• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 춘계학술발표회요약집
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• pp.104-104
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• 1999

The local heat transfer coefficient is experimentally investigated for the reflux condensation in a countercurrent flow between the steam-air mixture and the condensate. A single vertical tube has a geometry which is a length of 2.4m, inner diameter of 16.56mm and outer diameter of 19.05mm and is made of stainless steel. Air is used as a noncondensible gas. The secondary side is installed in the form of coolant block around vertical tube and the heat by primary condensation is transferred to the coolant water. The local temperatures are measured at 15 locations in the vertical direction and each location has 3 measurement points in the radial direction, which are installed at the tube center, at the outer wall and at the coolant side. In three different pressures, the 27 sets of data are obtained in the range of inlet steam flow rate 1.348 -3.282kg/hr, of inlet air mass fraction 11.8 -55.0%. The local heat transfer coefficient increases as the increase of inlet steam flow rate and decreases as the decrease of inlet air mass fraction. As an increase of the system pressure, the active condensing region is contracted and the heat transfer capability in this region is magnified. The empirical correlation is developed represented with the 165 sets of local heat transfer data. As a result, the Jacob number and film Reynolds number are dominant parameters to govern the local heat transfer coefficient. The rms error is 17. 7% between the results by the experiment and by the correlation.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2748-2752
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• 2012

Cr(III) and Co(III) complexes with acetylacetonate were anchored onto a mesoporous MCM-41 through Schiff condensation. The materials were characterized by XRD, FT-IR, BET, CHN and ICP techniques. Elemental analysis of samples revealed that one C=N bond was formed through Schiff condensation on MCM-41 surface. The catalysts were tested for the alcohol oxidations using t-butyl hydroperoxide (TBHP) and $H_2O_2$ as oxidant. The catalytic experiments were carried out at both room temperature and reflux condition. Various solvents such as dichloromethane, acetonitrile and water were examined in the oxidation of alcohols. Among the different solvents, catalytic activity is found more in acetonitrile. Further, the catalysts were recycled three times in the oxidation of alcohols and no major change in the conversion and selectivity is observed, which shows that the immobilized metal-acetylacetonate complexes are stable under the present reaction conditions.

• 대한화학회지
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• 제59권4호
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• pp.284-288
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• 2015

Three-component one-pot synthesis of 2-amino-3-cyano-7-hydroxy-4H-chromenes, which have been reported from condensation of malononitrile, aryl aldehydes and resorcinol in the presence of L-proline under reflux conditions in ethanol.

• Bulletin of the Korean Chemical Society
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• 제24권8호
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• pp.1181-1187
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• 2003

Condensation of 4-cyano-5,6-dimethyl-3-pyridazinone 1 with aromatic aldehydes gave the novel styryl derivatives 2a-c. Refluxing of compound 2a with phosphorus oxychloride furnished 3-chloropyridazine derivative 3. Compound 3 was reacted with thiourea and produced pyridazine-3(2H)thione 4. Thieno[2,3-c]- pyridazines 5a-e were achieved by cycloalkylation of compound 4 with halocompounds in methanol under reflux and in the presence of sodium methoxide. Also, refluxing of compound 4 with N-substituted chloroacetamide in the presence of potassium carbonate afforded thienopyridazines 6a-e. Cyclization of compound 6 with some electrophilic reagents as carbon disulfide and triethyl orthoformate furnished the novel pyrimido[4',5':4,5]thieno[2,3-c]pyridazines 12 and 13a-c, respectively. Diazotisation of compound 6 with sodium nitrite in acetic acid produced the pyridazino[4',3':4,5]thieno[3,2-d][1,2,3]triazines 14a-c. Ternary condensation of compound 1, aromatic aldehydes and malononitrile in ethanol containing piperidine under reflux afforded the novel phthalazines 16a-c. Compound 3 was subjected to some nucleophilic substitution reactions with amines and sodium azide and formed the aminopyridazines 17a, b and tetrazolo[1,5-b]-pyridazine 19, respectively. The structures of the synthesized compounds were established by elemental and spectral analyses.

• Nuclear Engineering and Technology
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• 제54권3호
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• pp.826-833
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• 2022

A two-phase natural circulation test using SMART integral test loop (SMART-ITL) was conducted to explore thermo-hydraulic phenomena of two-phase natural circulation in the SMART reactor. Specifically, the test examined the natural circulation in the primary loop under a stepwise coolant inventory loss while keeping the core power constant at 5% of the scaled full power. Based on the test results, three flow regimes were observed: single-phase natural circulation (SPNC), two-phase natural circulation (TPNC), and boiler-condenser natural circulation (BCNC). The flow rate remained steady in the SPNC, slightly increased in the TPNC, and dropped abruptly and maintained in the BCNC. Using a natural circulation flow map, the natural circulation characteristic in the SMART-ITL was compared with those in pressurized water reactor simulators. In the SMART-ITL, a BCNC regime appeared instead of siphon condensation and reflux condensation regimes because of the use of once-through steam generators.

• 대한화학회지
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• 제59권4호
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• pp.280-283
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• 2015

Hydrated ferric sulfate can be used as an efficient and reusable catalyst for the synthesis of 2H-indazolo[2,1-b]phthalazine-trione derivatives via one-pot three-component condensation reaction of phthalhydrazide, aromatic aldehydes and cyclic-1,3-diketones in ethanol under reflux conditions.

• 공업화학
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• 제10권2호
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• pp.293-298
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• 1999

Fluoran계 감열색소의 중간체인 2-Methyl-4-methoxydiphenylamine(MMDPA)을 합성하는 촉매반응의 반응기구를 규명하고 반응조건을 최적화하였다. 반응물질로서는 2-methyl-4-methoxyaniline(MMA), 3-methyl-4-nitroanisole(MNA), 그리고 cyclohexanone의 혼합물을 사용하였으며, 5 wt % Pd/C를 촉매로 사용하였다. 반응실험은 reflux condenser가 부착된 개방형 slurry reactor에서 진행시켰으며, 생성물은 GC/MS와 NMR에 의해서 분석하였다. 반응조건을 최적화 시킨 결과 xylene용매 속에서 0.01 gmoles MMA 투입기준으로 MMA : MNA : cyclohexanone = 1 : 2 : 150의 반응물조성, $160^{\circ}C$의 반응온도, 0.5 g 촉매량 조건에서 8~10시간 경과 후 90 mole %의 MMDPA수율을 얻을 수 있었다. MMA와 cyclohexanone간의 축합반응에 의해 생성된 중간생성물의 탈수소화 반응단계가 총괄반응을 율속함을 알 수 있었다. MNA를 MMA와 함께 반응물에 투입함으로써 hydrogen transfer반응에 의하여 총괄반응속도와 MMDPA수율이 증대되었다. 반응물에 과량으로 투입된 cyclohexanone은 MMA와의 축합반응을 촉진시키는 역할을 하였다.

• Advances in Energy Research
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• 제4권4호
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• pp.325-337
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• 2016

Cerbera Odollam (sea mango) is a proven promising feedstock for the production of biodiesel due to its high oil content. Fatty acid methyl esters (FAME) were produced as the final reaction product in the transesterification reflux condensation reaction of sea mango oil and methyl acetate (MA). Potassium methoxide was used as catalyst to study its reacting potential as a homogeneous base catalyst. The initial part of this project studied the optimum conditions to extract crude sea mango oil. It was found that the content of sea mango sea mango oil was 55%. This optimum amount was obtained by using 18 g of grinded sea mango seeds in 250 ml hexane. The extraction was carried out for 24 hours using solvent extraction method. Response surface methodology (RSM) was employed to determine the optimum conditions of the reaction. The three manipulated variables in this reaction were the reaction time, oil to solvent molar ratio, and catalyst wt%. The optimum condition for this reaction determined was 5 hours reaction time, 0.28 wt% of catalyst and 1:35 mol/mol of oil: solvent molar ratio. A series of test were conducted on the final FAME product of this study, namely the FTIR test, GC-FID, calorimeter bomb and viscometer test.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 춘계학술발표회요약집
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• pp.115-115
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• 1999

To demonstrate the applicability of RELAP5 to the prediction of the onset offlooding in the hot leg at the reflux condensation phase during mid-loop operation, numerical analysis is performed for the counter-current flow in a horizontal pipe with the inclined riser using the RELAP5/MOD3.2.2b code. It is found that the RELAP5, simulating the CCFL phenomena using interfacial friction along with the flow regime map in the horizontal pipe, produces unsatisfactory results. Under the CCFL condition, it is observed that large oscillation exists in the flow rate, void fraction, and etc. and the liquid flow rate is much lower than that predicted by the CCFL model measured in the experiment. The CCFL model of RELAP5 for the vertical volume is extended to the model for the horizontal and inclined volumes. The horizontal volume flow regime map and interfacial friction model coupled to the CCFL model are modified. And a new correlation developed from Kang's experiment is implemented to the CCFL model of RELAP5. With this modified RELAP5, the analysis of CCFL phenomena in the horizontal pipe and hot leg geometry is performed, and produces reasonable results in comparison with experimental data.

• 대한화학회지
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• 제57권2호
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• pp.234-240
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• 2013

The synthesis of title compounds were accomplished by synthetic sequence shown in Scheme 1. Chalcones on cyclocondensation with thiourea in ethanol and potassium hydroxide under reflux yielded the respective dihydropyramidin-2(1H)-thiones. Each of the dihydropyrimidin thiones was, then subjected to the Mannich condensation in alkaline medium using three different secondary amines, viz., dimethylamine, diethylamine and morpholine to obtain a new series of S-Mannich bases. All the synthesised compounds ($C_1-C_{15}$) were evaluated for their antiulcer and antibacterial activities. Compounds $C_4$, $C_5$, $C_6$, $C_{14}$ and $C_{15}$ exhibited relatively more potent antiulcer activity but not comparable to the standard; Omeprazole, while $C_1$, $C_2$, $C_3$ and $C_{13}$ were moderate in activity at 100 mg/kg p.o. All the compounds ($C_1-C_{15}$) showed mild to moderate activity against both Gram-positive (S.aureus, L.delbrueckii) and Gram-negative (P.vulgaris, E.coli) bacteria. Amongst the compounds tested, only $C_6$, $C_9$, $C_{12}$ and $C_{15}$ were found to be potent.