• Nuclear Engineering and Technology
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• v.53 no.1
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• pp.253-257
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• 2021

This work demonstrates the use of baromembrane method based on reverse osmosis (RO) process. The method is realized on mobile complex, which allows to concentrate and determine ultra-low activity of radionuclides in water cooling ponds of Russian nuclear fuel cycle enterprises. The existence level of radionuclide background creates difficult conditions for identification the contribution of liquid discharges enterprise, as standard monitoring methods have a very high detection level for radionuclides. Traditional methods for determining the background radionuclides concentrations require the selection of at least 500 liters (l) of water, followed by their evaporation to form a dry residue. This procedure with RO membranes requires at least 5 days. It is possible to reduce the time and energy spent on evaporation of hundreds of water liters by pre-concentrating radionuclides in a smaller sample volume with baromembrane method. This approach allows preliminary concentration of water samples from 500 l volume till 20 l volume during several hours. This approach is universal for the concentration of dissolved salts of any heavy metals, other organic compounds and allows the preparation of water countable samples in much shorter time compared to the traditional evaporation method.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.243-243
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• 2020

본 연구는 장래 유입수질 변화로 해수담수화(Desalination) 역삼투압(Seawater Reverse Osmosis) 공정의 전력비 예측 모델을 개발하고 별도의 해수담수화 추가공정이 필요한지 검토하였다. 플랜트 시설은 한번 설치되면 오랜 기간 운영이 되고, 주요 공정의 시설물 변경이 어려우며, 특히 해수담수화 시설의 경우에는 생활용수 및 공업용수를 수요자에 상시 공급함으로서 중간에 추가 시설물을 증설하거나 변경하기가 쉽지 않다. 따라서 해수담수화 시설의 계획 초기부터 현재의 유입수질 및 장래의 수질 변화를 예측하여 해수담수화 공정을 계획하는 것이 필요하다. 금회 검토는 해수온도 및 염분도 변화를 고려하여 서해에 위치한 대산산업단지 해수담수화 시설의 해수담수화 공정 전력비를 예측하였고, 입력 자료(온도 및 염분도)는 국가해양환경정보통합시스템(MEIS, Marine Environment Information System) 22년 과거자료(1997~2018년)를 이용하였다. 개발된 모형에 적용하여, 해수담수화에 필요한 전력비의 변화를 예측할 수 있으며, 이를 바탕으로 해수담수화 시설물 공정계획을 검토할 수 있었다. 금회 연구에서는 장래 수질변화 예측모형의 결과를 기반으로 해수담수화 시설물 공정을 제시하였다는데 의의가 있다.

• Membrane Journal
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• v.12 no.3
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• pp.182-191
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• 2002

Polyamide reverse osmosis (RO) membrane with thin film composite structure was commercialized for seawater desalination process. Recently, it has been reported that some RO processes for high pressure and recovery leads to reducing in energy cost and pretreatment scale compared with earlier process. The development of energy recovery, pumping device and RO elements with high pressure and rejection made high pressure and recovery process possible. In this study, permeation properties of commercialized seawater RO membrane were investigated under the condition of high pressure and recovery. In the RO sheet membrane test 3.5% NaCl of synthetic seawater was used. The synthetic seawater contained only sodium chloride. In the RO module test, natural seawater was used at Happo Bay, Masan city. As the results, RO membrane with high durability of pressure was better than that with high rejection of seawater for high pressure and recovery process. Seawater rejection of high concentrate tends to be improved by high pressure operation.

• Membrane Journal
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• v.24 no.2
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• pp.142-150
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• 2014

This paper is to develop the process suitable for the advanced treatment of liquid fertilizer from the livestock night soil treatment facility (biogas plant). Nanofiltration (NF) and reverse osmosis (RO) process was used, respectively, for the advanced treatment of liquid fertilizer. And membrane bioreactor (MBR) with and without biomedia were tested, respectively, for the pretreatment. It was found that almost T-N of the liquid fertilizer was composed of ammoniacal nitrogen. Transmembrane pressure of MBR with biomedia increased slowly during the operation time, while that of MBR without biomedia increased rapidly at the initial time. But there was no difference observed in the removal efficiencies of COD, T-N, and T-P irrespective of the dosage of biomedia. When the liquid fertilizer was pretreated by MBR with biomedia, the removal efficiencies of COD, T-N, and T-P were 99.8, 86.5%, and 99.8% by NF, and 99.9, 86.8%, and 99.8% by RO, respectively. Compared with the effluent quality standards of the livestock night soil treatment facility, the water quality treated by MBR and NF/RO process met the standard for COD and T-P, but exceeded the permitted standard for T-N. In order to meet the effluent quality standard for T-N, it is necessary to change the MBR operation cycle or to add the secondary treatment by NF/RO.

• Membrane and Water Treatment
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• v.13 no.2
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• pp.63-72
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• 2022

Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m^-2h^-1) with relatively low reverse solute flux (0.125 g m^-2h^-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m^-2h^-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.4
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• pp.227-238
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• 2013

The purpose of this study is to develop a process technology to produce high hardness drinking water which meet drinking water standard, remaining useful minerals like magnesium and calcium in the seawater desalination process while removing the sulfate ions and chloride ions. Seawater have been separated the concentrated seawater and desalted seawater by passing on Reverse Osmosis membrane (RO). Using Nano-filtration membrane (NF), We were prepared primary mineral concentrated water that sodium chloride were not removed. By the operation of electro-dialysis (ED) having ion exchange membrane, we were prepared concentrated mineral water (Mineral enriched desalted water) which the sodium chloride is removed. We have produced the high hardness water to meet the drinking water quality standards by diluting the mineral enriched desalted water with deionized water by RO. Reverse osmosis membranes (RO) can separate dissolved material and freshwater from seawater (deep seawater). The desalination water throughout the second reverse osmosis membrane was completely removed dissolved substances, which dissolved components was removed more than 99.9%, its the hardness concentration was 1 mg/L or less and its chloride concentration was 2.3 mg/L. Since the nano-filtration membrane pore size is $10^{-9}$ m, 50% of magnesium ions and calcium ions can not pass through the nano-filtration membrane, while more than 95% of sodium ions and chloride ions can pass through NF membrane. Nano-filtration membrane could be separated salt components like sodium ion and chloride ions and hardness ingredients like magnesium ions and calcium ions, but their separation was not perfect. Electric dialysis membrane system can be separated single charged ions (like sodium and chloride ions) and double charged ions (like magnesium and calcium ions) depending on its electrical conductivity. Above electrical conductivity 20mS/cm, hardness components (like magnesium and calcium ions) did not removed, on the other hand salt ingredients like sodium and chloride ions was removed continuously. Thus, we were able to concentrate hardness components (like magnesium and calcium ions) using nano-filtration membrane, also could be separated salts ingredients from the hardness concentration water using electrical dialysis membrane system. Finally, we were able to produce a highly concentrated mineral water removed chloride ions, which hardness concentration was 12,600 mg/L and chloride concentration was 2,446 mg/L. By diluting 10 times these high mineral water with secondary RO (Reverse Osmosis) desalination water, we could produce high mineral water suitable for drinking water standards, which chloride concentration was 244 mg/L at the same time hardness concentration 1,260 mg/L. Using the linked process with reverse osmosis (RO)/nano filteration (NF)/electric dialysis (ED), it could be concentrated hardness components like magnesium ions and calcium ions while at the same time removing salt ingredients like chloride ions and sodium ion without heating seawater. Thus, using only membrane as RO, NF and ED without heating seawater, it was possible to produce drinking water containing high hardness suitable for drinking water standard while reducing the energy required to evaporation.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.10
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• pp.678-683
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• 2012

One of alternatives to solve the global water shortages is the reuse of wastewater. The aim of this study was to evaluate whether it can be reused for industrial water from wastewater in "A" City with ultrafiltration (UF) and reverse osmosis (RO) process. The results obtained in this study were that the inorganics such as Na, Mg, Cl, Ca, Mn, $PO_4$, $SO_4$, etc. were removed with high treatment efficiency (more than 97%), respectively. However, the removal of $NH_4$-N, TN, $NO_3$-N, BOD was found to be 35.71%, 85.21%, 87.05% and 56%, respectively. The removal efficiency of nutrients was relatively low compared to other metal ions. Despite low nutrients removal, the treated wastewater is recommended to reuse, because the nutrient contents in influent from the secondary wastewater treatment plant were small amount. In addition, all other metrics in the wastewater were found to be lower amount than wastewater reuse criteria. Therefore, the wastewater treated by UF-RO could be sufficient to reuse for industrial waster.

• Membrane and Water Treatment
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• v.8 no.3
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• pp.279-292
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• 2017

This study was aimed at ultrafiltration (UF) as a pretreatment before reverse osmosis (RO) within the scheme of hybrid reverse osmosis-multistage flush (RO-MSF) desalination. Seawater at elevated temperature (after MSF heat-exchangers) was used as a feed in this process. The pretreatment system was represented as a set of functionally-linked technological segments such as: UF filtration, backwashing, chemical- enhanced backwashing, cleaning, waste disposal, etc. The process represents the sequences of operating cycles. The cycle, in turn, consists of the following unit operations: filtration, backwashing and chemical-enhanced backwashing (CEB). Quantitative assessment was based on the following indicators: normalized permeability, transmembrane pressure, specific energy and water consumption, specific waste generation. UF pre-treatment is accompanied by the following waste streams: $W1=1.19{\times}10$ power of $-2m^3$ (disposed NaOCl with 0.0044% wt.)/$m^3$ (filtrate); $W2=5.95{\times}10$ power of $-3m^3$ (disposed $H_2SO_4$ with 0.052% wt.)/$m^3$(filtrate); $W3=7.26{\times}10$ power of $-2m^3$ (disposed sea water)/$m^3$ (filtrate). Specific energy consumption is $1.11{\times}10$ power of $-1kWh/m^3$ (filtrate). The indicators evaluated over the cycles with conventional (non-chemical) backwashing were compared with the cycles accompanied by CEB. A positive impact of CEB on performance indicators was demonstrated namely: normalized UF resistance remains unchanged within the regime accompanied by CEB, whereas the lack of CEB results in 30% of its growth. Those quantitative indicators can be incorporated into the target function for solving different optimization problems. They can be used in the software for optimisation of operating regimes or in the synthesis of optimal flow- diagram. The cycle characteristics, process parameters and water quality data are attached.

• Journal of Korean Society on Water Environment
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• v.18 no.4
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• pp.387-394
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• 2002

The efficiency variation of UF(tubular)/RO(spiral wound) process using acrylic wastewater treated by photo-catalyst pretreatment and coagulant-filter-neutralization pretreatment processes were discussed wit the variation of appled pressure and temperature. Ultrafiltration tubular module using acrylic wastewater treated by photo-catalyst pretreatment and coagulant-filter-neutralization pretreatment processes was shown that COD and T-N were not highly affected with the variation of appled pressure and temperature. It was shown that removal efficiency of COD and T-N was low. Removal efficiency of TDS and turbidity with ultrafiltration tubular module was better with the acrylic wastewater by photo-catalyst pretreatment than acrylic wastewater by coagulant-filter-neutralization pretreatment. T-N and TDS were shown high removal efficiency in reverse osmosis membrane process.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.3
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• pp.200-205
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• 2013

Pretreatment process is the critical step of RO (Reverse Osmosis) membrane desalination plant in order to prevent RO membrane fouling. The pretreatment as a key component of RO process must be designed to produce a constant and high quality RO feedwater which has low silt density index (SDI). This experiment was conducted to assess parameters affecting SDI value, such as pH, seawater turbidity, temperature, and coagulant dose. The experimental results indicated that the source seawater turbidity did cause little effects on SDI values of filtered water. The 0.45 um hydrophilic membrane was more appropriate than the hydrophobic membrane for measuring SDI. The SDI value was increased with decreasing pH under the condition of below pH 7.0. In addition, the water temperature significantly affected the SDI values, showing higher SDI value with lower water temperature.