• Title/Summary/Keyword: recycled materials

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Bloating mechanism for coal ash with iron oxide (철분이 많이 함유된 석탄회의 발포거동)

  • Lee, Ki Gang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.2
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    • pp.77-83
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    • 2014
  • The purpose of this study was to figure out the impacts of iron oxide types and dosages to bloating when producing artificial lightweight aggregates by utilization of recycled resources such as bottom-ash, reject-ash and dredgedsoil. In order to figure out chemical characteristics of raw materials, XRD and XRF analyses were performed. 50 wt% of dredged-soil, 15 wt% of bottom-ash and 35wt.% of reject-ash were mixed, then the amount of iron oxide was varied at 5 to 30 wt% with intervals of 5 wt% with $Fe_2O_3$ and $Fe_3O_4$ respectively. As molded aggregates were sintered by rapid sintering in intervals of $40^{\circ}C$ from $1060^{\circ}C$ to $1180^{\circ}C$, specific gravity and water absorption were measured. As a result, the artificial lightweight aggregate with iron oxide of 10~15 vol% showed the lowest specific gravity, and it was identified that the more iron oxide vol% increases, the more specific gravity increases because of liquid phase sintering.

Overview and Recent Development of Recycling Small Waste Electrical and Electronic Equipment (WEEE) (폐소형가전제품 재활용 현황과 전망)

  • Jung, Insang;Park, Jihwan;Hwang, Jongsoo;Choi, Wonhee
    • Resources Recycling
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    • v.24 no.4
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    • pp.38-49
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    • 2015
  • The importance of recycling came to the fore by increasing of waste electrical and electronic equipment(WEEE) generation. Small WEEE recycling in particular represents a big challenge in Korea because it has various items and components. Main materials of small WEEE are typically well known for metals (copper, iron, aluminum, etc.), PCBs and plastics. Not only Korea but also overseas, the laws for small WEEE were in effect in order to recycle effectively, but the technology is not catched up with the regulation which has to recycle an allocated account of WEEE. In addition, recycling technologies and processes for small WEEE are not developed enough to recycling center properly. In that sense, if we develope the recycling process, have not only technology competitiveness but also resource conservation, improving the environment and economic profits. Therefore, through the analysis of economic value of recycled small WEEE, and current technologies both domestically and internationally, we design conceptual recycling process of small WEEE, and consider the way forward.

Equimolar Carbon Dioxide Absorption by Ether Functionalized Imidazolium Ionic Liquids

  • Sharma, Pankaj;Park, Sang-Do;Park, Ki-Tae;Jeong, Soon-Kwan;Nam, Sung-Chan;Baek, Il-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2325-2332
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    • 2012
  • A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.

Recycling of Organic Materials Using Purification by Recrystallization for Solution-Processed OLEDs (재결정화법에 의한 유기물 재활용 및 이를 이용한 습식 OLED 제작)

  • Lee, Jin-Hwan;Hong, Ki-Young;Shin, Dong-Kyun;Lee, Jin-Young;Park, Jong-Woon;Seo, Hwa-Il;Seo, Yu Seok
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.1
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    • pp.65-69
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    • 2016
  • We have investigated the possibility of recycling of an organic material that is wasted during thermal evaporation. To this end, we have collected a wasted organic material (N,N'-diphenly-N,N'-bis(1,1'-biphenyl)-4,4'-diamine(NPB)) from a vacuum chamber, purified it by recrystallization, and fabricated bilayer organic light-emitting diodes (OLEDs) with the recycled NPB. It is found that the surface roughness of thin films coated with the purified NPB is much enhanced. OLEDs fabricated by thermal evaporation of the purified NPB show lower device efficiency than OLEDs with the original NPB. However, the power efficiency of OLED fabricated by spin coating of the purified NPB is comparable with that of OLED with the original NPB. Therefore, such a recycling method by recrystallization would be more suitable for solution-processed OLEDs.

Leaching of Ca, Fe and Si in Electric Arc Furnace Steel Slag by Aqueous Acetic acid Solution for Indirect Carbonation (간접탄산염화를 위한 전기로제강슬래그 중 Ca, Fe 및 Si 성분의 초산수용액 침출)

  • Youn, Ki-Byoung
    • Resources Recycling
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    • v.26 no.1
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    • pp.37-42
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    • 2017
  • It has been reported that aqueous indirect carbonation process of calcium silicate mineral could be one of the most promising methods for $CO_2$ sequestration. The process consists of two main steps, extraction of Ca from calcium silicate and carbonation of the extracted solution by $CO_2$. Many types of acids such as HCl and $HNO_3$ can be used in the extraction step of the process. In the case of using aqueous acetic acid solution as the extraction solvent, acetic acid can be reproduced at the carbonation step of the extracted solution by $CO_2$ and recycled to extraction step for reuse it. Industrial by-products such as iron and steel slags are potential raw materials of the indirect carbonation process due to their high contents of calcium silicate. In this study, in order to examine the extraction efficiency of domestic electric arc furnace steel slag by aqueous acetic acid solution, extraction experiments of the slag were performed by using the aqueous acetic acid solutions of varying extraction conditions ; acetic acid concentrations, extraction temperatures and times.

International Trend in Environmentally Sound Management of Ships Recycling (환경적으로 건전한 선박 재활용에 관한 국제 동향)

  • Yun, Jong-Hwui;Gug, Seung-Gi;Lim, Jae-Dong
    • Proceedings of KOSOMES biannual meeting
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    • 2008.05a
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    • pp.11-17
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    • 2008
  • As of Jan. 2006, numbers of korean registered ocean-going vessels reached 546 which amounted to 13,716,733 G/T. Vessels, generally spooking, finish her life cycle and are dismantled or recycled. However, most of these activities have been done in undeveloped countries instead of in developed countries as the environmental restrictions in developed countries get more strict, accordingly international bodies adopted shipbreaking-related guidelines and prohibit transboundary of obsolete ships, taken as one of wastes. The authors made the Working Guidelines on Shipbreaking to cope with substandard working environment and reduce the environmental damage, and came up with a method to make a inventory of hazardous materials for effective control, finally framed a draft of Environmentally Sound Ship Recycling examining related international conventions such as Basel Convention, IMO Guideline, ILO Guideline and IMO new Convention(draft) on shipbreaking and recycling.

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Baroplastic Properties of Core-double Shell Type Nanoparticles Consisting of Crosslinked PS as a Core and PBA and PS as Shells (가교된 PS 코어와 PBA 및 PS 셸로 이루어진 코어-더블셸형 나노입자의 압력가소성)

  • Park, Ji-Young;Ryu, Sang-Woog
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.80-84
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    • 2014
  • Polymer nanoparticles with cross-linked core and PBA/PS double-shell were synthesized and their baroplastic properties were characterized. PBA/PS, the inner and outer shell with cross-linked core consisting of St and DVB were synthesized by three-stage emulsion polymerization. The obtained materials exhibited pressure-induced mixing of their components and could be processed at $25^{\circ}C$ by compression molding which means there was no effect of the presence of cross-linked core. Interestingly, the Young's modulus of molded objects has found to be affected strongly by the size of double-shell nanoparticles. Furthermore, the molded object of higher PBA content was successfully recycled 5 times at $25^{\circ}C$ and showed 0.55 MPa of modulus and 1.81 MPa of strength at break.

Compacted expansive elastic silt and tyre powder waste

  • Ghadr, Soheil;Mirsalehi, Sajjad;Assadi-Langroudi, Arya
    • Geomechanics and Engineering
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    • v.18 no.5
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    • pp.535-543
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    • 2019
  • Building on/with expansive soils with no treatment brings complications. Compacted expansive soils specifically fall short in satisfying the minimum requirements for transport embankment infrastructures, requiring the adoption of hauled virgin mineral aggregates or a sustainable alternative. Use of hauled aggregates comes at a high carbon and economical cost. On average, every 9m high embankment built with quarried/hauled soils cost $12600MJ.m^{-2}$ Embodied Energy (EE). A prospect of using mixed cutting-arising expansive soils with industrial/domestic wastes can reduce the carbon cost and ease the pressure on landfills. The widespread use of recycled materials has been extensively limited due to concerns over their long-term performance, generally low shear strength and stiffness. In this contribution, hydromechanical properties of a waste tyre sand-sized rubber (a mixture of polybutadiene, polyisoprene, elastomers, and styrene-butadiene) and expansive silt is studied, allowing the short- and long-term behaviour of optimum compacted composites to be better established. The inclusion of tyre shred substantially decreased the swelling potential/pressure and modestly lowered the compression index. Silt-Tyre powder replacement lowered the bulk density, allowing construction of lighter reinforced earth structures. The shear strength and stiffness decreased on addition of tyre powder, yet the contribution of matric suction to the shear strength remained constant for tyre shred contents up to 20%. Reinforced soils adopted a ductile post-peak plastic behaviour with enhanced failure strain, offering the opportunity to build more flexible subgrades as recommended for expansive soils. Residual water content and tyre shred content are directly correlated; tyre-reinforced silt showed a greater capacity of water storage (than natural silts) and hence a sustainable solution to waterlogging and surficial flooding particularly in urban settings. Crushed fine tyre shred mixed with expansive silts/sands at 15 to 20 wt% appear to offer the maximum reduction in swelling-shrinking properties at minimum cracking, strength loss and enhanced compressibility expenses.

Living Hanbok design using denim material and Korean patchwork 'Jogakbo' motif (데님 소재와 조각보 모티프를 활용한 생활한복 디자인)

  • Lee, Sihyun;Lee, Younhee
    • Journal of the Korea Fashion and Costume Design Association
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    • v.21 no.1
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    • pp.149-162
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    • 2019
  • The purpose of this study is to suggest various directions of living hanbok and proposed the living hanbok design that integrated the tradition and the contemporary, as well as the past and present with denim material that represents the youth cultureby while using the motif of Korean Jogakbo. For the research method, the data on living hanbok, denim, and Jogakbo were surveyed to develop and produce a living hanbok design. The development of a living hanbok design emphasized the meaning of longing for an accumulation of good fortune, by using the concept of 'wishing for fortune' including the symbolic images of denim and Jogakbo. The production results of this study are as follows. First, the Jogakbo motif consisted of patterns yearning for harmony, great fortune, longevity, and many children, and the living hanbok design integrated with the denim material symbolized the convergence of the past and present and the harmony of eastern and western cultures. The study could verify that the living hanbok design was recreated in a contemporary sense to be used everyday by expressing contemporary senses in a traditional image. Second, leftover fabric pieces and recycled materials that can be abandoned by the material market were used for denim. This study could also develop the living hanbok design as a sustainable design through upcycling, an important social trend, puting an emphasis on carrying out socio-ethical responsibilities. Third, denim Jogakbo work, which is connected by small pieces of denim material, used to be a difficult and labor intensive handicraft, but it could be proposed as a new high value-added fashion and generate contemporary living hanbok with a new image.

Material Properties of Fast hardening Polymer Mortar by Fine Aggregate Types and Replacement Ratio (잔골재 종류 및 치환율에 의한 속경성 폴리머 모르타르의 재료 특성)

  • Shin, Seung-Bong;Kim, Gyu-Yong;Nam, Jeong-Soo;Shin, Kyoung-Su;Lee, Bo-Kyeong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.145-151
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    • 2019
  • The Physical performance of use materials was evaluated to improve durability of fast-paced repair mortar used at rapid construction sites. The fastening performance and basic performance were evaluated by substituting ferronickel grinding slag residues, rapid settlement, and EVA-based polymer for mortar. As a result, the compressive strength, flexural strength and adhesion strength were increased due to the use of FS Fine Aggregate and RS Fine Aggregate. The chloride ion promotion test of fast-polymer mortar kept the chloride inhibitory performance from 7 days to 28 days when fNS was used less than 50%. Durability degradation due to the use of FS Fine Aggregate and RS Fine Aggregate has not been found, and it is believed that further consideration of economic and long-term durability will be required for use as alternative Aggregate for construction and civil engineering.