• 제목/요약/키워드: reduction atmosphere

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Corrosion Cost and Corrosion Map of Korea - Based on the Data from 2005 to 2010

  • Kim, Y.S.;Lim, H.K.;Kim, J.J.;Hwang, W.S.;Park, Y.S.
    • Corrosion Science and Technology
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    • 제10권2호
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    • pp.52-59
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    • 2011
  • Corrosion of metallic materials occurs by the reaction with corrosive environment such as atmosphere, marine, soil, urban, high temperature etc. In general, reduction of thickness and cracking and degradation are resulted from corrosion. Corrosion in all industrial facilities and infrastructure causes large economic losses as well as a large number of accidents. Economic loss by corrosion has been reported to be nearly 1-6% of GNP or GDP. In order to reduce corrosion damage of industrial facilities, corrosion map as well as a systematic investigation of the loss of corrosion in each industrial sector is needed. The Corrosion Science Society of Korea in collaboration with 15 universities and institutes has started to survey on the cost of corrosion and corrosion map of Korea since 2005. This work presents the results of the survey on cost of corrosion by Uhlig, Hoar, and input-output methods, and the evaluation of atmospheric corrosion rate of carbon steel, weathering steel, galvanized steel, copper, and aluminum in Korea. The total corrosion cost was estimated in terms of the percentage of the GDP of industry sectors and the total GDP of Korea. According to the result of Input/output method, corrosion cost of Korea was calculated as 2.9% to GDP (2005). Time of wetness was shown to be categories 3 to 4 in all exposure areas. A definite seasonal difference was observed in Korea. In summer and fall, time of wetness was higher than in other seasons. Because of short exposure period (12 months), significant corrosion trends depending upon materials and exposure corrosion environments were not revealed even though increased mass loss and decreased corrosion rate by exposure time.

선박조립과정의 FCAW 적용시 적정 보호가스 유량에 대한 연구 (A Study of Optimum Shielding Gas Flow Rate in FCAW for Shipbuilding)

  • 이훈동;심천식;송하철;염재선
    • 대한조선학회논문집
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    • 제48권1호
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    • pp.76-83
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    • 2011
  • FCAW(Flux Cored Arc Welding) is a widely used welding method in shipbuilding. It also conducts WPS(Welding Procedure Specification) requested by the classification variations of the factors which affect the quality on the welded area such as thickness of base metal, type of welding wire and shielding gas etc. which has to be satisfied. CO2 is commonly used as a shielding gas for FCAW due to the economic point of view. The amount of shielding gas is stated when classification certify WPS. However, the shielding gas is unnecessarily used at the shipyard leaning only on the welder's experience as there are classification standards for using the shielding gas. It causes production cost to rise. Also recently, CO2 is a main contributor for global warming, and large amounts of CO2 are discharged into the atmosphere during shipbuilding processes without any filtration. Therefore it was confirmed by the security of the welded area as a result of conducting the destructive and non-destructive tests with setting up the factors and the standards by using the Taguchi method. Then the FCAW shielding gas's amounts were calculated precisely when assembling a ship. It will be applied to cost reduction and prevention of environmental pollution at the shipyard.

활성화 이온빔 처리된 사파이어 기판상 MOCVD로 성장시킨 GaN의 열처리 효과 (Effects of Postannealing on GaN Grown by MOCVD on Reactive ion Beam Pretreated Sapphire Substrate)

  • 이상진;변동진;홍창희;김긍호
    • 한국재료학회지
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    • 제11권3호
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    • pp.191-196
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    • 2001
  • 사파이어 (0001) 기판의 활성화 이온빔 (RIB) 처리 후 MOCVD에서 성장한 GaN박막의 열처리를 통한 구조 변화를 살펴보고, 전기적 성질의 변화를 관찰하기 위하여 전기로를 이용하여 열처리를 하였다. 시편의 분석을 위하여 DCXRD, Hall, TEM을 사용하였다. 100$0^{\circ}C$에서 시간을 변화시키면서 열처리한 시편에서 DCXRD의 FWHM는 약 50 arc-sec 정도 감소하였고, Hall 이동도는 약 80$\textrm{cm}^2$/V.sec 정도 향상되었다. 가장 좋은 Hall 이동도를 보인 처리된 시편과 처리 전 시편의 TEM 비교 관찰에서 전위 밀도는 56~69% 정도 감소하였고 격자의 변형도 줄어들었다. 이것은 결정의 질과 전기적 성질 사이의 상관관계를 암시하며, 기판의 RIB 처리와 성장 후 적절한 열처리의 조합이 MOCVD로 성장시킨 GaN 박막의 특성을 개선시키는 것을 명확하게 보여준다.

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Y2O3 함량과 소결조건에 따른 상압소결 AlN 세라믹스의 열전도도 고찰 (Observation of Thermal Conductivity of Pressureless Sintered AlN Ceramics under Control of Y2O3 Content and Sintering Condition)

  • 나상문;고신일;이상진
    • 한국세라믹학회지
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    • 제48권5호
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    • pp.368-372
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    • 2011
  • Aluminum nitride (AlN) has excellent thermal conductivity, whereas it has some disadvantage such as low sinterability. In this study, the effects of sintering additive content and sintering condition on thermal conductivity of pressureless sintered AlN ceramics were examined on the variables of 1~3 wt% sintering additive ($Y_2O_3$) content at $1900^{\circ}C$ in $N_2$ atmosphere with holding time of 2~10 h. All AlN specimens showed higher thermal conductivity as the $Y_2O_3$ content and holding time increase. The formation of secondary phases (yttrium aluminates) by reaction of $Y_2O_3$ and $Al_2O_3$ from AlN surface promoted the thermal conductivity of AlN specimens, because the secondary phases could reduce the oxygen contents in AlN lattice. Also, thermal conductivity was increased by long sintering time because of the uniform distribution and the elimination of the secondary phases at the grain boundary by the evaporation effect during long holding time. A carbothermal reduction reaction was also affected on the thermal conductivity. The thermal conductivity of AlN specimens sintered at $1900^{\circ}C$ for 10 h showed 130~200W/mK according to the content of sintering additive.

수자원 개발사업 주민의견 유형분석을 통한 환경영향평가 개선방안 (Reformation Methods of Environmental Impact Assessment in Water Resources Development Project by Examining Local Resident Opinions)

  • 양기현;박재충;류영한;정용문;송상진;신재기
    • 환경영향평가
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    • 제20권3호
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    • pp.397-409
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    • 2011
  • This study was carried out for improving the effectiveness of water resources development project through local resident opinions in the environmental impact assessment(EIA). The EIA reports of seven dams were examined. Four dams -Youngju Dam, Seongduck Dam, Buhang Dam and Hantangang Dam- which included many local opinions including 470 opinions of 341 local residents were selected to be analyzed. Local residents submitted their opinions in the six fields which are meteorological phenomena, water quality, land use, fauna and flora, noise and vibration, and residence, and the major opinions of those opinions came from the atmosphere environment field which is 32% of total opinions and social and economic field which is 38% of total opinions, respectively. In submerged area, opinions of the measure for migration and compensation were 91% and in non-submerged area, opinions of the measure for meteorological phenomena was 86%. Those percentages were maximum in each area. Opinions concerned meteorological phenomena were 86% and 53% in Youngju Dam and Seongduck Dam where area is surrounded by existing dam, but there was only 9% and 0% of opinions in Buhang Dam and Hantangang Dam where area is without existing dam nearby. The reformation methods which reflected the resident's opinions were suggested on EIA in dam development projects. First of all, reliability and objectivity of the field of meteorological phenoma should be enhanced by scientific prediction of the phenomenon days. Secondly, techniques reducing uncertainty of various water quality prediction models ought to be developed and effectiveness of the reduction strategies in environmental impact should be quantified. Finally, the draft of EIA report should involve the detailed plans of migration and compensation's procedures, criteria and measures to support.

실험과 수치해석을 통한 동토지반 안정화용 수직형 열사이펀의 성능평가 (Experimental and Numerical Investigation of the Performance of Vertical Thermosyphon for Frozen Ground Stabilization)

  • 이장근;이철호;장창규;최창호
    • 한국지반신소재학회논문집
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    • 제13권4호
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    • pp.45-56
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    • 2014
  • 한대지역은 계절 변화에 따라 동결융해가 반복되는 상부의 활동층과 하부의 영하상태로 항시 유지되는 영구동토층으로 구성되어 있다. 한대지역에서 여름철에는 동결되어 있는 지반을 융해시키기 때문에 지반 강도저하 및 침하가 발생한다. 이러한 강도저하 및 침하는 상부 구조물의 구조적 안정성에 문제를 야기시켜 활동층을 포함하고 있는 한대지역에서는 지반의 온도를 항시 영하상태로 유지할 수 있는 동결지반 안정화 공법이 필요하다. 열사이펀이란 구조체 내부에 충전된 냉매의 자가적인 열순환에 의해 지반의 온도를 항시 영하상태로 유지할 수 있는 지반 안정화 공법 이다. 본 연구에서는 열사이펀의 지반 동결성능을 분석하기 위해 R-134a 냉매를 이용하여 충전율에 따른 열사이펀의 지반 온도제어를 실내실험과 수치해석을 통해 분석하고 열사이펀의 열전도율을 산정하였다.

Influence of Temperature and Water Activity on Deleterious Fungi and Mycotoxin Production during Grain Storage

  • Mannaa, Mohamed;Kim, Ki Deok
    • Mycobiology
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    • 제45권4호
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    • pp.240-254
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    • 2017
  • Cereal grains are the most important food source for humans. As the global population continues to grow exponentially, the need for the enhanced yield and minimal loss of agricultural crops, mainly cereal grains, is increasing. In general, harvested grains are stored for specific time periods to guarantee their continuous supply throughout the year. During storage, economic losses due to reduction in quality and quantity of grains can become very significant. Grain loss is usually the result of its deterioration due to fungal contamination that can occur from preharvest to postharvest stages. The deleterious fungi can be classified based on predominance at different stages of crop growth and harvest that are affected by environmental factors such as water activity ($a_w$) and eco-physiological requirements. These fungi include species such as those belonging to the genera Aspergillus and Penicillium that can produce mycotoxins harmful to animals and humans. The grain type and condition, environment, and biological factors can also influence the occurrence and predominance of mycotoxigenic fungi in stored grains. The main environmental factors influencing grain fungi and mycotoxins are temperature and $a_w$. This review discusses the effects of temperature and $a_w$ on fungal growth and mycotoxin production in stored grains. The focus is on the occurrence and optimum and minimum growth requirements for grain fungi and mycotoxin production. The environmental influence on aflatoxin production and hypothesized mechanisms of its molecular suppression in response to environmental changes are also discussed. In addition, the use of controlled or modified atmosphere as an environmentally safe alternative to harmful agricultural chemicals is discussed and recommended future research issues are highlighted.

LED용 BaGa2S4:Eu2+ 녹색 형광체의 합성 및 발광특성 (Synthesis and Luminescent Characteristics of BaGa2S4:Eu2+ Green Phosphor for Light Emitting Diode)

  • 김재명;박정규;김경남;이승재;김창해
    • 한국재료학회지
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    • 제16권12호
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    • pp.761-765
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    • 2006
  • [ $II-III_2-(S,Se)_4$ ] structured of phosphor has been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, the europium doped $BaGa_2S_4$ was prepared by solid-state method and had high potential application due to an emissive property of UV region. Also, the common sulfide phosphors were synthesized by using injurious $H_2S\;or\;CS_2$ gas. However, in this study $BaGa_2S_4:Eu^{2+}$ phosphor in addition to excess sulfur was prepared under at 5% $H_2/95%\;N_2$ reduction atmosphere. Thus, this process could be considered as large scale synthesis because of non-harmfulness and simplification. The photoluminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than that of commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could be applied to green phosphor for white LED of three wavelengths.

생체용 Ti-18Nb-6Zr-XO (X = 0~1.5at%) 합금의 형상기억특성에 미치는 산소 농도의 영향 (Effect of Oxygen Content on Shape Memory Characteristics of Ti-18Nb-6Zr-XO (X = 0~1.5at%) Alloys)

  • 박영철;옥지면;오정화;박수호;이준희;김재일
    • 한국재료학회지
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    • 제21권11호
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    • pp.617-622
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    • 2011
  • The effect of oxygen on the shape memory characteristics in Ti-18Nb-6Zr-XO (X = 0-1.5 at%) biomedical alloys was investigated by tensile tests. The alloys were fabricated by an arc melting method at Ar atmosphere. The ingots were cold-rolled to 0.45 mm with a reduction up to 95% in thickness. After severe cold-rolling, the plate was solution-treated at 1173 K for 1.8 ks. The fracture stress of the solution-treated specimens increased from 450 Mpa to 880 MPa with an increasing oxygen content up to 1.5%. The fracture stress increased by 287MPa with 1 at% increase of oxygen content. The critical stress for slip increased from 430 MPa to 695 MPa with an increasing oxygen content up to 1.5 at%. The maximum recovery strain of 4.1% was obtained in the Ti-18Nb-6Zr-0.5O (at%) alloy. The martensitic transformation temperature decreased by 140 K with a 1.0 at% increase in O content, which is lower than that of Ti-22Nb-(0-2.0)O (at%) by 20 K. This may have been caused by the effect of the addition of Zr. This study confirmed that addition of oxygen to the Ti-Nb-Zr alloy increases the critical stress for slip due to solid solution hardening without being detrimental to the maximum recovery strain.

온실가스 대량감축을 위한 $CO_2$ 지중저장의 기술 동향 (Trends of Underground $CO_2$ Storage Technology for the Large Scale Reduction of GHG)

  • 채광석;이상필;윤성욱;마츠오카 토시후미
    • 터널과지하공간
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    • 제20권5호
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    • pp.309-317
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    • 2010
  • CCS는 "이산화탄소의 포집 및 저장 기술"의 약어로서, 화석연료를 사용하는 화력발전소, 제철소 등에서 대규모로 배출하는 이산화탄소를 저감하기 위한 방법이다. CCS는 화석연료의 연소에서 발생되는 가스를 포집하여, 압축, 수송, 주입의 프로세스를 거처서 깊은 지하에 영구적으로 저장한다. CCS를 기존 화력발전소에 적용시에는 CCS 설비가 없는 발전소에 비해 약 80~90%의 이산화탄소를 줄일 수 있다. IPCC의 보고서에 의하면, CCS는 2010년까지 이산화탄소 총 감축량의 10~55%를 감당할 수 있는 경제적 잠재력이 있다고 보고되고 있다. 본 고에서는 CCS 기술의 해외 적용 사례 및 관련 핵심 기술 동향에 대해 간략하게 소개하고자 한다.