• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1329-1334
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• 1999

The curing characteristics of diglycidyl ether of bisphenol A (DGEBA) with diaminodiphenylmethane (DDM) as a curing agent were studied using differential scanning calorimetry (DSC), rheometrics mechanical spectrometry (RMS), and dielectric analysis (DEA). The isothermal curing kinetics measured by DSC were well represented with the generalized auto-catalytic reaction model. With the temperature sweep, the inverse relationship between complex viscosity measured by RMS and ionic conductivity obtained from DEA was established indicating that the mobility of free ions represented by the ionic conductivity in DEA measurement and the chain segment motion as revealed by the complex viscosity measured from RMS are equivalent. From isothermal curing measurements at several different temperatures, the ionic conductivity contribution was shown to be dominant in the dielectric loss factor at the early stage of cure. The contribution of the dipole relaxation in dielectric loss factor became larger as the curing further proceeded. The critical degrees of cure, at which the dipolar contribution in the dielectric loss factor starts to appear, increases as isothermal curing temperature is increased. The dielectric relaxation time at the same degree of cure was shorter for a sample cured at higher curing temperature.

• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.925-928
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• 2012

The accurate expression for the steady-state velocity of an irreversible enzyme-catalyzed reaction obtained by Shin and co-workers (J. Chem. Phys. 2001, 115, 1455) is generalized to allow for the rebinding of the product. The amplitude of the power-law ($t^{-1/2}$) relaxation of the free- and bound-enzyme concentrations to steady-state values is expressed in terms of the steady-state velocity and the intrinsic (chemical) rate constants. This result is conjectured to be exact, even though our expression for the steady-state velocity in terms of microscopic parameters is only approximate.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.70-73
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• 2006

In the present study, the flow-softening behavior occurring during high temperature deformation of AZ31 Mg alloy was investigated. Flow softening of AZ31 Mg alloy was attributed to (1) thermal softening by deformation heating and (2) microstructural softening by dynamic recrystallization. Artificial neural networks method was used to derive the accurate amounts of thermal softening by deformation heating. A series of mechanical tests (High temperature compression and load relaxation tests) was conducted at various temperatures ($250^{\circ}C{\sim}500^{\circ}C$) and strain rates ($10^{-4}/s{\sim}100/s$) to formulate the recrystallization kinetics and grain size relation. The effect of DRX kinetics on microstructure evolution (fraction of recrystallization) was evaluated by the unified SRX/DRX (static recrystallization/dynamic recrystallization) approaches

• Bulletin of the Korean Chemical Society
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• v.27 no.2
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• pp.197-202
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• 2006

In the reaction A + B $^\rightarrow_\leftarrow$ C, where A and B are ionic reactants having opposite charges, a B molecule approaching an A will experience a switching of the interaction potential when the A molecule is captured by one of the other B molecules in the medium. In the reversible case, the former B molecule still has a chance to react with the A, so that one needs to take into account the switched interaction between the reactant B and the product C as well as that between the reactants to treat the kinetics accurately. It is shown that this kind of interaction potential switching affects the relaxation kinetics in an intriguing way as observed in a recent experiment on an excited-state proton transfer reaction.

• Journal of the Korean Magnetic Resonance Society
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• v.21 no.2
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• pp.55-62
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• 2017

It is now well established that RNAs exhibit fundamental roles in regulating cellular processes. Many of these RNAs do not exist in a single conformation. Rather, they undergo dynamic transitions among many different conformations to mediate critical interactions with other biomolecules such as proteins, RNAs, DNAs, or small molecules. Here, we briefly review NMR techniques that describe the dynamic behavior of RNA by determining structural, kinetic, and thermodynamic properties.

• Mass Spectrometry Letters
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• v.15 no.1
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• pp.54-61
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• 2024

An improved voltage modulation method (VMM) was used to control the heat release and adsorption properties of the adsorbent. In this work, the voltage and flux modulation methods were considered under unified experimental conditions of dissociative surface ionization (SI) of polyatomic organic molecules, the criteria were found when under VMM conditions the current relaxation of SI carries information about the kinetic properties of thermal desorption of ionizable dissociation particles arriving on the surface of polyatomic molecules. Conditions were found under which the relaxation of the ionic current in the flux modulation method is determined by the kinetics of the heterogeneous dissociation reaction of the original polyatomic molecules. The values of the thermal desorption rate constant K⁺ and the activation energy E⁺ obtained with VMM for desorption of (CH₃)₂NCH⁺₂ ions with m/z 58 by adsorption of imipramine and amitriptyline molecules agree well with each other and with the results for the desorption of the same ions by adsorption of other molecules. This confirms one of the basic conditions for the equilibrium process SI - the a degree (β coefficient) of the same particles SI on the same emitter surface is the same and does not depend on the way these particles are formed on the emitter surface.

• Journal of the Korean Chemical Society
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• v.52 no.3
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• pp.217-222
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• 2008

We investigate the kinetics of diffusion-influenced catalytic reactions occurring in small reaction volume. From a simple exact model study, we find that the reaction rate coefficient decreases with the size of reaction volume. The explicit expression for the average reaction rate constant is presented, which can be regarded as a generalization of well-known Collins-Kimball rate constant into the reactions occurring in a small reaction volume. It turns out that the traditional diffusion influenced reaction dynamics is followed by a single exponential relaxation phase with a rate constant dependent on the reaction volume for the catalytic reactions occurring in small reaction volumes.

• Journal of Photoscience
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• v.9 no.2
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• pp.78-81
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• 2002

Fluorescence rise and decay curves of carotenoids were measured in solutions and in pigment protein complexes with a femtosecond time-resolved fluorescence spectroscopy. For linear carotenoids, the S$_2$ lifetimes showed the maximum value around n = 9-10. The conjugation of a keto-carbonyl group shortened the S$_2$lifetime and prolonged the S$_1$lifetime. The excitation relaxation dynamics within carotenoids and the excitation energy transfer kinetics from carotenoids to chlorophylls are discussed as a function of molecular structure of carotenoids.

• Bulletin of the Korean Chemical Society
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• v.26 no.12
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• pp.1986-1990
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• 2005

We study the relaxation kinetics of reversible reactions of the type A + B $^\leftarrow_\rightarrow$ C + B by applying the manyparticle kernel theory, which we have developed to investigate many particle effects on general diffusioninfluenced reactions. It is shown that for the target model, where A and C molecules are immobile and their interconversion is induced by the encounter with the B molecules that are present in much excess, the manyparticle kernel theory gives a result that coincides with the known exact result.

• Rapid Communication in Photoscience
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• v.3 no.4
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• pp.85-87
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• 2014

We studied the characteristics of emissive state of the first (p-G1) and second (p-G2) generation of phenylacetylene dendrimers bearing stilbene as a core by using time-resolved fluorescence spectroscopy in cyclohexane (c-Hex) and N, N-dimethylformide (DMF), which are nonpolar and polar solvents, respectively. Time-dependent red-shift of emission spectra p-G2 both in c-Hex and DMF was observed in comparison with p-G1. Besides, the time constant of red-shift of spectra was found to be larger in DMF than in c-Hex. This indicates that the emissive state of p-G2 has a polar character in DMF as a result of charge delocalization from core to peripheral dendrons followed by stabilization of emissive state.