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Effects of pH and the Existence of CO2 Gas on the Silica Surface Characteristics at Silica/Pb(II) Solution Interface (CO2 가스의 존재 여부와 용액의 pH가 Silica/Pb(II) 용액 계면에서 Silica 표면의 특성에 미치는 영향)

  • Lee, Sang-Eun
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.5
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    • pp.263-271
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    • 2003
  • Effects of the existence of $CO_2$ gas and pH on the silica surface characteristics at silica/Pb(II) and sodium dodecyl sulfonate (SDS, $C_{12}H_{25}SO_3Na$) solution interface were studied. The hydrophobic characteristics of silica surface was delineated by contact angle measurement and surface force measurement using atomic force microscopy (AFM). In $CO_2$ free condition provided by purging $N_2$ gas, the contact angle of fused silica surface in $10^{-4}M$ Pb(II) and SDS solution increased greatly up to $90^{\circ}$ compared with $40^{\circ}$ in atmospheric condition. It was due to the precipitation of $PbCO_3$ in atmospheric condition. In $CO_2$ free condition the change of contact angle and adhesion force ($F_{ad}$) in AFM, affected by pH change, was similar to the distribution of $PbOH^+$ ion in speciation diagram corresponding to $10^{-4}M$ total Pb(II). Therefore, it was convinced that the $PbOH^+$ ion among Pb(II) species would be the main adsorbing type on silica surface. Both of contact angle measurement and surface force measurement using AFM showed that the Pb only treatment made the silica surface hydrophobic. However, it could not be explained theoretically by current knowledge, and required further study in atomic level to solve the problem.

Environmental Characteristics According to the Depth in Deukryang Bay , Culturing Ground of Pen Shell ( Atrina Pectinata ) (수심에 따른 득량만 키조개 어장의 환경특성)

  • 최용규
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.2
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    • pp.127-141
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    • 1995
  • The distribution of water mass in Deukryang Bay was investigated using observational data obtained on July 12 (spring tide) and 19 (neap tide) in 1994. In characteristics of water mass at the bay the area is divided into three ones by a vertical attenuation coefficient k and a stratification parameter, log sub (10) (H/U super (3)), was H is depth, and U mean velocity in the bay. The contour of k=0.6 has a similar distribution to the isobath of 10m depth in spring tide, and of 5m depth in neap tide, respectively. This indicates that the water mass in the area between the isobath of 5m and 10m depth is changed by tidal periods. The stratification parameter corresponding to k=0.6 was 2.1~2.2. In the shallow water of 5m depth the characteristics of water mass was distributed in temperature of 25.5~31.$0^{\circ}C$ and salinity of 32.8~33.8PSU(Practical Salinity Unit), the temperature was high and the salinity distributed widely. In the deep water of 10m depth it was the temperature of 22.0~29.5$^{\circ}C$ and the salinity of 33.0~33.6PSU, the temperature was low and the salinity distributed narrowly. In the middle depth water of 5m to 10m depth, the temperature of 22.0~30.$0^{\circ}C$ and the salinity of 32.8~33.5PSU, its values showed the middle between the values of the deep area and the values of the shallow area.

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The Macroscopic Model for Signalized Intersections to Consider Progression in relation to Delay (지체시간과 연동성을 동시에 고려하는 신호교차로 시뮬레이션 모형의 개발)

  • Han, Yohee;Kim, Youngchan
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.11 no.6
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    • pp.15-22
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    • 2012
  • A performance index of singalized intersections is a standard to optimize signal control variables and to manage traffic flow. Traffic delays is generally used to minimize the average delay time on intersections or networks, progression efficiency is used to improve travel speed of main cooridors or to provide transit signal priority. We manage traffic flows with only selecting one index between delays and progression according to the objective of traffic management and field characteristics. In real field, the driver's satisfaction is high in any performance criteria when the waiting time is shorter and the unnecessary stop in front of traffic is smaller. This paper aims to develop simulation model to represent real progression with concurrently considering delays and progression. In order to reflect an effect of level of traffic volumes and residual queues which don't be considered in prior progression model, we apply shockwave model with flow-density diagram. We derive Cell Transmission Model of Daganzo in order to develop the delay index and the progression index for the macroscopic simulation model. In order to validate the effect, we analysis traffic delays and progression efficiency with comparing this model to Transyt-7F and PASSER V.

Petrogenesis of Mesozoic granites at Garorim Bay, South Korea: evidence for an exotic block within the southwestern Gyeonggi massif?

  • Kim, Ji In;Choi, Sung Hi;Yi, Keewook
    • Geosciences Journal
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    • v.23 no.1
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    • pp.1-20
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    • 2019
  • We present data from the Mesozoic Keumkang, Palbong, and Baekhwa granites in Garorim Bay, in the southwestern part of the Gyeonggi massif, South Korea. Using major and trace element concentrations, Sr-Nd-Pb isotopic compositions, and sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb ages, we aim to constrain the petrogenesis of the granites and explain their origin within a broader regional geological context. SHRIMP U-Pb zircon ages of $232.8{\pm}3.2$, $175.9{\pm}1.2$, and $176.8{\pm}9.8$ Ma were obtained from the Keumkang, Palbong and Baekhwa granites, respectively. The Late Triassic Keumkang granites belong to the shoshonite series and show an overall enrichment in large ion lithophile elements (LILE), a depletion in high field strength elements (HFSE) relative to primitive mantle, compared with neighboring elements in the primitive mantle-normalized incompatible trace element diagram with notable high Ba and Sr contents, and negligible Eu anomalies. The Keumkang granites are typified by highly radiogenic Sr and unradiogenic Nd and Pb isotopic compositions: $(^{87}Sr/^{86}Sr)_i=0.70931-0.70959$, $(^{143}Nd/^{144}Nd)_i=0.511472-0.511484$ [$({\varepsilon}_{Nd})_i=-17.0$ to -16.7], and $(^{206}Pb/^{204}Pb)=17.26-17.27$. The Middle Jurassic Palbong and Baekhwa granites belong to the medium- to high-K calc-alkaline series, and show LILE enrichment and HFSE depletion similar to the Keumkang granites, but exhibit significant negative anomalies in Ba, Sr, and Eu. Furthermore, they have elevated Y and Yb contents at any given $SiO_2$ content compared with other Jurassic granitoids from the Gyeonggi massif. The Palbong and Baekhwa granites have slightly less radiogenic Sr and more radiogenic Nd and Pb isotopic compositions [$(^{87}Sr/^{86}Sr)_i=0.70396-0.70908$, $(^{143}Nd/^{144}Nd)_i=0.511622-0.511660$, $({\varepsilon}_{Nd})_i=-15.4$ to -14.7, $(^{206}Pb/^{204}Pb)=17.56-17.76$] relative to the Keumkang granites. The Keumkang granites are considered to have formed in a post-collisional environment following the Permo-Triassic Songrim orogeny that records continent-continent collision between the North and South China blocks, and may have formed by fractional crystallization of metasomatized lithospheric mantle-derived mafic melts. The Palbong and Baekhwa granites may have been produced from a gabbroic assemblage at pressures of less than ~15 kbar, associated with subduction of the paleo-Pacific (Izanagi) plate at the Eurasian continental margin. Elevated ${\varepsilon}_{Nd}(t)$ values in the granitoids from the southwestern part of the Gyeonggi massif relative to those of the central and northern parts, together with the comparatively shallow depth of origin, imply the presence of an exotic block in the Korean lithosphere.

Research on the Construction of an Automation Model for Maintenance Managers Based on Smart Devices (스마트 디바이스 기반 유지보수 관리자용 자동화 모델 구축에 관한 연구)

  • Park, Jihwan;Chung, Suwan;Lee, Seojoon;Song, Jinwoo;Kwon, Soonwook
    • Korean Journal of Construction Engineering and Management
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    • v.22 no.1
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    • pp.72-80
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    • 2021
  • Based on the previous year's statistics, 37% of buildings in South Korea are aged over 30 years. As the number of the aging buildings increases, so does the need for maintenance. Building maintenance involves a significant number of works; the work of 'maintenance manager' accounting for the largest part. Currently, the maintenance history record is mostly in drawing or handwritten form which makes reviewing the data highly time consuming. Therefore, to improve the convenience of maintenance works and optimize historical data management, the existing maintenance process was analyzed. Problems were derived and a smart device-based automation model was established. In order to establish a smart device-based automation model, ① general flow of facility management process was analyzed and related articles were reviewed, ② current maintenance process was optimized, ③ functional block diagram of BIM Data, COBie Data, IoT, and AR-based automated maintenance management model was created, ④ a smart device-based automated maintenance management model was constructed, ⑤ finally, the above system was verified by testing the aforementioned model in the field site, evaluating the time required for the maintenance process and reviewing maintenance history data against the current one.

Assessment of Resistance Spot Weldability of Dissimilar Joints of Austenitic Stainless Steels/IF Steels and Ferritic Stainless Steels/IF Steels (페라이트계 및 오스테나이트계 스테인리스강과 IF강의 이종 접합부의 저항 점 용접성 평가)

  • Lee, Jin-Beom;Kim, Dong-Cheol;Nam, Dae-Geun;Kang, Nam Hyun;Kim, Soon-Kook;Yu, Ji-Hun;Rhym, YoungMok;Park, Yeong-Do
    • Korean Journal of Metals and Materials
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    • v.49 no.1
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    • pp.64-72
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    • 2011
  • The spot weldability of dissimilar metal joints between austenitic stainless steels (STS316)/IF steels and ferritic stainless steels (STS430)/IF steels was investigated. This study was aimed to determine the spot welding parameters for a dissimilar metal joint and to evaluate the dissimilar metal joint's weldability, including its welding nugget shape, tensile-shear strength, hardness, and microstructure. The comparison of these results was described in terms of fracture behavior. Compared with the weld lobe of similar metal joints, dissimilar metal joints (STS430/IF) had reduced weld current range. However, the weld lobe of STS316/IF steel joint showed increased weld current range. This is because the dilution of chemical composition in the molten weld pool suppressed the heat input being caused by Joule heat with current flow through the samples. The microstructure of the fusion zone was fully martensite and mixture of ferrite and martensite for austenitic stainless steel/IF steel and ferritic stainless steel/IF steel combination, respectively. The experimental results showed that the shape of nugget was asymmetric, in which the fusion zone of the austenitic and ferritic stainless steel sheet was larger due to the higher bulk-resistance. The predicted microstructure by using the Schaeffler diagram was well matched with experimental results. After peel test, the fracture was initiated from heat affected zone of ferritic stainless steel sheet side, however the final fracture was propagated into the IF steel sheet side due to its lower strength.

A Study on Improvement of Directional Errors for K-MLRS Launcher (천무 발사대 방향성 오류현상 개선에 관한 연구)

  • Kim, Hyeeun;Kim, Minchang;Yu, Hanjun;Bae, Gongmyeong;Oh, Eunbin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.705-713
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    • 2021
  • Because the cage assembly serves as the launch platform, an accurate aim is essential to ensure shooting accuracy for the target. On the other hand, the abnormal rotation of the cage due to the directional errors of the K-MLRS has continuously caused quality problems. The quality problem of weapon systems may have a negative impact on the military's power loss. In this study, improvement plans were derived by examining the defects and analyzing the directional errors of the K-MLRS launcher. In addition, all possible causes of directional errors were derived from the flow diagram for cage directionality. Based on the results, the defense design through the software program was intended to prevent the loss of direction. Through this study, the signal error of the resolver was improved by preventing unspecific signals in the data. Furthermore, the directional judgment method was improved to minimize the impact of data distortion. Lastly, directional storage and verification methods were improved so that data for the cage rotation direction would not be affected by errors. For the design improvement method, the reliability was verified through the system applicability. This study is expected to be a reference for failure analysis and design for similar weapon systems in the future.

Investigation of the interaction between spin density wave and superconductivity in two band high temperature iron based superconductor Ba1-xNaxFe2As2

  • Teklie Lissanu Tegegne
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.2
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    • pp.9-18
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    • 2024
  • The current study deals with the possible interplay between superconductivity and spin density wave in two band model high temperature iron based superconductor (FeBSC) Ba1-xNaxFe2As2. The electron and hole bands in the presence of the inter-band interaction between the two bands is becoming a vital issue to deal with the high temperature physics of the iron-based superconductors. In this research work, a model Hamiltonian appropriate for the system under consideration has been developed and the temperature dependent Green's function technique has been employed to get the solution for the equations of motion constructed for the two band model high temperature FeBSC Ba1-xNaxFe2As2. By making use of the decoupling procedure, the equations of motion for the dependence of superconducting transition temperature (TC) on spin density wave(SDW) order parameter (ΔSDW) in the electron intra-band (Δsc(e)) , hole intra-band (Δsc(h)) and inter-band (Δsc(eh)) for Ba1-xNaxFe2As2 have been obtained. We have also obtained the expression for the dependence of spin density wave transition temperature(TSDW) on ΔSDW for Ba1-xNaxFe2As2. Using some plausible approximations and appropriate experimental values for the parameters in the obtained equations of motion, phase diagrams of TC versus Δsc(e), Δsc(h) and Δsc(eh) are plotted. Furthermore, a phase diagram of TSDW versus ΔSDW is plotted for the material under consideration. Finally, using the above mentioned phase diagrams, the interplay between superconductivity and spin density wave in the two band model high temperature FeBSC Ba1-xNaxFe2As2 has been demonstrated to be a very distinct possibility. The agreement of the current finding with the experimental observations is quite commendable.

Plastic Behaviro of Two Phase Intermetallic Compounds Based on $Li_2$-type$(Ai, Cr)_3$/Ti ($Li_2$$(Ai, Cr)_3$/Ti기 2상 금속간화합물의 소성거동)

  • Park, Jeong-Yong;O, Myeong-Hun;Wi, Dang-Mun;Miura, S.;Mishima, Y.
    • Korean Journal of Materials Research
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    • v.4 no.8
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    • pp.906-914
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    • 1994
  • Plastic behavior of two-phase intermetallic compounds based on $LI_{2}$-type $(Al, Cr)_3$ Ti was investigated using compression test at R.T. and 77K. $LI_{2}$ single phase alloys and two-phase alloys consisting of mainly $LI_{2}$ phase and a few or 20% second phases were selected from AI-Ti-Cr phase diagram. In general, compared with Llz single phase, two-phase alloys consisting of 20% second phase showed relatively high yield strength and poor ductility. Among the alloys, however, AI-21Ti-23Cr alloy consisting of 20% $Cr_{2}Al$ phase showed available ductility as well as high yield strength. Plastic behavior of $LI_{2}$ single phase alloys and two-phase alloys consisting of a few% $Cr_{2}Al$ was also investigated. Homogenization of arc melted ingots substantially reduced the amount of second phases but introduced extensive pore. When Cr content increased in $Ll_{2}$ single phase alloys after the homogenization, the volume fraction of pore in the alloys decreased, and no residual pore was observed in two-phase alloys consisting of a few% $Cr_{2}Al$ phase. Environmental effect on the ductility of the alloys was investigated using compression test at different strain rates($1.2 \times 10^{-4}/s$ and $1.2 \times 10^{-2}/s$). Environmental embrittlement was least significant in A1-25Ti-10Cr alloy consisting of LIZ single phase among the alloys tested in this study. However, based on the combined estimation of the pore formation, environmental embrittlement and ingot cast structure, AI-21Ti-23Cr alloy consisting of 20% $Cr_{2}Al$ as the second phase is expected to show the best tensile elongation behavior.

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Techniques for Acquisition of Moving Object Location in LBS (위치기반 서비스(LBS)를 위한 이동체 위치획득 기법)

  • Min, Gyeong-Uk;Jo, Dae-Su
    • The KIPS Transactions:PartD
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    • v.10D no.6
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    • pp.885-896
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    • 2003
  • The typws of service using location Information are being various and extending their domain as wireless internet tochnology is developing and its application par is widespread, so it is prospected that LBS(Location-Based Services) will be killer application in wireless internet services. This location information is basic and high value-added information, and this information services make prior GIS(Geographic Information System) to be useful to anybody. The acquisition of this location information from moving object is very important part in LBS. Also the interfacing of acquisition of moving object between MODB and telecommunication network is being very important function in LBS. After this, when LBS are familiar to everybody, we can predict that LBS system load is so heavy for the acquisition of so many subscribers and vehicles. That is to say, LBS platform performance is fallen off because of overhead increment of acquiring moving object between MODB and wireless telecommunication network. So, to make stable of LBS platform, in this MODB system, acquisition of moving object location par as reducing the number of acquisition of unneccessary moving object location. We study problems in acquiring a huge number of moving objects location and design some acquisition model using past moving patternof each object to reduce telecommunication overhead. And after implementation these models, we estimate performance of each model.