• 한국지하수토양환경학회지:지하수토양환경
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• 제19권3호
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• pp.25-32
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• 2014

The amount of TPH contaminated soil treated at off-site remediation facilities is ever increasing. For the recycle of the treated-soil on farmlands, it is necessary to restore biological and physico-chemical soil characteristics and to remove residual TPH in the soil by an economic polishing treatment method such as phytoremediation. In this study, a series of experiments was performed to select suitable plant species and to devise a proper planting method for the phyto-restoration of TPH-treated soil. Rye (Secale cereale) was selected as test species through a germination test, among 5 other plants. Five 7-day-old rye seedlings were planted in a plastic pot, 20 cm in height and 15 cm in diameter. The pot was filled with TPH-treated soil (residual TPH of 1,118 mg/kg) up to 15 cm, and upper 5 cm was filled with horticulture soil to prevent TPH toxic effects and to act as root growth zone. The planted pot was cultivated in a greenhouse for 38 days along with the control that rye planted in a normal soil and the blank with no plants. After 38 days, the above-ground biomass of rye in the TPH-treated soil was 30.6% less than that in the control, however, the photosynthetic activity of the leaf remained equal on both treatments. Soil DHA (dehydrogenase activity) increased 186 times in the rye treatment compared to 10.8 times in the blank. The gross TPH removal (%) in the planted soil and the blank soil was 34.5% and 18.4%, respectively, resulting in 16.1% increase of net TPH removal. Promotion of microbial activity by root exudate, increase in soil permeability and air ventilation as well as direct uptake and degradation by planted rye may have contributed to the higher TPH removal rate. Therefore, planting rye on the TPH-treated soil with the root growth zone method showed both the potential of restoring biological soil properties and the possibility of residual TPH removal that may allow the recycle of the treated soil to farmlands.

• 한국산림과학회지
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• 제102권4호
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• pp.484-490
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• 2013

본 연구는 낙엽송 개체목의 가공처리 과정에서 생산되는 제재목 및 제재 부산물의 양을 분석하기 위한 시뮬레이션 모델을 개발하고자 수행되었다. 이 모델에서는 수간곡선 추정식을 이용하여 개체목의 전간재적을 산출하고 절동된 원목에 대한 목재 가공 시뮬레이션을 통해 판재 및 각재, 원주목의 규격에 따른 최대 생산가능량을 예측하였다. 또한 제재목 가공처리 과정에서 생산되는 톱밥 및 죽데기의 잔존재적에 대한 분석을 수행하였다. 그 결과 흉고직경 12 cm 이상부터 제재목의 생산이 가능한 것으로 나타났고, 제재목의 생산이 가능한 경우에는 보다 큰 규격의 판재와 각재를 생산하는 것이 상대적으로 작은 규격의 판재와 각재 혹은 원주목을 생산하는 것에 비해 더 많은 생산량을 얻을 수 있었다. 향후 이 모델은 낙엽송의 이용재적 산출을 통한 산림의 경제적 가치평가는 물론, 최근 목질계 바이오에너지 자원으로서 그 중요성이 점차 높아지고 있는 톱밥과 같은 제재 부산물의 양을 예측하는 데에도 활용될 수 있을 것이다.

• 펄프종이기술
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• 제48권1호
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• pp.119-126
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• 2016

In this study, we separated the lignin from the wood by using the high boiling point solvent for developing more environmental friendly pulping method. High boiling point solvents as Ethers, glycols and ketones were used to remove the lignin in the pine wood meals. The Yield and lignin content of residual wood meals was reduced according to the input of the catalyst. Me-C, E-Ca, TEG and MIBK had the best delignification rate of 9 kinds of high-boiling point solvents. At the hydrolysis ratio of the selected solvents, The TEG was highest remain ratio of carbohydrates and the E-Ca was lowest remain ratio of lignin. And the Me-C was most excellent lignin hydrolysis ratio at the low catalyst. The selectivity of delignification of Me-C, E-Ca, TEG and MIBK solvents were 49.6, 49.9, 53.8 and 53.1%, respectively, and its values were similar to those of the commercial Kraft Pulp.

• Asian-Australasian Journal of Animal Sciences
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• 제14권10호
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• pp.1383-1388
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• 2001

To explore the factors restricting animal performance in relation to sward structure under a strip-grazing system, measurements of sward factors, herbage intake and milk production at 3 levels of herbage allowance were made on perennial ryegrass (Latium perenne L.) sward for 3 experimental periods. About 29%, 36% and 52% of the biomass offered was removed by grazing in high $(42kg\;OM{\cdot}day^{-1}{\cdot}head^{-1})$, medium $(30kg\;OM{\cdot}day^{-1}{\cdot}head^{-1})$ and low $(18kg\;OM{\cdot}day^{-1}{\cdot}head^{-1})$ herbage allowance plots. Live leaf material was much more affected by grazing under different herbage allowance levels than dead material or leaf sheath. Grazing with a low herbage allowance decreased the proportion of live lamina by 93% and live lamina density by 96% before grazing. The density of dead material plus sheath was decreased by 17% after grazing at a low allowance, while it slightly increased or remained constant in the plots applied with high and medium allowances, respectively. The highly significant (p<0.01) correlations between herbage allowance and proportion (r=0.94) and density (r=0.91) of live lamina in residual sward after grazing were observed. Daily herbage intakes in the plots with high and medium levels of herbage allowance were not significantly different at $15.3kg\;OM{\cdot}head^{-1}$ in average, whereas with low level it decreased to $13.9kg\;OM{\cdot}head^{-1}$. Daily milk production was significantly (p<0.05) declined from $22.3kg{\cdot}head^{-1}$ (at high herbage allowance) to $19.7kg{\cdot}head^{-1}$ (at low herbage allowance). The data obtained clearly indicated that herbage intake and milk production were highly affected by the characteristics of residual sward, which were closely related to the level of herbage allowance.

• 한국대기환경학회지
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• 제27권6호
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• pp.650-662
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• 2011

The statistical tools such as empirical orthogonal function (EOF), and singular value decomposition (SVD) have been applied to analyze the characteristic of air pollutant over southeast Asia as well as to evaluate Zimeke's tropospheric column ozone (ZTO) determined by tropospheric residual method. In this study, we found that the EOF and SVD analyses are useful methods to extract the most significant temporal and spatial pattern from enormous amounts of satellite data. The EOF analyses with OMI $NO_2$ and OMI HCHO over southeast Asia revealed that the spatial pattern showed high correlation with fire count (r=0.8) and the EOF analysis of CO (r=0.7). This suggests that biomass burning influences a major seasonal variability on $NO_2$ and HCHO over this region. The EOF analysis of ZTO has indicated that the location of maximum ZTO was considerably shifted westward from the location of maximum of fire count and maximum month of ZTO occurred a month later than maximum month (March) of $NO_2$, HCHO and CO. For further analyses, we have performed the SVD analyses between ZTO and ozone precursor to examine their correlation and to check temporal and spatial consistency between two variables. The spatial pattern of ZTO showed latitudinal gradient that could result from latitudinal gradient of stratospheric ozone and temporal maximum of ZTO in March appears to be associated with stratospheric ozone variability that shows maximum in March. These results suggest that there are some sources of error in the tropospheric residual method associated with cloud height error, low efficiency of tropospheric ozone, and low accuracy in lower stratospheric ozone.

• Korean Chemical Engineering Research
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• 제48권6호
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• pp.704-711
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• 2010

당질계 및 전분질계 바이오 매스(1세대 바이오 매스)의 단점은 식량고갈의 문제로 인한 원료수급이 불안정하여 원료비 상승과 함께 원료 확보라는 문제에 당면해 있다. 이를 해결하기 위한 다양한 대책이 모색되었고 그 대책으로 목질계 바이오 매스(2세대 바이오 매스)에 대한 연구가 이루어져 왔다. 그러나 목질계 바이오 매스는 매우 복잡하고 어려운 Lignin 제거 문제에 직면하게 되었다. 그리하여 현재는 기존의 바이오 매스의 단점을 극복할 새로운 바이오 매스인 비 식용작물의 관심이 증가하고 있다. 비 식용작물 바이오 매스는 당질계 및 전분질계 바이오 매스와 달리 식량문제로 인한 원료비의 상승이나 원료 확보 면에서 안전하며 또한 기존 목질계 바이오 매스에 비해 보다 쉽게 Lignin을 제거할 수 있는 장점이 있다. 본 논문에서는 이러한 비 식용작물 중 Cellulose 함량이 높고 Lignin 함량이 상대적으로 낮은 억새를 이용하여 암모니아 공정 전처리의 최적화 조건을 연구하였다. 공정변수로는 암모니아 농도, 반응시간, 반응온도를 선정하였으며 전처리 후 각 반응물의 Cellulose 함유율, Lignin 함유율, 잔류 고체량 및 가수분해도를 반응표면 분석법을 이용하여 최적 전처리 조건을 확립하였다. 최적조건 탐색 결과는 암모니아 반응농도; 11.27%, 반응온도; $157.75^{\circ}C$, 반응시간; 10.01 min으로 최적 반응조건을 결정할 수 있었으며 최적조건으로 전처리 후 억새의 상대적인 Cellulose 함유율; 39.98%, Lignin 함유율; 8.01%, 가수분해도; 85.89%의 결과를 얻어, 억새가 기존 목질계 바이오 매스들보다 전처리 및 당화 발효에 있어 유리한 기질이라고 결론지을 수 있다.

• 대한환경공학회지
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• 제28권3호
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• pp.292-299
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• 2006

전자공여체로 벤조산염을 이용한 perchloroethene(PCE)의 환원성 탈염소화 과정에서 전자공여체의 첨가량 및 초기 미생물 식종량이 탈염소화에 미치는 영향을 평가하기 위하여 회분식 실험을 수행하였다. 벤조산염이 탈염소화를 위한 양론비 이하(전자공여체/수용체 비=0.5와 1)로 첨가된 경우 탈염소화 효율은 벤조산염 첨가량이 증가함에 따라 71%에서 94.3%로 증가하였으나, 탈염소화에 이용된 전자공여체의 분율은 92.7%에서 79.6%로 감소하였다. 메탄생성은 PCE와 trichloroethene(TCE)가 모두 cis-1,2-dichloroethene(cDCE)으로 전환된 후 문턱농도(threshold value, 10 nM) 이상으로 수소농도가 유지되는 동안 진행되었다. 벤조산염이 양론비 이상으로 첨가된 경우 탈염소화 완료 후 잔존하는 수소는 메탄생성량을 증가시켰다. 식종 미생물량의 증가는 지체기를 감소시켰지만 최대 탈염소화 속도는 벤조산염 분해 속도에 의해 결정되어 식종 미생물량에 큰 영향을 받지 않았다. 식종 미생물 농도가 높은 경우 초기 활발한 탈염소화로 인하여 메탄생성량은 감소하고, 탈염소화 효율은 증가하였다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 춘계학술발표논문집
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• pp.167-173
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• 2006

Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently - often much more efficiently. We propose the blended deinking agent with cellulolutic enzymes and synthetic collector in deinking pulp of conventional alkaline method. The deinking efficiency of old news print in alkaline pH was enhanced with enzyme treatments. The brightness of deinked pulp was increased with less residual ink particles and yield of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method. Enzymes in biomass were use to Chemical Deinking for reduce environment pollution through surfactant and improve surfactants. examining into compatibility Enzymes and surfactants, these new materials are studied efficiency of deinking efficiency.

• 에너지공학
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• 제13권1호
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• pp.1-11
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• 2004

가스화기술은 전세계적으로 수소에너지 사회로 진입하는 과정에서 필요한 대량수소 공급체계를 구축하는데 중단기적으로 필요한 기술이다. 장기적으로는 풍력이나 태양광과 같은 순수한 재생가능에너지에 기반한 수소공급 체계로 발전될 것이나, 향후 10-20년간 대량수순 제조가 필요하다면 경제성이 있는 기술을 $CO_2$ 발생이 최소화되면서 효율도 높은 기술로 발전시켜 적용하는 방향으로 진행될 것이다. 특히, 국내에서는 천연가스, 석탄, 중질잔사유, 폐기물, 바이오매스 등의 원료로부터 출발한 수소제조가 경제적인 측면에서 유리하므로 최소한 중단기적으로는 활용될 것으로 보인다 수소에너지 이슈가 부각되는 배경중의 하나가 기후변화협약에 대응한 $CO_2$저감의 필요성이므로, 이들 중단기적으로 활용될 원료들의 수소제조기술들은 반드시 $CO_2$저감이 가능한 기술로서 개발되어야 한다.

• Biotechnology and Bioprocess Engineering:BBE
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• 제10권2호
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• pp.115-121
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• 2005

Using a general Saccharomyces cerevisiae as a model strain, continuous ethanol fermentation was carried out in a stirred tank bioreactor with a working volume of 1,500 mL. Three different gravity media containing glucose of 120, 200 and 280 g/L, respectively, supplemented with 5 g/L yeast extract and 3 g/L peptone, were fed into the fermentor at different dilution rates. Although complete steady states developed for low gravity medium containing 120 g/L glucose, quasi-steady states and oscillations of the fermented parameters, including residual glucose, ethanol and biomass were observed when high gravity medium containing 200 g/L glucose and very high gravity medium containing 280 g/L glucose were fed at the designated dilution rate of $0.027\;h^{-1}$. The observed quasi-steady states that incorporated these steady states, quasi-steady states and oscillations were proposed as these oscillations were of relatively short periods of time and their averages fluctuated up and down almost symmetrically. The continuous kinetic models that combined both the substrate and product inhibitions were developed and correlated for these observed quasi-steady states.