• Title/Summary/Keyword: salt analysis

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Interpretation of Vertical Electrical Sounding Data in Saltwater Intrusion Area using Geostatistical Method (지구통계분석을 이용한 해수침투지역에서의 전기비저항탐사 자료 해석)

  • Song Sung-Ho;Lee Gyu-Sang;Yong Hwan-Ho;Kim Jin-Sung;Seong Baek-Uk;Woo Myung-Ha
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.05a
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    • pp.59-64
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    • 2005
  • Although experimental analysis for groundwater sample at wells located systematically are very effective to delineate seawater intrusion region at coastal area, this method is restricted in few wells and time. We have conducted electrical resistivity sounding at 30 points in the study areas to analyze the region of seawater intrusion and found the boundary between salt wedge and fresh water lens from the analysis results of geostatistical method using variogram for one-dimensional inversion results. The methodology adopted in this study would be useful for finding the seawater intrusion region and evaluating quantitatively.

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Analysis of UV Filters in Water using Stir Bar Sorptive Extraction (SBSE) and GC/MS-MS (교반막대 추출법과 GC/MS-MS를 이용한 수중의 자외선 차단제 분석)

  • Seo, Chang-Dong;Son, Hee-Jong;Jung, Jong-Moon;Choi, Jin-Taek;Jang, Seong-Ho
    • Journal of Environmental Science International
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    • v.23 no.6
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    • pp.1037-1047
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    • 2014
  • A highly sensitive analytical method based on stir bar sorptive extraction (SBSE) technique and gas chromatography/tandem mass spectrometry (GC/MS-MS) has been developed, allowing the simultaneous multi-analyte determination of seven UV filters in water samples. The stir bar coated with polydimethylsiloxane (PDMS) was added to 40 mL of water sample at pH 3 and stirred at 1,100 rpm for 120 min. Other SBSE parameters (salt effect and presence of organic solvent) were optimised. The method shows good linearity (coefficients > 0.990) and reproducibility (RSD < 12.9%). The extraction efficiencies were above 84% for all the compounds. The limits of detections (LOD) and limits of quantification (LOQ) were 2.1~8.6 ng/L and 6.8~27.5 ng/L, respectively. The developed method offers the ability to detect 8 UV filters at ultra-low concentration levels with only 40 mL of sample volume. Matrix effects in tap water, river water, wastewater treatment plant (WWTP) final effluent water and seawater were investigated and it was shown that the method is suitable for the analysis of trace level of 7 UV filters except of benzophenone (BP). The method developed in the present study has the advantage of being rapid, simple, high-sensitive and both user and environmentally friendly.

An Analysis of Aerosol Direct Radiative Forcing Using Satellite Data in East Asia During 2001-2010 (위성자료를 이용한 2001-2010년 동안의 동아시아 지역 에어로졸 직접복사강제력 분석)

  • Jeong, Ji-Hyun;Kim, Hak-Sung;Kim, Joon-Tae;Park, Yong-Pil;Choi, Hyun-Jung
    • Journal of Environmental Science International
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    • v.22 no.8
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    • pp.1053-1062
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    • 2013
  • The shortwave aerosol direct radiative forcing (SWARF) was analyzed using the Clouds and Earth's Radiant Energy System (CERES) data in the East Asian region from 2001 to 2010. In the Yellow Sea and the Korean Peninsula, located in the leeward side of China, significantly negative high SWARF at the top of atmosphere (TOA) occurs due to the long-range transport of anthropogenic (e.g. sulphate) and natural aerosols (e.g. mineral dust) from the East Asian continent. Conversely, eastern China has much higher levels of SWARF at the surface (SFC) due to anthropogenically emitted aerosol than in the Yellow Sea and the Korean Peninsula. Since the radiative forcing of aerosols in the atmosphere are different in type, aerosol types were classified into sea salt+sulphate, smoke, sulphate and dust by using satellite data. The analysis on the SWARF by the classified aerosol types indicated that sulphate occupies a predominant portion of the atmosphere in the Yellow Sea and the Korean Peninsula in the summer. In particular, the annual averages of the summer TOA SWARF increased in the Yellow Sea and the Korean Peninsula from 2001 to 2010.

Crystal Structure and Tautomerism Study of the Mono-protonated Metformin Salt

  • Wei, Xiaodan;Fan, Yuhua;Bi, Caifeng;Yan, Xingchen;Zhang, Xia;Li, Xin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3495-3501
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    • 2014
  • A novel crystal, the mono-protonated metformin acetate (1), was obtained and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. It was found that one of the imino group in the metformin cation was protonated along with the proton transfer from the secondary amino group to the other imino group. Its crystal structure was then compared with the previously reported diprotonated metformin oxalate (2). The difference between them is that the mono-protonated metformin cations can be linked by hydrogen bonding to form dimers while the diprotonated metformin cations cannot. Both of them are stabilized by intermolecular hydrogen bonds to assemble a 3-D supermolecular structure. The four potential tautomer of the mono-protonated metformin cation (tautomers 1a, 1b, 1c and 1d) were optimized and their single point energies were calculated by Density Functional Theory (DFT) B3LYP method based on the Polarized Continuum Model (PCM) in water, which shows that the most likely existed tautomer in human cells is the same in the crystal structure. Based on the optimized structure, their Wiberg bond orders, Natural Population Analysis (NPA) atomic charges, molecular electrostatic potential (MEP) maps were calculated to analyze their electronic structures, which were then compared with the corresponding values of the diprotonated metformin cation (cation 2) and the neutral metformin (compound 3). Finally, the possible tautomeric mechanism of the mono-protonated metformin cation was discussed based on the observed phenomena.

Prismatic-core advanced high temperature reactor and thermal energy storage coupled system - A preliminary design

  • Alameri, Saeed A.;King, Jeffrey C.;Alkaabi, Ahmed K.;Addad, Yacine
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.248-257
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    • 2020
  • This study presents an initial design for a novel system consisting in a coupled nuclear reactor and a phase change material-based thermal energy storage (TES) component, which acts as a buffer and regulator of heat transfer between the primary and secondary loops. The goal of this concept is to enhance the capacity factor of nuclear power plants (NPPs) in the case of high integration of renewable energy sources into the electric grid. Hence, this system could support in elevating the economics of NPPs in current competitive markets, especially with subsidized solar and wind energy sources, and relatively low oil and gas prices. Furthermore, utilizing a prismatic-core advanced high temperature reactor (PAHTR) cooled by a molten salt with a high melting point, have the potential in increasing the system efficiency due to its high operating temperature, and providing the baseline requirements for coupling other process heat applications. The present research studies the neutronics and thermal hydraulics (TH) of the PAHTR as well as TH calculations for the TES which consists of 300 blocks with a total heat storage capacity of 150 MWd. SERPENT Monte Carlo and MCNP5 codes carried out the neutronics analysis of the PAHTR which is sized to have a 5-year refueling cycle and rated power of 300 MWth. The PAHTR has 10 metric tons of heavy metal with 19.75 wt% enriched UO2 TRISO fuel, a hot clean excess reactivity and shutdown margin of $33.70 and -$115.68; respectively, negative temperature feedback coefficients, and an axial flux peaking factor of 1.68. Star-CCM + code predicted the correct convective heat transfer coefficient variations for both the reactor and the storage. TH analysis results show that the flow in the primary loop (in the reactor and TES) remains in the developing mixed convection regime while it reaches a fully developed flow in the secondary loop.

Enhanced drought and salinity tolerance in transgenic potato plants with a BADH gene from spinach

  • Zhang, Ning;Si, Huai-Jun;Wen, Gang;Du, Hong-Hui;Liu, Bai-Lin;Wang, Di
    • Plant Biotechnology Reports
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    • v.5 no.1
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    • pp.71-77
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    • 2011
  • Drought and salinity are the most important abiotic stresses that affect the normal growth and development of plants. Glycine betaine is one of the most important osmolytes present in higher plants that enable them to cope with environmental stresses through osmotic adjustment. In this study, a betaine aldehyde dehydrogenase (BADH) gene from spinach under the control of the stress-induced promoter rd29A from Arabidopsis thaliana was introduced into potato cultivar Gannongshu 2 by the Agrobacterium tumefaciens system. Putative transgenic plants were confirmed by Southern blot analysis. Northern hybridization analysis demonstrated that expression of BADH gene was induced by drought and NaCl stress in the transgenic potato plants. The BADH activity in the transgenic potato plants was between 10.8 and 11.7 U. There was a negative relationship (y = -2.2083x + 43.329, r = 0.9495) between BADH activity and the relative electrical conductivity of the transgenic potato plant leaves. Plant height increased by 0.4-0.9 cm and fresh weight per plant increased by 17-29% for the transgenic potato plants under NaCl and polyethylene glycol stresses compared with the control potato plants. These results indicated that the ability of transgenic plants to tolerate drought and salt was increased when their BADH activity was increased.

Development of Carrot-Fishery Soups Improved from Traditional Gruel of Cheju Island (제주 전통죽을 개량한 당근-해산물 수프류의 개발)

  • 오영주;황인주;고영환
    • Korean journal of food and cookery science
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    • v.12 no.3
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    • pp.331-338
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    • 1996
  • The main aim of this study was to develop carrot soups with fishery products, which is improved from traditional gruel of Cheju island. For this the optimal procedure and ingredient mixing ratio for making basic carrot soup was determined through the instrumental measurement, the sensory evaluation and the nutrient analysis, and then the carrot-fishery soups were prepared by mixing the fishery products from Cheju island. The results were as follows: The optimal procedure for making basic carrot soup was to saute the sliced carrots and soaked rices with the sesame oil for 5 min, add the water, bring to a boil for 6 min, simmer for 15 min, then puree the soup. The optimal ingredient mixing ratio in the basic carrot soup was carrot 300 g: rice 45 g: water 900 $m\ell$: sesame oil 15 $m\ell$: salt 5 g. For preparing carrot-fishery soups were the optimal fishery products mixing ratio i) 30% tile fish or crab, ii) prawn, abalone, top shell, or ear shell 20%, iii) sea urchin 15%, iv) fusiform or gulf weed 5%. The order of sensory evaluation scores, on a 5-point scale, were sea urchin, crab > top shell, tile fish > abalone, ear shell > prawn > coral fish > fusiform, gulf weed. Nutrient composition analysis showed that vitamin A was 5 times higher in carrot soup than in pumpkin soup. Sensory evaluation scores show that carrot soup was prepared to pumpkin soup. A portion (200 g) of the soup would provide 144% of the recommended daily allowance of vitamin A. The results of this work indicate that an acceptable carrot-fishery soups of better nutritional and sensory values than pumpkin soup can be prepared.

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A empirical Study of Secondary Victimization Among Sexually Abused Children and Adolescents (성폭력 피해 아동·청소년이 2차 피해로 인지한 경험 연구)

  • Chae, Hyun Suk
    • Korean Journal of Social Welfare
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    • v.68 no.1
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    • pp.117-140
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    • 2016
  • The purpose of this study is to explore in depth experience of child secondary victimization after sexual violence incident. In order to achieve this study goal, this study contact six child who experienced sexual abuse and acknowledged secondary victimization, and collected data by indepth interview about 2~4 times. collected data was analysed by Colaizzi's analysis method. The results of this study can draw six subcategories. Six subcategories are 'school to collapse protective device', 'family not to depend on' 'judicial authority to fester a wound' 'assailant to rub salt into a wound', and the people around him merely looked on. secondary victimization of child sex abuse victims signify experience to give menace such as huge blow after first victimization. Based on result of analysis, this study suggest and implication of social welfare to prevent Secondary Victimization of sexual violence victim child.

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A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior (리튬이온전지의 유기용매분해에 따른 SEI film 형성과 전기화학적 거동에 관한 연구)

  • Kim, Min-Seong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.545-549
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    • 2001
  • We have produced electrolyte solution out of 1.15M $LiPF_6$ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M $LiPF_6$ DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M $LiPF_6$ EC/DEC(1/2 by vol%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC,DMC and EMC brought the de-decomposition peak of salt anion of $PF_6$ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. $Li/Li^+$). In addition, a kinetics current peak, in which intercalation of Lt is proceeded at 750mV, 450mV(vs. $Li/Li^+$), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance($R_{ct}$) according to the electric potential of $Li^+$ intercalation at 750mV(vs. $Li/Li^+$), which was the same as the resistance ($R_f$) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance($R_p$) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

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Isolation and characterization of Brcpi1 gene encoding phytocystatin from chinese cabbage (Brassica rapa L.) seedlings (배추 유래 phytocystatin 유전자, Brcpi1의 분리 및 발현특성 분석)

  • Jung, Yu-Jin;Cho, Yong-Gu;Kang, Kwon-Kyoo
    • Journal of Plant Biotechnology
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    • v.36 no.4
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    • pp.407-414
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    • 2009
  • A cDNA clone encoding phytocystatin was isolated from Brassica rapa seedlings, through rapid amplification of cDNA ends (RACE). This gene (name as Brcpi1; GenBank accession no.: EF079953) had a total length of 881 bp with an open reading frame of 609 bp, and encoded predicted polypeptide of 203 amino acid (aa) residues including a putative N-terminal signal peptide. Other relevant regions found its sequence included the G and PW conserved aa motifs, and the consensus LARFAV sequence for phytocystatins and the reactive site QVVAG. The BrCPI1 protein shared 95, 94, 81, 80 and 78% identity with other CPI proterins isolated from Brassica oleracea (BoCPI-1), Arabidopsis thaliana (AtCY SB), Glycine max (GmCPI), Oryza sativa (OsCYS-2) and Zea may (ZmCPI) at amino acid level, respectively. Southern blot analysis showed that Brcpi1 was a low copy gene. Expression pattern analysis revealed that Brcpi1 was a tissue-specific expressing gene during reproductive growth and strongly expressed at mature seedling stages. Furthermore, overexpression of Brcpi1 in transgenic Arabidopsis was enhanced tolerance to salt and cold stresses. Meanwhile the juvenile seedling of Brcpi1 transgenic plants was not affected by various concentrations ABA in MS medium. Taken together, the results showed that Brcpi1 functioned as a cysteine protease inhibitor and it exhibited a protective agent against diverse types of abiotic stress, which induced this gene in a tissue- and stress-specific manner.