• Membrane Journal
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• v.24 no.1
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• pp.63-68
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• 2014

Manufacturing facility for non-alcoholic drink, the parts of the food industry, disposes wastewater which includes high organic concentration and low nitrogen, phosphorus concentration. For this kind of wastewater, the treatment plant consists mainly of aerobic reactor and chemical coagulation process. And sand-filter or activated carbon process is normally installed further. However, aerobic reactor must have long HRT to treat high concentration of organic contaminant included in this wastewater, so the large site area is required. And settling tank which is normally applied for wastewater treatment facility has some problems such as water quality degradation caused by the sludge spill. To solve these problems, we applied MBR system for the wastewater. And the MBR pilot plant was installed nearby the wastewater treatment facility of W food factory and operated during long term to evaluate treatment efficiency. This plant was operated about 3 months and than the result was 97% of organic removal rate on conditions of flow rate $20m^3/day$, HRT 29 hr, recycle 4Q. However, contaminant removal ratio of bio-reactor decreased and TMP of membrane increased rapidly on more conditions.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.437-442
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• 2016

A new route for PBT (Poly butylene terephthalate) production from recycled PET (Poly ethylene terephthalate) has been explored. The route consists of glycolysis of PET (Poly ethylene terephthalate) wastes using 1,4-butandiol into BHBT oligomers and polycondensation of the oligomers into PBT oligomer. This process uses post-consumer or post-industrial recycled PET and converts it into high-end PBT type engineering thermoplastic via a chemical recycling process. Zink acetate was used as a catalyst for both glycolysis and polycondensation. Two types of reactor for the glycolysis, batch and semi-batch reactor, were investigated and their performances were compared. Semi-batch reactor removes ethylene glycol (EG) and THF (tetrahydrofuran) during the reaction. Amounts of EG and THF generated during the glycolysis reaction were measured and used as criteria for the reactor performance. Performance of semi-batch reactor was shown to be better than that of batch reactor. Optimum reaction condition for the semi-batch reactor was BD/PET ratio of 4, and reaction temperature of $220^{\circ}C$, giving high EG yield (max 91%) and low production of THF. In addition, it was confirmed that the molecular weight of PBT oligomer increases in accordance with the progress of the polycondensation reaction.

• Resources Recycling
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• v.13 no.1
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• pp.28-38
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• 2004

The characteristics of cyanide decomposition in aqueous phase by electric oxidization have been explored in an effort to develop a process to recycle waste water. Considering current efficiency and voltage, the free cyanide decomposition experiment by electric oxidization indicated that 5 V of voltage and copper catalytic Cu/CN mole ratio 0.05 was the most appropriate condition, where current efficiency was 26%, and decomposition speed was 5.6 mM/min. High voltage and excess copper addition increased decomposition speed a little bit but not current efficiency. The experiment of free cyanide density change proves that high density cyanide is preferred because speed and current efficiency increase with density. Also, the overall decomposition reaction could be represented by the first order with respcect to cyanide with the rate constant of $1.6∼7.3${\times}$10^{-3}$ $min^{-1}$ The mass transfer coefficient of electric oxidization of cyanide came out as $2.42${\times}$10^{-5}$ $min^{-1}$ Furthermore, the Damkohler number was calculated as 5.7 in case of 7 V and it was found that the mass transfer stage was the rate determining step.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.2
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• pp.79-87
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• 2013

Effects of pig manure with various composting periods(0, 15, 30, 50, 80 days) on feeding rate, biomass, cocoon production of earthworm(Eisenia fetida) population and physicochemical property of vermicast produced from pig manure were investigated. The feeding rate of earthworm was increased with longer composting period of pig manure. But the biomass production of earthworm population was highest upon the pig manure composted for 30 days. Upon the pig manure composted for 80 days, the biomass was severely reduced. Cocoon production was decreased with longer composting period and especially lower on the pig manure composted for 80 days. Values of pH, EC, C/N ratio of vermicasts produced from pig manure composts were lower than those of pig manures. And the organic material contents of vermicasts were uniformly reduced irrespective of composting duration of pig manure, whose values were 35.9-39.8%. From these results, the optimum composting period of pig manure for vermicomposting could be 15-30 days. And the application of vermicomposting upon the composted pig manure could be an efficient way for the treatment of pig feces, which can stabilize and recycle the organic wastes more rapidly than the conventional composting method.

• Journal of the Korean GEO-environmental Society
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• v.15 no.3
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• pp.33-40
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• 2014

In this paper, mechanical and germination characteristics of stabilized dredged soils were investigated to recycle dredged soil in eco-friendly manner such as waterfront construction. Non sintering binder (NSB), which was developed by using interchemical reactions between slag, high-calcium fly ash, alkali activator on the dredged marine clay, was added to dredged soil. Ordinary portland cement was also used for the comparison of two binders. Experimental tests such as flow test and unconfined compressive test were carried out to evaluate characteristics of stabilized dredged soil. Leaching test, pH measure, vegetation germination test were also conducted to consider environmental applicability. The unconfined compressive tests shows that unconfined compressive strength (UCS) also increases with the increase of curing time and mixed ratio. UCS of NSB mixtures were higher than those of OPC mixtures. Germination tests showed that germination and sprouting date are better in NSB mixture than OPC mixture. It can be explained that germination decreased as pH and 7-day strength increased.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.128-135
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• 2011

In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.

• KSBB Journal
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• v.19 no.6 s.89
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• pp.484-488
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• 2004

Fermentation studies were conducted in batch and continuous flow cell-recycle reactors with food by-products as substrates. The genus Propionibacterium acidipropionici ATCC 4965 was utilized in the production of organic acids. Good performance was achieved in the batch fermentation using hydrol as a carbon source and corn steep liquor (CSL) as nitrogen and vitamin sources. Product yields and productivity based on maximum values were 0.80 g total acids/g glucose and 0.26 g total acids/L/h, respectively, when $3\%$, (w/v) of hydrol and $2.5\%$, (w/v) of CSL were utilized. Continuous fermentation with cell-recycling system using the optimum amounts of substrates resulted in dramatic increase in cell concentration (X) and maximum productivity (P). Compared to the batch fermentation, X and P were increased by as much as 21 and 13 times, respectively, at the dilution ratio of $0.2\;hr^{-1}$, indicating that cell recycling fermentation of food by-products provides valuable means for the mass production of organic acids as well as utilizing cell mass as good nutrient resources.

• Applied Chemistry for Engineering
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• v.16 no.2
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• pp.243-249
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• 2005

Esterification of lactic acid with alcohols catalyzed by Amberlyst-type ion exchange resins and sulfuric acid was carried out in a batch reactor with total /or partial recycle of distilled condensates, respectively. The esterification of lactic acid in the total-recycling reactor (n-butanol/lactic acid = 4, $100^{\circ}C$) was promoted by decreasing the residual water and increasing the mole ratio of n-butanol/lactic acid. Also, it was confirmed that methanol with simple structure and tert-butanol with superior substitution reactivity were more effective in increasing the conversion of esterification reaction, compared to ethanol, n-butanol, and iso-butanol. In a partial-recycling reactor (n-butanol/ammonium lactate = 4, $115^{\circ}C$), the conversion of ammonium lactate into butyl lactate with 1.0 wt% Amberyst-type resins was higher in comparison to that with 0.2 mol $H_2SO_4$ (per 1.0 mol ammonium lactate). The esterification was gradually occurred during the initial stage of reaction in the presence of solid catalyst, whereas the initial addition of $H_2SO_4$ did not affect the initial rate of esterification reaction because of ammonium sulfate formation by the neutralizing reaction of ammonium lactate with sulfuric acid.

• Resources Recycling
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• v.25 no.6
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• pp.13-22
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• 2016

This study is aimed at compare and evaluate the environmental impact of End-of-Life Vehicle(ELV) on the eco-friendly technology dismantling and recycling system, using Life Cycle Assessment (LCA) method. In this study, it was analyzed for the environmental impacts of raw materials, disassemble process, recycle parts separation and waste treatment into the process of ELV treatment by greenhouse gas and resource consumption, etc. Through this study, the indoor rail type dismantling technology were recycling rate applied on the alternate system was increased by approximately 8%. As a result, it was 3 to 88% by improving the environmental impact category. In addition, the added benefit of approximately 8 - 62% in pre-market occurred through the recycling rate, improve parts reuse rate of ELV. Through the results of this study, legal compliance, improved reuse and recycling ratio, used parts market reach, enable exports has identified the need for the effort that the dissemination and diffusion of eco-friendly technology.

• Journal of the Korean GEO-environmental Society
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• v.12 no.12
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• pp.71-78
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• 2011

This paper aims to present the evaluation of engineering characteristics and reusing possibility of waste powders produced in dolomite and limestone nonmetal mining by physical and mechanical experiments on compaction, uniaxial compressive strength, permeability, chemical composition, and so on. Granite soil, 2 types of limestone waste powder, and 1 type of dolomite waste powder were used for main materials, and cement and bentonite were used for admixed materials in this experiments. The findings based on the experimental results are the severe difference of chemical composition of the dolomite & limestone waste powder and the crushed rock waste powder, and the outstanding of engineering characteristics of the dolomite waste powder with high content of MgO compared with the limestone waste powder. The engineering properties on compaction, uniaxial compressive strength, and permeability are enhanced with increase of admixed ratio of waste powder on granite soil. From the experimental results, it can be suggested that the dolomite waste powder admixed with in-situ granite soil is useful as geo-materials with considering of distribution costs.