• Journal of Korean Society of Environmental Engineers
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• v.38 no.9
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• pp.476-481
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• 2016

Pressure retarded osmosis (PRO) is a quite new technique for power generation using an osmotically driven membrane process. In the PRO process, water permeates through a semipermeable membrane from a low concentration feed solution to a high concentration draw solution due to osmotic pressure. This study carried out to evaluate the performance of the 8 in spiral wound membrane module using reverse osmosis concentrate for a draw solution and reverse osmosis permeate for a feed solution. Three different flowrates of draw and feed solution, such as 2.4 L/min, 5.0 L/min, and 10.0 L/min were used to estimate the power density and water flux under various range of hydraulic pressure differences between 5 bar and 30 bar. In addition, the effects of feed and draw solution concentration, flowrate, and mixing ratio on 8 in spiral wound PRO membrane module performance were investigated in this study. As major results, increases of the draw solution concentration lead to the improvement of power denstiy, and water flux. Also, increase of flowrate resulted in the improvement of power density and water flux. In addition, optimal mixing ratio of draw and feed solution inlet flowrate was found to be 1:1 to attain a maximum power denstiy.

• Korean Journal of Food Science and Technology
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• v.25 no.4
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• pp.321-326
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• 1993

Membrane separation technology with polymeric membranes for the effective separation and energy conservation has emerged to be a new technology for separation in recent years. In this research, the reverse osmosis process was applied to the concentration process of clarified apple juices. The changes of concentration and permeate flux of apple juice in this process were measured at different membrane characteristics, operating pressures, temperature and flow rate. And the changes of quality were also measured at different pressures. The prediction model for the permeate flux based on these data was established. Generally, the osmotic pressure increased as the concentration of the feed increased in the RO process, which caused a reduction of permeate flux. The changes of permeate flux were not much dependent on temperature and flow rate, but very much dependent on pressure. The most effective factor in increased permeate flux was found to be the operating pressure, followed by temperature and flow rate. The final prediction model for the permeate flux was developed by the $SPSS^x$ computer program. The result showed that recovery of sugar was not affected by processing pressures, but the percentage recovery of total flavor was increased with increasing pressure.

• Membrane and Water Treatment
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• v.8 no.5
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• pp.449-462
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• 2017

Direct treatment of municipal wastewater by forward osmosis (FO) process was evaluated in terms of water flux decline, reverse salt diffusion, pollutants rejection and concentration efficiency by using synthetic seawater as the draw solution. It was found that when operating in PRO mode (active layer facing the draw solution), although the FO membrane exhibited higher osmotic water flux, more severe flux decline and reverse salt diffusion was also observed due to the more severe fouling of pollutants in the membrane support layer and accompanied fouling enhanced concentration polarization. In addition, although the water flux decline was shown to be lower for the FO mode (active layer facing the feed solution), irreversible membrane fouling was identified in both PRO and FO modes as the water flux cannot be restored to the initial value by physical flushing, highlighting the necessity of chemical cleaning in long-term operation. During the 7 cycles of filtration conducted in the experiments, the FO membrane exhibited considerably high rejection for TOC, COD, TP and $NH_4{^+}-N$ present in the wastewater. By optimizing the volume ratio of seawater draw solution/wastewater feed solution, a concentration factor of 3.1 and 3.7 was obtained for the FO and PRO modes, respectively. The results demonstrated the validity of the FO process for direct treatment of municipal wastewater by using seawater as the draw solution, while facilitating the subsequent utilization of concentrated wastewater for bioenergy production, which may have special implications for the coastline areas.

• Membrane Journal
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• v.28 no.5
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• pp.368-377
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• 2018

The n-nitrilotris(methylene) phosphonic acid (NTPA) potassium salt was synthesized as a draw solute for forward osmosis. NTPA-4K, NTPA-5K and NTPA-6K were synthesized by varying the content of KOH added to NTPA and confirmed by $^1H$-NMR and $^{13}C$-NMR. The osmotic pressure, viscosity, water flux and reverse salt flux were measured to characterize the draw solute. In the forward osmosis process when distilled water was used as a feed solution and 0.5 M of NTPA-4K, NTPA-5K and NTPA-6K were used as a draw solution, the water flux was 35.8, 38.8 and 42.2 LMH, the reverse salt flux was 5.4, 6.9 and 7.4 gMH, respectively. It was confirmed that the water flux was lower than the conventional NaCl draw solution, but the reverse salt flux was much lower. In order to recover the diluted draw solution, nanofiltration was conducted. The results showed that the draw solute could be retained by above 90%.

• Clean Technology
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• v.9 no.2
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• pp.49-55
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• 2003

The generation of livestock wastewater in Korea amounts to $130,000m^3/day$, 0.43% of the total waste water volume, but which corresponds to 8.6% of total BOD loading. Furthermore this wastewater contains a large amount of nitrogen and phosphorus that are major causes of eutrophication in rivers and lakes. The average volume of livestock wastewater in a Korea's single farm is only $2.5m^3/day$, which necessitates development of a simple and economical process for the removal of nitrogen and phosphorus. Introduction of filtration method removes more than 90% of suspended solids. Subsequent application of reverse osmosis removes more then 95% of total nitrogen and phosphorus in the wastewater. The effluent of this treatment will yield less than 200 mg/L of total nitrogen and 1 mg/L of total phosphorous, which are lower than 260 mg/L of total N and 50 mg/L of total P, the regulation values of Ministry of Environment, Korea. Treating $2m^3/day$ of livestock wastewater was found to be feasible with the application of filtration and reverse osmosis and the electricity requirement was estimated to be about 30 Kwh/month.

• Membrane Journal
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• v.30 no.3
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• pp.190-199
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• 2020

The utilization of multiple water sources becomes important due to the master plan for development of water supply released by Ministry of Environment, Korea in 2018. In this study, therefore, the analysis of comprehensive effect in blending applicable water sources in Daesan where 100,000 ㎥/d seawater desalination plant will be constructed for industrial use was performed. The increase in mixing ratio of other water sources with seawater reduced salinity up to 50%, but negatively impacted the turbid and organic matter. Lab-scale reverse osmosis performance test also found that membrane fouling was exacerbated in blended water condition. The simulation results of reverse osmosis indicated 39% energy saving on average is expected at the one-to-one blending ratio, however, long-term performance test at the pilot-scale plant is highly required to evaluate the inclusive impact of mixing seawater and other water sources.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.3
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• pp.299-312
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• 2016

The main objective of this paper is to develop computer simulation program for performance evaluation and cost estimation of a reverse osmosis (RO) and pressure-retarded osmosis (PRO) hybrid process to propose guidelines for its economic competitiveness use in the field. A solution-diffusion model modified with film theory and a simple cost model was applied to the simulation program. Using the simulation program, the effects of various factors, including the Operating conditions, membrane properties, and cost parameters on the RO and RO-PRO hybrid process performance and cost were examined. The simulation results showed that the RO-PRO hybrid process can be economically competitive with the RO process when electricity cost is more than 0.2 $/kWh, the PRO membrane cost is same as RO membrane cost, the power density is more than $8W/m^2$ and PRO recovery is same as 1/(1-RO recovery).

• Membrane Journal
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• v.32 no.4
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• pp.209-217
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• 2022

Ion exchange membrane (IEM) is an important class of membrane applied in batteries, fuel cells, chloride-alkali processes, etc to separate various mono and multivalent ions. The membrane process is based on the electrically driven force, green separation method, which is an emerging area in desalination of seawater and water treatment. Electrodialysis (ED) is a technique in which cations and anions move selectively along the IEM. Anion exchange membrane (AEM) is one of the important components of the ED process which is critical to enhancing the process efficiency. The introduction of cross-linking in the IEM improves the ion-selective separation performance due to the reduction of free volume. During the desalination of seawater by reverse osmosis (RO) process, there is a lot of dissolved salt present in the concentrate of RO. So, the ED process consisting of a monovalent cation-selective membrane reduces fouling and improves membrane flux. This review is divided into three sections such as electrodialysis (ED), anion exchange membrane (AEM), and cation exchange membrane (CEM).

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 1993.10a
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• pp.584-590
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• 1993

The constructed closed recycling system discussed in this technical report will be economically viable in future for the production of fish and vegetable in earth, space station and space colony, further, it will contribute a lot in the prevention of pollution in the world's ecological system. To make combined system, water management (Nitrification) is required, and it took 45 days to breed microorganism which facilitates this process. After this period , the recycle was confirmed to be working .Using derived equations, the expected nutrient characteristics of waste water were determined and it was found that the resulting nutrient balance was almost same as that in hydroponic solution when KOH was added to maintain pH level. Reverse osmosis (RO) system could solve the problem of the low nutrient concentration . It was found that plants grow well in fish waste water which was produced using RO system. RO system could combine fish and plant production through the advantageous use of separated high concentration water for plant and permeated water for fish in integrated combined system.

• Membrane Journal
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• v.11 no.4
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• pp.152-160
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• 2001

The pretreatment for COD removal of acrylic wastewater and separation characteristics of ultrafiltration hollow fiber type module and reverse osmosis spiral wound type module with the variation of applied pressure and temperature were discussed. Thc optimum washing time of membranes was decided with long team operation and the degree of fouling was discussed with operating time. Permeate flux was decreased rapidly at 14 hrs and that of reverse osmosis membrane was indicated similarly. CaO find sand filter for the first step, neutralization process with treated acrylic wastewater as the second step, UF/RO processes were used as final strep. It was shown treat COD and TDS were below allowable discharge value with the result.