• Journal of the Korean Society of Industry Convergence
• /
• v.25 no.2_2
• /
• pp.289-297
• /
• 2022

Deterioration in durability of structures due to the steel corrosion is difficult to determine whether or not corrosion is initiated and how much propagated, and moreover, repair and maintenance are not easy to deal with. Therefore, preventive treatments can be the best option to avoid the deterioration. Various methods for preventing corrosion of steel, such as electrochemical treatments, anti-corrosion agents and steel surface coatings, are being developed, but economic and environmental aspects make it difficult to apply them to in-situ field. Thus, the purpose of this study was to improve corrosion resistance by using CA-based clinker that are relatively simple and expected to be economically profitable Existing CA-based clinkers had problems such as flash setting and low strength development during the initial hydration process, but in order to solve this problem, CA clinker with low initial reactivity were used as binder in this study. The cement paste used in the experiments was replaced with CA₂ clinker for 0%, 10%, 20%, and 30% in OPC. And the mixture used in the chloride binding test for the extraction of water-soluble chloride was intermixed with Cl- 0.5%, 1%, 2%, and 3% by weight of binder content. To evaluate characteristic of hydration heat evolution, calorimetry analysis was performed and simultaneously chloride binding capacity and acid neutralization capacity were carried out. The identification of hydration products with curing ages was verified by X-ray diffraction analysis. The free chloride extraction test showed that the chlorine ion holding ability improved in order OC 10 > OC 30 > OC 20 > OC 0 and the pH drop resistance test showed that the resistance capability in pH 12 was OC 0 > OA 10 > OA 20 > OA 30. The XRD analyses showed that AFm phase, which can affect the ability to hold chlorine ions, tended to increase when CA₂ was mixed, and that in pH12 the content of calcium hydroxide (Ca(OH)₂), which indicates pH-low resistance, decreased as CA₂ was mixed

• Journal of the Korean Geotechnical Society
• /
• v.35 no.6
• /
• pp.27-38
• /
• 2019

Bearing capacity of a pile in homogeneous soil is the sum of end bearing and skin resistance, and the skin resistance is more prominent in sandy soil. Bearing capacity of a pile in pile groups especially in sandy ground should be designed under the consideration of the influence by the adjacent piles. In this study, the end bearing capacity of a pile in pile groups was experimentally investigated. For this purpose, piles were installed in sandy ground in a circular test box, and end bearing - settlement behavior of the pile was measured while the pile was loaded. As the results, end bearing - settlement relation curves of the piles showed a distinct limit value. Limit value of the end bearing was little affected by skin friction and pile diameter, and it became a constant value as pile penetrates deeper. End bearing was not affected by the adjacent piles in a group of piles, when their clearance was larger than the pile diameter.

• Computers and Concrete
• /
• v.34 no.4
• /
• pp.379-391
• /
• 2024

The ultra-high performance concrete (UHPC) mixed with hybrid fibers has excellent mechanical properties and durability, and the hybrid fibers have a certain impact on the bearing capacity, deformation capacity, and crack propagation of beams. Many scholars have conducted a series of studies on the bending performance of prestressed UHPC beams, but there are few studies on prestressed UHPC beams mixed with hybrid fibers. In this study, five bonded post-tensioned partially prestressed UHPC beams mixed with steel fibers and macro-polyolefin fibers were poured and subjected to four-points symmetric loading bending tests. The effects of different prestressing degrees and prestressing levels on the load-deflection curves, crack propagation, failure modes and ultimate bearing capacity of beams were discussed. The results showed that flexural failure occurred in the prestressed UHPC beams with hybrid fibers, and the integrity of specimens was good. When the prestressing degree was the same, the higher the prestressing level, the better the crack resistance capacity of UHPC beams; When the prestressing level was 90%, increasing the prestressing degree was beneficial to improve the crack resistance and ultimate bearing capacity of UHPC beams. When the prestressing degree increased from 0.41 to 0.59, the cracking load and ultimate load increased by 66.0% and 41.4%, respectively, but the ductility decreased by 61.2%. Based on the plane section assumption and considering the bridging effect of short fibers, the cracking moment and ultimate bearing moment were calculated, with good agreement between the test and calculated values.

• Journal of Yeungnam Medical Science
• /
• v.12 no.2
• /
• pp.269-281
• /
• 1995

The effect of persistant mild hyperglycemic hyperinsulinemia on the development of the insulin resistance in rats was studied in vivo. Also, the characteristics of the insulin resistance compared with the insulin resistance of STZ diabetic rats. Persistant mild hyperglycemic hyperinsulinemic rat model was produced by ingestion of glucose polymer for 8 days. The glucose disappearance and infusion rate was measured by hyperinsulinemic euglycemic clamp technique at steady state of blood glucose and insulin levels. The clamped level of blood glucose was 100 mg/dl, and the clamped levels of insulin were $70{\mu}U/ml$ (physiologic condition) and $3000{\mu}U/ml$ (supramaximal condition). Hepatic glucose producticon rate was calculated using measured data. And the glycogen synthetic capacity of skeletal muscle(soleus) and liver was measured after 2 hours of hyperinsulinemic euglycemic clamp study. The glucose disappearance and glucose infusion rate in glucose polymer group was decreased in the both physiological and supramaximal insulin level compared to the rate of the normal control group. The rate of STZ diabetic group wase lowest at supramaximal insulin level among two another experimental groups. The hepatic glucose production rate of glucose polymer group was decreased compared to normal control but increased in STZ diabetic group. The glycogen synthetic capacity of skeletal muscle and liver of glucose polymer group was not significantly different from normal control group, but it was markdly decreased in STZ diabetic group. These results suggest that persistant mild hyperglycemic hyperinsulinemia may induce insulin resistance, but glycogen synthetic capacity is intact.

• Journal of the Korean Geosynthetics Society
• /
• v.18 no.3
• /
• pp.45-53
• /
• 2019

In this study, it was analyzed the cases of bored PHC piles designed for the building foundations. The overall length of the piles varies within a maximum of 35 m. However, the average length was 17.0 to 18.9 m depending on the kind of the bedrock, with no significant difference. The socket length entered into the bedrock was designed with approximately 58% of the whole piles being 1m, the minimum length of the specification, and up to 5m. Although the range in design efficiency was very large, on average it was about 70%, consistent with the usual known extent. Applications with low design efficiency were mainly shown on the foundation of low-rise buildings or rides with low design load. On the weathered rock, the design load, which governs the design result was widely distributed at 65 to 97% of allowable bearing capacity of ground. The ratio of allowable axial load of piles to allowable bearing capacity of ground is also widely distributed between 36 and 115%, so optimization efforts are required along with design efficiency. On the other hand, the allowable bearing capacity on the soft or hard rock was highly equal, mostly within 90% of the allowable axial load of piles. In the design, the end bearing resistance averaged over 75% of the allowable bearing capacity. However, the results of the dynamic pile load test show that the end bearing resistance was predominant under the E.O.I.D conditions, and in some cases, the end bearing resistance was at least 25% under the restrike conditions.

• Corrosion Science and Technology
• /
• v.8 no.2
• /
• pp.74-80
• /
• 2009

The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

• Membrane Journal
• /
• v.23 no.6
• /
• pp.469-474
• /
• 2013

An anion exchange membrane was prepared for a separator in the alkaline water electrolysis. An anion exchange membrane was prepared by the chloromethylation and amination of polyvinyl chloride (PVC) used as a base polymer. The membrane properties of the prepared anion exchange membrane such as the membrane resistance and ion exchange capacity were measured. The minimum membrane resistance of the prepared anion exchange membrane was $2.9{\Omega}{\cdot}cm^2$ in 1M NaOH aq. solution. This membrane had 2.17 meq./g-dry-membrane and 43.4% for the ion exchange capacity and water content, respectively. The membrane properties of the prepared anion exchange membrane was compared with that of the commercial anion exchange membrane. The membrane resistance decreased in the order; AHT>IOMAC> Homemade membrane> AHA>APS=AFN. The ion exchange capacity decreased in the order; Homemade membrane>AFN>APS>AHT>AHA>IOMAC.

• Journal of Korean Society of Steel Construction
• /
• v.26 no.6
• /
• pp.499-509
• /
• 2014

This study focuses on mixing steel fiber in the concrete to improve the ductility and toughness of the columns. The purpose of the study is to evaluate the load capacity and deformation capacity associated with the amount of steel fiber and loading condition and to analyze the interplay between the steel fiber reinforced concrete and the welding built-up square tube in terms of structure and fire resistance performance. Reinforcement of concrete with steel fiber(Vf=0.375%), when cross-section shape and boundary condition (load ratio) remained unchanged, improved fire resistance performance by 1.1~1.3 times. It is deemed that the area resisting thermal load increased and fire resistance performance was improved since the concrete reinforced with steel fiber restrained cracking. In addition, the fact that the cross-sections of the concrete were barely damaged indicates that load share capacity was greatly improved.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.12
• /
• pp.3553-3558
• /
• 2014

The reduced graphene oxide(rGO)/aluminum phosphate($AlPO_4$)-coated $LiMn_{1.5}Ni_{0.5}O_4$ (LMNO) cathode material has been developed by hydroxide precursor method for LMNO and by a facile solution based process for the coating with GO/$AlPO_4$ on the surface of LMNO, followed by annealing process. The amount of $AlPO_4$ has been varied from 0.5 wt % to 1.0 wt %, while the amount of rGO is maintained at 1.0 wt %. The samples have been characterized by X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy. The rGO/$AlPO_4$-coated LMNO electrodes exhibit better cyclic performance compared to that of pristine LMNO electrode. Specifically, rGO(1%)/$AlPO_4$(0.5%)- and rGO(1%)/$AlPO_4$(1%)-coated electrodes deliver a discharge capacity of, respectively, $123mAhg^{-1}$ and $122mAhg^{-1}$ at C/6 rate, with a capacity retention of, respectively, 96% and 98% at 100 cycles. Furthermore, the surface-modified LMNO electrodes demonstrate higher-rate capability. The rGO(1%)/$AlPO_4$(0.5%)-coated LMNO electrode shows the highest rate performance demonstrating a capacity retention of 91% at 10 C rate. The enhanced electrochemical performance can be attributed to (1) the suppression of the direct contact of electrode surface with the electrolyte, resulting in side reactions with the electrolyte due to the high cut-off voltage, and (2) smaller surface resistance and charge transfer resistance, which is confirmed by total polarization resistance and electrochemical impedance spectroscopy.

• Fisheries and Aquatic Sciences
• /
• v.16 no.1
• /
• pp.7-14
• /
• 2013

A 10-week feeding trial was conducted to examine the effects of dietary spirulina and quercetin on growth, innate immunity, disease resistance and dietary antioxidant capacity in the juvenile olive flounder. Triplicate groups of fish (initial body weight, $2.9{\pm}0.01g$) were fed one of isonitrogenous (48% crude protein) and isocaloric (17.4 MJ/kg DM) experimental diets containing 0% spirulina (as a control), 3.4% spirulina, or 6.8% spirulina with or without supplementation of 0.5% quercetin (designated as CON, SP3.4, SP6.8, and SP6.8 + Q, respectively) at a rate of 3% body mass twice daily. Higher dietary antioxidant capacity was found with spirulina supplementation, and the highest value (P < 0.05) was obtained with SP6.8 + Q diet. At the end of the feeding trial, no significant effects were observed on growth performance, body composition and disease resistance against Edwardsiella tarda. Lysozyme activity was significantly increased by spirulina supplementation (P < 0.05), and the highest value was observed in the group fed SP6.8 + Q diet. Also, significantly higher respiratory burst activity (P < 0.05) was found in SP3.4 group. According to the results of this study, dietary supplementation of 3.4% spirulina may enhance innate immunity of olive flounder.