• Title/Summary/Keyword: sample environment

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$KMnO_4$를 이용한 TCE 제거 실험 연구(I): -Headspace sample과 liquid sample 분석과 비교-

  • 현승규;우남칠;최인혁;이기철
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.370-375
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    • 2004
  • KMnO$_4$에 의한 TCE 용액의 분해에서 Headspace를 가진 반응 용기는 liquid sample을 headspce의 관측값으로 반응의 특성을 나타낼 수 없다. 이런 특성에 의해 in-situ KMnO$_4$ 이용은 TCE의 제거 효율에서 자연적인 휘발을 고려해야한다. 1:2.45 몰비에서 liquid sample의 결과 반감기는 약 80분이고 160분에 약 67%의 제거율을 보인다. 1:12.27 몰비의 경우 반감기는 10분이고 90분에 95%의 제거효율을 보인다.

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The Influence of Sample Size on Environment Assessment Using Benthic Macroinvertebrates (저서성 대형무척추동물을 이용한 환경평가에서 표본크기가 미치는 영향)

  • Kim, Ah Reum;Oh, Min Woo;Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.29 no.6
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    • pp.790-798
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    • 2013
  • Benthic macroinvertebrates are widely used as biological indicators for assessing the integrity of aquatic ecosystem. However, sampling has usually been done with fixed sample size due to time consuming and costly process. This study was conducted to find out the influence of sample size on the biological indices (H' DI, R1, J, EPT, ESB and BMI) of benthic macroinvertebrates. The 15 replicate samples were quantitatively collected from each 3 different site of two mountain streams in May, 2011. With the replicate data, we combined the abundance of each species with all the possible combinations of the sample size. Along with the increase of sample size, the number of species increased continuously and did not converge. BMI showed little difference whereas other biological indices increased or decreased.

A New Approach on Adsorption and Transport of Cesium in Organic Matter-rich Soil and Groundwater Environments Changed by Wildfires (산불로 인해 변화하는 토양지하수 환경에서의 세슘 흡착 및 거동에 대한 새로운 고찰)

  • Bae, Hyojin;Choung, Sungwook;Jeong, Jina
    • Journal of Korean Society on Water Environment
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    • v.38 no.1
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    • pp.10-18
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    • 2022
  • This study was conducted to investigate the effect of soil and groundwater environment changed by wildfire on cesium adsorption and transport. Soil samples (A, B) used in the study were collected from Gangwon-do, where wildfires frequently occur, and the adsorption and transport of cesium in the samples were evaluated through batch and column experiments. As a result of the batch adsorption experiments with various concentrations of cesium (CW ≈ 10~105 ㎍/L), the adsorption distribution coefficient (Kd) of cesium was higher in sample A for all observed concentrations. It means that the adsorption capacity of sample A was higher to that of sample B, which was also confirmed through the parameters of adsorption isotherm models (Freundlich and Langmuir model) applied to the experimental results. The fixed bed column experiments simulated the actual soil and groundwater environment, and they showed that cesium was retarded approximately 43 and 27 times than a nonreactive tracer in sample A and B, respectively. In particular, a significant retardation occurred in the sample A. Although sample A contains little clays, total organic carbon (TOC) contents were 3 times greater than sample B. These results imply that particulate organic matter caused by wildfire might influence the adsorption and transport of cesium in the organic matter-rich soil and groundwater environment.

Thermoelectric Properties of Sb Deficiency N-Type Skutterudite Co4Sb12 (Sb가 결핍된 N형 Skutterudite Co4Sb12의 열전 특성)

  • Tak, Jang-Yeul;Van Du, Nguyen;Jeong, Min Seok;Lee, NaYoung;Nam, Woo Hyun;Seo, Won-Seon;Cho, Jung Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.496-500
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    • 2019
  • In this study, we investigate the effect of an Sb-deficiency on the thermoelectric properties of double-filled n-type skutterudite ($In_{0.05}Yb_{0.15}Co_4Sb_{12-x}$). Samples were prepared by encapsulated induction melting, consecutive long-time annealing, and finally spark plasma sintering processes. The Sb-deficient sample contained a $CoSb_2$ secondary phase. Both the double-filled n-type skutterudite pristine and Sb-deficient samples showed metallic behavior in electrical conductivity with increasing temperature. The carrier concentration of the Sb-deficient sample decreased compared with that of the pristine sample. Due to a decrease in carrier concentration, the Sb deficient sample showed decreased electrical conductivity and an increased Seebeck coefficient compared with the conductivity and coefficient of the pristine sample. Furthermore, the Sb deficient sample showed an increase in the power factor (${\sigma}{\cdot}S^2$); the power factor maximum shifted to athe lower temperature side than ones of the pristine sample. As a result, the Sb-deficient sample represents an improved average figure of merit (ZT) and a $ZT_{max}$ temperature lower than that of the pristine sample. Therefore, we propose that Sb-deficient double-filled n-type skutterudite thermoelectric material ($In_{0.05}Yb_{0.15}Co_4Sb_{12-x}$) be used in the 573~673 K temperature range.

A Study on Chemical Features of Fog Sample in Summer at Mt. Sobaek (하계 소백산 안개의 화학적 특성에 관한 연구)

  • 최재천;이민영;이선기;남재철
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.399-406
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    • 1996
  • Acidic fog is catastrophic to aviation and potentially affect materials, vegetation, crops and public health. This paper was carried out to investigate the chemical features of fog sample at Mt. Sobaek (mean sea level : 1, 340m) from June to August 1995. Each sample was analyzed for pH, electrical conductivity and major ions (anion : $Cl^N)_3^-, SO_4^{2-}, cation : Na^+, NH_4^+, K^+, Mg^{2+}, Ca^{2+}$) by ion chromatography. The quality analysis of fog sample data was performed based on ion balance and electrical conductivity method. The wind directions are subdivided into the northerly and southerly wind according to the wind direction data at the Sobaek-san meteorological observation station. Statistical analyses were performed on the complete set of results in order to obtain a description of fog sample. All the statistical treatment was carried out using the SPSS/PC + software package. The major ion concentration of fog samples was higher for the northwesterly wind cases than sourtheasterly wind cases. The pH of fog sample varied between 2.95 and 6.08. The average pH and electrical conductivity of total sample (n=210) were 4.39 and 113.0 $\mu$S/cm, respectively. It may be noted that in nearly all the cases, the dominant major ions in the fog sample at Mt. Sobaek were $SO_4^{2-}, NO_3^-, H^+ and NH_4^+$.

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Extraction of Reducing Sugar with Anti-Oxidative Scavengers from Peels of Carya cathayensis Sarg.: Use of Subcritical Water

  • Shimanouchi, Toshinori;Ueno, Shohei;Yang, Wei;Kimura, Yukitaka
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.41-45
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    • 2014
  • The peels of Carya cathayensis Sarg. (PCCS) were treated under subcritical water conditions ($130^{\circ}C$ to $280^{\circ}C$ for 0 to 120 min). The extract from PCCS included reducing sugar, proteins, and compounds with radical scavenging activity. Addressing the reducing sugar that is a resource of bioethanol, we could maximize the reducing sugar under the subcritical water ($190^{\circ}C$ for 60 min) and obtain 0.24 g/g-sample together with 9.7 units/mg-sample of radical scavenging activity. The obtained extract was estimated to correspond to 1 L of bioethanol/100 g-sample. It was therefore considered that the treatment by subcritical water could yield reducing sugar and natural compounds with radical scavenging activity.

A Study on Vegetation Index for Zoning of Natural Ecosystem on Baekdudaegan (백두대간 자연생태계의 지역구분을 위한 식생지수에 관한 연구)

  • 김갑태
    • Korean Journal of Environment and Ecology
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    • v.16 no.3
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    • pp.223-232
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    • 2002
  • For the zoning of natural ecosystem, Vegetation Index is calculated from the vegetation data surveyed on Baekdudaegan (Pijae-Doraegijae). Five factors -biodiversity, conservation value of the stand, environmental quality, longevity of the stand, site productivity- are considered in the calculation of Vegetation Index. Vegetation Index might be a useful zoning tool for management of Baekdudaegan. For Vegetation Index I, 59 sample plots 52.2% of total 113 sample plots are belong to core area, 34 sample plots 30.l% and 20 sample plots 17.7% are belong to buffer zone and transition area, respectively. For Vegetation Index II, 49 sample plots 43.4% of total 113 sample plots are belong to core area, 38 sample plots 33.6% and 26 sample plots 23.0% are belong to buffer zone and transition area, respectively.

The Influence of Workplace Violence Experience on Depression among Female Caregivers (여성 간병 돌봄 노동자의 직장 내 폭력 경험이 우울에 미치는 영향)

  • Lee, Su Jeong;Kim, Jinsook
    • Korean Journal of Occupational Health Nursing
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    • v.30 no.2
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    • pp.37-45
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    • 2021
  • Purpose: This study aimed to investigate the influence of workplace violence experience on depression among female caregivers in Korea. Methods: This study was a secondary data analysis of data from the 5th Korean Working Conditions Survey (KWCS). The study sample consisted of 484 female caregivers. IBM SPSS 25.0 was used for complex sample analysis, which considered sampling the weights of variables. Based on the survey questions, we used complex sample cross-tabulation and the complex sample general linear model (CSGLM). Results: About 10.1% of female caregivers experienced workplace violence. The factors influencing workplace violence experience on depression were organizational justice (p=.048) and illness (p=.004). However, in cases with no violence, the influencing factors were psychological work environment (p=.001), work environment satisfaction (p=.024), and work engagement (p=.004). Conclusion: Caregivers are vulnerable to workplace violence. Therefore, it is necessary to formulate a policies such as organizational justice, work environment satisfaction, and work engagement to improve the working environment.

Surveys on the residual level of fluoroquinolones in eggs (식용란의 플루오로퀴놀론계 합성항균제의 잔류에 관한 조사)

  • Koh Ba-Ra-Da;Park Seong-Do;Jang Mi-Sun;Na Ho-Myung;Kim Yong-Hwan
    • Korean Journal of Veterinary Service
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    • v.28 no.3
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    • pp.235-243
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    • 2005
  • This surveies were carried out to investigate the residual levels of fluoroquinolones in chicken and quail eggs by bioassay and HPLC method. The eggs of 240 samples collected from market and farm in Gwangju Metropolitan city were examined from May to December in 2003. Residual antibiotic materials were detected from 47 samples of the 240 eggs by bioassay. Of the 240 eggs assayed, ciprofloxacin, danofloxacin, norfloxacin, ofloxacin, orbifloxacin and perfloxacin were not detected but enrofloxacin was detected from 5 samples in 228 chicken eggs and 1 sample in 12 quail eggs using HPLC with fluorescence detector by multi-residue method. 2 sample eggs in 6 sample which were detected by HPLC were not positive with bioassay. The average residual concentration of enrofloxacin was 0.494 mg/kg in 6 positive samples. The highest residual concentration of enrofloxacin was 1.83mg/kg.

Quantification of Uncertainty Associated with Soil Sampling and Its Reduction Approaches (토양오염도 평가시 시료채취 불확실성 정량화 및 저감방안)

  • Kim, Geonha
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.94-101
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    • 2013
  • It is well known that uncertainty associated with soil sampling is bigger than that with analysis. In this research, uncertainties for soil sampling when assessing TPH and BTEX concentration in soils were quantified based on actual field data. It is almost impossible to assess exact contamination of the site regardless how carefully devised for sampling. Uncertainties associated with sample reduction for further chemical analysis were quantified approximately 10 times larger than those associated with core sampling on site. Bigger uncertainties occur when contamination level is low, sample quantity is small, and soil particle is coarse. To minimize the uncertainties on field, homogenization of soil sample is necessary and its procedures are proposed in this research as well.