• 한국산업보건학회지
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• 제3권1호
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• pp.91-98
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• 1993

This study was carried out to investigate characteristic of vinyl chloride emissioned from poly vinyl chloride extrusion process and to evaluate the efficiency of local exhaust ventilation system. Before local ventilation facility was constructed in poly vinyl chloride extrusion process, the average worker exposure to vinyl chloride was 3.15 ppm, which exceeded Threshold Limit Value of American Conference of Gorvernmental Industrial Hygienists (ACGIH-TLV), 1 ppm. lt is possible that vinyl chloride residues in the poly vinyl chloride resin was released or degased due to extrusion heat. The larger the width of vinyl tube become, the higher worker exposure to vinyl chloride was. It is estimated that vinyl chloride from vinyl chloride resin increased as amount of poly vinyl chloride resin extruded in the extrusion process increased. Canopy hood was an appropriate type for poly vinyl chloride resin extrusion process. This local exhaust ventilation has fan static pressure of 7.65 inch wg($190mmH_2O$, total volumetric flowlate of 4,796 CFM ($135.8m^3$/min) and fan power requirement of 12 hp (8.952 Kw). After this local exhaust ventilation was constructed there, the average concentration of worker exposure to vinyl chloride was reduced to be 0.46 ppm, which was below the Threshold Limit Value, 1 ppm. Also, the removal efficiency rate of vinyl chloride attained by local exhaust ventilation was 85.3%. It was a statistically significant (p<0.01).

• 한국유체기계학회 논문집
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• 제17권2호
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• pp.35-40
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• 2014

The optimal removal efficiency to develop wastewater treatment system using the magnetic ion exchange resin. The secondary sedimentation effluent of wastewater in W wastewater treatment plant located in Gyeong-gi Province was used as the influent. To compare the sedimentation effluent reacted with the magnetic ion exchange resin to the influent, the concentrations of CODmm, TN, $NO{_3}^-$-N and TP were measured. The flux of the influent and HRT were set to 250 mL/min, 10 min, respectively, and BVTR has adjusted to 200, 150, 100. The removal efficiency of CODmn, TN, $NO{_3}^-$-N and TP in the 200 BVTR from 71%, 40.37%, 46.34%, 42.03%, 150 BVTR from 55.22%, 37.83%, 50.38% 41.6% and 100 BVTR from 74%, 59.15%, 79.94%, 79.16%, respectively. The results on 200 BVTR, 150 BVTR, 100 BVTR tests show that 100 BVTR is the optimal factor capable of the highest rate of rejection of the organic material.

• Nuclear Engineering and Technology
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• 제55권10호
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• pp.3665-3676
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• 2023

The use of ion exchange resins to remove ionic impurities from solution is prevalent in industrial process systems, including in the primary heat transport system (PHTS) purification circuit of nuclear power plants. Despite its extensive use in the nuclear industry, our general understanding of ion exchange cannot fully explain the complex chemistry in ion exchange beds, particularly when operated at or near their saturation limit. This work investigates the behaviour of mixed-bed ion exchange resin, saturated with species representative of corrosion products in a CANDU (Canadian Deuterium Uranium) reactor PHTS, particularly with respect to iron chemistry in the resin bed and the removal of lithium ions from solution. Experiments were performed under deaerated conditions, analogous to normal PHTS operation. The results show interesting iron chemistry, suggesting the hydrolysis of cation resin bound ferrous species and the subsequent formation of either a solid hydrolysis product or the soluble, anionic Fe(OH)₃^-.

• Journal of Radiation Protection and Research
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• 제29권1호
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• pp.1-8
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• 2004

ANL에서 개발한 유 무기 복합의 신이온교환수지인 Diphosil은 silica 물질에 diphosphonic acid 그룹을 결합시킨 구조를 가지고 있다. Diphosil을 원전 운영 중 발생되는 방사성폐액 처리에 적용하기 위해 주대상 핵종인 $^{137}Cs,\;^{60}Co$을 사용하여 흡착 평형과 컬럼 실험을 수행하였다. 흡착 평형 실험을 통하여 $^{137}Cs$과 $^{60}Co$의 제거율과 그 제거율에 미치는 다양한 조건에서 비방사성 이온의 영향을 조사하였다. 대상 핵종에 대한 파과곡선은 모의 방사성 폐액을 이용한 실험실 수준의 컬럼 실험을 통해 구하였고, Diphosil의 제거능력을 현재 원전에서 쓰이고 있는 Amberlite IRN 77 수지와 비교하였다.

• 한국환경과학회지
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• 제31권1호
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• pp.1-8
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• 2022

In this study, solid-liquid separation conditions for coagulation and sedimentation experiments using inorganic coagulant (aluminum sulfate and Poly-Aluminum Chloride (PAC)) were optimized with brine wastewater discharged by the epoxy-resin process. When the turbidity and suspended solid (SS) concentration in raw wastewater were 74 NTU and 4.1 mg/L, respectively, their values decreased the lowest in a coagulant dosage of 135.0 - 270.0 mg Al³⁺/L. The epoxy resin was re-dispersed in the upper part of wastewater treated above 405.0 mg Al³⁺/L. The removal efficiencies of turbidity and SS via dosing with aluminum sulfate and PAC were evaluated at initial turbidity and SS of 74 - 630 NTU and 4.1 - 38.5 mg/L, respectively. They increased most in the range from 135.0 - 270.0 mg Al³⁺/L. The solid-liquid separation condition was quantitatively compared to the correlation of SS removal efficiency between the coagulant dosage and SS concentration based on the concentration of aluminum ions. The empirical formula, R = be^aD, shows the relationship between SS removal efficiency (R) and coagulant dosage (D) at 38.5 mg/L; it produced high correlation coefficients (r²) of 0.9871 for aluminum sulfate and 0.9751 for PAC.

• 공업화학
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• 제24권1호
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• pp.49-54
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• 2013

혼합용액에서 nitrate 이온을 선택적으로 제거하기 위해 복합탄소전극을 제조하였다. 질산이온 선택성 수지(BHP55, Bonlite Co.) 분말을 탄소전극 표면에 코팅하여 전극을 제조하였다. 제조한 전극으로 BHP55 셀을 제작하여 chloride, nitrate, sulfate 이온이 혼합된 용액에 대해 축전식 탈염 실험을 수행하였다. 그리고 BHP55 셀에서의 질산 이온 제거량을 이온교환막을 결합한 MCDI 셀의 결과와 비교하였다. BHP55 셀에서 이온의 총 흡착량은 MCDI 셀에서 보다 31% 증가한 $38.3meq/m^2$를 나타냈다. 또한 BHP55 셀에서 질산 이온의 흡착량은 $15.9meq/m^2$ (전체 흡착량의 42%)이었고, 이는 MCDI 셀에서 보다 2.1배 큰 것으로 나타났다. 실험결과 제조한 복합탄소전극은 음이온 혼합용액에서 질산 이온을 선택적으로 제거하는데 매우 효과적임을 알 수 있었다.

• 한국환경과학회지
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• 제9권4호
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• pp.319-323
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• 2000

Nitrate-selective ion exchange resin which have bulky tertiary amine as functional group have been synthesized by the reaction of chloromethylated polystyrene-divinylbenzene copolymer and the corresponding tertiary amine [$NR_3=NE_{t3} 1, N{(C_2 H_4 H_3)}_32]$in ethanol, while commercial resin has $NMe_3$ as functional group. The fundamental properties such as bulk density, water content, appearance index, exchange capacity, effective size, uniformity coefficient of synthesized anion exchange resin (1) have been measured. The ion exchange resin (1) and (2) exhibited the better selectivity for nitrate than sulfate in both batch and continuous column experiments.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.81.1-81.1
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• 2012

나노임프린트 리소그라피(Nano-Imprint Lithography, NIL) 기술은 기판위의 resin을 나노구조물이 각인된 스탬프로 눌러서 나노구조물을 형성하는 기술로, 경제적이고 효과적으로 나노구조물을 제작할 수 있는 기술이다. 그중에서도 UV 기반의 나노임프린트(UV-NIL) 기술은 resin을 투명한 스탬프로 누른뒤 UV로 경화시켜 나노구조물을 형성하는 기술로써 고온, 고압($140{\sim}180^{\circ}C$, 10~30bar)이 필요한 가열식 나노임프린트 기술에 비해 상온, 상압($20^{\circ}C$, 1bar)에서도 구조물 형성이 가능하여 다층구조 형성에 적합하다. 연속적인 임프린팅 공정에 의해 resin이 quarz 스탬프에 잔류하여 패터닝에 결함을 유발하게 되므로 오염물을 제거하기 위한 세정공정이 필요하다. 하지만 UV에 의해 경화된 resin은 cross-linking을 형성하여 화학적인 내성이 증가하게 되므로 제거하기가 어렵다. 현재는 resin 제거를 위한 세정공정으로 SPM($H_2SO_4/H_2O_2$) 세정이 사용되고 있는데 세정시간이 길고 세정 후에 입자 또는 황 잔유물이 남으며 많은 유해용액 사용의 문제점이 있어 효과적으로 resin을 제거할 세정공정이 필요한 상황이다. 본 연구에서는 친환경적인 UV 세정 및 오존수 세정공정을 적용하여 경화된 resin을 제거하는 연구를 진행하였다. 실험샘플은 약 100nm 두께의 resin을 증착한 $1.5cm{\times}1.5cm$ $SiO_2$ 쿠폰 wafer를 사용하였으며, UV 및 오존수의 처리시간을 달리하여 resin 제거효율을 평가하였다. ATR-FTIR 장비를 사용하여 시간에 따른 resin의 두께를 측정한 결과, UV 세정으로 100nm 높이의 resin중에 80nm의 bulk resin이 단시간에 제거가 되었고 나머지 20nm의 resin thin film은 오존수 세정으로 쉽게 제거되는 것을 확인 하였다. 또한 표면에 남은 resin residue와 particle을 제거하기 위해서 SC-1 세정을 진행하였고 contact angle과 optical microscope 장비를 사용하여 resin이 모두 제거된 것을 확인하였다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제8권1호
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• pp.17-26
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• 2003

TRIGA원자로 주변 토양을 인공적으로 오염시킬 때, 오염용액 내의 코발트농도가 작아짐에 따라 코발트의 흡착평형 계수는 증가했고, 이 오염토양 질량 대 Citrc acid용액 부피 비율률 1:5로 하였을 때 토양제염효율이 높았다. 0.01M, 0.01M, 0.0001M코발트용액으로 오염된 TRIGA토양을 0.01M Citric acid로 Washing한 후의 토양세척액의 코발트 농도는 각각 136.0, 14.0, 1.5 ppm이었다. 화학침전법에 의해 토양세척폐액 내의 코발트농도가 낮아질수록 제거율은 저하했다. 그러나 다량의 NaOH가 첨가되어야 하고 최종침전폐기물의 부피가 오염토양부피의 약 10%정도나 되었다. 이온교환수지법에 의한 재생실험결과 강산성수지를 많이 넣을수록 코발트제염 효율은 증가했고 pH는 감소했다. 코발트농도가 다른 세 종류의 토양세척폐액에 강산성수지를 넣고 흡착실험을 한 결과 일정한 코발트 제거효율을 얻기 위해 필요한 강산성수지의 질량은 모두 거의 일정했다. 즉, 95%이상의 제거효율을 얻기 위해 0.625 g 이상의 강산성수지가 필요했다. 한편, 토양부피의 약9.2%의 다량의 강산성수지 폐기물이 발생하는 것이 문제점이다.

• 대한치과보철학회지
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• 제29권1호
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• pp.91-109
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• 1991

The purpose of this study were to comfirm the effects of the thickness and kinds of porcelain, etchants, illumination time, elapsed time for the measurement, and chemical cure component to the bond strength of porcelain laminate and composite resin cement, and to compare the effects between the light cured resin and the dual cured resins. The etched porcelain surface, the sectioned surface crossing porcelain and resin after bonding, and the debonded surfaces were observed by the SEM. One product of laminate porcelain powder, one light cured resin and two dual cured resins were selected. Each resin cements are lightened through the thin porcelain disc which was cut from cylindrical porcelain specimen by the diamond saw, and by the light through the porcelain disc they were bonded. Changes of thickness and kinds of porcelain, etchants, illumination time, and the elapsed time for the measurement were considered as variables for the bond strength. And the bond strength of porcelain and dual cured resins under the conditions of autopolymerization or the removal of chemical cure component were measured and compared. Bond strength were measured by shear stress. The etched surface, the cross-sectioned surface, and the debonded surface of porcelain or resin were observed by SEM. On the summary of this study, the following conclusions can be stated; 1. Bond strength of light cured resin was decreased inversely by the thickened porcelain laminate and showed the lowest value to the masking dentin porcelain among 4 kinds of porcelain powder. 2. Bond strength of autopolymerization of dual cured resin without illumination in dark chamber were from 75% to 98% to the data of dual cured resin with illumination. 3. Bond strength of dual cured resin used without chemical cured components were same to them of light cured resin. 4. Cross-sectioned surface treated by silane did not show the gap between the porcelain and resin. 5. Illumination over 80 seconds did not make the significant increase of bond strength on all kinds of resin.