• 제목/요약/키워드: resin lifetime

검색결과 19건 처리시간 0.022초

확산한계전류밀도 고찰에 의한 방청도료의 내식성평가 (Evaluation of Corrosion Resistance of Anti-Corrosive Paint by Investigation of Diffusion Limiting Current Density)

  • 문경만;김윤해;이명훈;이인원;박현;전호환
    • 한국해양공학회지
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    • 제23권4호
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    • pp.64-68
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    • 2009
  • It has been observed that coated steel structures deteriorate more rapidly than the designed lifetime due to acid rain caused by air pollution, etc. Therefore, improving the corrosion resistance of anti-corrosive paint is very important in terms of safety and the economic point of view. In this study, the corrosion resistance of five kinds of anti-corrosive paints, including the Acryl, Fluorine, and Epoxy resin series, were investigated with electrochemical methods, such as corrosion potential measurements, polarization curves, diffusion limiting current density, etc. As a result, the corrosion resistance of the F101 specimen with the fluorine resin series was found to be superior to the other specimens, while E100 with the epoxy resin series also showed a somewhat good corrosion resistance. Furthermore, it was observed that the amount of water and oxygen entering the inner side of a painted film increased with an increase in immersion time, irrespective of the kind of resin series. However, the oxygen diffusion limiting current density of a specimen with good corrosion resistance was relatively decreased compared to other specimens, because of the difficulty of oxygen diffusion penetrating to the inner side of the film. Consequently it is suggested that we can qualitatively evaluate the corrosion resistance of an anti-corrosive paint by measuring the diffusion limiting current density as an electrochemical method.

수중 경화형도료의 부식특성에 관한 전기화학적 고찰 (Evaluation of Corrosion Characteristics of Underwater Hardening Paint)

  • 문경만;오민석;이명훈;이성렬;김윤해
    • 한국해양공학회지
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    • 제25권2호
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    • pp.85-91
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    • 2011
  • Many protection methods such as surface coating, electric protection, or other methods have been applied to the numerous steel structures widely used in continental and marine areas to control their corrosion, which is done from an economic point of view. Most of these steel structures are primarily protected by coating methods. However, some steel piles under seawater are protected by the electric protection method, that is, either using an impressed current or a sacrificial anode method. Furthermore, environmental contamination may cause a severely corrosive environment, which, in turn, causes the accelerated corrosion of steel structures. Subsequently, coated steel structures could deteriorate more rapidly than the designed lifetime because of the acid rain caused by air pollution, etc. Therefore, a coating of marine paint exposed to seawater, that is, underwater hardening painting, is increasingly required to be fast drying as well as highly corrosion resistant. In this study, five types of underwater hardening paints were prepared with different resin series and additives. Their corrosion and water resistances were investigated using electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements, etc. Even though it is generally accepted that the corrosion resistance of bare steel tends to increase with a shift of the corrosion potential in the noble direction, the corrosion resistance of a sample with a coating exhibited a relatively better tendency when it had a lower corrosion potential in this study. The corrosion current density was also decreased with a decrease in the diffusion limiting current density, which may mean that there is some relationship between corrosion and water resistance. The S sample of the ceramic resin series showed the relatively best corrosion and water resistance among those of samples, while the worst corrosion and water resistance were observed for the R sample of the epoxy resin series. The corrosion and water resistance of those samples tended to deteriorate with an increase in the immersion days, and their corrosion and water resistances were considered to be apparently improved by the types of resin and additives.

에어 버블링을 이용한 침강속도 제어기법 적용 습식워터젯용 연마제 개발 (Development of the Abrasives for Water-jet by Using an Air Bubbling Sedimentation Rate Control Technique)

  • 이대형;김영배;모세웅;김민호;이종무
    • 한국세라믹학회지
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    • 제47권3호
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    • pp.232-236
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    • 2010
  • In recent years abrasive water jet (AWJ) has received significant attention as a technology used in the manufacturing industry for cutting materials. In this paper we report the development of a new preparation method of abrasives for water jet by using an air bubbling sedimentation rate control technique. The SiC abrasives prepared by an air bubbling sedimentation rate control technique using latex resin are found to be superior to the conventional abrasives not only in surface roughness uniformity but also in lifetime. The AWJ test results also show that the former has also better impact-resistance and wear-resistance than the latter.

문화재 복원용 속(速)경화형 Epoxy계 수지의 가속열화시험 및 고장분석 연구 (Accelerated Degradation Test and Failure Analysis of Rapid Curing Epoxy Resin for Restoration of Cultural Heritage)

  • 남병직;장성윤
    • 보존과학회지
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    • 제33권6호
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    • pp.467-483
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    • 2017
  • 본 연구에서는 문화재 복원용 속(速)경화형 Epoxy계 수지인 $Araldite^{(R)}$ rapid의 온도 스트레스에 의한 열화 특성을 분석하였다. 인장강도 및 접착강도는 $40{\sim}60^{\circ}C$에서 12,624시간까지 감소하여 내구성 및 접착특성의 미약한 열화가 발생하였다. 외부 응력 및 온도에 대한 안정성은 속(速)경화형에 비해 일반 경화형 Epoxy계 수지가 우수하여, 복원부의 강도 특성 및 응력 상태를 고려한 복원재료의 적절한 선택과 적용이 요구된다. $40{\sim}60^{\circ}C$에서 12,624시간까지 색차의 증가와 광택도의 감소 등 색상 및 광택 안정성은 취약하여, 향후 광학특성의 개선을 위한 안정성 향상 연구가 필요하다. 특히 접착제의 열적 특성(중량감소량, 열분해온도, 유리전이온도)은 기계적 물성 변화에 부분적으로 관여하였고, 피착재의 계면 특성 및 접착제의 기체투과특성(수분투과도)은 접착성능의 중요인자로 작용하였다. 따라서 도자기, 벽돌 및 석재와 같은 다공성 재질의 경우 항온항습에 의한 보존환경 관리가 중요하며, 옥외 전시유물의 경우 노출환경에 의한 물성 변화를 최소화할 수 있는 보존대책의 수립이 절실하다. 향후 이러한 결과는 문화재에 사용된 Epoxy계 수지의 열화속도 및 수명예측 자료로 활용될 것으로 기대된다.

LED Encapsulation을 위한 스태틱 믹서의 전산 설계 및 유동해석을 이용한 액상 실리콘의 혼합 특성에 대한 연구 (A Study on the Computational Design of Static Mixer and Mixing Characteristics of Liquid Silicon Rubber using Fluidic Analysis for LED Encapsulation)

  • 조용규;하석재;호소;조명우;최종명;홍승민
    • Design & Manufacturing
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    • 제7권1호
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    • pp.55-59
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    • 2013
  • A Light Emitting Diode(LED) is a semiconductor device which converts electricity into light. LEDs are widely used in a field of illumination, LCD(Liquid Crystal Display) backlight, mobile signals because they have several merits, such as low power consumption, long lifetime, high brightness, fast response, environment friendly. In general, LEDs production does die bonding and wire bonding on board, and do silicon and phosphor dispensing to protect LED chip and improve brightness. Then lens molding process is performed using mixed liquid silicon rubber(LSR) by resin and hardener. A mixture of resin and hardener affect the optical characteristics of the LED lens. In this paper, computational design of static mixer was performed for mixing of liquid silicon. To evaluate characteristic of mixing efficiency, finite element model of static mixer was generated, and fluidic analysis was performed according to length of mixing element. Finally, optimal condition of length of mixing element was applied to static mixer from result of fluidic analysis.

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Investigation of Degradative Signals on Outdoor Solid Insulators Using Continuous Wavelet Transform

  • Uzunoglu, Cengiz Polat
    • Journal of Electrical Engineering and Technology
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    • 제11권3호
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    • pp.683-689
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    • 2016
  • Most outdoor solid insulators may suffer from surface degradations due to non-stationary currents that flow on the insulator surface. These currents may be classified as leakage, discharge and tracking currents due to their disturbing potencies respectively. The magnitude of these currents depends on the degree of the contamination of surface. The leakage signals are followed by discharge signals and tracking signals which are capable of forming carbonized tracking paths on the surface between high voltage and earth contacts (surface tracking). Surface tracking is one of the most breakdown mechanisms observed on the solid insulators, especially polymers which may cause severely reduced lifetime. In this study the degradations observed on polyester resin based insulators are investigated according to the IEC 587 Inclined Plane Test Standard. The signals are monitored and recorded during tests until surface tracking initiated. In order to prevent total breakdown of an insulator, early detection of tracking signals is vital. Continuous Wavelet Transform (CWT) is proposed for classification of signals and their energy levels observed on the surface. The application of CWT for processing and classification of the surface signals which are prone to display high frequency oscillations can facilitate real time monitoring of the system for diagnosis.

The development of a portable MO4- (M = 188Re or 99mTc) concentration device for extending the lifetime of RI generators

  • Choi, Kang-Hyuk;Park, Ul Jae;Kim, Jong Bum;Jang, Beom-Su
    • 대한방사성의약품학회지
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    • 제5권1호
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    • pp.3-10
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    • 2019
  • The activities per volume of $^{188}Re$ and $^{99m}Tc$ from their generators are dependent on the specific activity of their mother nuclides $^{188}W$ and $^{99}Mo$ respectively. After a particular lapse of time, the eluted RI activity is exponentially reduced and thus cannot satisfy the needs of clinical application. The purpose of this study is to develop a $^{188}Re$ and $^{99m}Tc$ concentration device with a compact size that can extend the period of use as well as conveniently concentrate the RI. We designed the concentration module by including two-different check valves that do not required any manual on-off operations. In these concentration process, cation exchange resin embedded with Ag and anion exchange resins were used. After completing the concentrating step, the recovering yield was identified to be more than 93% for $^{188}Re$ generators and 88% for $^{99m}Tc$ generators. Moreover, all these procedures were done within 5 min.

TGA를 이용한 Chlorinated Poly Vinyl Chloride(CPVC)의 활성화 에너지 평가 (Evaluation of the Activation Energy of Chlorinated Poly Vinyl Chloride (CPVC) Using Thermogravimetric Analysis)

  • 박형주
    • 한국화재소방학회논문지
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    • 제33권1호
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    • pp.1-6
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    • 2019
  • 열중량 분석법(TGA)을 이용하여 소방용 합성수지 배관으로 사용되는 CPVC의 활성화 에너지를 측정하였다. 열중량 분석법을 이용한 활성화 에너지는 Kissinger method와 Flynn-Wall-Ozawa method를 이용하여 계산하였다. 활성화 에너지를 계산한 결과 Kissinger method에 의해 128.07 kJ/mol, Flynn-Wall-Ozawa method에 의해 145.60 kJ/mol로 나타났다. Kissinger method와 Flynn-Wall-Ozawa method에 의해 계산된 활성화 에너지의 차이는 해석 방법이 다르다는 점을 감안했을 때 큰 차이가 없다고 판단된다. 향후 가속열화을 이용한 열적 열화평가 및 공기오븐노화시험을 통한 CPVC의 연소특성을 시험하고, 수명을 예측하고자 한다.

자연 노화에 따른 카본 에폭시 압력용기의 섬유 인장 강도 변화 (Natural Aging Effect on the Fiber Tensile Strength of Carbon Epoxy Pressure Vessel)

  • 황태경;박재범;김형근;도영대
    • Composites Research
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    • 제20권2호
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    • pp.1-9
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    • 2007
  • 카본 에폭시로 제작된 복합재 압력용기의 노화 특성과 구조 사용 수명 평가를 위해 실내와 실외에서 10년과 15년간 자연노화 시켰다. 노화 특성의 통계적 분포를 구하기 위해 노화된 압력용기로부터 링 시편을 채취하여 수압 파괴 시험을 실시하였다. 그리고 섬유와 수지 계면의 노화 특성 확인을 위해 시험 파편 계면을 SEM을 이용하여 관찰하였다. 섬유 인장 파손 변형률의 와이블 파라미터 값 기준으로 실내에서 10년, 15년 노화되었을 경우 각각 19%와 23% 저하되었으나, 실내와 실외의 노화 특성 차이는 크지 않았다. 그러나 압력용기 외면에 적용한 표면 페인트는 노화 방지에 큰 효과를 나타내었다.