• Title/Summary/Keyword: salt reduction

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Mechanism of the Electrode Reduction of Cupferron in Neutral and Alkaline Media (중성 및 알카리성수용액에서 Cupferron 의 전극환원메카니즘)

  • Hwang, Kum-Sho;Hwang, Jung-Ui
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.11 no.1
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    • pp.32-55
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    • 1975
  • The ammonium salt of N-Nitrosophenylhydroxiamine, namely Cupferron, is a well-known analytical reagent which precipitates a great number of metal ions in acid medium. Various structures of electrode reduction for N-Nitrosophenylhydroxiamine have been suggested in acid and alkaline media by many researchers, but not in neutral medium. So the mechanism of electrode reaction of Cupferron was investigated by both chronopotentiometric and polarographic methods. It was estimated that the reduction of Cupferron occurs in a three-step mechanism through which a chemical step is interposed between two charge transfer, the ECE (charge transfer-chemical reaction-charge transfer) mechanism, over a range of neutral and alkaline media. The chemical reaction of the process was assumed to be acid-base catalyzed from the fact that kapp (over all rate constant) of chemical reaction is pH dependent.

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Synthesis of FePt Nanoparticles by Chemical Reduction Process (화학적인 환원 공정에 의한 FePt 나노입자의 합성)

  • 김순길;이창우;이재성
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.242-246
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    • 2004
  • FePt nanoparticles for high-density magnetic recording media were synthesized by the simultaneous chemical reduction of Fe(acac) $_2$ and Pt(acac) $_2$ with 1,2-hexadecanediol as the reducing reagent. TEM images showed that the shape of as-synthesized FePt nanoparticle was spherical and average particle size was 3 nm. Also, SAD pattern showed that crystal structure was disordered FCC (face centered cubic). These FCC structured nanoparticles were transformed FCT (face centered tetragonal) structure by annealing at 55$0^{\circ}C$ for 30 min in Ar atmosphere. XRD analysis revealed that as-synthesized FePt nanoparticles were transformed from disordered FCC to ordered FCT. Finally, the coercivity of 2 kOe for FePt nanoparticles with FCT structure was obtained by VSM measurement.

Development of cobalt encased in nitrogen and sulfur co-doped carbon nanotube for non-precious metal catalyst toward oxygen reduction reaction

  • Kim, Tae-Hyun;Sang, Byoung-In;Yi, Sung-Chul
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.499-503
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    • 2018
  • In this paper, cobalt embedded in nitrogen and sulfur co-doped carbon nanotubes (CoNSTs) were synthesized for oxygen reduction reaction (ORR) catalysts. The CoNSTs were prepared through a facile heat treatment method without any templates. Different amounts of the metal salt were employed to examine the physicochemical and electrochemical properties of the CoNSTs. The CoNSTs showed the bamboo-like tube morphology with the encased Co nanoparticles in the tubes. Through the x-ray photoelectron spectroscopy analysis, the catalysts exhibited different chemical states of the nitrogen and sulfur species. As a result, the CoNST performed high activity toward the ORR in an acidic condition with the onset potential of 0.863 V (vs. reversible hydrogen electrode). It was clearly demonstrated from the electrochemical characterizations that the quality of the nitrogen and sulfur species significantly influences the ORR activity rather than the total amount of the dopants.

Effect of sodium restriction on blood pressure of unstable or uncontrolled hypertensive patients in primary care

  • De Keyzer, Willem;Tilleman, Katrien;Ampe, Jan;De Henauw, Stefaan;Huybrechts, Inge
    • Nutrition Research and Practice
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    • v.9 no.2
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    • pp.180-185
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    • 2015
  • BACKGROUND/OBJECTIVES: The aims of the present study are: 1) to quantify sodium consumption of patients with unstable or uncontrolled hypertension, 2) to investigate if reduced sodium intake can lower BP in these patients, and 3), to assess the acceptability and feasibility of this approach. SUBJECTS/METHODS: This study included 25 adults (age: 50+ years) with frequently elevated BP or patients with uncontrolled, uncomplicated hypertension despite drug treatment in a general practice setting. BP and salt intake (24h urinary excretion and food records) were measured at baseline and after a sodium reduced diet. RESULTS: Mean (${\pm}SD$) systolic (SBP) over diastolic (DBP) blood pressure (mmHg) at baseline was $150.7({\pm}9.5)$/$84.149({\pm}5.6)$. Mean urinary sodium excretion was 146 mmol/24h. A reduction of 28 mmol sodium excretion decreased SBP/DBP to $135.5({\pm}13.0)$/$82.5({\pm}12.8)$ (P < 0.001). After one month of no dietary advice, only in 48%, SBP was still ${\leq}140mmHg$. CONCLUSION: Assessment of sodium intake using food records, 24h urine collections and probing questions to identify use of sodium containing supplements or drugs are essential for tailored advice targeted at sodium intake reduction. The results of the present study indicate that reduced sodium intake can lower BP after 4 weeks in unstable or uncontrolled hypertensive patients.

Study on the Improvement of Lung CT Image Quality using 2D Deep Learning Network according to Various Noise Types (폐 CT 영상에서 다양한 노이즈 타입에 따른 딥러닝 네트워크를 이용한 영상의 질 향상에 관한 연구)

  • Min-Gwan Lee;Chanrok Park
    • Journal of the Korean Society of Radiology
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    • v.18 no.2
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    • pp.93-99
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    • 2024
  • The digital medical imaging, especially, computed tomography (CT), should necessarily be considered in terms of noise distribution caused by converting to X-ray photon to digital imaging signal. Recently, the denoising technique based on deep learning architecture is increasingly used in the medical imaging field. Here, we evaluated noise reduction effect according to various noise types based on the U-net deep learning model in the lung CT images. The input data for deep learning was generated by applying Gaussian noise, Poisson noise, salt and pepper noise and speckle noise from the ground truth (GT) image. In particular, two types of Gaussian noise input data were applied with standard deviation values of 30 and 50. There are applied hyper-parameters, which were Adam as optimizer function, 100 as epochs, and 0.0001 as learning rate, respectively. To analyze the quantitative values, the mean square error (MSE), the peak signal to noise ratio (PSNR) and coefficient of variation (COV) were calculated. According to the results, it was confirmed that the U-net model was effective for noise reduction all of the set conditions in this study. Especially, it showed the best performance in Gaussian noise.

Electrochemical Oxidation of Silver (I) Salt (Ag(I) 염의 전해산화)

  • Duk Mook Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.2
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    • pp.158-163
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    • 1985
  • The anodic oxidations of the Silver(I) / Silver(II) / Silver(III) system have been studied in aq. 2M $AgNO_3$ solution with Platinum and Carbon electrodes. It has been found that $Ag_7O_8NO_3$ can be produced at relatively higher current density. Deposited black Oxy-salt were analyzed with several methods such as oxidizing power, X-ray powder diffraction patterns, thermal analysis, and reduction curves. It decomposed to AgO upon being suspended in boiling water. AgO compound obtained from $Ag_7O_8NO_3$ were purer and denser than Alfa-product AgO.

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데침과 열수 침적의 병용 열처리와 trehalose 첨가가 오이 김치의 저장중의 효소 활성의 변화와 관능 검사에 미치는 효과

  • 이혜정
    • Proceedings of the Korean Journal of Food and Nutrition Conference
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    • 2001.12a
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    • pp.131-131
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    • 2001
  • The enzyme activity and organoleptic properties of Korean pickled cucumber were studies for their changes during fermentation. The Korean pickled cucumber were prepared by blanching and high temperature soaking in salt solution and trehalose treatment The results shelved that the effect of combined heat and trehalose treatment significantly reduced the fermentation rate and softening rate of texture while a rather rapid fermentation was for those pleserved with salt. The effect of trehalose treatment enhenced fermentation and it was significantly reduced softening rate of texture by 2% treatment. The sensory evaluation of Korean pickled cucumber was found that combined heat treatment with blanching and hot solution had a positive effect for reduction of softening of cucumber tissue, however, odor and taste were not significantly affected. This study suggested that combined heat and trehalose treatment might have potential for affording protection against softness of cucumber tissue during the fermentation time.

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The Study on Effect of Collision Safety by Corrosion of Body Structure (차체구조물의 부식이 충돌안전도에 미치는 영향에 관한 연구)

  • 박인송;정태용
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.141-148
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    • 2002
  • Repair were made for front pillar, center pillar and side-step panel for lightweight vehicles with head-on and 40% off-set collision of 15 km/h in a RCAR standard. The salt dilution was sprayed and the compression tests were performed for vehicles with and without anti-corrosional treatment after repair. After 764 hours of salt-dilt sprayed test without using anti-corrosion, the mean penetration depth fur corrosion was shown to be 58% of the thickness. The resulyed decrease in bending stiffness by 10∼20% can cause reduction of the residual life and crash-absorption capability for damaged vehicles. The corrosoin safety tests showed that the anti-corrosional treatment should be made to improve the safety characteristics for a or damaged car.

Characteristics and Correlation among Water Quality Parameters of Idong Reservoir Watershed (논문 - 이동저수지 유역의 수질 특성 및 항목간 상관관계 분석)

  • Kim, Hyung-Joong;Haam, Jong-Hwa;Kim, Dong-Hwan;Hong, Dae-Byuk
    • KCID journal
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    • v.18 no.2
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    • pp.15-24
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    • 2011
  • This study was carried out to analyze characteristics of water quality and correlation among water quality parameters in Idong reservoir used for agricultural water. The pH and concentrations of DO, SS, BOD, COD, TP, Chl-a in Idong reservoir almost met the water quality standards for agricultural water, but TN concentration exceeded the water quality standards for agricultural water. All of water quality items had no significant difference between horizontal points at 95% confidence level and the Idong reservoir was possible to be treated as the single water body. As NIP ratio of the Idong reservoir is 52, TP is a limiting nutrient salt. As TN exceeds the water quality standards, it is required to preserve TP below current state to prevent water bloom by eutrophication. Therefore, reduction of phosphorus from the watershed is necessary for controlling the eutrophication of Idong reservoir.

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Effect of Admixtures on the Steel Corrosion in Mortar (혼화재를 혼입한 모르터내의 철근부식성상에 관한 연구)

  • 임순지;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.145-149
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    • 1995
  • This study is to recognize the effect of silica-fume, fly-ash, and chemical proportion in mortar that have salt on the inside affect steel bar corrosion. water-binder ratio, 0.5, compounds, each of 10, 15, 20% by weight of cement, Nacl mixing weight, 0.5, 1.0, 2.0% by weight of binder, The speciment is sealed and cured for 28days, the corrosion area ratio and weight reduction ratio is measured after the accelerated corrosion test of 20 cycles. The conclusion shows that there is no suppression effect of steel bar corrosion of silica-fume, fly-ash, in case of having salt on the inside.

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