• Title/Summary/Keyword: residual condition

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Removal of Phenol Loaded with Activated Carbon by Potentiostatic Method (정전위전해에 의한 활성탄에 함유된 페놀 제거)

  • 김성우;박승조
    • Resources Recycling
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    • v.10 no.4
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    • pp.18-23
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    • 2001
  • Air pollutants, phenol was generated in case of thermal regeneration of used activated carbon loaded with phenol and because of this problem, removal process of phenol were studied. Electrolytic oxidation of samples, used S.company granular activated carbon (WS-GAC), used C.company granular activated carbon (WC-GAC) and used L.company granular activated carbon (WL-GAC) loaded with phenol carried out by potentiostatic method in this study. In case of experiment was to come into operation in condition of samples containing 100 mg/g phenol, supporting electrolyte was 1.0% sodium chloride solution, Ti-Ir (10$\times$10$\textrm{cm}^2$) electrode and electrode distance was 2 cm, current density was $1.25 A/dm^2$, Obtained from the results of electrolytic oxidation experiments were not detected residual phenol. And then we knew about reaction time of electrolytic oxidation, current density, concentration of supporting electrolyte and electrode and electrode distance were 60 minutes, 1.25 A/dm$^2$, 1.0%, 2 cm.

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CONCEPTUAL DESIGN OF THE SODIUM-COOLED FAST REACTOR KALIMER-600

  • Hahn, Do-Hee;Kim, Yeong-Il;Lee, Chan-Bock;Kim, Seong-O;Lee, Jae-Han;Lee, Yong-Bum;Kim, Byung-Ho;Jeong, Hae-Yong
    • Nuclear Engineering and Technology
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    • v.39 no.3
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    • pp.193-206
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    • 2007
  • The Korea Atomic Energy Research Institute has developed an advanced fast reactor concept, KALIMER-600, which satisfies the Generation IV reactor design goals of sustainability, economics, safety, and proliferation resistance. The concept enables an efficient utilization of uranium resources and a reduction of the radioactive waste. The core design has been developed with a strong emphasis on proliferation resistance by adopting a single enrichment fuel without blanket assemblies. In addition, a passive residual heat removal system, shortened intermediate heat-transport system piping and seismic isolation have been realized in the reactor system design as enhancements to its safety and economics. The inherent safety characteristics of the KALIMER-600 design have been confirmed by a safety analysis of its bounding events. Research on important thermal-hydraulic phenomena and sensing technologies were performed to support the design study. The integrity of the reactor head against creep fatigue was confirmed using a CFD method, and a model for density-wave instability in a helical-coiled steam generator was developed. Gas entrainment on an agitating pool surface was investigated and an experimental correlation on a critical entrainment condition was obtained. An experimental study on sodium-water reactions was also performed to validate the developed SELPSTA code, which predicts the data accurately. An acoustic leak detection method utilizing a neural network and signal processing units were developed and applied successfully for the detection of a signal up to a noise level of -20 dB. Waveguide sensor visualization technology is being developed to inspect the reactor internals and fuel subassemblies. These research and developmental efforts contribute significantly to enhance the safety, economics, and efficiency of the KALIMER-600 design concept.

Fabrication and Characterization of InGaN/GaN LED structures grown on selectively wet-etched porous GaN template layer

  • Beck, Seol;Cho, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.124-124
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    • 2010
  • Much interest has been focused on InGaN-based materials and their quantum structures due to their optoelectronics applications such as light emitting diode (LED) and photovoltaic devices, because of its high thermal conductivity, high optical efficiency, and direct wide band gap, in spite of their high density of threading dislocations. Build-in internal field-induced quantum-confined Stark effect in InGaN/GaN quantum well LED structures results in a spatial separation of electrons and holes, which leads to a reduction of radiative recombination rate. Therefore, many growth techniques have been developed by utilizing lateral over-growth mode or by inserting additional layers such as patterned layer and superlattices for reducing threading dislocations and internal fields. In this work, we investigated various characteristics of InGaN multiple quantum wells (MQWs) LED structures grown on selectively wet-etched porous (SWEP) GaN template layer and compared with those grown on non-porous GaN template layer over c-plane sapphire substrates. From the surface morphology measured by atomic force microscope, high resolution X-ray diffraction analysis, low temperature photoluminescence (PL) and PL excitation measurements, good structural and optical properties were observed on both LED structures. However, InGaN MQWs LED structures grown on SWEP GaN template layer show relatively low In composition, thin well width, and blue shift of PL spectra on MQW emission. These results were explained by rough surface of template layer, reduction of residual compressive stress, and less piezoelectric field on MQWs by utilizing SWEP GaN template layer. Better electrical properties were also observed for InGaN MQWs on SWEP GaN template layer, specially at reverse operating condition for I-V measurements.

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A Study on the Separation of Cadmium from Waste Ni-Cd Secondary Batteries by Ion Substitution Reaction (이온치환 반응을 이용한 니켈-카드뮴 폐이차전지에서 카드뮴의 분리에 대한 연구)

  • Kim, Dae-Weon;Park, Il-Jeong;Ahn, Nak-Kyoon;Jeong, Hang-Chul;Jung, Soo-Hoon;Choi, Joong-Yup;Yang, Dae-Hoon
    • Resources Recycling
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    • v.27 no.4
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    • pp.36-43
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    • 2018
  • In order to recycle waste nickel-cadmium batteries, cadmium was selectively removed by ion substitution reaction so that cadmium and nickel could be separated efficiently. The electrode powder obtained by crushing the electrode in the waste nickelcadmium battery was leached with sulfuric acid. The cadmium in the nickel-cadmium solution was precipitated with cadmium sulfide by the addition of sodium sulfide. Ion substitution experiments were carried out under various conditions. At the optimum condition with pH = -0.1 and $Na_2S/Cd=2.3$ at room temperature, the residual Cd in the solution was about 100 ppm, and most of it was precipitated with CdS.

Effects of annealing temperature on structural and optical properties of CdS Films prepared by RF magnetron sputtering

  • Hwang, Dong-Hyeon;An, Jeong-Hun;Son, Yeong-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.233-233
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    • 2010
  • CdS thin films were deposited on glass substrates by R.F. magnetron sputtering method and some of the samples were treated by rapid thermal annealing (RTA) process. Effects of thermal annealing on structural and optical properties were investigated at different temperatures ranging from 100 to $600^{\circ}C$. The crystallographic structure of the films and the size of the crystallites in the films were studied by X-ray diffraction. The crystallite sizes were found to increase, and the X-ray diffraction patterns were seen to sharpen by annealing. Optical properties of the films were calculated using the envelope method and the photoluminescence measurements. The optical properties of the films were seen to be dependent on the film thicknesses. The energy gap of the films was found to decrease by annealing. The band edge sharpness of the optical absorption was seen to oscillate by thermal annealing. Annealing over $400^{\circ}C$ was seen to degrade the optical properties of the film. The best annealing temperature for the films was found to be $400^{\circ}C$ from the optical properties. It is observed that the CdS film annealed at $400^{\circ}C$ reveals the strongest UV emission intensity and narrowest full width at half maximum among the temperature ranges studied. The enhanced UV emission from the film annealed at $400^{\circ}C$ is attributed to the improved crystalline quality of CdS thin film due to the effective relaxation of residual compressive stress and achieving maximum grain size. The results show that heat treatments under optimal annealing condition can provide significant improvements in the properties of CdS thin films.

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A Study of Thermo-rheological Behaviour from Long Term Responses of Solid Composite Propellant (고체 추진제 장시간 물성거동 반응 연구)

  • Ryu, Taeha;Kim, Nakhyun;Khil, Taeock;Choi, Yongkyu
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.1
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    • pp.8-16
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    • 2017
  • Structural integrity of solid rocket depends on the residual reactions between constituents of its composition(post cure, migration etc.), the oxygen(or anti-oxydent) in the free volume and humidity (desiccant) under the perfect sealed condition. Mechanical Properties of composite solid propellant arising from those factors are very complex. Moreover the propulsion are faced with thermal loads from diurnal & seasonal cycle till firing. In this study, the fast evaluation method of long term mechanical properties is suggested based on Thermo-Rheological Simplicity from curing oven to cool-down stage in view point of thermal stabilization. For this subject, endurance tester having temperature control capability are devised. From the results from incremental load and strain, non-linear characteristics are discussed.

Applicability of Soil Washing with Neutral Phosphate for Remediation of Arsenic-contaminated Soil at the Former Janghang Smelter Site ((구)장항제련소 주변 부지 매입구역 비소 오염토양에 대한 중성 인산염 토양세척법의 적용가능성 평가)

  • Im, Jinwoo;Kim, Young-Jin;Yang, Kyung;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.19 no.4
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    • pp.45-51
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    • 2014
  • In accordance with the view on remediated soil as a resource, this study assessed the applicability of soil washing with the neutral phosphate for remediation of arsenic (As)-contaminated soil. Three soil samples of different land uses (i.e., rice paddy, upland field and forest land) were collected from the study site, and the aqua regia-extractable As concentrations were 59.2, 30.8 and 53.1 mg/kg, respectively. Among the neutral phosphate reagents, ammonium phosphate showed the highest As washing efficiency. The optimized washing condition was 2-hr washing with 0.5M ammonium phosphate solution (pH 6) and soil to liquid ratio of 1 : 5. The extraction efficiencies of As did not guarantee the residual soil As concentrations to satisfy the Korea soil regulatory level (i.e., Worrisome level) in the three soil samples. To enhance washing efficiency, the As-contaminated soil was submerged in washing solution (1 : 1, w/v) for 24 hr and 1-hr washing with 0.5M ammonium phosphate solution was tested. As extraction efficiencies of 36.1 (rice paddy), 21.4 (upland field) and 26.4% (forest land) were attained, which satisfied the Worrisome level for Region 1 (25 mg/kg of As) in rice paddy, but not in upland field and forest land.

RDF Gasification Using a Pilot-Scale Two-Stage Gasification System (파일럿 규모 2단 가스화 시스템 공정을 이용한 RDF 가스화)

  • Park, In-Hee;Park, Young-Kwon;Lee, Young-Man;Bae, Wookeun;Kwak, Yeon-Ho;Cheon, Kyeong-Ho;Park, Sung Hoon
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.286-290
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    • 2011
  • Syngas was produced out of pellet refuse derived fuel (RDF) produced from an RDF production facility of W city, Korea. A two-stage gasification system was developed to use the RDF char as an auxiliary heat source for gasification reaction. The composition and heating value of syngas as well as the heating value of residual product (char) were measured at a different residence time to investigate the optimal operating condition of the two-stage gasification system for syngas production. The optimal char residence time to minimize the energy cost due to an external heat source supply was also deduced.

Variance component analysis of growth and production traits in Vanaraja male line chickens using animal model

  • Ullengala, Rajkumar;Prince, L. Leslie Leo;Paswan, Chandan;Haunshi, Santosh;Chatterjee, Rudranath
    • Animal Bioscience
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    • v.34 no.4
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    • pp.471-481
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    • 2021
  • Objective: A comprehensive study was conducted to study the effects of partition of variance on accuracy of genetic parameters and genetic trends of economic traits in Vanaraja male line/project directorate-1 (PD-1) chicken. Methods: Variance component analysis utilizing restricted maximum likelihood animal model was carried out with five generations data to delineate the population status, direct additive, maternal genetic, permanent environmental effects, besides genetic trends and performance of economic traits in PD-1 chickens. Genetic trend was estimated by regression of the estimated average breeding values (BV) on generations. Results: The body weight (BW) and shank length (SL) varied significantly (p≤0.01) among the generations, hatches and sexes. The least squares mean of SL at six weeks, the primary trait was 77.44±0.05 mm. All the production traits, viz., BWs, age at sexual maturity, egg production (EP) and egg weight were significantly influenced by generation. Model four with additive, maternal permanent environmental and residual effects was the best model for juvenile growth traits, except for zero-day BW. The heritability estimates for BW and SL at six weeks (SL6) were 0.20±0.03 and 0.17±0.03, respectively. The BV of SL6 in the population increased linearly from 0.03 to 3.62 mm due to selection. Genetic trend was significant (p≤0.05) for SL6, BW6, and production traits. The average genetic gain of EP40 for each generation was significant (p≤0.05) with an average increase of 0.38 eggs per generation. The average inbreeding coefficient was 0.02 in PD-1 line. Conclusion: The population was in ideal condition with negligible inbreeding and the selection was quite effective with significant genetic gains in each generation for primary trait of selection. The animal model minimized the over-estimation of genetic parameters and improved the accuracy of the BV, thus enabling the breeder to select the suitable breeding strategy for genetic improvement.

Dynamic vulnerability assessment and damage prediction of RC columns subjected to severe impulsive loading

  • Abedini, Masoud;Zhang, Chunwei
    • Structural Engineering and Mechanics
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    • v.77 no.4
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    • pp.441-461
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    • 2021
  • Reinforced concrete (RC) columns are crucial in building structures and they are of higher vulnerability to terrorist threat than any other structural elements. Thus it is of great interest and necessity to achieve a comprehensive understanding of the possible responses of RC columns when exposed to high intensive blast loads. The primary objective of this study is to derive analytical formulas to assess vulnerability of RC columns using an advanced numerical modelling approach. This investigation is necessary as the effect of blast loads would be minimal to the RC structure if the explosive charge is located at the safe standoff distance from the main columns in the building and therefore minimizes the chance of disastrous collapse of the RC columns. In the current research, finite element model is developed for RC columns using LS-DYNA program that includes a comprehensive discussion of the material models, element formulation, boundary condition and loading methods. Numerical model is validated to aid in the study of RC column testing against the explosion field test results. Residual capacity of RC column is selected as damage criteria. Intensive investigations using Arbitrary Lagrangian Eulerian (ALE) methodology are then implemented to evaluate the influence of scaled distance, column dimension, concrete and steel reinforcement properties and axial load index on the vulnerability of RC columns. The generated empirical formulae can be used by the designers to predict a damage degree of new column design when consider explosive loads. With an extensive knowledge on the vulnerability assessment of RC structures under blast explosion, advancement to the convention design of structural elements can be achieved to improve the column survivability, while reducing the lethality of explosive attack and in turn providing a safer environment for the public.