• Title/Summary/Keyword: rock salt

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Deterioration Evaluation and Material Characteristics of the Usuki Stone Buddha Statues in Oita, Japan (일본 오이타현 우스키 마애불상군의 재질특성 및 손상도 평가)

  • Cho, Ji-Hyun;Lee, Chan-Hee;Kim, Ji-Young;Morii, Masayuki;Lee, Myeong-Seong;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.28 no.1
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    • pp.39-52
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    • 2012
  • The Usuki Stone Buddha Statues in Oita are consisted of 60 Buddhas which represent of Japan carved on the rock-cliff in the 12 to 14th centuries. The basement rock of the statues is dark gray welded lapilli tuff that containing the Aso-4 pyroclastic rock group. Deterioration maps for the Hoki I and the Furuzono Buddha Statues group show multi-directional fissures on the Cakra, and sheeting-off zone at the margin of uprising water. Deterioration rate of the Hoki I group was calculated fissure about 121 in number, 19% of sheeting-off zone and 51% of biological weathering in surface of area. And the Furuzono group was also evaluated as about 48 of fissures in number, 24% of sheeting-off zone and 41% biological weathering. The slope stability assessment results, the Hoki I developed discontinuous planes has possibility of planar, toppling and wedge failures in all caves. Ultrasonic velocity of the Aizen-myooh (basement rock) ranges from 1,520 to 2,794 (average 2,298m/s). And pedestal of Amita-yeorae which has been replaced by new fresh rock is measured as 3,242 to 4,141 (average 3,813m/s). Therefore, we establish of planing conservation treatment and reinforcement methods to fissure, cavity, sheeting-off zone in the Buddha surface.

Material Characteristics and Application Efficiency of Treatments for Usuki Stone Buddha Statues in Japan (일본 우스키 석불군의 재질특성과 보존처리제 적용 효과)

  • Lee, Myeong Seong;Lee, Jae Man;Lee, Sun Myung;Kim, Sa Dug;Morii, Masayuki
    • Korean Journal of Heritage: History & Science
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    • v.44 no.3
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    • pp.78-91
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    • 2011
  • The Usuki Stone Buddha Statues in Japan are carved on mainly dark gray welded lapilli tuff accompanied by lenticular fiamme. This rock is composed of matrix which contains feldspar and opaque minerals with some phenocrysts of quartz and feldspar. The matrix is slight to highly welded. The statues have been weathered and weakened by salt and freezing of water. To enhance the mechanical properties of the rock, consolidants and water repellents were applied. The absorption ratio of the rock was highly decreased after the treatment of the water repellents, the consolidant OH 100, as well. Ultrasonic velocity revealed similarly higher values in the treated rock by KSE 300 and OH 100, compared to non-treated rock. KSE 300, especially, highly increased the Equotip surface hardness. All studied consolidants and water repellents were found to change the original color of the stone. SNL, specifically, resulted the significant change in color. In addition, KSE 300 were observed to improve resistance to weathering such as microcrack and fracture through freezing-thawing test after treatment.

제설제가 고속도로 주변토양에 미치는 영향

  • Lee Ju-Gwang;Lee Byeong-Deok;Gang Hye-Jin;Gang Hui-Man
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.226-229
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    • 2006
  • Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. Finding the deicing chloride agents impacts on the environment and develop the minimizing strategies, we evaluated that chloride deicing agents influence on highway roadside soil and establish the optimun strategies.

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전도성 세라믹인 티타늄 아산화물 TiO와 $Ti_4O_{7}$의 산화전극으로서의 전기화학적 특성

  • Park, So-Yeong;Kim, Cheol;Mo, Seon-Il;Ji, Eun-Ok;Kwon, Yeong-Uk
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1994.05a
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    • pp.121-125
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    • 1994
  • 전극물질 및 전극촉매로서의 세라믹물질의 중요성은 상당히 크다. magneli phase를 갖는 $Ti_4O_{7}$과 rock salt구조를 갖는 TiO등의 티타늄 아산화물들은 전도성 세라믹으로서 전기전도도는 탄소보다도 좋으며, 높은 산화전위에서도 산화되지 않을 뿐만아니라, 강산용액에서도 내식성이 강하여 $SO_2$$O_2$의 산화전극 물질로 사용할 수 있다. $SO_2$$O_2$의 산화에 뛰어난 활동도를 보이는 촉매인 Pt나 Ru를 전기화학적으로 $Ti_4O_{7}$이나 TiO에 입혀서 그 전기화학적인 특성을 조사하였다.

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Corrosion Resistance Characteristics of Cr-free Coating Solution for Degraded STS316L (열화한 STS316L에 대한 Cr-free 코팅액의 내식특성)

  • Lee, So-Young;Kim, Young-Soo;Jeong, Hee-Rock;Ahn, Seok-hwan;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.29 no.6
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    • pp.475-480
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    • 2015
  • In this study, we developed a Cr-free organic/inorganic hybrid solution and investigated its coating properties on degraded STS316L. Both the OIBD-1 solution and OIBD-2 solution had excellent corrosion resistance and adhesion ability. However, the solution had some problems in a boiling water environment. In addition, the flexibility was excellent, and the scratch resistance was relatively good.

Comparative Analysis of Geomorphological and Folklore Approaches to Weathered Landforms - Focusing on Tafoni, Gnamma, Gamsil and Alter - (풍화지형에 대한 지형학적 분석과 고고민속학적 접근에 관한 비교 연구 - 타포니와 나마, 감실과 알터를 중심으로 -)

  • Park, Kyeong
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.3
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    • pp.119-131
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    • 2017
  • Typical weathering landforms and phenomena including tafoni and gnamma are usually interpreted as man-made alteo (praying water bowl) or dragon-alteo by folklore researchers. Despite some terminological ambiguity, they are certainly natural weathering pits and are introduced in our discipline for fifty years, however, unfortunately most of them are interpreted as petroglyphs used and prepared for ritual ceremony. Several seemingly artificially-made rock holes are also found in many places, but most of them are weathered landforms by salt weathering. Author believes that communication effort to use common language and publish more researches in interdisciplinary journals are very essential to propagate scientific achievements made by geomorphologists to other discipline. Also geomorphologists specialized in weathering processes are encouraged to participate in preservation of stone artifacts and archaeological remains.

Electronic Structure of Oxygen in the Defective Nickel Monoxide

  • Lee, Gwang Sun;Gu, Hyeon Ju;Ham, Gyeong Hui;An, Un Seon
    • Bulletin of the Korean Chemical Society
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    • v.16 no.2
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    • pp.164-168
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    • 1995
  • The band structure of nickel monoxide having a cation defect rock salt structure is calculated by means of the tight-binding extended Huckel method. The calculation is also made for the net charge, the DOS, the COOP, the electron density of the constituent atoms, and the O 1s binding energy shift when one of the adjacent nickel atoms is defected. It is found that the band gap near the Γ direction on the Brillouin zone is about 0.2 eV, and that all of the properties calculated including the electronic structure of the oxygen atom are more effectively affected by the surface defect than the inside one. The core O 1s binding energy shift is calculated by the use of valence potential method and the results are very satisfactory in comparison with the XPS experimental findings.

A preliminary study of watertightness and salt water resistance of spray-applied membrane (뿜어붙임멤브레인의 방수성능 및 염수저항성의 기초평가)

  • Choi, Soon-Wook;Kang, Tae-Ho;Chang, Soo-Ho;Lee, Cheol-Ho;Kim, Jintae;Choi, Myung-Sik
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.283-299
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    • 2017
  • The leakage of tunnel causes the long-term durability of the structures such as concrete lining to deteriorate. The cause of durability degradation can be various substances contained in groundwater such as chloride, sulphate, water, and gas. In this study, a series of test were carried out to determine the watertightness performance and the resistance to salt water of the spray-applied membrane used as non-structural rock support or as a waterproof material for tunnels. As a result, it was found that the penetration of water could occur in a specimen, and the reason was that the internal pores generated by the mixing of the liquid polymer and the powder material and the internal pores were connected by the water pressure. The tensile strength of the test specimens immersed in distilled water and saline water was found to be reduced to less than half of the tensile strength in normal condition. In addition, The elongation was measured to be higher in distilled water than in salt water. However, this result will require further investigation.

Phase Evolution in LiMO2(M=Co,Ni) Cathode Materials for Secondary Lithium Ion Batteries : Effect of Temperature and Oxygen Partial Pressure (리튬 2차 전지용 양극활물질 LiMO2(M=Co,Ni)의 온도와 산소 분압에 따른 상전이 거동)

  • Huang, Cheng-Zhu;Kim, Ho-Jin;Jeong, Yeon-Uk;Lee, Joon-Hyung;Kim, Jeong-Joo
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.292-297
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    • 2005
  • $LiMO_{2}(M=Co,Ni)$ samples were synthesized with $Li_{2}CO_{3},\;Co_{3}O_{4}$, and NiO by the solid-state reaction method. In the case of $LiCoO_{2}$, at low temperature$(T=400^{\circ}C)$ spinel structure was synthesized and the obtained spinel phase was transformed to layered phase at high temperature$(T\ge600^{\circ}C)$. The phase transition behaviors of $LiCoO_{2}$ were investigated with various heating temperature and time. The rate of transition was directly proportional to the concentrations of reactant, and activation energy of reaction was around 6.76 kcal/mol. When CoO(rock salt structure) was used as a starting material instead of $Co_{3}O_{4}$(spinel structure), layered structure of $LiCoO_{2}$ was obtained at low temperature. In the case of $LiNiO_{2}$ the transition from layered structure to rock salt structure occurred easily by disordering/ordering reaction, but did not occur in $LiCoO_{2}$. The difference in metal ion radii in $LiCoO_{2}$ and $LiNiO_{2}$ results in different behaviors of phase transitions.

Geostatistical Interpretation of Water Quality and Hydrogeochemistry of shallow Groundwater in the Uljin Area, Korea (지구통계 기법을 활용한 울진 지역 천부 지하수의 수질 및 수리지구화학 특성 해석)

  • 김남진;윤성택;김형수;정경문;김규범
    • Economic and Environmental Geology
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    • v.34 no.2
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    • pp.175-192
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    • 2001
  • We have collected hydrogeochemical data of shallow groundwaters in the Uljin area located at eastern coastal area of Korea. Geostatistical analysis (ANOVA test, cluster analysis, and factor analysis) of the collected data sets was pert'onned, in order to evaluate both the spatial and/or temporal variation of water quality data and the groundwater contamination, as weJl as the principal reactions occurring in the aquifer. Results of the ANOVA test show that regional water chemistry are not significantly changed spatially in eight watersheds. However, some ions such as $Ca^{2+}$, $HCO_{3}^{-}$ and $SO_{4}^{2-}$ show a meaningful watershed variation. Water chemistry variation according to sampling time (season) is not shown, except for $SO_{4}^{2-}$. The cluster analysis shows that significant water chemistry variation is eXplained by the distance from the coast. Factor analysis indicates that the water chemistry is changed according to various factors as follows: in the order of decreasing importance, water-rock interaction (mainly, carbonate dissolution), sea-salt spraying, and then contamination by fertilizers and agrochemicals.

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