• Title/Summary/Keyword: salt-sensitivity

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AC Complex Impedance Study on the Resistive Humidity Sensors with Ammonium Salt-Containing Polyelectrolyte using a Different Electrode Pattern

  • Cha, Jae-Ryung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2781-2786
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    • 2013
  • We examined the effect of electrode fingers and gaps of coplanar interdigitated electrode (IDE) structures to characterize the ammonium salt-containing polyelectrolyte film of resistance-based humidity sensors. IDEs designed for this purpose were flexible gold electrodes deposited on a polyimide substrate using a printing process because the geometry presents a potential for tunable sensitivity over other electrode designs. The basic design of the sensors consisted of IDEs with a different number of electrode fingers such as 3, 4, and 5 and gap sizes of 310, 360, 410, and $460{\mu}m$. Details of the AC complex impedance characteristics such as the Nyquist plot, Bode plot, and activation energy based on electrode construction were investigated.

Corrosion Characteristics of Amorphous Alloy Ribbon ($Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$) in Hydrochloric Acid Aqueous Solution

  • Choi, Chil-Nam;Hyo, Kyung-Yang;Yang, Myung-Sun
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.05a
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    • pp.236-237
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    • 2001
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves with amorphous $Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$ alloy ribbon. The results were particularly examined to identify the influences of corrosion potential including various conditions such as hydrochloric acid, temperature, salt, pH, and oxygen. The optimum conditions were established with variations including temperature, salt, pH, oxygen, corrosion rate, and resistance of corrosion potential. The mass tranfer coefficient(${\alpha}$) value was determined with the Tafel's slope for the anodic dissolution based on the polarization effect with optimum conditions. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity($I_{r}/I_{f}$).

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A Fiber Optic Sensor for Measurements of Solute Concentration in Fluids

  • Kim, Chang-Bong;Su, C.B.
    • Journal of the Optical Society of Korea
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    • v.7 no.2
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    • pp.102-105
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    • 2003
  • A new and simple calibration technique that greatly enhances the measurement sensitivity of conventional fiber-optic reflectometry based on Fresnel reflection from the tip of a fiber is used for demonstrating the feasibility of measuring solute concentrations and index changes in fluids to very high precision. The amplitude of pulses originating from reflection from the fiber-fluid interface is compared in real-time with the amplitude of reference pulses from a fiber-air interface such that errors caused by pulse amplitude fluctuations and slightly varying detector responses are corrected. Using solutions of salt and water, it is demonstrated that the technique is capable of measuring index changes of about $1 {\times} 10^{-5}$ corresponding to a salt concentrations of 0.01 %.

Dosimetric Characteristics of Flexible Radiochromic Film Based on LiPCDA

  • Jung, Seongmoon;Cho, Jin Dong;Kim, Jung-in;Park, Jong Min;Choi, Chang Heon
    • Progress in Medical Physics
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    • v.32 no.4
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    • pp.179-184
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    • 2021
  • This study aimed to determine the optimal thickness of the active layer and scan mode for a flexible radiochromic film (F-RCF) based on the active lithium salt of pentacosa-10,12-diynoic acid (LiPCDA). F-RCFs of 90, 120, 140, and 170-㎛ thickness were fabricated using LiPCDA. Several pieces of the F-RCFs were exposed to doses ranging from 0 to 3 Gy. Transmission and reflection modes were used to scan the irradiated F-RCFs. Their dose-response curves were obtained using a second-order polynomial equation. Their sensitivity was evaluated for both scanning modes, and the uniformity of the batch was also examined. For both the transmission and reflection modes, the sensitivity increased as the film thickness increased. For the reflection mode, the dose response increased dramatically under 1 Gy. The value of the net optical density varied rapidly as the thickness of the film increased. However, the dose-response curves showed a supralinear-curve relationship at doses greater than 2 Gy. The sensitivity of the reflection scan at doses greater than 2 Gy was higher than that of the reflection scan within 0-2 Gy. The sensitivity steadily decreased with increasing doses, and the sensitivity of the two modes was within 0.1 to 0.2 at 2 Gy and was saturated beyond that. For the transmission scan, the sensitivity was approximately 0.2 at 3 Gy. For the intra-batch test result, the maximum net optical density difference of the intra-batch was 5.5% at 2 Gy and 7.4% at 0.2 Gy in the transmission and reflection scans, respectively. In the low-dose range, film thickness of more than 120-㎛ was proper in the transmission mode. In contrast, the transmission mode showed a better result compared to the reflection mode. Therefore, the proper scan mode should be selected according to the dose range.

Colorimetric Determination of Trace Mercury(II) in Water by Back Extraction and PAR (역추출과 PAR법에 의한 수질중 미량 수은의 비색정량에 관한 연구)

  • 정창웅
    • Journal of Environmental Health Sciences
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    • v.21 no.3
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    • pp.96-101
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    • 1995
  • A selective and highly sensitive spectrophotometric measurements have been developed for the determination of trace mercury(II) with thiosulfate and PAR. Hg(II)-thiosulfate complex was extracted into high molecular alkylamine such as quaternary ammonium salt and back extracted into 1 M-HCl solution. The Hg(II)-PAR complex has maximum absorbance at 499 nm and obeys Beer's law in the range of 0.04~1.0 $\mu g/mL$ of mercury(II). The molar absorptivity and Sandell's sensitivity are $6.27\times 10^4 L.mole^{-1} cm^{-1}$ and $3.2\times 10^{-3}g/cm^2$ respectively.

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Redox Reaction of Poly(ethyleneterephthalate) Polymer in Aprotic Solvent

  • Choi, Chil-Nami
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_1
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    • pp.47-53
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    • 2001
  • We carroed our to measure the variations of potential with current density (polarization curves) for poly(ethyleneterephthalate). The results were particularly examined to identify the influences on corrosion potential and corrosion rate of various factors including temperature, pH, exposure time, salt, and enzyme. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum passive current density were designated as the relative corrosion sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

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ANALYSIS OF EQUILIBRIUM METHODS FOR THE COMPUTATIONAL MODEL OF THE MARK-IV ELECTR OREFINER

  • Cumberland, Riley;Hoover, Robert;Phongikaroon, Supathorn;Yim, Man-Sung
    • Nuclear Engineering and Technology
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    • v.43 no.6
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    • pp.547-556
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    • 2011
  • Two computational methods for determining equilibrium states for the Mark-IV electrorefiner (ER) have been assessed to improve the current computational electrorefiner model developed at University of Idaho. Both methods were validated against measured data to better understand their effects on the calculation of the equilibrium compositions in the ER. In addition, a sensitivity study was performed on the effect of specific unknown activity coefficients-including sodium in molten cadmium, zirconium in molten cadmium, and sodium chloride in molten LiCl-KCl. Both computational methods produced identical results, which stayed within the 95% confidence interval of the experimental data. Furthermore, sensitivity to unavailable activity coefficients was found to be low (a change in concentration of less than 3 ppm).

SPECTRAL SENSITIZATION OF BENZOXAZOLO CARBOCYANINE DYE IN PHOTOGRAPHIC EMULSION

  • Kim, Yeoung-Chan
    • Journal of Photoscience
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    • v.5 no.1
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    • pp.45-46
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    • 1998
  • The green-sensitive silver halide emulsion layer has been studied UV-Vis absorption band of 9-methvl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt in methanol solution and 10% methanol containing 10$^{-2}$ M KCl. the products were observed at 502nm and 540nm(J-band), respectively. The maximum spectral sensitivity of sensntizing silver halide emulsion showed at 546nm. In conclusion, benzoxazolo carbocyanine dye can be used as a green-sensitizing dye for the photographic emulsion.

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Drug Resistance of Staphylococcus aureus Isolates from Raw Cow Milk (생유에서 분리된 포도구균의 약제내성)

  • Kim Jong-Myeon;Song Hee-Jong;Kwak Taik-Hoon
    • Journal of the korean veterinary medical association
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    • v.15 no.3
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    • pp.143-148
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    • 1979
  • A total of 360 Staphylococcus isolates from 26 raw cow milk sample in milk plants of Jeonju district during Octover 1977, identified by $7.5\%$ salt resistant reaction and other biological properties. Antibiotic sensitivity test was also perfor

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Effect of Rock Mass Properties on Coupled Thermo-Hydro-Mechanical Responses at Near-Field Rock Mass in a Heater Test - A Benchmark Sensitivity Study of the Kamaishi Mine Experiment in Japan

  • Hwajung Yoo;Jeonghwan Yoon;Ki-Bok Min
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.1
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    • pp.23-41
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    • 2023
  • Coupled thermo-hydraulic-mechanical (THM) processes are essential for the long-term performance of deep geological disposal of high-level radioactive waste. In this study, a numerical sensitivity analysis was performed to analyze the effect of rock properties on THM responses after the execution of the heater test at the Kamaishi mine in Japan. The TOUGH-FLAC simulator was applied for the numerical simulation assuming a continuum model for coupled THM analysis. The rock properties included in the sensitivity study were the Young's modulus, permeability, thermal conductivity, and thermal expansion coefficients of crystalline rock, rock salt, and clay. The responses, i.e., temperature, water content, displacement, and stress, were measured at monitoring points in the buffer and near-field rock mass during the simulations. The thermal conductivity had an overarching impact on THM responses. The influence of Young's modulus was evident in the mechanical behavior, whereas that of permeability was noticed through the change in the temperature and water content. The difference in the THM responses of the three rock type models implies the importance of the appropriate characterization of rock mass properties with regard to the performance assessment of the deep geological disposal of high-level radioactive waste.