• 제목/요약/키워드: retarded system

검색결과 150건 처리시간 0.026초

Ti-capping층이 NiSi의 열적안정성에 미치는 영향 (Effects of Ti-capping Layers on the Thermal Stability of NiSi)

  • 박수진;이근우;김주연;전형탁;배규식
    • 한국재료학회지
    • /
    • 제13권7호
    • /
    • pp.460-464
    • /
    • 2003
  • Ni and Ti films were deposited by the thermal evaporator, and then annealed in the N$_2$ ambient at 300-80$0^{\circ}C$ in a RTA(rapid thermal annealing) system. Four point probe, AEM, FESEM, AES, and XPS were used to study the effects of Ti-capping layers on the thermal stability of NiSi thin films. The Ti-capped NiSi was stable up to $700^{\circ}C$ for 100 sec. RTA, while the uncapped NiSi layers showed high sheet resistance after $600^{\circ}C$. These results were due to that the Ni in-diffusion and Si out-diffusion were retarded by the capping layer, resulting in the suppression of the formation of NiSi$_2$and Si grains at the surface.

망간코팅 여재를 이용한 수용액상의 망간 제거연구 (Removal of Manganese(II) from Aqueous Solution Using Manganese Coated Media)

  • 김석준;김원기;이승목;양재규
    • 한국물환경학회지
    • /
    • 제26권3호
    • /
    • pp.454-459
    • /
    • 2010
  • This study investigated the applicability of manganese coated media such as manganese coated sand (MCS), manganese coated sericite (MCSe) and manganese coated starfish material calcined at $550^{\circ}C$ (MCSf) to remove Mn(II) in synthetic wastewater. Manganese coated media prepared at different pH was applied in the treatment of soluble Mn(II) in batch and column experiments at various Mn(II) concentrations. The amount of Mn coated on three different media was approximately 800~1100 mg/kg. From the stability test, negligible dissolution of Mn was observed above pH 3.0. In batch test, more than 40% of Mn(II) was removed by all sand media at various manganese concentrations. In order to see the effect of additional oxidant for the removal of Mn(II), 4 mg/L of hypochlorite was added in Mn(II) solution during column experiment. Breakthrough of Mn(II) was greatly retarded in the presence of hypochlorite in all column reactors packed with different media. Among the manganese coated media, MCSf prepared at pH 4 indicated the highest removal capacity. The removal efficiency of Mn(II) was also increased in the multi-layer system (0.5 g of MCS, MCSe, and MCSf each).

Ti-capped NiSi 형성 및 열적안정성에 관한 연구 (A Study on the Formation of Ti-capped NiSi and it′s Thermal Stability)

  • 박수진;이근우;김주연;배규식
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
    • /
    • pp.288-291
    • /
    • 2002
  • Application of metal silicides such as TiSi$_2$ and CoSi$_2$ as contacts and gate electrodes are being studied. However, TiSi$_2$ due to the linewidth-dependance, and CoSi$_2$ due to the excessive Si consumption during silicidation cannot be applied to the deep-submicron MOSFET device. NiSi shows no such problems and can be formed at the low temperature. But, NiSi shows thermal instability. In this investigation, NiSi was formed with a Ti-capping layer to improve the thermal stability. Ni and Ti films were deposited by the thermal evaporator. The samples were then annealed in the N$_2$ ambient at 300-800$^{\circ}C$ in a RTA (rapid thermal annealing) system. Four point probe, FESEM, and AES were used to study the thermal properties of Ti-capped NiSi layers. The Ti-capped NiSi was stable up to 700$^{\circ}C$ for 100 sec. RTA, while the uncapped NiSi layers showed high sheet resistance after 600$^{\circ}C$. The AES results revealed that the Ni diffusion further into the Si substrate was retarded by the capping layer, resulting in the suppression of agglomeration of NiSi films.

  • PDF

댐 방류조건에 따른 저수지 유속과 수온 영향 (The Effect of Current and Temperature of a Reservoir by the Simulation of Dam Outflow)

  • 유순주;하성룡;정동일
    • 한국물환경학회지
    • /
    • 제22권6호
    • /
    • pp.1060-1067
    • /
    • 2006
  • Water quality in the Daecheong reservoir has been deteriorated by algal bloom due to nutrient supply from the upstream of the Daecheong reservoir after heavy rainfall. Algal bloom is propagated from eutrophicated tributary into the main body of the reservoir according to the hydrological conditions. This study is aimed to estimate the water current and temperature effect by the simulation of dam spill flow control using water quality model, CE-QUAL-W2 in 2003. Water current was resulted in nutrient transport from upstream of main reservoir and nutrients were delivered up to downstream by fast water velocity. Algal blooms occurred in stagnate zone of reservoir downstream as the current of downstream was retarded according to dam outflow control. Consequently water balance in stagnate zone triggered a rise of water temperature in summer. It affected algal bloom in the embayment of the reservoir. The simulation result by outflow control scenarios showed that spill flow augmentation induced in water body instability of stagnate zone so that water temperature declined. It could be suggested that outflow control minimize algal bloom in the downstream in the flooding season as long as water elevation level is maintained properly.

The Research of Beach Deformation after Construction of the Jetties

  • Park, Sang-Kil;Han, Chong-Soo;Roh, Tae-Young;Park, O-Young;Ahn, Ik-Seong;Lee, Ji-Hun
    • International Journal of Ocean System Engineering
    • /
    • 제1권4호
    • /
    • pp.185-191
    • /
    • 2011
  • This research was described the prevention of coastal topographical change and sediment diffusive concentration incoming from small estuary after construction jetties. This structure is constructed to decrease sediment deposition incoming from the upstream river due to the urbanization and industrial development and to minimize effects on the coastal ecosystem. The physical modeling and numerical modeling for waves were conducted to analyze the configuration of Imrang sand beach deformation without and with construction of jetty. The specification of the installed jetty, which is able to control sedimentation concentration was decided based on the prediction of the Imrang beach area changes by space and time. As a result, the jetties constructed in the estuary retarded the rate of sand sediment, so that the effect area of sand sedimentation was obviously decreased. In addition, the measured field data indicated that the sediment deposition inside of dikes could be controlled and the right side area of jetties could be preserved without sediment deposition.

공장자동화 사업의 투자 정당성 분석, 경제성 분석만으로 충분한가\ulcorner (Capital Budgeting Methods Are Not Enough : Justification of Factory Automation Projects)

  • Yong-Tae Park
    • 기술경영경제학회:학술대회논문집
    • /
    • 기술경영경제학회 1992년도 제2회 학술발표회
    • /
    • pp.97-118
    • /
    • 1992
  • To date, the implementation and adoption of new manufacturing technologies has been retarded despite their technical advances and strategic virtues such as flexibility and synergy effect. This phenomenon is partly attributable to the lack of commensurate development and widespread dissemination of adequate selection and justification procedures. Many strategically vital automation projects have been rejected and/or seemingly promising proposals have turned out to be fiascos since the justification process has been solely based on the traditional capital budgeting or engineering economy methods. As the degree of system automation/integration increases, a variety of benefit/cost attributes, both quantitative and qualitative, should be taken into account and more comprehensive and analytic justification methods should be applied in the justification process. This paper points out the distinct characteristics of advanced technologies and presents an illustrative set of procedures that can be used in the justification process. It outlines the algorithmic structure of each procedure and also describes the advantages/disadvantages of each procedure and the conditions under which it is most appropriate to employ. The selection of appropriate justification technique is situation-specific. In general, it is recommended that more complex and sophisticated procedures be used as the degree of integration increases. Nonetheless, traditional procedures may be used as well to make in-depth analyses of the local impact.

  • PDF

Catechol생산을 위한 Tyrosinase의 안정화 (Stabilization of Tyrosinase for Catechol Production)

  • 박종현;김용환유영제이윤식
    • KSBB Journal
    • /
    • 제9권5호
    • /
    • pp.525-531
    • /
    • 1994
  • 본 연구에서는 tyrosinase 효소반응시에 발생하는 반응 비활성화를 막아 조엽 얀정성을 향상시키는 것을 목적으로 연구를 수행하였다. Quinone에 의해 친핵성 공격을 받는 lysine기를 bifunctional rea gent인 glutaraldehyde로 변형시켜 줌으로써 효소 의 비활성화를 줄일 수 있었다. 또한, 고정화된 효소 를 충진층 반응기에 충진시켜 비활생화를 열으키는 생산물을 연속적으로 제거함으로써 효소의 얀정성을 크게 향상시켰다. 고정화 방법으로는 glass bead를 이용한 담체 가교법을 이용하였으며, 이때 glutaral­d dehyde와 효소의 lysine이 반응하게 되어 qumone 에 의한 친핵성 공격을 받지 않게 되어 안정성이 더욱 향상되 었다. 반응매 질로 borate buffer를 이용하 게되면 catechol과 borate의 복합체 형성으로 catechol에서 qumone으로의 전환이 줄어들게 되어 효소 비활성화가 감소하였다.

  • PDF

The effect of dynamic operating conditions on nano-particle emissions from a light-duty diesel engine applicable to prime and auxiliary machines on marine vessels

  • Lee, Hyungmin;Jeong, Yeonhwan
    • International Journal of Naval Architecture and Ocean Engineering
    • /
    • 제4권4호
    • /
    • pp.403-411
    • /
    • 2012
  • This study presents the nano-sized particle emission characteristics from a small turbocharged common rail diesel engine applicable to prime and auxiliary machines on marine vessels. The experiments were conducted under dynamic engine operating conditions, such as steady-state, cold start, and transient conditions. The particle number and size distributions were analyzed with a high resolution PM analyzer. The diesel oxidation catalyst (DOC) had an insignificant effect on the reduction in particle number, but particle number emissions were drastically reduced by 3 to 4 orders of magnitude downstream of the diesel particulate filter (DPF) at various steady conditions. Under high speed and load conditions, the particle filtering efficiency was decreased by the partial combustion of trapped particles inside the DPF because of the high exhaust temperature caused by the increased particle number concentration. Retarded fuel injection timing and higher EGR rates led to increased particle number emissions. As the temperature inside the DPF increased from $25^{\circ}C$ to $300^{\circ}C$, the peak particle number level was reduced by 70% compared to cold start conditions. High levels of nucleation mode particle generation were found in the deceleration phases during the transient tests.

Triphenylmethane Dye와 Cyanide Ion과의 반응에 대한 Micelle의 촉매작용 (Micelle Catalysis on the Reaction between Triphenylmethane Dyes and Cyanide Ion)

  • 구원회
    • 대한화학회지
    • /
    • 제17권6호
    • /
    • pp.411-415
    • /
    • 1973
  • Cyanide ion과 triphenylmethane dye와의 반응은 cetyltrimethyl ammonium bromide(CTABr)의 cationic micelle에 의하여 현저히 반응속도가 빨라지며 sodium lauryl sulfate(NaLS)의 anionic micelle에 의하여 반응속도가 늦어진다. 또한 CTABr존재하의 반응은 inorganic anion에 의하여 inhibition, 되며 NaLS존재하의 반응은 inorganic cation중의 몇가지, 특히 $Zn^{++},\;Cd^{++}$등에 의하여 현저하게 반응이 빨라지는 salt effect를 나타낸다. 물과 잘 혼합되는 몇가지 유기용매의 micelle catalysis에 대한 영향은 대체로 수용액 일때보다 작게 나타나서 반응속도가 늦어지거나 malachite green과의 반응에서 methanol은 수용액일때보다 반응속도가 빨라지는 특이한 solvent effect를 나타내었다.

  • PDF

Expression of Gal4-VP16 and Gal4-DNA binding domain under the control of the T lymphocyte-specific lck proximal promoter in transgenic mice

  • Ryu, Chun-Jeih;Whitehurst, Charles E.;Chen, Jianzhu
    • BMB Reports
    • /
    • 제41권8호
    • /
    • pp.575-580
    • /
    • 2008
  • Thymocyte-specific transcriptional regulatory systems can be used to better understand the relationship between transcription and V(D)J recombination during early T cell development. In this study, we generated transgenic mice expressing the transactivator Gal4-VP16 or the Gal4 DNA binding domain (Gal4-DBD) under the control of the lck proximal promoter, which is only active in immature thymocytes. From these studies Gal4-VP16 and Gal4-DBD expression was shown to significantly alter thymic cellularity and differentiation without significantly changing the $CD3^+$ thymocyte distribution. Furthermore, the presence of Gal4-VP16 or Gal4-DBD in the transgenic thymocytes retarded the mobility of the Gal4 DNA binding motif as determined by a gel mobility shift assay, suggesting that the developmental alteration did not affect the functional property of the transgenic proteins. These results indicated that lck promoter-driven Gal4-VP16 or Gal4-DBD expression did not affect $CD3^+$ mature thymocytes, thus this system can be applied to study transcriptional regulation of transresponder genes in bigenic mouse model thymocytes.