flowering date and stem height.

• Journal of the Korean Geotechnical Society
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• v.30 no.6
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• pp.51-59
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• 2014

Shallow landslides and debris flows are a common form of soil slope instability in South Korea. These events may be generally initiated as a result of intense rainfall or lengthening rainfall duration because of the effects of climate change. This paper presents the evaluation of rainfall-induced natural soil slope stability and reinforced soil slope instability under vertical load (railway or highway load) throughout South Korea based on quantitative analysis obtained from 58 sites rainfall observatories for 38 years. The slope stability was performed for infinite and geogrid-reinforced soil slopes by taking an average of maximum rainfall every ten years from 1973 to 2010. Seepage analysis is carried out on unsaturated soil slope using the maximum rainfall at each site, and then the factor of safety was calculated by coupled analysis using saturated and unsaturated strength parameters. The contour map of South Korea shows four stages in 10-year-time for the degree of landslide hazard. The safety factor map based on long term observational data will help prevent rainfall-induced soil slope instability for appropriate design of geotechnical structures regarding disaster protection.

• The Journal of Advanced Prosthodontics
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• v.10 no.3
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• pp.218-226
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• 2018

PURPOSE. The aim of this study was to define a color space of non-vital teeth and to compare it with the color space of matched vital teeth, recorded in the same patients. MATERIALS AND METHODS. In a group of 218 patients, with the age range from 17 to 70, the middle third of the buccal surface of 359 devitalized teeth was measured using a clinical spectrophotometer (Vita Easyshade Advance). Lightness ($L^*$), chromatic parameters ($a^*$, $b^*$), chroma ($C^*$), hue angle (h) and the closest Vita shade in Classical and 3D Master codifications were recorded. For each patient, the same data were recorded in a vital reference tooth. The measurements were performed by the same operator with the same spectrophotometer, using a standardized protocol for color evaluation. RESULTS. The color coordinates of non-vital teeth varied as follows: lightness $L^*$: 52.83-92.93, $C^*$: 8.23-58.90, h: 51.20-101.53, $a^*$: -2.53-24.80, $b^*$: 8.10-53.43. For the reference vital teeth, the ranges of color parameters were: $L^*$: 60.90-97.16, $C^*$: 8.43-39.23, h: 75.30-101.13, $a^*$: -2.36-9.60, $b^*$: 8.36-39.23. The color differences between vital and non-vital teeth depended on tooth group, but not on patient age. CONCLUSION. Non-vital teeth had a wider color space than vital ones. Non-vital teeth were darker (decreased lightness), more saturated (increased chroma), and with an increased range of the hue interval. An increased tendency towards positive values on the $a^*$ and $b^*$ axes suggested redder and yellower non-vital teeth compared to vital ones.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.519-533
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• 2010

Activity oefficients and solubilities of L-Alanine in aqueous solutions containing each of four electrolytes(NaCl, KCl, $NaNO_3$ and $KNO_3$) were measured at 298.15 K. The measurements of activity coefficients were carried out in the electrochemical cell coupled with two ion-selective electrodes(cation and anion), and the solubilities were measured by the gravimetric analysis of saturated solutions in equilibrium with the solid phase of L-alanine. To model the activity coefficients and solubilities of amino acid in the amino acid/electrolyte aqueous solutions, thermodynamic relations of the residual Helmholtz free energy in the amino acid/electrolyte aqueous solutions were developed based on the perturbed-chain statistical associating fluid theory(PC-SAFT) combined with the primitive mean spherical approximation(primitive-MSA). In the present model, it is assumed that the zwitterions of L-alanine are associated with each other and cross-associated with water molecules, and also cross-associated with the cation and anion dissociated from an electrolyte(inorganic salt). The activity coefficients and solubilities of L-Alanine calculated from the theoretical model proposed in this work are found to be well agreeable with experimental data.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.41 no.1
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• pp.13-22
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• 2004

This paper drives the exact expression of bit error rate(BER) performance for successive interference cancellation(SIC) algorithm against multipath interference components in a high-speed downlink packet access(HSDPA) system of W-CDMA downlink and the BER performance is evaluated by numerical analysis. Numerical results showed that the average BER performance is rapidly saturated in terms of increasing the number of multipath and is revealed significant improvement for improvement Processing gain(PG). For example, the average BER Performance of the SIC algorithm is superior to the performance of conventional scheme by more than 7dB and 1.4dB for processing gain PG=54 and 128 under the two-path channel and average BER=$1.0{\times}10^{-3}$, respectively. This results also indicated that the average BER saturation is occurred at nearly one weight factor which is assigned to pilot and data channels. Likewise, the average BER performance is greatly degraded due to increasing the interference power in proportional to the number of multipath with increasing multicode K. And the smaller multipath fading channel gain is arrived later, the more the average BER performance is improved. The results of performance analysis in this paper indicated that the multipath interference cancellation is required to improve the BER performance in a HSDPA system under multicode for high-speed packet transmission, low spreading factor, and multipath fading channel.

• Korean Journal of Social Welfare
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• v.57 no.1
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• pp.31-60
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• 2005

This study was performed to analyze empowerment process of the disabled. Participants were 11 disabled college students and they were individually face-to-face in-depth interviewed until data were saturated. This study used the grounded theory approach based on Strauss and Corbin(1998). With the qualitative constant comparative analysis, 105 concepts, 22 subcategories, and 12 categories were generated. In the axial coding, a paradigm model was proposed as follows: The central phenomenon of the empowerment process of the disabled adolescents was 'Rising from the Limits'. The causal conditions were 'Just living' and 'realizing disabilities'. The contextual conditions were 'Being excluded', 'But wishing', and 'Breaking down'. The intervening conditions were 'Without giving up' and 'Taking support'. The action/interaction strategies were 'Grasping own lifestyle' and 'Being proactive'. The consequences were 'Acquiring the self-control', 'Getting generosity', and 'Participating in society'. In the selective coding, the core category was 'to live together stately with grasping own lifestyle pro-actively as the disabled'. Based on the core category, three types and 4 stages of the empowerment process of the disabled adolescents were found. The types were 'Social change oriented type', 'Self-development oriented type', and 'Passive effort oriented type' and the stages took 'Isolation stage', 'Rising stage', 'Mastering stage' and 'Stately being together stage'. In particular, this process had the circulation structure of which these 4 stages are not terminated, and developed and repeated. In conclusion, these results convey to us the understanding and knowledge about empowerment process of the disabled as their healthy -whole and unique- development process. And some implications and suggestions for the social work services and theories about the disabled focusing on the pre-adulthood period.