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Adsorption Characteristics of Carbon Dioxide on Chitosan/Zeolite Composites (키토산/제올라이트 복합체의 이산화탄소 흡착 특성)

  • Hong, Woong-Gil;Hwang, Kyung-Jun;Jeong, Gyeong-Won;Yoon, Soon-Do;Shim, Wang Geun
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.179-186
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    • 2020
  • In this study, chitosan/zeolite composites were prepared by using basalt-based zeolite impregnated with aqueous chitosan solution for the adsorptive separation of CO2. The prepared composites were characterized by scanning electron microscopy (SEM), Fourier-transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption analysis. In addition, the adsorption equilibrium isotherms for CO2 and N2 were measured at 298 K using a volumetric adsorption system, and the results were analyzed by applying adsorption isotherm equations (Langmuir, Freundlich, and Sips) and energy distribution function. It was found that CO2 adsorption capacities were well correlated with the structural characteristics of chitosan and zeolite, and the ratio of elements [N/C, Al/(Si + Al)] formed on the surface of the composite. Moreover, the CO2/N2 adsorption selectivity was calculated under the mixture conditions of 15 V : 85 V, 50 V : 50 V, and 85 V : 15 V using the Langmuir equation and the ideal adsorption solution theory (IAST).

Development of Hydraulic Jet Dredge ( 1 ) - Water tank Experiment for the Excavating Performance of Water-Jet Nozzle on the Sand - (분사식 행망의 개발에 관한 연구 ( I ) - 분사노즐의 사면 굴삭성능에 관한 수조실험 -)

  • Jo, Bong-Gon;Go, Gwan-Seo
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.27 no.4
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    • pp.255-265
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    • 1991
  • In order to find the excavating performance of water-jet nozzle on the sand, the authors were carried out the excavating experiment with the model nozzles which were semi circular sectioned nozzles and rectangular nozzle in water tank. The results were as follows. 1) Excavating maximum depth and width on the sand by the water jet were straightly increased in proportion to the velocity of water jet and the section area of nozzle, and that, by the nozzle distance from the excavating point on the sand, the depth was decreased, while the width was increased straightly. 2) Rectangular nozzle which the thick of hole is 1mm, was a little bit better than the circular nozzle of the same sectioned area on the excavating performance. 3) Empirical equations between the velocity of water jet, the distance of nozzle, and the maximum excavating depth and width by angle of nozzle were expressed as linear, they were as follows on the 45$^{\circ}$ angle of the rectangular nozzle(1$\times$12mm); D=0.0093V sub(0)-0.23H+5.7. W=0.0147V sub(0)+1.06H+10.2. where, D is the maximum excavating depth(cm), W is the maximum excavation width(cm), V sub(0) is the velocity of water jet(cm/s); 926$\leq$V sub(0)$\leq$1504, H is the distance(cm) from nozzle tip to water-jetted point on the surface of sand.

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Prediction of Optimal Extraction Conditions in Microwave-Assisted Process for Antioxidant-Related Components from Thymus quinquecostatus (Microwave-Assisted Process에 의한 섬백리향의 항산화 관련 성분의 최적 추출조건 예측)

  • Kwon Young-ju;Noh Jung-eun;Lee Jung-eun;Lee Sung-Ho;Choi Yong-Hee;Kwon Joong-Ho
    • Food Science and Preservation
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    • v.12 no.4
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    • pp.344-349
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    • 2005
  • Microwave-assisted process (MAP) was applied to extract antioxidant-related components from Thymus quinquecostatus var. japonica Hara. Microwave power(2,450 MHz, $0{\sim}160$ W) and extraction time($1{\sim}5\;min$) were used as independent variables($X_i$) for central composite design to yield 10 different extraction conditions. Response surface methodology was applied to predict optimum extraction conditions for dependent variables of extracts, such as total yield, total phenolics, flavonoid, and electron donation ability depending on different powers and extraction times of MAP. Determination coefficients($R^2$) of regression equations for dependent variables were higher than 0.93 excluding that of total phenolics, and microwave power was predicted more influential than extraction time in MAP (p<0.05). The optimal extraction time for each dependent variable was ranged from 3.36 to 4.97 min, but microwave power showed wide ranges depending on variables. The superimposed contour maps for maximized dependent variables illustrated extraction conditions of 64 to 100 W in microwave power and 2.9 to 4.0 min in extraction time.

Calibrating Capacitance Sensor for Determining Water Content of Volcanic-Ash Soils (화산회토양의 수분함량측정을 위한 Capacitance Soil Moisture Sensor의 Calibration)

  • Moon, Kyung-Hwan;Joa, Jae-Ho;Choi, Kyung-San;Seo, Hyoeng-Ho;Lim, Han-Cheol;Hyun, Hae-Nam
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.3
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    • pp.331-336
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    • 2011
  • Capacitance soil moisture sensor is extensively used by soil research and irrigation management with its convenience and accuracy. This experiment was conducted to evaluate the acceptability of capacitance soil moisture sensor, named EnviroSCAN made by Sentek Ltd., in Jeju Island where volcanic ash soils are widely distributed, and to calibrate it to various soils with different amount of soil organic matter. For sensor calibration equation of volcanic ash soils, a logarithm function is better than a typical power function of non-volcanic ash soils. So there are possibilities of under evaluated in soil water contents in very wet and very dry conditions by using typical power function with volcanic ash soil areas. We suggested practical coefficients of typical calibration equation for using capacitance sensor in volcanic ash soils, also suggested equations for estimation of them with soil organic matter contents. The measurement of soil water content with a capacitance sensor can be affected by some soil characteristics such as porosity, soil organic matter content, EC, etc. So those factors should be controlled for improving the accuracy of measurement.

A study of improvement of river water quality(T-P) in pilot-scale operation (파일롯 규모의 운영에 따른 하천수질(T-P) 개선에 관한 연구)

  • Choi, Kyoungsoo;Lee, Chaeyoung
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.5
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    • pp.323-334
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    • 2021
  • Pilot-scale coagulation and sedimentation processes were operated to investigate the T-P (Total phosphorus) removal efficiency. A multiple regression model was also derived to predict the water quality improvement effect with river water characteristics. The inflow rates for the pilot-scale facility were 157-576 m3/day, and the coagulant doses were in the range of 13.7-58.5 mg/L (average 38.9 mg/L) for PAC (Poly alum chloride) and 16.5-62.1 mg/L (average 36.0 mg/L) for alum. The results found that the influent BOD (Biochemical oxygen demand) and T-P concentrations were 4.9 mg/L and 0.115 mg/L, and the removal efficiencies were 52.7% and 59.4%, respectively. T-P removal efficiencies on wet weather days were higher by 10% than dry weather days because influent solids influenced T-P's coagulation process. The pH of river water was 6.9-7.8, and the average pH was 7.3. Although the pH variation was not significant, the trend showed that the treatment efficiency of T-P and PO4-P removal increased. Thus, the pH range considered in this study seems to be appropriate for the coagulation process, which is essential for phosphorous removal. The T-P removal efficiencies were 19.6-93.3% (average 59.2%) for PAC and 16.4-98.5%(average 55.9%) for alum; thus, both coagulants showed similar results. Furthermore, the average coagulant doses were similar at 42.4 mg/L for PAC and 41.3 mg/L for alum. When the T-P concentration of the effluent was compared by the [Al]/[P] ratio, the phosphorus concentration of the treated water decreased with an increasing [Al]/[P] ratio, and the lowest T-P concentration range appeared at the [Al]/[P] ratio of 10-30. A seasonal multiple regression analysis equations were derived from the relationships between 10 independent and dependent variables (T-P concentration of effluent). This study could help lake water quality maintenance, reduce eutrophication, and improve direction settings for urban planning, especially plans related to developing waterfront cities.

Study on the Estimation of Duncan & Chang Model Parameters-initial Tangent Modulus and Ultimate Deviator Stress for Compacted Weathered Soil (다짐 풍화토의 Duncan & Chang 모델 매개변수-초기접선계수와 극한축차응력 산정에 관한 연구)

  • Yoo, Kunsun
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.12
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    • pp.47-58
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    • 2018
  • Duncan & Chang(1970) proposed the Duncan-Chang model that a linear relation of transformed stress-strain plots was reconstituted from a nonlinear relation of stress-strain curve of triaxial compression test using hyperbolic theory so as to estimate an initial tangent modulus and ultimate deviator stress for the soil specimen. Although the transformed stress-strain plots show a linear relationship theoretically, they actually show a nonlinearity at both low and high values of strain of the test. This phenomenon indicates that the stress-strain curve is not a complete form of a hyperbola. So, if linear regression analyses for the transformed stress-strain plot are performed over a full range of strain of a test, error in the estimation of their linear equations is unavoidable depending on ranges of strain with non-linearity. In order to reduce such an error, a modified regression analysis method is proposed in this study, in which linear regression analyses for transformed stress-strain plots are performed over the entire range of strain except the range the non-linearity is shown around starting and ending of the test, and then the initial tangent modulus and ultimate deviator stresses are calculated. Isotropically consolidated-drained triaxial compression tests were performed on compacted weathered soil with a modified Proctor density to obtain their model parameters. The modified regression analyses for transformed stress-strain plots were performed and analyzed results are compared with results estimated by 2 points method (Duncan et al., 1980). As a result of analyses, initial tangent moduli are about 4.0% higher and ultimate deviator stresses are about 2.9% lower than those values estimated by Duncan's 2 points method.

Correlation between Microstructure and Mechanical Properties of the Additive Manufactured H13 Tool Steel (적층 제조된 H13 공구강의 미세조직과 기계적 특성간의 상관관계)

  • An, Woojin;Park, Junhyeok;Lee, Jungsub;Choe, Jungho;Jung, Im Doo;Yu, Ji-Hun;Kim, Sangshik;Sung, Hyokyung
    • Korean Journal of Materials Research
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    • v.28 no.11
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    • pp.663-670
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    • 2018
  • H13 tool steels are widely used as metallic mold materials due to their high hardness and thermal stability. Recently, many studies are undertaken to satisfy the demands for manufacturing the complex shape of the mold using a 3D printing technique. It is reported that the mechanical properties of 3D printed materials are lower than those of commercial forged alloys owing to micropores. In this study, we investigate the effect of microstructures and defects on mechanical properties in the 3D printed H13 tool steels. H13 tool steel is fabricated using a selective laser melting(SLM) process with a scan speed of 200 mm/s and a layer thickness of $25{\mu}m$. Microstructures are observed and porosities are measured by optical and scanning electron microscopy in the X-, Y-, and Z-directions with various the build heights. Tiny keyhole type pores are observed with a porosity of 0.4 %, which shows the lowest porosity in the center region. The measured Vickers hardness is around 550 HV and the yield and tensile strength are 1400 and 1700 MPa, respectively. The tensile properties are predicted using two empirical equations through the measured values of the Vickers hardness. The prediction of tensile strength has high accuracy with the experimental data of the 3D printed H13 tool steel. The effects of porosities and unmelted powders on mechanical properties are also elucidated by the metallic fractography analysis to understand tensile and fracture behavior.

Formation Estimation of Shaly Sandstone Reservoir using Joint Inversion from Well Logging Data (복합역산을 이용한 물리검층자료로부터의 셰일성 사암 저류층의 지층 평가)

  • Choi, Yeonjin;Chung, Woo-Keen;Ha, Jiho;Shin, Sung-ryul
    • Geophysics and Geophysical Exploration
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    • v.22 no.1
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    • pp.1-11
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    • 2019
  • Well logging technologies are used to measure the physical properties of reservoirs through boreholes. These technologies have been utilized to understand reservoir characteristics, such as porosity, fluid saturation, etc., using equations based on rock physics models. The analysis of well logs is performed by selecting a reliable rock physics model adequate for reservoir conditions or characteristics, comparing the results using the Archie's equation or simandoux method, and determining the most feasible reservoir properties. In this study, we developed a joint inversion algorithm to estimate physical properties in shaly sandstone reservoirs based on the pre-existing algorithm for sandstone reservoirs. For this purpose, we proposed a rock physics model with respect to shale volume, constructed the Jacobian matrix, and performed the sensitivity analysis for understanding the relationship between well-logging data and rock properties. The joint inversion algorithm was implemented by adopting the least-squares method using probabilistic approach. The developed algorithm was applied to the well-logging data obtained from the Colony gas sandstone reservoir. The results were compared with the simandox method and the joint inversion algorithms of sand stone reservoirs.

The Effect of Results of Early Youth's Self-Esteem and Depression is Life Satisfaction : Aggression Behavior Media Effect (초기 청소년의 자아존중감과 우울감이 삶의 만족도에 미치는 영향 : 행동적 공격성의 매개효과)

  • Suh, In-Sun;Cho, Ouk-Sun;Um, Soon-Ok
    • Journal of Convergence for Information Technology
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    • v.9 no.6
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    • pp.153-163
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    • 2019
  • The purpose of this study is to research the effect of life satisfaction on young people at an early age and the impact of media on behavioral aggressiveness during this process. To this end, a group of primary schools located in Jiangnan and Jiangbei in the Seoul area and the Nanjing Road in the city were selected and 290 early youths from grades 4-6 of elementary school were chosen as specimens of structural equations. The results indicate that firstly, the personal causes of early youth have a positive (+) effect on the self-esteem life satisfaction and negative (-) impact on liquidity aggressiveness. Secondly, depression has a negative impact on life satisfaction, while action aggressiveness has no effect. Thirdly, the mobility aggression of early youth has a negative impact on life satisfaction (-), and there is a partial media relationship between self-esteem and life satisfaction. However, there is no media relationship between depression and life satisfaction. Based on the above research results, the project of improving youth early life satisfaction and reducing mobile aggression was proposed.

Estimation of drift force by real ship using multiple regression analysis (다중회귀분석에 의한 실선의 표류력 추정)

  • AHN, Jang-Young;KIM, Kwang-il;KIM, Min-Son;LEE, Chang-Heon
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.57 no.3
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    • pp.236-245
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    • 2021
  • In this study, a drifting test using a experimental vessel (2,966 tons) in the northern waters of Jeju was carried out for the first time in order to obtain the fundamental data for drift. During the test, it was shown that the average leeway speed and direction by GPS position were 0.362 m/s and 155.54° respectively and the leeway rate for wind speed was 8.80%. The analysis of linear regression modes about leeway speed and direction of the experimental vessel indicated that wind or current (i.e. explanatory variable) had a greater influence upon response variable (e.g. leeway speed or direction) with the speed of the wind and current rather than their directions. On the other hand, the result of multiple regression model analysis was able to predict that the direction was negative, and it was demonstrated that predicted values of leeway speed and direction using an experimental vessel is to be more influential by current than wind while the leeway speed through variance and covariance was positive. In terms of the leeway direction of the experimental vessel, the same result of the leeway speed appeared except for a possibility of the existence of multi-collinearity. Then, it can be interpreted that the explanatory variables were less descriptive in the predicted values of the leeway direction. As a result, the prediction of leeway speed and direction can be demonstrated as following equations. Ŷ1= 0.4031-0.0032X1+0.0631X2-0.0010X3+0.4110X4 Ŷ2= 0.4031-0.6662X1+27.1955X2-0.6787X3-420.4833X4 However, many drift tests using actual vessels and various drifting objects will provide reasonable estimations, so that they can help search and rescue fishing gears as well.