• 한국수소및신에너지학회논문집
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• 제28권1호
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• pp.24-29
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• 2017

A fluorinated polybenzimidazole (FPBI) was synthesized from 3,3-diaminobenzidine (DAB) of tetraamine, 2,2-bis(4-carboxyphenyl)hexafluoropropane of aromatic biscarboxylic acid, and 4,4-sulfonyldibenzoic acid of aromatic biscarboxylic acid in polyphosphoric acid (PPA). A FPBI was easily cast and made into clear films. The structure of condensation polymers and corresponding membranes were analyzed using GPC (gel permeation chromatography), $^1H$-NMR ($^1H$ nuclear magnetic resonance) and FT-IR (fourier transform infrared). TGA (thermogravimetric analysis) analysis showed that the prepared membranes were thermally stable, so that elevated temperature fuel cell operation would be possible. The proton conductivity of the FPBI membranes increased with increasing temperatures in the polymer. A FPBI membrane has a maximum ion conductivity of 45 mS/cm at $90^{\circ}C$ and 100% relative humidity.

• The Korean Journal of Ceramics
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• 제6권4호
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• pp.343-347
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• 2000

The alkali volatilization of TV screen glass melts with various $K_2$O/R$_2$O mole fraction was investigated by dependence of weight loss on time. The melt conductivity was also determined to evaluate relative alkali diffusion in melts. Based on the results of time dependence and compositional dependence of volatilization combining the results of conductivity, the rate determining process of the volatilization was suggested. From the viewpoint of the production and the application of TV glass it was also discussed a correlation between the dependence of properties on $K_2$O/R$_2$O and the present commercial composition.

• 한국조경학회지
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• 제41권5호
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• pp.1-8
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• 2013

이 연구는 2종의 저관리 경량형 옥상녹화시스템(세덤박스와 우수저장형 옥상녹화시스템)을 대상으로 옥상녹화 효과를 평가하기 위해 옥상의 건조한 조건에 잘 견딜 수 있는 내건성 식물 12종을 대상으로 실험을 실시하였다. 실험은 우수저장형 옥상녹화시스템의 기초 연구를 위해 식물의 내건성을 평가하였다. 식물의 내건성 평가를 위해 무관리 조건에서 12종 식물의 건조스트레스의 저항성을 평가하였다. 내건성 평가는 처리 시간에 따라 12종 식물의 상대수분함량의 변화, 전해질 용출 평가, 엽록소 함량의 변화, 토양수분과 건조 스트레스와의 관계를 연구하였다. 건조처리 시간이 길수록 식물들의 상대수분 함량과 엽록소 함량이 감소하면서, 전해질 용출이 증가하였다. 따라서 식물의 내건성 평가 결과, Pulsatilla koreana, Ainsliaea acerifolia를 제외한 10종이 내성이 강하여 옥상녹화에 적용 가능한 종으로 판단되며, 우수저장형 옥상녹화 시스템에서 식물들의 내건성은 식생박스의 식물들보다는 강한 것으로 나타났다. 따라서 우수저장형 옥상녹화 시스템이 식물의 생육과 건조조건에 대한 저항성 증진 효과가 있는 것이 증명되어 도시 옥상녹화에 이용할 수 있다.

• 한국주조공학회지
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• 제35권4호
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• pp.67-74
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• 2015

In this study, Mg-Zn alloys are investigated in terms of their thermal properties after an addition of Cu. Al element is added to improve the mechanical properties and castability in general case. However, it was excluded here because it significantly decreases the thermal conductivity. On the other hand, Zn was added as a major element, which had less influence on reducing the conductivity and can complement the mechanical properties as well. Cu was also added, and it improved the heat transfer characteristics as the amount was increased. The composition ranges of Zn and Cu are 6 wt.% and 0~1.5 wt.%, respectively. Mg-6Zn-xCu alloy was prepared by a gravity casting method using a steel mold and then the thermal conductivity and the microstructure of the as-cast material were investigated. By measuring the density_(${\rho}$), specific heat_(Cp) and thermal diffusivity_(${\alpha}$), the thermal conductivity_(${\lambda}$) was calculated by the equation ${\lambda}={\rho}{\cdot}Cp{\cdot}{\alpha}$. As the amount of Cu increased in the Mg-6Zn-xCu alloy, the heat transfer characteristics were improved, resulting in a synergistic effect which is slow when the added Cu exceeds 1 wt.%. In order to investigate the relative thermal conductivity/emission of the Mg-6Zn-xCu alloy, AZ91 and AZ31 were experimentally evaluated and compared using a separate test equipment. As a result, the Mg-6Zn-1.5Cu alloy when compared to AZ91 showed improvements in the thermal conductivity ranging from 30 to 60% with a nearly 20% improvement in the thermal emission.

• Korean Chemical Engineering Research
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• 제54권2호
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• pp.181-186
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• 2016

최근에 저가의 고분자 전해질 연료전지(Proton Exchange Membrane Fuel Cells, PEMFC)용 비불소계 전해질 막 연구개발이 활발히 진행되고 있다. 본 연구에서는 sulfonated Poly(ether ether ketone)(sPEEK)막의 특성을 술폰화도, 상대습도, 단위 전지 온도에 따라 PEMFC 운전 조건에서 비교하였다. I-V 분극곡선, 수소투과도, 전기화학적 표면적, 막 저항 및 부하 전달 저항 등을 측정 분석했다. 술폰화도와 온도, 상대습도가 높을수록 성능이 높았으며, 특히 낮은 슬폰화도와 낮은 상대습도에서 이온 전도도 감소 때문에 성능이 큰 폭으로 감소함을 확인하였다.

• 한국전기전자재료학회논문지
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• 제28권7호
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• pp.419-423
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• 2015

Sintering, microstructure, thermal conductivity and microwave dielectric properties of xLiF-(1-x)MgO ceramics (x=0.03~0.10 mol) were investigated. The high density was obtained in the specimens of $x{\geq}0.06$, i.e., 0.04 LiF-0.96 MgO in mol, whereas the amount of 0.03 mol LiF was insufficient to densify. From the result that the contact flattening in the sintered specimen was observed, the densification occurred through the liquid-phase sintering. The specimen of x=0.06 showed the highest room-temperature thermal conductivity. Relative density, thermal conductivity, dielectric constant, and quality factor ($Q{\times}f$) of the specimen for x=0.06 sintered at $900^{\circ}C$ for 4 h were 97.8%, $39.2Wm^{-1}K^{-1}$, 9.45, and 14,671 GHz, respectively.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.144-149
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• 2017

A proton-conducting bisphenylpropaned sulfonated fluorinated blockcopolymer (BPSFBC) was synthesized. Five kinds of polymer electrolyted composite membranes were preparated by incorporating silica ($SiO_2$) with various weight ratio. And their characteristics were investigated by FT-IR (fourier transform infrared), $^1H-NMR$ ($^1H$ nuclear magnetic resonance), TGA (thermogravimetric analysis), water uptake, FE-SEM (field emission scanning electron microscopes), and ion conductivity properties. The water uptake and ion conductivity were increased until 9 wt% $SiO_2$, and then decreased. The maximum proton conductivity equal to $52mScm^{-1}$ was measured for the BPSFBC/$SiO_2$-9 composite membrane at $90^{\circ}C$ and 100% relative humidity. From the measured results, it is distinct that the manufactured composite membrane BPSFBC/$SiO_2$-9 can be considered as a polymer membrane suitable for a fuel cell electrolyte.

• Advances in materials Research
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• 제5권3호
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• pp.131-140
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• 2016

Copper/silicon nitride ($Cu/Si_3N_4$) composites are fabricated by powder technology process. Copper is used as metal matrix and very fine $Si_3N_4$ particles (less than 1 micron) as reinforcement material. The investigated powder were used to prepare homogenous ($Cu/Si_3N_4$) composite mixtures with different $Si_3N_4$ weight percentage (2, 4, 6, 8 and10). The produced mixtures were cold pressed and sintered at different temperatures (850, 950, 1000, $1050^{\circ}C$). The microstructure and the chemical composition of the produced $Cu/Si_3N_4$ composites were investigated by (SEM) and XRD. It was observed that the $Si_3N_4$ particles were homogeneously distributed in the Cu matrix. The density, electrical conductivity and coefficient of thermal expansion of the produced $Cu/Si_3N_4$ composites were measured. The relative green density, sintered density, electrical conductivity as well as coefficient of thermal expansion were decreased by increasing the reinforcement phase ($Si_3N_4$) content in the copper matrix. It is also founded that the sintered density and electrical conductivity of the $Cu/Si_3N_4$ composites were increased by increase the sintering temperature.

• 한국지열·수열에너지학회논문집
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• 제8권4호
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• pp.8-16
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• 2012

The use of energy pile foundation has been increased for economic utilization of geothermal energy. This paper describes an experimental and numerical study on thermal response tests (TRTs) using W and 3U-shaped ground heat exchangers (GHEs) in precast-high strength concrete (PHC) energy piles. Ground thermal conductivity and borehole thermal resistance were measured and compared with those numerical analysis. W-shpaed GHE showed higher heat transfer behavior than 3U-shaped one because of different conditions such as pile size and volume of grout. That is, ground thermal conductivity using W-shaped GHE was higher than that of 3U shaped GHE, and borehole thermal resistance vice versa. The relative error of borehole resistance values between numerical and analytical solution was less than 5%.

• 한국산림과학회지
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• 제63권1호
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• pp.21-27
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• 1984

본(本) 연구(硏究)는 몇 종(種)의 침엽수(針葉樹)에 대하여 Shoot water potential의 일변화(日變化) 및 지(枝)의 Xylem conductivity의 특성(特性)을 측정고찰(測定考察)한 것으로 다음과 같은 결과를 얻었다. 1) Shoot water potential은 광도(光度)의 크기에 따라 변화(變化)하며, 광도(光度)의 감소(減少)가 시작된지 2시간(時間) 늦게 Shoot water potential의 증가(增加)가 시작되었다. 2) 지엽(枝葉)의 일중(日中) 최대수분(最大水分) 결차(缺差)는 12시(時)부터 14시(時) 사이에 일어나며, 그 값의 크기는 일본잎갈나무 -22 bar, 잣나무 -18 bar, 소나무 -15 bar, 젓나무 -14 bar, 리기다소나무 -10 bar 정도였다. 3) 수고(樹高) 1 m 당(當) 지엽(枝葉)의 수분결차(水分缺差)의 크기를 경사도(傾斜度)(${\varphi}_L/m$)로 나타내면 잣나무 -1.7 bar/m, 일본잎갈나무 -2.1 bar/m였다. 4) 지(枝)의 Relative Xylem conductivity (K, $cm^2/hr{\cdot}atm$)의 평균치(平均値)는 일본잎갈나무 2878, 리기다소나무 2763, 소나무 2652, 잣나무 2113 이었다.