• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.5
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• pp.204-210
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• 2004

Though the recycling rate of coal fly ash generated from domestic thermoelectric power plants is gradually increased, at present, the most amount of coal bottom ash is disposed by a landfill instead of recycling. Therefore, to reuse a coal bottom ash as high-value materials the synthesis of zeolite made from a coal bottom ash was investigated in this study. NaPl, hydroxy-sodalite and tobermorite were produced through the alkaline hydrothermal reaction of pulvelized bottom ash at various temperatures; 80, 120, $150^{\circ}C$, and the concentration of NaOH at the range from 1 to 5 M. Especially, NaPl with excellent cation exchange capability had a high crystallinity at ${\leq}2$ M NaOH and ${\leq}120^{\circ}C$.

• Clean Technology
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• v.18 no.1
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• pp.111-119
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• 2012

These days many companies are trying to reduce, recycle and reuse their wastes. Even though many wastes can be recycled, those are incinerated or landfilled. To solve these problems, there are many projects to make efforts to recycle wastes in especially the industrial complexes. But, due to the absence of information about waste recycling, recyclable wastes are still incinerated or landfilled. Based on these research background, this study aims to suggest the evaluation methodology of the $CO_2$ emissions and cost reduced by circulating the industrial waste to resource. We evaluated the environmental and economic effect between companies which emit the plastic waste and organic solvent waste and use them as raw-materials in the off-line recycling information exchange network. The environmental and economic aspects were analyzed comparing waste recycling with waste incineration. By recycling the plastic waste as raw-materials, $CO_2$ emission were reduced 1,070 ton in 2009 and 1,234 ton in 2010 and 657.4 million won in 2009 and 755.0 million won in 2010 were reduced. In recycling the organic solvent waste, 7.3 ton-$CO_2$ in 2010 and 5.6 ton-$CO_2$ in 2011 were reduced and 15.9 million won in 2010 and 12.2 million won in 2011 were reduced.

• Journal of Environmental Impact Assessment
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• v.22 no.2
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• pp.135-145
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• 2013

The recycling of coal bottom ash generated from coal power plants in Korea has been limited due to heterogenous characteristics of the materials. The most common management option for the ash is disposal in landfills (i.e. ash pond) near ocean. The presence of large coarse and fine materials in the ash has prompted the desire to beneficially use it in an application such as fill materials. Prior to reuse application as fill materials, the potential risks to the environment must be assessed with regard to the impacts. In this study, a total of nine test cells with bottom ash samples collected from pretreated bottom ash piles and coal ash pond in a coal-fired power plant were constructed and operated under the field conditions to evaluate the leachability over a period of 210 days. Leachate samples from the test cells were analyzed for a number of chemical parameters (e.g., pH, salinity, electrical conductance, anions, and metals). The concentrations of chemicals detected in the leachate were compared to appropriate standards (drinking water standard) with dilution attenuation factor, if possible, to assess potential leaching risks to the surrounding area. Based on the leachate analysis, most of the samples showed slightly high pH values for the coal ash contained test cells, and contained several ions such as sodium, potassium, calcium, magnesium, chloride, sulfate, and nitrate in relatively large quantities. Three elements (aluminum, boron, and barium) were commonly detected above their respective detection limits in a number of leachate samples, especially in the early leaching period of time. The results of the test cell study indicate that the pollutants in the leachate from the coal ash test cells were not of a major concern in terms of leaching risk to surface water and groundwater under field conditions as fill materials. However, care must be taken in extending these results to actual applications because the results presented in this study are based on the limited field test settings and time frame. Structural characteristics and analysis for coal bottom ash may be warranted to apply the materials to actual field conditions.

• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.4
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• pp.64-68
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• 2010

Recently, MBT(Mechanical Biological Treatment) facilities were built up and operated to separate and recycle MSW(Municipal Solid Wastes)in South Korea. However, the size distribution of MSW is very rough, and it is causing operation problem because MSW would be crushed in undersize diameter by mechanical equipment before feeding each seperation process. Also, the organic material should be pre-seperated to reuse recycle material in MSW. In this research, the reactor of 1ton/batch using the super-heated steam was tested to present the separation efficiency and the size distribution of MSW by experimental factors.

• Membrane and Water Treatment
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• v.15 no.4
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• pp.153-162
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• 2024

The current research project focuses on the feasibility of recycling and reusing utilized osmosis membranes from the Beni Saf water seawater desalination station in the province of Ain Temouchent. The composite Reverse Osmosis (RO) membrane, which is referenced BW30-400-FR and manufactured by Dow Filmtec TM, is used for all the tests. Three solvents are tested: potassium permanganate (KMnO₄), sodium hydroxide (NaOH), hydrogen peroxide (H₂O₂), and the mixture of NaOH with KMnO₄ for the degradation of the active layer of the RO membrane. A frontal filtration of wastewater using these modified membranes was carried out. An analysis of the physicochemical properties of the filtrate was performed using a spectrophotometer. The results of the frontal filtration performed under perpendicular pressure using a filtration ramp show that the membranes immersed in the NaOH and KMnO₄ mixture for 24 hours produced a higher hydraulic flux compared to those immersed in NaOH and H₂O₂. At the end of the proposed treatment, the samples are analyzed by scanning electron microscopy (SEM) in addition to analyzing the clogging powder by EDX. The obtained results show the effectiveness of the proposed treatment for the degradation of the active layer in order to transform it into microfiltration and/or ultrafiltration.

• Advances in concrete construction
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• v.13 no.6
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• pp.433-450
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• 2022

The conventional disposal methods of waste tires are harmful to the environment. Moreover, the recycling/reuse of waste tires in domestic and industrial applications is limited due to parent product's quality control and environmental concerns. Additionally, the recycling industry often prefers powdered rubber particles (<0.60 mm). However, the processing of waste tires yields both powdered and coarser (>0.60 mm) size fractions. Reprocessing of coarser rubber requires higher energy increasing the product cost. Therefore, the waste tire rubber (WTR) less favored by the recycling industry is encouraged for use in construction products as one of the environment-friendly disposal methods. In this study, WTR fiber >0.60 mm size fraction is collected from the industry and sorted into 0.60-1.18, 1.18-2.36-, and 2.36-4.75-mm sizes. The effects of different fiber size fractions are studied by incorporating it as fine aggregates at 10%, 20%, and 30% in the self-compacting rubberized concrete (SCRC). The experimental investigations are carried out by performing fresh and hardened state tests. As the fresh state tests, the slump-flow, T500, V-funnel, and L-box are performed. As the hardened state tests, the scanning electron microscope, compressive strength, flexural strength and split tensile strength tests are conducted. Also, the water absorption, porosity, and ultrasonic pulse velocity tests are performed to measure durability. Furthermore, SCRC's energy absorption capacity is evaluated using the falling weight impact test. The statistical significance of content and size fraction of WTR fiber on SCRC is evaluated using the analysis of variance (ANOVA). As the general conclusion, implementation of various size fraction WTR fiber as fine aggregate showed potential for producing concrete for construction applications. Thus, use of WTR fiber in concrete is suggested for safe, and feasible waste tire disposal.

• Resources Recycling
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• v.17 no.3
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• pp.3-9
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• 2008

The measurement of physicochemical properties and chemical composition of SSA(sewage sludge ash) has been carried out and the preparation of lightweight material has also been performed using SSA for reuse as building or construction materials. For this aim, lightweight material has been prepared by forming the mixture of SSA, lightweight filler and inorganic binder followed by calcination at elevated temperature and characterized in terms of density and compressive strength. The pH of fly ash was found to be slightly alkaline, pH 8.69, due to the addition of caustic soda in order to neutralize the acidic gas while the pH of bottom ash was 6.48 Heavy metal leachability based on the standard leach test was also found to be below the detection limit for Cd, Cu, Pb, As and Cr of SSA. As far as the compressive strength of lightweight material was concerned, the compressive strength of lightweight material using fly ash was higher than that of lightweight material using bottom ash.

• Resources Recycling
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• v.26 no.1
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• pp.11-15
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• 2017

The amount of the wood chip ash is expected to increase continuously as demand of wood chip-based heat and electricity increase. Thus, there is increased interest in wood chip ash utilization. In this study, as a program of utilization in wood chip ash, the physical and chemical properties of wood chip ashes generated from a combined heat and power plant were investigated. The chemical analysis showed that the main contents of wood chip ash are composed of silica, alumina and alkali. A possibility of reuse as secondary cementitious materials was investigated by the analysis of strength activity index, and compared with coal ash. The highest value for Strength activity index of wood chip fly ash was 78% at 90 days curing time. This result revealed that wood chip fly ash has the potential to be utilized as the admixture for cementitious material.

• Resources Recycling
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• v.14 no.4 s.66
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• pp.34-40
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• 2005

Reusing of electroless Co-Cu-P waste solution was investigated in the respect of plating time, plating rate, solution composition and deposit. Plating time of cobalt-catalytic surface took longer than that of zincated-catalytic surface. It was possible to reuse the waste solution by mixing $50\%$ fresh solution at batch type. Plating time of initial solution at continuous type took longer 7.5 times over than that of batch type. Plating time of $50\%$ waste solution additive at continuous type took longer 2.5 times over than that of batch type. Component change of cobalt-topper for electroless deposition was greatly affected by deposit inferiority and rapid decrease in plating rate.

• Resources Recycling
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• v.18 no.5
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• pp.44-51
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• 2009

Fundamental study has been made on the recovery of copper from the electronic scrap by hydrometallurgical process. Nitric acid was used as a leaching agent to dissolve the metals such as Cu, Sn, Pb, Fe etc. from the crushed electronic scraps. TBP was employed to extract nitric acid from the strong nitric acid leaching solutions and to reclaim nitric acid. From the experimental results, Cu was effectively leached by 3.0-4.0 M nitric acid. And 95% of nitric acid in the leaching solution was extracted by 60% TBP, and 98% of nitric acid was stripped from the loaded organic phase by distilled water and it was possible to reuse as a leaching agent.