• Journal of Adhesion and Interface
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• v.1 no.1
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• pp.30-37
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• 2000

This study focused on the direct blending of bonding agents (resorcinol, hexamethylenetetramine, NaOH) into rubber compound to simplify the composite manufacturing process. The mechanism of direct blending system was studied by comparing the following two cases. The one is direct blending of bonding agents into rubber compound and then allows the reaction (Case I). The other is mixing of reactant obtained by reaction of bonding agents (Case II). According to the morphology analysis, the Case II showed the clean interfacial area between bonding agents and matrix rubber, while the Case I created the new interphase under proper processing condition. Also, the optimum adhesion strength between SBR and nylon cord could be obtained with bonding agents whose molar ratios of resprcinol/hexamethylenetetramine was 1.2/1 in the recipes.

• Elastomers and Composites
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• v.56 no.4
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• pp.243-249
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• 2021

The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, we investigated the effect of varying the content of butadiene rubber (BR) on the properties of the rubber compounds and the amount of particulate matter in the TBR tire tread compound. Furthermore, we utilized carbon black in the NR/BR blend compounds owing to its excellent compatibility, and we used silica in the ENR-25/BR blend compounds because it can interact chemically with epoxide groups. The NR/BR blend compounds and the ENR-25/BR blend compounds were evaluated by varying their BR content between 20 phr and 30 phr. The results showed that the ENR-25/BR blend compounds had superior wear resistance than the NR/BR blend compounds. This was caused by the interaction between silica and ENR. In addition, it was confirmed that the increased wear resistance as the BR content increased. Furthermore, compared to the NR/BR blend compounds, ENR-25/BR blend compounds exhibited a lower tan 𝛿 value at 60℃ because silica was used as filler. This indicates a higher fuel efficiency. The measurement results for wear particulate matter showed that as increasing the BR content resulted in generation of less wear particulate matter. This was caused by the increased wear resistance. Moreover, the ENR-25/BR blend compounds with excellent filler-rubber interaction exhibited lower quantities of generated wear particulate matters as compared to the NR/BR blend compounds.

• Elastomers and Composites
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• v.40 no.1
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• pp.29-36
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• 2005

Mixing condition and procedure affect properties or a filled rubber compound such as filler dispersion, viscosity, and bound rubber formation. Influence of separate load of styrene-butadiene rubber (SBR) and acrylonitrile-butadiene rubber (NBR) on properties or silica-filled SBR compounds containing NBR was studied. Cure time and cure rate became faster as NBR content increased. The crosslink density increased with increase in the NBR content. The bound rubber content also increased as the NBR content increased. NBR content of the bound rubber was higher than that of the compounded rubber. The bound rubber content was higher when SBR and NBR were loaded separately than when loading simultaneously. The cure time and cure rate were slower for the separate load than for the simultaneous one. The crosslink density was also lower for the former case than for the latter one.

• Interaction and multiscale mechanics
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• v.2 no.2
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• pp.129-151
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• 2009

This paper presents a meshfree procedure using a convex generalized meshfree (GMF) approximation for the large deformation analysis of particle-reinforced rubber compounds on microscopic level. The convex GMF approximation possesses the weak-Kronecker-delta property that guarantees the continuity of displacement across the material interface in the rubber compounds. The convex approximation also ensures the positive mass in the discrete system and is less sensitive to the meshfree nodal support size and integration order effects. In this study, the convex approximation is generated in the GMF method by choosing the positive and monotonic increasing basis function. In order to impose the periodic boundary condition in the unit cell method for the microscopic analysis, a singular kernel is introduced on the periodic boundary nodes in the construction of GMF approximation. The periodic boundary condition is solved by the transformation method in both explicit and implicit analyses. To simulate the interface de-bonding phenomena in the rubber compound, the cohesive interface element method is employed in corporation with meshfree method in this study. Several numerical examples are presented to demonstrate the effectiveness of the proposed numerical procedure in the large deformation analysis.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.47-51
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• 2007

The present paper reports the life time prediction of Acrylonitrile-Butadiene rubber (NBR) fuel cell gasket materials as a function of operational variables like acid concentration, ageing time and temperature. Both material and accelerated acid-heat aging tests were carried out to predict the useful life of the NBR rubber gasket for use as a fuel cell stack. The acid ageing of the gasket compounds has been investigated at 120, 140 and $160^{\circ}C$, with aging times from 3 to 600 h and increasing acid ($H_2SO_4$) concentrations of 5, 6, 7 and 10 vol%. Material characteristics the gas compound such as cross-link density, tensile strength and elongation at break were studied. The hardness of the NBR rubber was found to decrease with decreasing acid concentration at both 120 and $140^{\circ}C$, but at $160^{\circ}C$ interestingly the hardness of the NBR rubber increased abruptly in a very short time at different acid concentrations. The tensile strength and elongation at break were found to decrease with increase in both the acid concentrate ion & temperature. The life time of the compounds were evaluated using the Arrhenius equation.

• Elastomers and Composites
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• v.49 no.2
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• pp.149-154
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• 2014

Friction and abrasion behaviors were investigated for SBR rubber compounds reinforced by silica and carbon black. Knife-blade abrader, newly designed based on tearing energy theory, was utilized in order to evaluate the effect of frictional work on the wear rate of the rubber compounds. It was found that the power law relation between frictional work and wear rate worked, in which as the wear rate was increased as frictional work increased. The wear rate could be determined successfully using the knife-blade abrader in which a moving distance of the knife blade in the process of wearing was measured continuously, instead of intermittent measurements of weight loss by wear during experiment.

• Elastomers and Composites
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• v.58 no.3
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• pp.136-141
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• 2023

Polyacrylic rubber (ACM) is well known for its excellent heat resistance and chemical stability. Additionally, its performance can be readily manipulated by modifying its functional groups, rendering it highly attractive to various industries. However, extreme climate changes have necessitated an expansion of the operating temperature range and lifespan of ACM products. This requires the optimization of both the compounding process and functional-group design. Hence, we investigated the relationship between the cross-linking system and mechanical properties of an ACM with a carboxylic cure site. The crosslink density is determined by chemical kinetics according to the structure of additives, such as diamine crosslinkers and guanidine accelerators. This interaction enables the manipulation of the scotch time and mechanical properties of the compound. This fundamental study on the correlation analysis between cross-linking systems, physical properties, and storage stability can provide a foundation for material research aimed at satisfying the increasingly demanding service conditions of rubber products.

• Elastomers and Composites
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• v.59 no.1
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• pp.8-16
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• 2024

As regulations on greenhouse gas emission have strengthened globally, the demand for improved fuel efficiency in automobiles continues to rise. In response, the tire industry is actively conducting research to improve fuel efficiency by enhancing tire performance. In this study, silica-filled epoxidized natural rubber (ENR)/butadiene rubber (BR) blend compounds were manufactured according to ENR types and silica contents, and their physical properties and vulcanizate structure were evaluated. ENR-50, which has a higher epoxide content than ENR-25, exhibited stronger filler-rubber interaction, resulting in superior abrasion resistance. In addition, because of its high glass transition temperature (T_g), the wet grip performance of ENR-50 improved, even though the rolling resistance increased. Increasing the amount of silica had little effect on the abrasion resistance due to the increase in filler-rubber interaction and decrease in toughness. In addition, ENR-50 exhibited better wet grip performance; however, the rolling resistance increased. The results indicated that truck bus radial (TBR) tire tread compounds can be designed by applying ENR-50 to improve wear resistance and wet grip performance. In addition, by applying ENR-25 and reducing the silica contents improve fuel efficiency.

• Macromolecular Research
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• v.9 no.2
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• pp.92-99
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• 2001

Silica-filled rubber compounds have slower cure characteristics than carbon black-filled ones due to the adsorption of curatives on the silica surface. Fatty acid was used as a cure activator along with zinc oxide in a sulfur cure system. Poly(ethylene glycol), PEG, was used in silica-filled rubber compounds to prevent adsorption of the curatives on the silica surface. In this study, influence of the size of fatty acid and PEG on properties of silica-filled NR compounds was investigated. It was found that the size of fatty acid and PEG affected the curt: characteristics and physical properties. The cure rate becomes faster as the PEG size increases. By increasing the size of fatty acid or PEG, the delta torque of the compound decreases while the Mooney viscosity increases. The modulus of the vulcanizate decreases with increasing the molecular weight of fatty acid or PEG. The experimental results were explained by the filler dispersion and by the prevention of the curative-adsorption on the silica surface.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.291-293
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• 2012

Recently, environmental pollution and global warming and greenhouse gases are increasing, because Efforts to improve are continued throughout the world. As part of the resource recycling industry has become an important research area. In the field of waterproofing industry, focus on the resource recycling is growing, due to serious resource depletion and sharp price. Therefore, in this research on the resource recycling such as reclaimed rubber and rubber waste is enable and these eco-friendly materials are applied high adhesive flexible non-exposed type self adhesion compound waterproofing material was measured eco-friendly performance and field application was evaluated.