• Title/Summary/Keyword: residual oxygen

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Effect of Debinding and Sintering Conditions on the Tensile Properties of Water-atomized STS 316 L Parts by Powder Injection Molding (수분무 STS 316L 분말사출성형체의 탈지 및 소결공정에 따른 인장 특성)

  • 윤태식;성환진;안상호;이종수
    • Journal of Powder Materials
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    • v.9 no.4
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    • pp.218-226
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    • 2002
  • The purpose of the present study is to investigate the influence of thermal debinding and sintering conditions on the sintering behavior and mechanical properties of PIMed 316L stainless steel. The water atomized powders were mixed with multi-component wax-base binder system, injection molded into flat tensile specimens. Binder was removed by solvent immersion method followed by thermal debinding, which was carried out in air and hydrogen atmospheres. Sintering was done in hydrogen for 1 hour at temperatures ranging from 1000℃ to 1350℃ The weight loss, residual carbon and oxygen contents were monitored at each stage of debinding and sintering processes. Tensile properties of the sintered specimen varied depending on the densification and the characteristics of the grain boundaries, which includes the pore morphology and residual oxides at the boundaries. The sinter density, tensile strength (UTS), and elongation to fracture of the optimized specimen were 95%, 540 MPa, and 53%, respectively.

Al2O3 Coating on Transparent Polycarbonate Substrates for the Hard-coating Application (투명 폴리카보네이트 보호코팅을 위한 산화알루미늄 박막)

  • Kim, Hun;Nam, Kyoung-Hee;Jang, Dong-Su;Lee, Jung-Joong
    • Journal of the Korean institute of surface engineering
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    • v.40 no.4
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    • pp.159-164
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    • 2007
  • Transparent aluminum oxide films were deposited on polycarbonate (PC) substrates by inductively coupled plasma (ICP) assisted reactive sputtering. the oxygen flow rate was regulated by controlling the target voltage with a proportional integrate derivative controller. The PC substrate was treated with plasma prior to the deposition in order to the enhance the adhesive strength of the $Al_2O_3$ film. The characteristics of hardness, structure, density, transmittance, deposition rate, surface roughness and residual stress were investigated to estimate the possibility for the hard coating.

Role of residual ferrites on crevice SCC of austenitic stainless steels in PWR water with high-dissolved oxygen

  • Sinjlawi, Abdullah;Chen, Junjie;Kim, Ho-Sub;Lee, Hyeon Bae;Jang, Changheui;Lee, Sanghoon
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2552-2564
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    • 2020
  • The crevice stress corrosion cracking (SCC) susceptibility of austenitic stainless steels was evaluated in simulated pressurized water reactor (PWR) environments. To simulate the abnormal condition in temporary clamping devices on leaking small bore pipes, crevice bent beam (CBB) tests were performed in the oxygenated as well as hydrogenated conditions. No SCC cracks were found for SS316 in both conditions. SS304 also showed good resistance in the hydrogenated condition. However, all SS304 specimens showed SCC cracks in the oxygenated condition, indicating poor crevice SCC resistance. It was found that residual ferrites were selectively dissolved because of the galvanic corrosion coupled with the neigh-bouring austenite phase, resulting in SCC initiation in SS304. Crack morphologies were mostly transgranular assisted by the damaged δ-ferrite and deformation-induced slip bands.

A Study on the Automation of the $N_2$ Splash Slag Coating System ($N_2$ Splash Slag Coating 시스템 자동화 연구)

  • Jang, Pill-Jang;Lee, Kee-Seong;Shin, Dong-Cheol;Cho, Hyun-Chul
    • Proceedings of the KIEE Conference
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    • 2002.11c
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    • pp.92-95
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    • 2002
  • A study on the system automation for the nitrogen splash slag coating in Basic Oxygen Blowing Furnace (BOF) is described. The engineers are trying to do their best efforts to increase the life of converter lining by developing improved refractory material and optimal operation techniques in the steel plants, A new slag coating method is needed to reduce the erosion rates of the refractory. In the current slag costing method, the BOF was swung back and forth. The new method uses the oxygen lance to blow the residual slag to the walls and cone of the converter. The nitrogen gas is used for blowing. This method is developed based on the automation process at factory in POSCO dated on the May 1998. The test results of nitrogen splash slag coating system for the BOF at POSCO are show to show the effectiveness of the system.

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Effect of Synthesis Temperature on the Composition of Electrolytic Iron Phosphide

  • Kim, Hokon;Shin, Heon-Cheol
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.78-83
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    • 2018
  • In this study, we investigated the composition of an electrolytic Fe phosphide at different synthesis temperatures. We found that the ratio of Fe in the electrodeposit increases with synthesis temperature, whereas the oxygen content introduced into the electrodeposit by the atmospheric oxidation of Fe decreases. The aim of this study was to identify the reason for this effect. For this purpose, the ratio of Fe and P in the electrodeposits prepared at different temperatures was analyzed in depth. In addition, the types and ratios of Fe phosphide phases were considered. It was proved that with increase in temperature, a significant amount of Fe reacted with P to form Fe phosphide phases, and consequently, the amount of residual pure Fe that would react directly with oxygen decreased.

Effect of residual oxygen in a vacuum chamber on the deposition of cubic boron nitride thin film

  • Oh, Seung-Keun;Kang, Sang Do;Kim, Youngman;Park, Soon Sub
    • Journal of Ceramic Processing Research
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    • v.17 no.7
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    • pp.763-767
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    • 2016
  • The structural characterization of cubic boron nitride (c-BN) thin films was performed using a B4C target in a radio-frequency magnetron sputtering system. The deposition processing conditions, including the substrate bias voltage, substrate temperature, and base pressure were varied. Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to analyze the crystal structures and chemical binding energy of the films. For the BN film deposited at room temperature, c-BN was formed in the substrate bias voltage range of -400 V to -600 V. Less c-BN fraction was observed as the deposition temperature increased, and more c-BN fraction was observed as the base pressure increased.

Management of Skull Base Osteoradionecrosis with Hyperbaric Oxygen Therapy (고압산소요법으로 치료한 뇌기저부 방사선골괴사 1예)

  • Hwang, Eun;Lee, Jong-Joo;Shin, Yoo-Seob;Kim, Chul-Ho
    • Korean Journal of Head & Neck Oncology
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    • v.27 no.1
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    • pp.66-69
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    • 2011
  • Skull base osteoradionecrosis(ORN)is a rare complication of radiotherapy for nasopharyngeal carcinoma, but is one of the most severe and possibly fatal condition followed by radiotherapy. However, the treatment of skull base ORN has seldom been thoroughly described yet. Here we report a case of skull base ORN that was successfully treated with hyperbaric oxygen therapy(HBO). A 52-year-old man visited our department complaining of trismus and foul odor. He was diagnosed with nasopharyngeal cancer with multiple lymph node metastasis one year ago and underwent concurrent chemoradiotherapy. On the physical examination, mucopus and crusts with exposed necrotic bone was seen in the right nasopharynx. On the paranasal sinus magnetic resonance imaging, osteoradionecrosis which was extending from the right nasopharynx to the clivus, petrous apex, and cavernous sinus was noted. Nasopharynx biopsy resulted of ulcer with no malignant cells. HBO therapy was performed with debridement of nasopharynx for 3 months. There was no sign of recurrence or residual ORN 18 months after HBO therapy.

Effect of bleaching on human teeth and reduced treatment on negative influence -Review (치아 미백제가 치아에 미치는 영향과 부작용 최소화를 위한 처치에 관한 고찰)

  • Choi, Jae-Yoon;Shim, Youn-Soo
    • Journal of Korean society of Dental Hygiene
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    • v.6 no.4
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    • pp.481-493
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    • 2006
  • The purpose of the review article was to summarize and discuss the available information concerning the effect of bleaching on human teeth and reduced treatment on negative influence. Tooth bleaching effect was differ from extent of concentration and application period of a tooth bleaching agent, certainly full knowledge prior treatment about adverse effect possible appearance and follow clinical treatment for the least reduce. It remains unclear in how far those observation may result in significant adverse effect under clinical conditions. Nevertheless, further investigation are necessary to elucidate these aspect more precisely. The findings of the study were as follows : 1. It is recommended to delay placement of restorations after termination of bleaching therapy for at least 1-3 weeks. 2. Reduced negative influence that is clinical feasibility of catalase in protecting bleached surface against Oxygen radical. 3. The residual peroxide in tooth after bleaching seems to be removed by gradual diffusion and it may be possible to eliminate the adverse effect on tooth by using water displacement solution, ethylalcohol and aceton including it for effective removal of free radical oxygen.

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Acute Toxicity of Ozone on Survival and Physiological Conditions of Olive Flounder, Paralichthys Olivaceus (넙치(Paralichthys olivaceus)의 생존과 생리상태에 미치는 오존의 급성 독성)

  • Kim, Heung-Yun;Oh, Myung-Joo;Jung, Sung-Ju
    • Journal of fish pathology
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    • v.12 no.1
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    • pp.32-41
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    • 1999
  • Ozonization for rearing seawater in land-based culture system has recently been utilized for disinfection of pathogenic microorganisms and improvement of water quality. This study was conducted to examine the effects of total residual oxidants (TRO) in ozone-treated seawater on survival, blood parameters, osmolality and oxygen consumption, and gill tissue of the flounder. Paralichthys olivaceus. Experiments were carried out with the starved flounder of 12~19 cm in total length at $20^{\circ}C$. The 48-hr and 96-hr $LC_{50}$ for the flounder amounts to 26.4 ppb and 22.3 ppb, respectively. With increase of TRO concentration from 24 to 39 ppb, the values of hematocrit, hemoglobin concentration, red blood cell count and osmolality of the flounder with respect to exposure time were significantly elevated, however, the oxygen consumption rates decreased. In the case of the fish exposed to 13 ppb for 96 hrs, blood glucose increased with an elapse of exposure time, while survival rate was 100%. Death apparently resulted by massive destruction of gill lamellar epithelium, severe osmotic imbalance and the lack of oxygen uptake. The results of this experiment indicated that to protect aquaculture organisms, the ozone-treated seawater should not contain any residual oxidants, and that relatively long-term exposure to TRO of low concentration can impact on survival and physiological conditions of the flounder.

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The Power Loss Characteristics of Mn-Zn Ferrites at MHz Region with Sintering Condition (소성조건에 따른 MHz 대역의 Mn-Zn ferrite 전력손실 특성)

  • Suh J.J.;Song B.M
    • Resources Recycling
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    • v.12 no.6
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    • pp.26-31
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    • 2003
  • The power loss characteristics of Mn-Zn ferrite were observed with the sintering temperature. In case of $1150 ^{\circ}C$ sintering, the core loss increased with measuring temperature, and does not have minimum value at the point where the magnetocrystalline anisotropy be 'zero'. This reason mainly due to the change of core loss mechanism with grain size which affects residual loss. The grain size and sintered density slightly increased with equilibrium oxygen partial pressure at$ 1150 ^{\circ}C$ sintering. The resistivity and initial permeability showed no significance with atmosphere, these results due to complex effect of $Fe^{2+}$ concentration and microstructure change. The core loss at $100^{\circ}C$ decreased as the equilibrium oxygen partial pressure increased.e increased.