• Journal of Environmental Science International
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• v.21 no.8
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• pp.891-899
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• 2012

The chlorination pattern of naphthalene vapor when passed through a 1 cm particle bed of 0.5% (mass) copper (II) chloride ($CuCl_2$) mixed with silicon dioxide ($SiO_2$) was studied. Gas streams consisting of 92% (molar) $N_2$, 8% $O_2$ and 0.1% naphthalene vapor were introduced to an isothermal flow reactor containing the $CuCl_2/SiO_2$ particle bed. Chlorination of naphthalene was studied from 100 to $400^{\circ}C$ at a gas velocity of 2.7 cm/s. Mono through hexachlorinated naphthalene congeners were observed at $250^{\circ}C$ whereas a broader distribution of polychlorinated naphthalenes (PCNs) including hepta and octachlorinated naphthalenes was observed at $300^{\circ}C$. PCN production was peak at $250^{\circ}C$ with 3.07% (molar) yield, and monochloronaphthalene (MCN) congeners were the major products at two different temperatures. In order to assess the effect of a residence time on naphthalene chlorination, an experiment was also conducted at $300^{\circ}C$ with a gas velocity of 0.32 cm/s. The degree of naphthalene chlorination increased as a gas velocity decreased.

• Journal of Korean Society on Water Environment
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• v.35 no.6
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• pp.557-566
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• 2019

Paldang is a river reservoir in the Midwest of Korea, which is a drinking water source for the metropolitan area. Since the Paldang Reservoir is shallow, and has a short hydraulic residence time, its water quality is directly impacted by two incoming rivers, the north Han River (NHR) and the south Han River (SHR). The NHR has different seasonal patterns of water temperature from the SHR because the NHR is greatly impacted by the discharge water from upstream dams. The electrical conductivity (EC) and other material concentrations of the SHR are usually higher than those of the NHR because its basin is limestone-based. The difference in water temperature in the two rivers causes density flow, and the distribution of the EC within the reservoir can be an indicator for monitoring density flow. From the vertical gradient of the EC at the dam site, from spring to fall, it was confirmed that the SHR flowed into the upper layer, and the NHR flowed into the lower layer, and vice versa at other times. The relative difference (RD) of the EC between the upper layer and the lower layer at the dam site was used as an indicator for density flow. The RD of the EC showed a very significant correlation with the RD of total organic carbon (r = 0.70, p < 0.001) and the RD of total nitrogen (r = 0.58, p < 0.01). This relationship is based on the assumption that the difference in electrical conductivity and water quality between the SHR and the NHR is constant. However, in many cases this assumption is inconsistent. Thus, further study is needed on more suitable indicators to evaluate the impact of density flow on water quality.

• Asian Pacific Journal of Cancer Prevention
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• v.16 no.17
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• pp.7991-7995
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• 2015

Background: To identify the epidemiological characteristics of colorectal cancer mortality in China during the period of 1991-2011, and forecast the future five-year trend. Materials and Methods: Mortality data for colorectal cancer in China from 1991 to 2011 was used to describe epidemiological characteristics in terms of age group, gender, and rural/urban residence. Trend surface analysis was performed to analyze the geographical distribution of colorectal cancer. Four models including curve estimation, time series modeling, gray modeling and joinpoint regression were applied to forecast the trends for the future five years. Results: Since 1991 the colorectal cancer mortality rate increased yearly, and our results showed that the trend would continue to increase in the ensuing 5 years. The mortality rate in males was higher than that of females and the rate in urban areas was higher than in rural areas. The mortality rate was relatively low for individuals less than 60 years of age, but increased dramatically afterwards. People living in the northeastern China provinces or in eastern China had a higher mortality rate for colorectal cancer than those living in middle or western China provinces. Conclusions: The steadily increasing mortality of colorectal cancer in China will become a substantial public health burden in the foreseeable future. For this increasing trend to be controlled, further efforts should concentrate on educating the general public to increase prevention and early detection by screening. More effective prevention and management strategies are needed in higher mortality areas (Eastern parts of China) and high-risk populations (60+ years old).

• Journal of Distribution Science
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• v.17 no.5
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• pp.95-102
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• 2019

Purpose - The purpose of the research is to identify the demographic characteristics of the customers with high private label purchase intention. According to the previous research demographics such as gender, age, income, and residence type affect private label purchase intention indirectly through psychographics rather than directly. For instance, higher income group is time pressured, price-insensitive, quality-sensitive, less likely to enjoy shopping utilitarian products, and less likely to be variety-seeking. The main contribution of this research is to verify the results found in the previous empirical foreign research using scanner data and to investigate the differences of the characteristics of private label users between Korea and the foreign countries. Research design, data, and methodology - In order to empirically test the proposed hypotheses, scanner data of a Korean major super center was analyzed. Results - Empirical results show that private labels are more favored by old people over 50s, dwellers in individual house, lower income group, and frequent store visitors. Age of 30s, dwellers in the apartment of 30 pyung, higher income group, and consumers who purchased a large amount are less likely to purchase private labels. Gender turned out not to affect private label purchase. It should be noted that there is a significant multicollinearity among independent variables. Conclusions - The research findings provide managerial implication for retailers' private label strategy. In general, retailers heavily send private label coupons to the customers with high purchase volume. According to the research, however, store visit frequency is much more positively associated with private label purchase than purchase amount. The study has some limitations. The samples are only consumers with private label purchase experience. The data were drawn from one store and only 8 commodity products were used for the analysis. Also, if more demographics were available, a more complete description on the private brand users' profile could have been derived. We propose the following future research. Research using the data including consumers without private label experience, research investigating direction of causality between private label loyalty and store loyalty, and research using hedonic private label products such as TV and PC could be promising.

• Macromolecular Research
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• v.16 no.1
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• pp.15-20
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• 2008

The enhanced permeability and retention (EPR) effect is used extensively for the passive targeting of many macromolecular drugs for tumors. Indeed, the EPR concept has been a gold standard in polymeric anticancer drug delivery systems. This study investigated the tumoral distribution of self-assembled nanoparticles based on the EPR effect using fluorescein and radio-labeled nanoparticles. Self-assembled nanoparticles were prepared from amphiphilic chitosan derivatives, and their tissue distribution was examined in tumor-bearing mice. The size of the nanoparticles was controlled to be 330 run, which is a size suited for opening between the defective endothelial cells in tumors. The long-circulating polymer nanoparticles were allowed to gradually accumulate in the tumors for 11 days. The amount of nanoparticles accumulated in the tumors was remarkably augmented from 3.4%ID/g tissue at 1 day to 25.9%ID/g tissue at 11 days after i.v. administration. The self-assembled nanoparticles were sustained at a high level throughout the 14 day experimental period, indicating their long systemic retention in the blood circulation. The ${\gamma}$-images provided clear evidence of selective tumor localization of the $^{131}I$-labeled nanoparticles. Confocal microscopy revealed the fluorescein-labeled nanoparticles to be preferentially localized in the perivascular regions, suggesting their extravasation to the tumors through the hyperpermeable angiogenic tumor vasculature. This highly selective tumoral accumulation of nanoparticles was attributed to the leakiness of the blood vessels in the tumors and their long residence time in the blood circulation.

• Particle and aerosol research
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• v.17 no.3
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• pp.43-54
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• 2021

Size distributions of atmospheric particulate matter (PM) and its water-soluble organic and inorganic components were measured between January and February 2021 at an urban site in Gwangju in order to identify the major factors that determine their size distributions. Their size distributions during the study period were mainly divided into two groups. In the first group, PM, NO₃^-, SO₄^2-, NH₄⁺ and water-soluble organic carbon (WSOC) exhibited bi-modal size distributions with a dominant condensation mode at a particle size of 0.32 ㎛. This group was dominated by local production of secondary water-soluble components under atmospheric stagnation and low relative humidity (RH) conditions, rather than long-range transportation of aerosol particles from China. On the other hand, in the second group, they showed tri-modal size distributions with a very pronounced droplet mode at a diameter of 1.0 ㎛. These size distributions were attributable to the local generation and accumulation of secondary aerosol particles under atmospheric conditions such as atmospheric stagnation and high RH, and an increase in the influx of atmospheric aerosol particles by long-distance transportation abroad. Contributions of droplet mode NO₃^-, SO₄^2-, NH₄⁺ and WSOC to fine particles in the second group were significantly higher than those in the first group period. However, their condensation mode contributions were about two-fold higher in the first group than in the second group. The significant difference in the size distribution of the accumulation mode of the WSOC and secondary ionic components between the two groups was due to the influx of aerosol particles with a long residence time by long-distance transport from China and local weather conditions (e.g., RH).

• Journal of the Korean Society for Marine Environment & Energy
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• v.1 no.1
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• pp.39-46
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• 1998

This study presents a numerical model that can simulate changes of particle size distribution (PSD) of PCB-contaminated coastal sediments. The developed model has one spatial dimension including sedimentation and vortical dispersion as well as coagulation. The reason for considering the vortical transport mechanisms is to calculate residence time of the particles. Using the model and Initial PSD data based on actual coastal sediments contaminated with PCBs, this study shows results of model simulations. Within 48 hours of the simulation time, the PSD changed significantly and the particles were removed from water in different rates between different particle sizes. It also shows that coagulation can act an important role in this process. The model may be useful in assessing the range of resuspended sediments that can pollute neighboring areas during environmental remediation projects such as dredging.

• Journal of the Korean Regional Science Association
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• v.10 no.2
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• pp.17-29
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• 1994

This study attempts to examine the regional distribution and the locational pattern of leisure facilities at Kangnam-gu in Seoul. For the convenience of the analysis the facilities are classified into public and private sector and then the facilities are classified into 11 types: mineral spring resort, play ground, neighborhood park, swimming pool, gymnasium, bowling, pingpong, aerobic, golf practice, health, and billiard facilities. For the purpose data was collected from statistical yearbook in 1993 and lists of registered facility at department of living physics of Kangnam-gu office. The data of the density of facilities and the opportunity of facilities per facilities type and per region are analysed with the technology of GIS. Results may be summarized as follows. First of all, correlation between the results of Location-Allocation model and the results of Interaction model is very high. Secondly, on comparing the density of facilities with the opportunity of the facility use per eleven facility types, three discrete spatial pattems are found. The mineral spring resort facility type with the highest unbalanced density and opportunity of facility use is to be found. Play ground, neighborhood park, swimming pool, gymnasium, bowling, pingpong, and aerobic facility types have the high unbalanced density and opportunity of facility use. The golf practice, health, and billiard facility types have spatially balanced density and opportunity of facility use. Thirdly, as comparing the density and the opportunity of the facility use per 'dong' administration unit, the spatial patterns of the public and the private facilities are different in density of the facility use and otherwise two are similar in the opportunity of the facility use. Fourthly, patterns of facilities users have different charateristics based on facility use time, expense, residence, and access time and four regional patterns are to be found ; user favorable, facility profitable, user balanced, and unfavorable.

• KIEAE Journal
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• v.15 no.5
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• pp.107-112
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• 2015

Purpose: This study desires to investigate an effect of indoor temperature, humidity, and illuminance targeting a planting system of double-skin facade and cavity space adjacent to the outside within a certain period of winter. Through this, the study suggests a basic material about an energy conservation effect of double window system using planting to reduce heating load of a building in winter, so desires to contribute to indoor thermal comfort effect and illuminance correction study of double window and indoor plant. Method: Considering effects such as day and night climatic elements and air conditions in winter, illuminance measurement was conducted through a double-skin facade of space, a subject of the measurement, on the basis of practical residence time of a resident, and this study analyzed characteristics of indoor illuminance about this. The study measured and compared a change of insolation, dry-bulb temperature, and relative humidity at each indoor-outdoor measuring point, so measured and compared characteristics of an indoor temperature effect by elements of double-skin facade and indoor plant. Result: Through this study, the researcher could determine that indoor plant within double window in winter not only blocks solar radiation but also photosynthesizes, so is somewhat disadvantageous to winter thermal comfort reducing heating load. In addition, solar radiation going through interior plays a role to bring down somewhat high humidity to about 50% of reasonable humidity, so plays a direct role of maintenance of comfortable indoor space. Although there are effects such as blocking of solar radiation and temperature reduction, this has a positive influence on humidity control and proper illuminance distribution. The researcher could determine that illuminance, temperature, and humidity by solar radiation penetration for the whole measuring time play a role to supplement indoor environment mutually.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.21 no.3
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• pp.91-102
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• 2016

The spatio-temporal variations of the dissolved methane concentration were investigated and the methane budget was estimated in the Nakdong Estuary in January, September, and November of 2014. Dissolved methane showed seasonal variation (21~874 nM) with high concentration in summer due to enhanced temperature and fresh water discharge. Decreasing trends of dissolved methane from the river to the estuary were consistent in all seasons showing the main source of the estuarine methane is river discharge. However, the decreasing trends were modified seasonally due to the local sources such as organic-rich sediments in intertidal zone or near the estuarine barrage. Dissolved methane concentration in the Nakdong Estuary was high, compared to other estuaries probably due to the well developed wetland in Nakdong-river system and stagnation effect from barrages and dams. Dominant sink for the Nakdong estuarine methane was outflux into the atmosphere. Relatively long residence time (produced by barrier island and estuarine dam) in the estuary might provide the enough time for the outgassing.